A facile method to introduce iron secondary metal centers into metal–organic frameworks

Deming, Derek A.; Hurlock, Matthew J.; Li, Xiaoyu; Kriegsman, Kyle W.; Ding, Guodong; Guo, Xiaofeng; Zhang, Qiang

doi:10.1016/j.jorganchem.2019.06.037

Title: A facile method to introduce iron secondary metal centers into metal–organic frameworks

Journal Article · 01 July 2019 · Journal of Organometallic Chemistry

DOI: https://doi.org/10.1016/j.jorganchem.2019.06.037 · OSTI ID:1801261

Deming, Derek A. ^[1]; Hurlock, Matthew J. ^[1]; Li, Xiaoyu ^[1]; Kriegsman, Kyle W. ^[1]; Ding, Guodong ^[1]; Guo, Xiaofeng ^[1]; Zhang, Qiang ^[1]

Washington State Univ., Pullman, WA (United States)

In this report, we report the successful incorporation of iron (0) species into a 2, 2'-bipyridine functionalized metal–organic framework (MOF) (UiO-67-bpydc). Considering the limited window size of the MOF, a small molecule, iron pentacarbonyl, was used to introduce iron (0) to coordinate to the backbone of the MOF. The newly generated material contains the iron coordinated linker, Fe(CO)₃(bpydc), which was supported by a series of characterization techniques. DFT calculation was also used to help understand the structure of the formed complex inside the MOF. The MOF structure remained unchanged after the post-synthetic modification, and the resulted material is a great precursor to generate MOF supported catalyst.

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Research Organization:: Washington State Univ., Pullman, WA (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE); USDOE

Grant/Contract Number:: NE0008582

OSTI ID:: 1801261

Alternate ID(s):: OSTI ID: 1691656

Journal Information:: Journal of Organometallic Chemistry, Vol. 897, Issue C; ISSN 0022-328X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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