Structural drivers controlling sulfur solubility in alkali aluminoborosilicate glasses

Xu, Xinyi; Youngman, Randall E.; Kapoor, Saurabh; Goel, Ashutosh

doi:10.1111/jace.17778

Title: Structural drivers controlling sulfur solubility in alkali aluminoborosilicate glasses

Journal Article · 30 March 2021 · Journal of the American Ceramic Society

DOI: https://doi.org/10.1111/jace.17778 · OSTI ID:1787156

^[1];

^[2]; Kapoor, Saurabh ^[3];

^[1]

Department of Materials Science and Engineering Rutgers, The State University of New Jersey Piscataway NJ USA
Science and Technology Division Corning Incorporated Corning NY USA
Centre of Excellence Sterlite Technologies Ltd, MIDC Waluj Aurangabad India

Abstract If the direct feed approach to vitrify the Hanford's tank waste is implemented, the low activity waste (LAW) will comprise higher concentrations of alkali/alkaline‐earth sulfates than expected under the previously proposed vitrification scheme. To ensure a minimal impact of higher sulfate concentrations on the downstream operations and overall cost of vitrification, advanced glass formulations with enhanced sulfate loadings (solubility) are needed. While, the current sulfate solubility predictive models have been successful in designing LAW glasses with sulfate loadings <2 wt.%, it will be difficult for them to design glass compositions with enhanced loadings due to our limited understanding of the fundamental science governing these processes. In this pursuit, this article unearths the underlying compositional and structural drivers controlling the sulfate solubility in model LAW glasses. It has been shown that the preferentially removes non‐framework cations from the modifier sites in the silicate network, thus, leading to the polymerization in the glass network via the formation of ring‐structured borosilicate units. Furthermore, though the sulfate solubility slightly decreases with increasing Li ⁺ /Na ⁺ in the glasses, the prefers to be charge compensated by Na ⁺ , as it is easier for to break Na–O bonds instead of Li–O bonds.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: 89304018CEM000006

OSTI ID:: 1787156

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 10 Vol. 104; ISSN 0002-7820

Publisher:: Wiley-BlackwellCopyright Statement

Country of Publication:: United States

Language:: English

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