Aluminum hydroxide-mediated synthesis of mesoporous metal oxides by a mechanochemical nanocasting strategy
Abstract
Mesoporous metal oxides (MOs) have attracted significant interest in heterogeneous catalysis due to their wide pore size distribution and high pore volume. In this work, we present a facile mechanochemical nanocasting strategy using aluminum hydroxide as the mesoporous structure-directing agent, which overcomes the drawbacks associated with wet template-assisted methods. In this procedure, by simply grinding a mixture of commercial aluminum hydroxide and MO precursors, a series of mesoporous MOs with high specific surface areas and narrow pore size distributions have been constructed in a short time (e.g., Fe2O3, 280 m2 g–1; Co3O4, 155 m2 g–1; CeO2, 192 m2 g–1; ZrO2, 170 m2 g–1; CuOx–CeOy, 177 m2 g–1; FeOx–CeOy, 170 m2 g–1; CoOx–CuOy–CeOz, 154 m2 g–1; CoOx–FeOy–CeOz, 133 m2 g–1). It is expected that this strategy may open up new opportunities for fabricating a number of advanced porous materials with abundant porosity in the near future.
- Authors:
-
[3];
[4];
[5];
[5];
[4]
- China Univ. of Petroleum, Beijing (China); Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Hebei Univ. of Engineering, Tianjing (China)
- Shanghai Jiao Tong Univ. (China)
- Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- China Univ. of Petroleum, Beijing (China)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; National Natural Science Foundation of China (NSFC); Open Foundation of the State Key Laboratory of Ocean Engineering; USDOE
- OSTI Identifier:
- 1785489
- Alternate Identifier(s):
- OSTI ID: 1569770
- Grant/Contract Number:
- 21776174; U1662103; 21673290; 1809
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 40; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Liu, Jixing, Cheng, Huifang, Bao, Jiafeng, Zhang, Pengfei, Liu, Miaomiao, Leng, Yan, Zhang, Zihao, Tao, Runming, Liu, Jian, Zhao, Zhen, and Dai, Sheng. Aluminum hydroxide-mediated synthesis of mesoporous metal oxides by a mechanochemical nanocasting strategy. United States: N. p., 2019.
Web. doi:10.1039/c9ta06727b.
Liu, Jixing, Cheng, Huifang, Bao, Jiafeng, Zhang, Pengfei, Liu, Miaomiao, Leng, Yan, Zhang, Zihao, Tao, Runming, Liu, Jian, Zhao, Zhen, & Dai, Sheng. Aluminum hydroxide-mediated synthesis of mesoporous metal oxides by a mechanochemical nanocasting strategy. United States. https://doi.org/10.1039/c9ta06727b
Liu, Jixing, Cheng, Huifang, Bao, Jiafeng, Zhang, Pengfei, Liu, Miaomiao, Leng, Yan, Zhang, Zihao, Tao, Runming, Liu, Jian, Zhao, Zhen, and Dai, Sheng. Sat .
"Aluminum hydroxide-mediated synthesis of mesoporous metal oxides by a mechanochemical nanocasting strategy". United States. https://doi.org/10.1039/c9ta06727b. https://www.osti.gov/servlets/purl/1785489.
@article{osti_1785489,
title = {Aluminum hydroxide-mediated synthesis of mesoporous metal oxides by a mechanochemical nanocasting strategy},
author = {Liu, Jixing and Cheng, Huifang and Bao, Jiafeng and Zhang, Pengfei and Liu, Miaomiao and Leng, Yan and Zhang, Zihao and Tao, Runming and Liu, Jian and Zhao, Zhen and Dai, Sheng},
abstractNote = {Mesoporous metal oxides (MOs) have attracted significant interest in heterogeneous catalysis due to their wide pore size distribution and high pore volume. In this work, we present a facile mechanochemical nanocasting strategy using aluminum hydroxide as the mesoporous structure-directing agent, which overcomes the drawbacks associated with wet template-assisted methods. In this procedure, by simply grinding a mixture of commercial aluminum hydroxide and MO precursors, a series of mesoporous MOs with high specific surface areas and narrow pore size distributions have been constructed in a short time (e.g., Fe2O3, 280 m2 g–1; Co3O4, 155 m2 g–1; CeO2, 192 m2 g–1; ZrO2, 170 m2 g–1; CuOx–CeOy, 177 m2 g–1; FeOx–CeOy, 170 m2 g–1; CoOx–CuOy–CeOz, 154 m2 g–1; CoOx–FeOy–CeOz, 133 m2 g–1). It is expected that this strategy may open up new opportunities for fabricating a number of advanced porous materials with abundant porosity in the near future.},
doi = {10.1039/c9ta06727b},
journal = {Journal of Materials Chemistry. A},
number = 40,
volume = 7,
place = {United States},
year = {Sat Sep 28 00:00:00 EDT 2019},
month = {Sat Sep 28 00:00:00 EDT 2019}
}
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