Closing the Nanographene Gap: Surface‐Assisted Synthesis of Peripentacene from 6,6′‐Bipentacene Precursors (in German)
Abstract
Abstract The thermally induced cyclodehydrogenation reaction of 6,6′‐bipentacene precursors on Au(111) yields peripentacene stabilized by surface interactions with the underlying metallic substrate. STM and atomic‐resolution non‐contact AFM imaging reveal rectangular flakes of nanographene featuring parallel pairs of zig‐zag and armchair edges resulting from the lateral fusion of two pentacene subunits. The synthesis of a novel molecular precursor 6,6′‐bipentacene, itself a synthetic target of interest for optical and electronic applications, is also reported. The scalable synthetic strategy promises to afford access to a structurally diverse class of extended periacenes and related polycyclic aromatic hydrocarbons as advanced materials for electronic, spintronic, optical, and magnetic devices.
- Authors:
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1786170
- Grant/Contract Number:
- SC0010409; AC02-05CH11231
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 127 Journal Issue: 50; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- German
Citation Formats
Rogers, Cameron, Chen, Chen, Pedramrazi, Zahra, Omrani, Arash A., Tsai, Hsin‐Zon, Jung, Han Sae, Lin, Song, Crommie, Michael F., and Fischer, Felix R. Closing the Nanographene Gap: Surface‐Assisted Synthesis of Peripentacene from 6,6′‐Bipentacene Precursors. Germany: N. p., 2015.
Web. doi:10.1002/ange.201507104.
Rogers, Cameron, Chen, Chen, Pedramrazi, Zahra, Omrani, Arash A., Tsai, Hsin‐Zon, Jung, Han Sae, Lin, Song, Crommie, Michael F., & Fischer, Felix R. Closing the Nanographene Gap: Surface‐Assisted Synthesis of Peripentacene from 6,6′‐Bipentacene Precursors. Germany. https://doi.org/10.1002/ange.201507104
Rogers, Cameron, Chen, Chen, Pedramrazi, Zahra, Omrani, Arash A., Tsai, Hsin‐Zon, Jung, Han Sae, Lin, Song, Crommie, Michael F., and Fischer, Felix R. Tue .
"Closing the Nanographene Gap: Surface‐Assisted Synthesis of Peripentacene from 6,6′‐Bipentacene Precursors". Germany. https://doi.org/10.1002/ange.201507104.
@article{osti_1786170,
title = {Closing the Nanographene Gap: Surface‐Assisted Synthesis of Peripentacene from 6,6′‐Bipentacene Precursors},
author = {Rogers, Cameron and Chen, Chen and Pedramrazi, Zahra and Omrani, Arash A. and Tsai, Hsin‐Zon and Jung, Han Sae and Lin, Song and Crommie, Michael F. and Fischer, Felix R.},
abstractNote = {Abstract The thermally induced cyclodehydrogenation reaction of 6,6′‐bipentacene precursors on Au(111) yields peripentacene stabilized by surface interactions with the underlying metallic substrate. STM and atomic‐resolution non‐contact AFM imaging reveal rectangular flakes of nanographene featuring parallel pairs of zig‐zag and armchair edges resulting from the lateral fusion of two pentacene subunits. The synthesis of a novel molecular precursor 6,6′‐bipentacene, itself a synthetic target of interest for optical and electronic applications, is also reported. The scalable synthetic strategy promises to afford access to a structurally diverse class of extended periacenes and related polycyclic aromatic hydrocarbons as advanced materials for electronic, spintronic, optical, and magnetic devices.},
doi = {10.1002/ange.201507104},
journal = {Angewandte Chemie},
number = 50,
volume = 127,
place = {Germany},
year = {Tue Oct 20 00:00:00 EDT 2015},
month = {Tue Oct 20 00:00:00 EDT 2015}
}
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