Switching in Metal–Organic Frameworks

Bigdeli, Fahime; Lollar, Christina T.; Morsali, Ali; Zhou, Hong‐Cai

doi:10.1002/anie.201900666

Title: Switching in Metal–Organic Frameworks

Journal Article · 27 May 2019 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201900666 · OSTI ID:1801399

Bigdeli, Fahime ^[1];

^[2]; Morsali, Ali ^[1];

^[3]

Tarbiat Modares Univ., Tehran (Iran). Dept. of Chemistry. Faculty of Sciences
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering

Abstract In recent years, metal–organic frameworks (MOFs) have become an area of intense research interest because of their adjustable pores and nearly limitless structural diversity deriving from the design of different organic linkers and metal structural building units (SBUs). Among the recent great challenges for scientists include switchable MOFs and their corresponding applications. Switchable MOFs are a type of smart material that undergo distinct, reversible, chemical changes in their structure upon exposure to external stimuli, yielding interesting technological applicability. Although the process of switching shares similarities with flexibility, very limited studies have been devoted specifically to switching, while a fairly large amount of research and a number of Reviews have covered flexibility in MOFs. This Review focuses on the properties and general design of switchable MOFs. The switching activity has been delineated based on the cause of the switching: light, spin crossover (SCO), redox, temperature, and wettability.

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Research Organization:: Univ. of California, Berkeley, CA (United States). Center for Gas Separations (CGS) (EFRC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE

Grant/Contract Number:: SC0001015

OSTI ID:: 1801399

Alternate ID(s):: OSTI ID: 1576802

Journal Information:: Angewandte Chemie (International Edition), Vol. 59, Issue 12; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (107)

Azobenzene-Functionalized Metal-Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules Park, Jinhee; Sun, Lin-Bing; Chen, Ying-Pin Angewandte Chemie, Vol. 126, Issue 23 https://doi.org/10.1002/ange.201310211	journal	May 2014
A Mesh-Adjustable Molecular Sieve for General Use in Gas Separation Ma, Shengqian; Sun, Daofeng; Wang, Xi-Sen Angewandte Chemie International Edition, Vol. 46, Issue 14 https://doi.org/10.1002/anie.200604353	journal	March 2007
Guest-Induced Emergent Properties in Metal–Organic Frameworks Allendorf, Mark D.; Foster, Michael E.; Léonard, François The Journal of Physical Chemistry Letters, Vol. 6, Issue 7 https://doi.org/10.1021/jz5026883	journal	March 2015
Computational Design of Functionalized Metal–Organic Framework Nodes for Catalysis Bernales, Varinia; Ortuño, Manuel A.; Truhlar, Donald G. ACS Central Science, Vol. 4, Issue 1 https://doi.org/10.1021/acscentsci.7b00500	journal	December 2017
Flexible metal–organic frameworks Schneemann, A.; Bon, V.; Schwedler, I. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00101J	journal	January 2014
Lichtinduziertes Schalten der Leitfähigkeit von MOFs mit eingelagertem Spiropyran Garg, Shubham; Schwartz, Heidi; Kozlowska, Mariana Angewandte Chemie, Vol. 131, Issue 4 https://doi.org/10.1002/ange.201811458	journal	December 2018
Removal and safe reuse of highly toxic allyl alcohol using a highly selective photo-sensitive metal–organic framework Gong, Le Le; Feng, Xue Feng; Luo, Feng Green Chemistry, Vol. 18, Issue 7 https://doi.org/10.1039/C5GC02182K	journal	January 2016
Controlled Generation of Singlet Oxygen in Living Cells with Tunable Ratios of the Photochromic Switch in Metal-Organic Frameworks Park, Jihye; Jiang, Qin; Feng, Dawei Angewandte Chemie International Edition, Vol. 55, Issue 25 https://doi.org/10.1002/anie.201602417	journal	April 2016
The first porous MOF with photoswitchable linker molecules Modrow, Antje; Zargarani, Dordaneh; Herges, Rainer Dalton Transactions, Vol. 40, Issue 16 https://doi.org/10.1039/c0dt01629b	journal	January 2011
Improving the Fatigue Resistance of Diarylethene Switches Herder, Martin; Schmidt, Bernd M.; Grubert, Lutz Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja513027s	journal	February 2015
Dative and covalent-dative postsynthetic modification of a two-fold interpenetration pillared-layer MOF for heterogeneous catalysis: A comparison of catalytic activities and reusability Saedi, Zahra; Safarifard, Vahid; Morsali, Ali Microporous and Mesoporous Materials, Vol. 229 https://doi.org/10.1016/j.micromeso.2016.04.017	journal	July 2016
Structure and properties of dynamic metal–organic frameworks: a brief accounts of crystalline-to-crystalline and crystalline-to-amorphous transformations Halder, Arijit; Ghoshal, Debajyoti CrystEngComm, Vol. 20, Issue 10 https://doi.org/10.1039/C7CE02066J	journal	January 2018
Mechanically induced luminescence changes in molecular assemblies Sagara, Yoshimitsu; Kato, Takashi Nature Chemistry, Vol. 1, Issue 8 https://doi.org/10.1038/nchem.411	journal	October 2009
Reversible Tuning Hydroquinone/Quinone Reaction in Metal–Organic Framework: Immobilized Molecular Switches in Solid State Gui, Bo; Meng, Xiangshi; Chen, Yi Chemistry of Materials, Vol. 27, Issue 18 https://doi.org/10.1021/acs.chemmater.5b02648	journal	September 2015
Conformational Molecular Rectifiers Troisi, Alessandro; Ratner, Mark A. Nano Letters, Vol. 4, Issue 4 https://doi.org/10.1021/nl0352088	journal	April 2004
Application of Mechanosynthesized Azine-Decorated Zinc(II) Metal–Organic Frameworks for Highly Efficient Removal and Extraction of Some Heavy-Metal Ions from Aqueous Samples: A Comparative Study Tahmasebi, Elham; Masoomi, Mohammad Yaser; Yamini, Yadollah Inorganic Chemistry, Vol. 54, Issue 2 https://doi.org/10.1021/ic5015384	journal	December 2014
Dynamic Photo-Switching in Metal-Organic Frameworks as a Route to Low-Energy Carbon Dioxide Capture and Release Lyndon, Richelle; Konstas, Kristina; Ladewig, Bradley P. Angewandte Chemie, Vol. 125, Issue 13 https://doi.org/10.1002/ange.201206359	journal	February 2013
Light-Induced Spin Crossover and the High-Spin→Low-Spin Relaxation Hauser, Andreas Topics in Current Chemistry https://doi.org/10.1007/b95416	book	July 2004
Metal–organic framework tethering PNIPAM for ON–OFF controlled release in solution Nagata, Shunjiro; Kokado, Kenta; Sada, Kazuki Chemical Communications, Vol. 51, Issue 41 https://doi.org/10.1039/C5CC02339D	journal	January 2015
Spin Crossover Probes Confer Multistability to Organic Conducting Polymers Koo, Yong-Sung; Galán-Mascarós, José Ramón Advanced Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adma.201402579	journal	September 2014
Bistable Dithienylethene-Based Metal–Organic Framework Illustrating Optically Induced Changes in Chemical Separations Furlong, Brandon J.; Katz, Michael J. Journal of the American Chemical Society, Vol. 139, Issue 38 https://doi.org/10.1021/jacs.7b07856	journal	September 2017
Highly sensitive and selective ratiometric fluorescent metal–organic framework sensor to nitroaniline in presence of nitroaromatic compounds and VOCs Bagheri, Minoo; Masoomi, Mohammad Yaser; Morsali, Ali Sensors and Actuators B: Chemical, Vol. 243 https://doi.org/10.1016/j.snb.2016.11.144	journal	May 2017
Mechanized azobenzene-functionalized zirconium metal-organic framework for on-command cargo release Meng, Xiangshi; Gui, Bo; Yuan, Daqiang Science Advances, Vol. 2, Issue 8 https://doi.org/10.1126/sciadv.1600480	journal	August 2016
Luminescent metal–organic frameworks Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802352m	journal	January 2009
Rational design of metal–organic frameworks with anticipated porosities and functionalities Zhang, Muwei; Bosch, Mathieu; Gentle III, Thomas CrystEngComm, Vol. 16, Issue 20 https://doi.org/10.1039/C4CE00321G	journal	January 2014
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO₂ Adsorption Studies Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804 https://doi.org/10.1021/ja408959g	journal	October 2013
Computational Screening of Metal–Organic Frameworks for Membrane-Based CO ₂ /N ₂ /H ₂ O Separations: Best Materials for Flue Gas Separation Daglar, Hilal; Keskin, Seda The Journal of Physical Chemistry C, Vol. 122, Issue 30 https://doi.org/10.1021/acs.jpcc.8b05416	journal	March 2018
A Resistance-Switchable and Ferroelectric Metal–Organic Framework Pan, Liang; Liu, Gang; Li, Hui Journal of the American Chemical Society, Vol. 136, Issue 50 https://doi.org/10.1021/ja508592f	journal	December 2014
Photoswitching CO ₂ Capture and Release in a Photochromic Diarylethene Metal-Organic Framework Luo, Feng; Fan, Cong Bin; Luo, Ming Biao Angewandte Chemie, Vol. 126, Issue 35 https://doi.org/10.1002/ange.201311124	journal	May 2014
A Novel Three-Way Chromophoric Molecular Switch: pH and Light Controllable Switching Cycles Gobbi, Luca; Seiler, Paul; Diederich, François Angewandte Chemie International Edition, Vol. 38, Issue 5 https://doi.org/10.1002/(SICI)1521-3773(19990301)38:5<674::AID-ANIE674>3.0.CO;2-0	journal	March 1999
Influence of the Amide Groups in the CO ₂ /N ₂ Selectivity of a Series of Isoreticular, Interpenetrated Metal–Organic Frameworks Safarifard, Vahid; Rodríguez-Hermida, Sabina; Guillerm, Vincent Crystal Growth & Design, Vol. 16, Issue 10 https://doi.org/10.1021/acs.cgd.6b01054	journal	September 2016
High-Throughput Computational Screening of Multivariate Metal–Organic Frameworks (MTV-MOFs) for CO ₂ Capture Li, Song; Chung, Yongchul G.; Simon, Cory M. The Journal of Physical Chemistry Letters, Vol. 8, Issue 24 https://doi.org/10.1021/acs.jpclett.7b02700	journal	December 2017
Reversible Alteration of CO ₂ Adsorption upon Photochemical or Thermal Treatment in a Metal–Organic Framework Park, Jinhee; Yuan, Daqiang; Pham, Khanh T. Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja209197f	journal	December 2011
Conductance Photoswitching of Metal-Organic Frameworks with Embedded Spiropyran Garg, Shubham; Schwartz, Heidi; Kozlowska, Mariana Angewandte Chemie International Edition, Vol. 58, Issue 4 https://doi.org/10.1002/anie.201811458	journal	December 2018
Photo-induced motion of azo dyes in organized media: from single and liquid crystals, to MOFs and machines Bushuyev, O. S.; Friščić, T.; Barrett, C. J. CrystEngComm, Vol. 18, Issue 38 https://doi.org/10.1039/C6CE01128D	journal	January 2016
Computer-aided discovery of a metal–organic framework with superior oxygen uptake Moghadam, Peyman Z.; Islamoglu, Timur; Goswami, Subhadip Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03892-8	journal	April 2018
A new highly-connected 3D [Co4(μ3-OH)2] cluster-based framework from different dicarboxylates and N-donor co-ligands: Synthesis, structure and magnetic property Mu, Yi-Qiang; Zhu, Ben-Feng; Li, Dong-Sheng Inorganic Chemistry Communications, Vol. 33 https://doi.org/10.1016/j.inoche.2013.04.019	journal	July 2013
Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties Healey, Katherine; Liang, Weibin; Southon, Peter D. Journal of Materials Chemistry A, Vol. 4, Issue 28 https://doi.org/10.1039/C6TA04160D	journal	January 2016
Switchable Conductive MOF–Nanocarbon Composite Coatings as Threshold Sensing Architectures Freund, Pascal; Senkovska, Irena; Kaskel, Stefan ACS Applied Materials & Interfaces, Vol. 9, Issue 50 https://doi.org/10.1021/acsami.7b13924	journal	December 2017
Photoswitching CO ₂ Capture and Release in a Photochromic Diarylethene Metal-Organic Framework Luo, Feng; Fan, Cong Bin; Luo, Ming Biao Angewandte Chemie International Edition, Vol. 53, Issue 35 https://doi.org/10.1002/anie.201311124	journal	May 2014
Reversed thermo-switchable molecular sieving membranes composed of two-dimensional metal-organic nanosheets for gas separation Wang, Xuerui; Chi, Chenglong; Zhang, Kang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14460	journal	February 2017
Visible Light-Driven Artificial Molecular Switch Actuated by Radical–Radical and Donor–Acceptor Interactions Sun, Junling; Wu, Yilei; Liu, Zhichang The Journal of Physical Chemistry A, Vol. 119, Issue 24 https://doi.org/10.1021/acs.jpca.5b04570	journal	May 2015
Redoxschaltbarer, excitonengekoppelter Circulardichroismus: eine neue Strategie für die Entwicklung molekularer Schalter Zahn, Steffen; Canary, James W. Angewandte Chemie, Vol. 110, Issue 3 https://doi.org/10.1002/(SICI)1521-3757(19980202)110:3<321::AID-ANGE321>3.0.CO;2-E	journal	February 1998
Light-induced spin-crossover magnet Ohkoshi, Shin-ichi; Imoto, Kenta; Tsunobuchi, Yoshihide Nature Chemistry, Vol. 3, Issue 7 https://doi.org/10.1038/nchem.1067	journal	June 2011
A Mesh-Adjustable Molecular Sieve for General Use in Gas Separation Ma, Shengqian; Sun, Daofeng; Wang, Xi-Sen Angewandte Chemie, Vol. 119, Issue 14 https://doi.org/10.1002/ange.200604353	journal	March 2007
Guest-to-Host Transmission of Structural Changes for Stimuli-Responsive Adsorption Property Yanai, Nobuhiro; Uemura, Takashi; Inoue, Masafumi Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja2115713	journal	March 2012
Photophysical pore control in an azobenzene-containing metal–organic framework Brown, Jonathan W.; Henderson, Bryana L.; Kiesz, Matthew D. Chemical Science, Vol. 4, Issue 7 https://doi.org/10.1039/c3sc21659d	journal	January 2013
Guest-Triggered Aggregation-Induced Emission in Silver Chalcogenolate Cluster Metal-Organic Frameworks Wu, Xiao-Hui; Luo, Peng; Wei, Zhong Advanced Science, Vol. 6, Issue 2 https://doi.org/10.1002/advs.201801304	journal	November 2018
Photoswitchable Adsorption in Metal-Organic Frameworks Based on Polar Guest-Host Interactions Wang, Zhengbang; Grosjean, Sylvain; Bräse, Stefan ChemPhysChem, Vol. 16, Issue 18 https://doi.org/10.1002/cphc.201500829	journal	October 2015
Spin Crossover in the {Fe(pz)[Pt(CN) ₄ ]} Metal–Organic Framework upon Pyrazine Adsorption Pham, C. Huy; Paesani, Francesco The Journal of Physical Chemistry Letters, Vol. 7, Issue 19 https://doi.org/10.1021/acs.jpclett.6b01788	journal	September 2016
Pressure and Temperature Control of Spin-Switchable Metal-Organic Coordination Polymers from Ab Initio Calculations Tarafder, K.; Kanungo, S.; Oppeneer, P. M. Physical Review Letters, Vol. 109, Issue 7 https://doi.org/10.1103/PhysRevLett.109.077203	journal	August 2012
Defective Metal-Organic Frameworks Dissegna, Stefano; Epp, Konstantin; Heinz, Werner R. Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201704501	journal	January 2018
Gold(III) – metal organic framework bridges the gap between homogeneous and heterogeneous gold catalysts Zhang, X.; Llabrés i. Xamena, F. X.; Corma, A. Journal of Catalysis, Vol. 265, Issue 2 https://doi.org/10.1016/j.jcat.2009.04.021	journal	July 2009
Optically Controlled Molecular Metallofullerene Magnetism via an Azobenzene-Functionalized Metal–Organic Framework Meng, Haibing; Zhao, Chong; Nie, Mingzhe ACS Applied Materials & Interfaces, Vol. 10, Issue 38 https://doi.org/10.1021/acsami.8b11098	journal	September 2018
Electrochemically addressable trisradical rotaxanes organized within a metal–organic framework McGonigal, Paul R.; Deria, Pravas; Hod, Idan Proceedings of the National Academy of Sciences, Vol. 112, Issue 36 https://doi.org/10.1073/pnas.1514485112	journal	August 2015
Switching Thin Films of Azobenzene-Containing Metal-Organic Frameworks with Visible Light Müller, Kai; Knebel, Alexander; Zhao, Fangli Chemistry - A European Journal, Vol. 23, Issue 23 https://doi.org/10.1002/chem.201700989	journal	April 2017
Photochromic Metal-Organic Frameworks: Reversible Control of Singlet Oxygen Generation Park, Jihye; Feng, Dawei; Yuan, Shuai Angewandte Chemie, Vol. 127, Issue 2 https://doi.org/10.1002/ange.201408862	journal	December 2014
Stimuli-Responsive Metal-Organic Framework (MOF) with Chemo-Switchable Properties for Colorimetric Detection of CHCl ₃ Razavi, Sayed Ali Akbar; Masoomi, Mohammad Yaser; Morsali, Ali Chemistry - A European Journal, Vol. 23, Issue 51 https://doi.org/10.1002/chem.201702127	journal	August 2017
PCN-250 under Pressure: Sequential Phase Transformation and the Implications for MOF Densification Yuan, Shuai; Sun, Xing; Pang, Jiandong Joule, Vol. 1, Issue 4 https://doi.org/10.1016/j.joule.2017.09.001	journal	December 2017
Reversible luminescence switch in a photochromic metal–organic framework Sun, Jian-Ke; Cai, Li-Xuan; Chen, Yong-Juan Chemical Communications, Vol. 47, Issue 24 https://doi.org/10.1039/c1cc11550b	journal	January 2011
Spacer directed metallo-supramolecular assemblies of pyridine carboxylates Teo, Peili; Hor, T. S. Andy Coordination Chemistry Reviews, Vol. 255, Issue 1-2 https://doi.org/10.1016/j.ccr.2010.08.014	journal	January 2011
Organic-based molecular switches for molecular electronics Fuentes, Noelia; Martín-Lasanta, Ana; Álvarez de Cienfuegos, Luis Nanoscale, Vol. 3, Issue 10 https://doi.org/10.1039/c1nr10536a	journal	January 2011
Photoswitchable metal organic frameworks: turn on the lights and close the windows Castellanos, S.; Kapteijn, F.; Gascon, J. CrystEngComm, Vol. 18, Issue 22 https://doi.org/10.1039/C5CE02543E	journal	January 2016
Long-lasting phosphorescence with a tunable color in a Mn ²⁺ -doped anionic metal–organic framework Yang, Xiaogang; Yan, Dongpeng Journal of Materials Chemistry C, Vol. 5, Issue 31 https://doi.org/10.1039/C7TC02493B	journal	January 2017
A spin crossover porous hybrid architecture for potential sensing applications Tissot, Antoine; Kesse, Xavier; Giannopoulou, Styliani Chemical Communications, Vol. 55, Issue 2 https://doi.org/10.1039/C8CC07573E	journal	January 2019
Ein neuer dreifacher chromophorer molekularer Schalter: pH- und lichtabhängige Schaltcyclen Gobbi, Luca; Seiler, Paul; Diederich, François Angewandte Chemie, Vol. 111, Issue 5 https://doi.org/10.1002/(SICI)1521-3757(19990301)111:5<737::AID-ANGE737>3.0.CO;2-3	journal	March 1999
Effects of Extending the π-Electron System of Pillaring Linkers on Fluorescence Sensing of Aromatic Compounds in Two Isoreticular Metal–Organic Frameworks Azhdari Tehrani, Alireza; Ghasempour, Hosein; Morsali, Ali Crystal Growth & Design, Vol. 15, Issue 11 https://doi.org/10.1021/acs.cgd.5b01175	journal	October 2015
Tunable molecular separation by nanoporous membranes Wang, Zhengbang; Knebel, Alexander; Grosjean, Sylvain Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13872	journal	December 2016
pH Clock-Operated Mechanized Nanoparticles Angelos, Sarah; Khashab, Niveen M.; Yang, Ying-Wei Journal of the American Chemical Society, Vol. 131, Issue 36 https://doi.org/10.1021/ja9010157	journal	September 2009
Thermodynamic insight into stimuli-responsive behaviour of soft porous crystals Vanduyfhuys, L.; Rogge, S. M. J.; Wieme, J. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-017-02666-y	journal	January 2018
Switchable cobalt coordination polymers: Spin crossover and valence tautomerism Drath, Olga; Boskovic, Colette Coordination Chemistry Reviews, Vol. 375 https://doi.org/10.1016/j.ccr.2017.11.025	journal	November 2018
cis-to-trans isomerization of azobenzene investigated by using thin films of metal–organic frameworks Yu, Xiaojuan; Wang, Zhengbang; Buchholz, Maria Physical Chemistry Chemical Physics, Vol. 17, Issue 35 https://doi.org/10.1039/C5CP03091A	journal	January 2015
Controlled Generation of Singlet Oxygen in Living Cells with Tunable Ratios of the Photochromic Switch in Metal-Organic Frameworks Park, Jihye; Jiang, Qin; Feng, Dawei Angewandte Chemie, Vol. 128, Issue 25 https://doi.org/10.1002/ange.201602417	journal	April 2016
Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks Ni, Zhao-Ping; Liu, Jun-Liang; Hoque, Md. Najbul Coordination Chemistry Reviews, Vol. 335 https://doi.org/10.1016/j.ccr.2016.12.002	journal	March 2017
Remarkable Pressure Responses of Metal–Organic Frameworks: Proton Transfer and Linker Coiling in Zinc Alkyl Gates Ortiz, Aurélie U.; Boutin, Anne; Gagnon, Kevin J. Journal of the American Chemical Society, Vol. 136, Issue 32 https://doi.org/10.1021/ja5060059	journal	July 2014
Switchable molecule-based materials for micro- and nanoscale actuating applications: Achievements and prospects Manrique-Juárez, María D.; Rat, Sylvain; Salmon, Lionel Coordination Chemistry Reviews, Vol. 308 https://doi.org/10.1016/j.ccr.2015.04.005	journal	February 2016
Dynamic Photo-Switching in Metal-Organic Frameworks as a Route to Low-Energy Carbon Dioxide Capture and Release Lyndon, Richelle; Konstas, Kristina; Ladewig, Bradley P. Angewandte Chemie International Edition, Vol. 52, Issue 13 https://doi.org/10.1002/anie.201206359	journal	February 2013
Interior Decoration of Stable Metal–Organic Frameworks Lollar, Christina Tori; Qin, Jun-Sheng; Pang, Jiandong Langmuir, Vol. 34, Issue 46 https://doi.org/10.1021/acs.langmuir.8b00823	journal	May 2018
A Redox-Active Bistable Molecular Switch Mounted inside a Metal–Organic Framework Chen, Qishui; Sun, Junling; Li, Peng Journal of the American Chemical Society, Vol. 138, Issue 43 https://doi.org/10.1021/jacs.6b09880	journal	October 2016
Photoresponsive porous materials: the design and synthesis of photochromic diarylethene-based linkers and a metal–organic framework Patel, Dinesh G. (Dan); Walton, Ian M.; Cox, Jordan M. Chem. Commun., Vol. 50, Issue 20 https://doi.org/10.1039/C3CC49666J	journal	January 2014
Recent progress in the synthesis of metal–organic frameworks Sun, Yujia; Zhou, Hong-Cai Science and Technology of Advanced Materials, Vol. 16, Issue 5 https://doi.org/10.1088/1468-6996/16/5/054202	journal	October 2015
Responsive Metal–Organic Frameworks and Framework Materials: Under Pressure, Taking the Heat, in the Spotlight, with Friends Coudert, François-Xavier Chemistry of Materials, Vol. 27, Issue 6 https://doi.org/10.1021/acs.chemmater.5b00046	journal	February 2015
Selective CO ₂ Capture in Metal–Organic Frameworks with Azine-Functionalized Pores Generated by Mechanosynthesis Masoomi, Mohammad Yaser; Stylianou, Kyriakos C.; Morsali, Ali Crystal Growth & Design, Vol. 14, Issue 5 https://doi.org/10.1021/cg500033b	journal	April 2014
A pressure-amplifying framework material with negative gas adsorption transitions Krause, Simon; Bon, Volodymyr; Senkovska, Irena Nature, Vol. 532, Issue 7599 https://doi.org/10.1038/nature17430	journal	April 2016
A 3D POM–MOF composite based on Ni(ΙΙ) ion and 2,2′-bipyridyl-3,3′-dicarboxylic acid: Crystal structure and proton conductivity Wei, Meilin; Wang, Xiaoxiang; Sun, Jingjing Journal of Solid State Chemistry, Vol. 202 https://doi.org/10.1016/j.jssc.2013.03.041	journal	June 2013
Microwave-assisted crystallization inclusion of spiropyran molecules in indium trimesate films with antidromic reversible photochromism Zhang, Feng; Zou, Xiaoqin; Feng, Wei Journal of Materials Chemistry, Vol. 22, Issue 48 https://doi.org/10.1039/c2jm34618d	journal	January 2012
Redox-Switched Exciton-Coupled Circular Dichroism: A Novel Strategy for Binary Molecular Switching Zahn, Steffen; Canary, James W. Angewandte Chemie International Edition, Vol. 37, Issue 3 https://doi.org/10.1002/(SICI)1521-3773(19980216)37:3<305::AID-ANIE305>3.0.CO;2-T	journal	February 1998
On/off switchable electronic conduction in intercalated metal-organic frameworks Ogihara, Nobuhiro; Ohba, Nobuko; Kishida, Yoshihiro Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1603103	journal	August 2017
Azobenzene Guest Molecules as Light-Switchable CO ₂ Valves in an Ultrathin UiO-67 Membrane Knebel, Alexander; Sundermann, Lion; Mohmeyer, Alexander Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.7b00147	journal	March 2017
Reversible three equal-step spin crossover in an iron( ii ) Hofmann-type metal–organic framework Liu, Fu-Ling; Li, Dong; Su, Li-Jie Dalton Transactions, Vol. 47, Issue 5 https://doi.org/10.1039/C7DT04205A	journal	January 2018
Computational structure determination of novel metal–organic frameworks Wahiduzzaman, Mohammad; Wang, Sujing; Sikora, Benjamin J. Chemical Communications, Vol. 54, Issue 77 https://doi.org/10.1039/C8CC05455J	journal	January 2018
Crystalline-State Reaction with Allosteric Effect in Spin-Crossover, Interpenetrated Networks with Magnetic and Optical Bistability Niel, Virginie; Thompson, Amber L.; Muñoz, M. Carmen Angewandte Chemie International Edition, Vol. 42, Issue 32 https://doi.org/10.1002/anie.200351853	journal	August 2003
Dynamic Interplay between Spin-Crossover and Host−Guest Function in a Nanoporous Metal−Organic Framework Material Southon, Peter D.; Liu, Lang; Fellows, Elizabeth A. Journal of the American Chemical Society, Vol. 131, Issue 31 https://doi.org/10.1021/ja902187d	journal	August 2009
Switching the Proton Conduction in Nanoporous, Crystalline Materials by Light Müller, Kai; Helfferich, Julian; Zhao, Fangli Advanced Materials, Vol. 30, Issue 8 https://doi.org/10.1002/adma.201706551	journal	January 2018
Stimuli-Responsive DNA-Functionalized Metal-Organic Frameworks (MOFs) Kahn, Jason S.; Freage, Lina; Enkin, Natalie Advanced Materials, Vol. 29, Issue 6 https://doi.org/10.1002/adma.201602782	journal	December 2016
Spin crossover with thermal hysteresis: practicalities and lessons learnt Brooker, Sally Chemical Society Reviews, Vol. 44, Issue 10 https://doi.org/10.1039/C4CS00376D	journal	January 2015
Photo-responsive MOFs: light-induced switching of porous single crystals containing a photochromic diarylethene Walton, Ian M.; Cox, Jordan M.; Coppin, Jarrett A. Chemical Communications, Vol. 49, Issue 73 https://doi.org/10.1039/c3cc44119a	journal	January 2013
Grand Challenges and Future Opportunities for Metal–Organic Frameworks Hendon, Christopher H.; Rieth, Adam J.; Korzyński, Maciej D. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00197	journal	June 2017
An Electrically Switchable Metal-Organic Framework Fernandez, Carlos A.; Martin, Paul C.; Schaef, Todd Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06114	journal	August 2014
Rotaxane-Based Molecular Muscles Bruns, Carson J.; Stoddart, J. Fraser Accounts of Chemical Research, Vol. 47, Issue 7 https://doi.org/10.1021/ar500138u	journal	April 2014
Soft porous crystals Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu Nature Chemistry, Vol. 1, Issue 9, p. 695-704 https://doi.org/10.1038/nchem.444	journal	November 2009
An investigation of the catalytic activity in a series of isoreticular Zn(II)-based metal-organic frameworks Bigdeli, Fahime; Abedi, Sedigheh; Hosseini-Monfared, Hassan Inorganic Chemistry Communications, Vol. 72 https://doi.org/10.1016/j.inoche.2016.08.010	journal	October 2016
Crystalline-State Reaction with Allosteric Effect in Spin-Crossover, Interpenetrated Networks with Magnetic and Optical Bistability Niel, Virginie; Thompson, Amber L.; Muñoz, M. Carmen Angewandte Chemie, Vol. 115, Issue 32 https://doi.org/10.1002/ange.200351853	journal	August 2003
Dynamic Photo-Switching in Metal-Organic Frameworks as a Route to Low-Energy Carbon Dioxide Capture and Release Lyndon, Richelle; Konstas, Kristina; Ladewig, Bradley P. Angewandte Chemie https://doi.org/10.1002/ange.201301126	journal	February 2013
Azobenzene-Functionalized Metal-Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules Park, Jinhee; Sun, Lin-Bing; Chen, Ying-Pin Angewandte Chemie International Edition, Vol. 53, Issue 23 https://doi.org/10.1002/anie.201310211	journal	May 2014
Computer-aided discovery of a metal-organic framework with superior oxygen uptake. Moghadam, Peyman Z.; Islamoglu, Timur; Goswami, Subhadip Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.30869	text	January 2018
Tunable molecular separation by nanoporous membranes Wang, Zhengbang; Knebel, Alexander; Grosjean, Sylvain Nature Research https://doi.org/10.5445/ir/1000065426	text	January 2016

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Reversible thermo-induced spin crossover in a mononuclear cis -dicyanamido-cobalt( ii ) complex containing a macrocyclic tetradentate ligand Ghosh, Subrata; Selvamani, Subramani; Mehta, Sakshi Dalton Transactions, Vol. 49, Issue 27 https://doi.org/10.1039/d0dt01888k	journal	January 2020

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