DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Spatial BCS-BEC crossover in superconducting $$\textit{p–n}$$ junctions

Abstract

Here, we present a theory of superconducting $$\textit{p–n}$$ junctions. To this end, we consider a two band model of doped bulk semiconductors with attractive interactions between the charge carriers and derive the superconducting order parameter, the quasiparticle density of states, and the chemical potential as a function of the semiconductor gap $$Δ_0$$ and the doping level ε. We verify previous results for the quantum phase diagram for a system with constant density of states in the conduction and valence band, which show BCS-superconductor to Bose-Einstein-condensation (BEC) and BEC-to-insulator transitions as a function of doping level and the size of the band gap. Then, we extend this formalism to a density of states which is more realistic for 3D systems and derive the corresponding quantum phase diagram, where we find that a BEC phase can only exist for small band gaps $$Δ_0 < Δ ^{\ast}_0$$. For larger band gaps, we find rather a direct transition from an insulator to a BCS phase. Next, we apply this theory to study the properties of superconducting $$\textit{p–n}$$ junctions. We derive the spatial variation of the superconducting order parameter along the $$\textit{p–n}$$ junction. As the potential difference across the junction leads to energy band bending, we find a spatial crossover between a BCS and BEC condensate, as the density of charge carriers changes across the $$\textit{p–n}$$ junction. For the two-dimensional system, we find two possible regimes, when the bulk is in a BCS phase, a BCS-BEC-BCS junction with a single BEC layer in the space charge region, and a BCS-BEC-I-BEC-BCS junction with two layers of BEC condensates separated by an insulating layer. In three dimensions we find that there can also be a conventional BCS-I-BCS junction for semiconductors with band gaps exceeding $$Δ^{\ast}_0$$. Thus, we find that there can be BEC layers in the well controlled setting of doped semiconductors, where the doping level can be varied to change and control the thickness of BEC and insulator layers, making Bose-Einstein condensates thereby possibly accessible to experimental transport and optical studies in solid-state materials.

Authors:
ORCiD logo [1];  [2];  [3]; ORCiD logo [4]
  1. Jacobs University, Bremen (Germany)
  2. Univ. of California, Los Angeles, CA (United States)
  3. Univ. of California, Los Angeles, CA (United States); Jacobs University, Bremen (Germany)
  4. Jacobs University, Bremen (Germany); Pohang Univ. of Science and Technology (POSTECH) (Korea)
Publication Date:
Research Org.:
Univ. of Southern California, Los Angeles, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC); German Research Foundation (DFG)
OSTI Identifier:
1800982
Alternate Identifier(s):
OSTI ID: 1605965
Grant/Contract Number:  
FG03-01ER45908
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 101; Journal Issue: 9; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Materials Science; Physics

Citation Formats

Niroula, A., Rai, G., Haas, S., and Kettemann, S. Spatial BCS-BEC crossover in superconducting $\textit{p–n}$ junctions. United States: N. p., 2020. Web. doi:10.1103/physrevb.101.094514.
Niroula, A., Rai, G., Haas, S., & Kettemann, S. Spatial BCS-BEC crossover in superconducting $\textit{p–n}$ junctions. United States. https://doi.org/10.1103/physrevb.101.094514
Niroula, A., Rai, G., Haas, S., and Kettemann, S. Mon . "Spatial BCS-BEC crossover in superconducting $\textit{p–n}$ junctions". United States. https://doi.org/10.1103/physrevb.101.094514. https://www.osti.gov/servlets/purl/1800982.
@article{osti_1800982,
title = {Spatial BCS-BEC crossover in superconducting $\textit{p–n}$ junctions},
author = {Niroula, A. and Rai, G. and Haas, S. and Kettemann, S.},
abstractNote = {Here, we present a theory of superconducting $\textit{p–n}$ junctions. To this end, we consider a two band model of doped bulk semiconductors with attractive interactions between the charge carriers and derive the superconducting order parameter, the quasiparticle density of states, and the chemical potential as a function of the semiconductor gap $Δ_0$ and the doping level ε. We verify previous results for the quantum phase diagram for a system with constant density of states in the conduction and valence band, which show BCS-superconductor to Bose-Einstein-condensation (BEC) and BEC-to-insulator transitions as a function of doping level and the size of the band gap. Then, we extend this formalism to a density of states which is more realistic for 3D systems and derive the corresponding quantum phase diagram, where we find that a BEC phase can only exist for small band gaps $Δ_0 < Δ ^{\ast}_0$. For larger band gaps, we find rather a direct transition from an insulator to a BCS phase. Next, we apply this theory to study the properties of superconducting $\textit{p–n}$ junctions. We derive the spatial variation of the superconducting order parameter along the $\textit{p–n}$ junction. As the potential difference across the junction leads to energy band bending, we find a spatial crossover between a BCS and BEC condensate, as the density of charge carriers changes across the $\textit{p–n}$ junction. For the two-dimensional system, we find two possible regimes, when the bulk is in a BCS phase, a BCS-BEC-BCS junction with a single BEC layer in the space charge region, and a BCS-BEC-I-BEC-BCS junction with two layers of BEC condensates separated by an insulating layer. In three dimensions we find that there can also be a conventional BCS-I-BCS junction for semiconductors with band gaps exceeding $Δ^{\ast}_0$. Thus, we find that there can be BEC layers in the well controlled setting of doped semiconductors, where the doping level can be varied to change and control the thickness of BEC and insulator layers, making Bose-Einstein condensates thereby possibly accessible to experimental transport and optical studies in solid-state materials.},
doi = {10.1103/physrevb.101.094514},
journal = {Physical Review B},
number = 9,
volume = 101,
place = {United States},
year = {Mon Mar 23 00:00:00 EDT 2020},
month = {Mon Mar 23 00:00:00 EDT 2020}
}

Works referenced in this record:

Observation of Josephson effect in YBa 2 Cu 3 O 7− x /Nd 1.85 Ce 0.15 CuO 4− y bilayer junctions
journal, November 1995

  • Takeuchi, I.; Mao, S. N.; Xi, X. X.
  • Applied Physics Letters, Vol. 67, Issue 19
  • DOI: 10.1063/1.114813

From semiconductors to superconductors: a simple model for pseudogaps
journal, August 1999

  • Nozières, P.; Pistolesi, F.
  • The European Physical Journal B, Vol. 10, Issue 4
  • DOI: 10.1007/s100510050897

Self-consistent solution for proximity effect and Josephson current in ballistic graphene SNS Josephson junctions
journal, July 2008


Microscopic Theory of Superconductivity
journal, April 1957


Unconventional superconductivity in magic-angle graphene superlattices
journal, March 2018


Josephson effect between electron-doped and hole-doped iron pnictide single crystals
journal, August 2009

  • Zhang, Xiaohang; Saha, Shanta R.; Butch, Nicholas P.
  • Applied Physics Letters, Vol. 95, Issue 6
  • DOI: 10.1063/1.3205123

Superconductor-Insulator Transition and Fermi-Bose Crossovers
journal, May 2016


Tuning across the BCS-BEC crossover in the multiband superconductor Fe 1+ y Se x Te 1− x : An angle-resolved photoemission study
journal, April 2017


The Existence of a Superconducting State in Semiconductors
journal, January 1964


Spatial inhomogeneities in disordered d -wave superconductors
journal, December 2000


Fermi Surface of the Most Dilute Superconductor
journal, April 2013


On-chip superconductivity via gallium overdoping of silicon
journal, November 2010

  • Skrotzki, R.; Fiedler, J.; Herrmannsdörfer, T.
  • Applied Physics Letters, Vol. 97, Issue 19
  • DOI: 10.1063/1.3509411

Theory of Superconductivity
journal, December 1957


Boundary Effects in Superconductors
journal, January 1964


Localization of preformed Cooper pairs in disordered superconductors
journal, January 2011

  • Sacépé, Benjamin; Dubouchet, Thomas; Chapelier, Claude
  • Nature Physics, Vol. 7, Issue 3
  • DOI: 10.1038/nphys1892

Proximity effect in a superconductor-quasicrystal hybrid ring
journal, October 2019


Suppression of superconductivity in homogeneously disordered systems
journal, March 1994


The electronic nature of high temperature cuprate superconductors
journal, September 2003


Evolution from BCS superconductivity to Bose condensation: Role of the parameter k F ξ
journal, March 1994


Properties of superconducting p-n junctions
journal, November 1993


Ordering, metastability and phase transitions in two-dimensional systems
journal, April 1973

  • Kosterlitz, J M; Thouless, D J
  • Journal of Physics C: Solid State Physics, Vol. 6, Issue 7, p. 1181-1203
  • DOI: 10.1088/0022-3719/6/7/010

Solution of the Bogoliubov–de Gennes equations at zero temperature throughout the BCS–BEC crossover: Josephson and related effects
journal, March 2010


Bound Electron Pairs in a Degenerate Fermi Gas
journal, November 1956


Evolution from BCS superconductivity to Bose condensation: analytic results for the crossover in three dimensions
journal, February 1998

  • Marini, M.; Pistolesi, F.; Strinati, G. C.
  • The European Physical Journal B, Vol. 1, Issue 2
  • DOI: 10.1007/s100510050165

Superconductivity in diamond
journal, April 2004

  • Ekimov, E. A.; Sidorov, V. A.; Bauer, E. D.
  • Nature, Vol. 428, Issue 6982
  • DOI: 10.1038/nature02449

Role of Spatial Amplitude Fluctuations in Highly Disordered s -Wave Superconductors
journal, November 1998


Enhancement of the Critical Temperature of Superconductors by Anderson Localization
journal, January 2012


Surface Superconductivity and the Metal-Oxide-Semiconductor System
journal, October 1980


Observation of Resonance Condensation of Fermionic Atom Pairs
journal, January 2004


Study of high temperature superconducting p–n junction
journal, September 2007

  • Wu, Chunte; Wang, Ming-Jye; Wu, Maw-Kuen
  • Physica C: Superconductivity and its Applications, Vol. 460-462
  • DOI: 10.1016/j.physc.2007.03.390

Eigenfunction Fractality and Pseudogap State near the Superconductor-Insulator Transition
journal, January 2007


Single- and two-particle energy gaps across the disorder-driven superconductor–insulator transition
journal, July 2011

  • Bouadim, Karim; Loh, Yen Lee; Randeria, Mohit
  • Nature Physics, Vol. 7, Issue 11
  • DOI: 10.1038/nphys2037

Condensation of Pairs of Fermionic Atoms near a Feshbach Resonance
journal, March 2004


Role of the Dopant in the Superconductivity of Diamond
journal, November 2004


Gate-controlled low carrier density superconductors: Toward the two-dimensional BCS-BEC crossover
journal, August 2018


Dependence of the Superconducting Transition Temperature on the Doping Level in Single-Crystalline Diamond Films
journal, December 2004


Superconductivity in doped cubic silicon
journal, November 2006

  • Bustarret, E.; Marcenat, C.; Achatz, P.
  • Nature, Vol. 444, Issue 7118
  • DOI: 10.1038/nature05340

Inhomogeneous pairing in highly disordered s -wave superconductors
journal, November 2001