Title: Low Melting Temperature of Anhydrous Mantle Materials at the Core‐Mantle Boundary

Journal Article · · Geophysical Research Letters

Abstract One of the central challenges in accurately estimating the mantle melting temperature is the sensitivity of the probe for detecting a small amount of melt at the solidus. To address this, we used a multichannel collimator to enhance the diffuse X‐ray scattering from a small amount of melt and probed an eutectic pyrolitic composition to increase the amount of melt at the solidus. Our in situ detection of diffuse scattering from the pyrolitic melt determined an anhydrous melting temperature of 3,302 ± 100 K at 119 ± 6 GPa and 3,430 ± 130 K at the core‐mantle boundary (CMB) conditions, as the upper bound temperature. Our CMB temperature is approximately 700 K lower than the previous estimates, implying much faster secular cooling and higher concentrations of S, C, O, and/or H in the region, and nonlinear, advocating the basal magma ocean hypothesis.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-06CH11357; FG02-94ER14466
OSTI ID:
1786751
Journal Information:
Geophysical Research Letters, Journal Name: Geophysical Research Letters Journal Issue: 20 Vol. 47; ISSN 0094-8276
Publisher:
American Geophysical Union (AGU)Copyright Statement
Country of Publication:
United States
Language:
English

References (59)

Melting experiments on peridotite to lowermost mantle conditions: PERIDOTITE MELTING TO CMB PRESSURE journal June 2014
Lowermost mantle anisotropy and deformation along the boundary of the African LLSVP journal May 2014
The postspinel boundary in pyrolitic compositions determined in the laser-heated diamond anvil cell journal June 2014
Thermodynamics of the MgO‐FeO‐SiO 2 system up to 140 GPa: Application to the crystallization of Earth's magma ocean journal September 2015
Ultralow Velocity Zone Locations: A Global Assessment journal February 2018
The composition of the Earth journal March 1995
Thermodynamics of silicate liquids in the deep Earth journal February 2009
Solidus and liquidus profiles of chondritic mantle: Implication for melting of the Earth across its history journal April 2011
Thermodynamics of the MgO–SiO2 liquid system in Earth's lowermost mantle from first principles journal January 2013
Phase relations in the Fe–FeSi system at high pressures and temperatures journal July 2013
The P-wave boundary of the Large-Low Shear Velocity Province beneath the Pacific journal October 2014
First-principles calculations of the lattice thermal conductivity of the lower mantle journal October 2015
Experimental constraints on melting temperatures in the MgO–SiO2 system at lower mantle pressures journal August 2017
Fe–FeO and Fe–Fe3C melting relations at Earth's core–mantle boundary conditions: Implications for a volatile-rich or oxygen-rich core journal September 2017
Melting behavior of the lower-mantle ferropericlase across the spin crossover: Implication for the ultra-low velocity zones at the lowermost mantle journal December 2018
Melting curve of iron to 290 GPa determined in a resistance-heated diamond-anvil cell journal March 2019
Melting experiments on the Fe–C binary system up to 255 GPa: Constraints on the carbon content in the Earth's core journal June 2019
Thermal conductivity near the bottom of the Earth's lower mantle: Measurements of pyrolite up to 120 GPa and 2500 K journal April 2020
Thermal evolution of the core with a high thermal conductivity journal October 2015
Toward a coherent model for the melting behavior of the deep Earth’s mantle journal April 2017
High-pressure experiments and the phase diagram of lower mantle and core materials journal May 2000
Vitreous forsterite (Mg 2 SiO 4 ): Synthesis, structure, and thermochemistry journal July 2001
Melting relations of hydrous pyrolite in CaO-MgO-Al 2 O 3 -SiO 2 -H 2 O System at the transition zone pressures journal April 2001
The MgSiO 3 system at high pressure: Thermodynamic properties of perovskite, postperovskite, and melt from global inversion of shock and static compression data : MgSiO journal January 2009
Experimental Determination of Eutectic Liquid Compositions in the MgO-SiO 2 System to the Lowermost Mantle Pressures journal September 2018
Implications for the Melting Phase Relations in the MgO ‐ FeO System at Core‐Mantle Boundary Conditions journal February 2019
The core–mantle boundary layer and deep Earth dynamics journal April 1998
Seismological constraints on a possible plume root at the core–mantle boundary journal June 2005
A crystallizing dense magma ocean at the base of the Earth’s mantle journal December 2007
Spin crossover and iron-rich silicate melt in the Earth’s deep mantle journal April 2011
Solid–liquid iron partitioning in Earth’s deep mantle journal July 2012
Powering Earth’s dynamo with magnesium precipitation from the core journal January 2016
Experimental determination of the electrical resistivity of iron at Earth’s core conditions journal June 2016
Direct measurement of thermal conductivity in solid iron at planetary core conditions journal June 2016
An early geodynamo driven by exsolution of mantle components from Earth’s core journal July 2016
Crystallization of silicon dioxide and compositional evolution of the Earth’s core journal February 2017
Core–mantle boundary heat flow journal January 2008
Continent-sized anomalous zones with low seismic velocity at the base of Earth's mantle journal June 2016
Viscosity jump in the lower mantle inferred from melting curves of ferropericlase journal December 2017
Deep and persistent melt layer in the Archaean mantle journal January 2018
Multichannel collimator for structural investigation of liquids and amorphous materials at high pressures and temperatures journal October 2002
Use of a multichannel collimator for structural investigation of low-Z dense liquids in a diamond anvil cell: Validation on fluid H 2 up to 5 GPa journal June 2013
Lattice thermal conductivity of lower mantle minerals and heat flux from Earth's core journal October 2011
Spin and valence dependence of iron partitioning in Earth’s deep mantle journal September 2016
Beyond sixfold coordinated Si in SiO 2 glass at ultrahigh pressures journal September 2017
Advanced flat top laser heating system for high pressure research at GSECARS: application to the melting behavior of germanium journal September 2008
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration journal May 2015
The equation of state of B2-type NaCl journal March 2010
Quantitative structure factor and density measurements of high-pressure fluids in diamond anvil cells by x-ray diffraction: Argon and water journal April 2002
Thermodynamic parameters in the Earth as determined from seismic profiles journal September 1981
Constraints on seismic velocities in the Earth from traveltimes journal July 1995
Melting of Peridotite to 140 Gigapascals journal September 2010
Melting of Iron at Earth's Inner Core Boundary Based on Fast X-ray Diffraction journal April 2013
The New Core Paradox journal October 2013
Low Core-Mantle Boundary Temperature Inferred from the Solidus of Pyrolite journal January 2014
Seismic Evidence for Partial Melt at the Base of Earth's Mantle journal September 1996
Ultra-Low Velocity Zones Near the Core-Mantle Boundary from Broadband PKP Precursors journal March 1998
Seismic evidence for partial melting at the root of major hot spot plumes journal July 2017
How Did Early Earth Become Our Modern World? journal May 2014

Similar Records

Water‐Induced Diamond Formation at Earth's Core‐Mantle Boundary
Journal Article · 2022 · Geophysical Research Letters · OSTI ID:1882242

Thermoelastic Properties of Iron-Rich Ringwoodite and the Deep Mantle Aerotherm of Mars
Journal Article · 2025 · Geophysical Research Letters · OSTI ID:2514542

High-pressure elastic properties of dolomite melt supporting carbonate-induced melting in deep upper mantle
Journal Article · 2020 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1660986

Related Subjects