DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Cookoff of Black Powder and Smokeless Powder

Abstract

We have completed a series of both vented and sealed cookoff experiments of black powder and smokeless powder in our Sandia Instrumented Thermal Ignition (SITI) apparatus at bulk densities of 1078 and 729 kg/m3, respectively. The confining aluminum cylinder was ramped from room temperature to a set point temperature and then held at the setpoint temperature until ignition. The setpoint temperatures varied between 495 to 523 K for the black powder and 401 to 412 K for the more sensitive smokeless powder. The vented experiments show a significant delay in thermal ignition, indicating that the ignition is dependent on pressure. Post experimental debris shows greater violence for our smokeless powder experiments than our black powder experiments. A simplified universal cookoff model (UCM) was calibrated using the black powder and smokeless powder SITI data and used to predict pressurization and thermal ignition. The current work presents the first calibration of the UCM with a double base propellant. Finally, this work also presents the first pressure-dependent cookoff model for black powder and smokeless powder.

Authors:
ORCiD logo [1];  [1]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1784620
Report Number(s):
SAND-2021-6006J
Journal ID: ISSN 0721-3115; 696264
Grant/Contract Number:  
AC04-94AL85000; NA0003525
Resource Type:
Accepted Manuscript
Journal Name:
Propellants, Explosives, Pyrotechnics
Additional Journal Information:
Journal Volume: 46; Journal Issue: 3; Journal ID: ISSN 0721-3115
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING; cookoff; thermal ignition; black powder; smokeless powder; double base propellent; Bullseye®

Citation Formats

Hobbs, Michael L., and Kaneshige, Michael J. Cookoff of Black Powder and Smokeless Powder. United States: N. p., 2021. Web. doi:10.1002/prep.202000214.
Hobbs, Michael L., & Kaneshige, Michael J. Cookoff of Black Powder and Smokeless Powder. United States. https://doi.org/10.1002/prep.202000214
Hobbs, Michael L., and Kaneshige, Michael J. Thu . "Cookoff of Black Powder and Smokeless Powder". United States. https://doi.org/10.1002/prep.202000214. https://www.osti.gov/servlets/purl/1784620.
@article{osti_1784620,
title = {Cookoff of Black Powder and Smokeless Powder},
author = {Hobbs, Michael L. and Kaneshige, Michael J.},
abstractNote = {We have completed a series of both vented and sealed cookoff experiments of black powder and smokeless powder in our Sandia Instrumented Thermal Ignition (SITI) apparatus at bulk densities of 1078 and 729 kg/m3, respectively. The confining aluminum cylinder was ramped from room temperature to a set point temperature and then held at the setpoint temperature until ignition. The setpoint temperatures varied between 495 to 523 K for the black powder and 401 to 412 K for the more sensitive smokeless powder. The vented experiments show a significant delay in thermal ignition, indicating that the ignition is dependent on pressure. Post experimental debris shows greater violence for our smokeless powder experiments than our black powder experiments. A simplified universal cookoff model (UCM) was calibrated using the black powder and smokeless powder SITI data and used to predict pressurization and thermal ignition. The current work presents the first calibration of the UCM with a double base propellant. Finally, this work also presents the first pressure-dependent cookoff model for black powder and smokeless powder.},
doi = {10.1002/prep.202000214},
journal = {Propellants, Explosives, Pyrotechnics},
number = 3,
volume = 46,
place = {United States},
year = {Thu Jan 28 00:00:00 EST 2021},
month = {Thu Jan 28 00:00:00 EST 2021}
}

Works referenced in this record:

The explosion of a ship, loaded with black powder, in Leiden in 1807
journal, May 2001


The Polymorphism of Potassium Nitrate
journal, February 1930


The Differentiation of Black and Smokeless Gunpowders
journal, March 1985

  • Dahl, Darwin B.; Lott, Peter F.
  • Analytical Chemistry, Vol. 57, Issue 3
  • DOI: 10.1021/ac00280a782

Combustion of Black Powder. Part IV: Effect of carbon and other parameters
journal, February 1992

  • Hussain, Ghulam; Rees, Gwilym J.
  • Propellants, Explosives, Pyrotechnics, Vol. 17, Issue 1
  • DOI: 10.1002/prep.19920170102

Combustion of Black Powder. Part 1: Thermo-analytical studies
journal, April 1990


A Comparison of Three Methods for Selecting Values of Input Variables in the Analysis of Output from a Computer Code
journal, May 1979

  • McKay, M. D.; Beckman, R. J.; Conover, W. J.
  • Technometrics, Vol. 21, Issue 2
  • DOI: 10.2307/1268522

VII. Note on regression and inheritance in the case of two parents
journal, January 1895

  • Pearson, Karl
  • Proceedings of the Royal Society of London, Vol. 58, Issue 347-352, p. 240-242
  • DOI: 10.1098/rspl.1895.0041

A New Phase Change Material Based on Potassium Nitrate with Silica and Alumina Nanoparticles for Thermal Energy Storage
journal, June 2015

  • Chieruzzi, Manila; Miliozzi, Adio; Crescenzi, Tommaso
  • Nanoscale Research Letters, Vol. 10, Issue 1
  • DOI: 10.1186/s11671-015-0984-2

Melting-crystallization and premelting properties of sodium nitrate-potassium nitrate. Enthalpies and heat capacities
journal, October 1982

  • Rogers, Derek J.; Janz, George J.
  • Journal of Chemical & Engineering Data, Vol. 27, Issue 4
  • DOI: 10.1021/je00030a017

Thirteen Ways to Look at the Correlation Coefficient
journal, February 1988

  • Rodgers, Joseph Lee; Nicewander, W. Alan
  • The American Statistician, Vol. 42, Issue 1
  • DOI: 10.2307/2685263

JCZS: An Intermolecular Potential Database for Performing Accurate Detonation and Expansion Calculations
journal, October 1999


A temperature-profile Study of the Combustion of Black Powder and its constituent binary mixtures
journal, April 1989


Experimental study on thermal expansion coefficient of composite multi-layered flaky gun propellants
journal, June 2019


Thermal conductivity of packed beds: A review
journal, July 1987


Characteristics and Manufacture of Spherical Smokeless Powders
journal, January 2015

  • Botelho, Fernanda Diniz; Galante, Erick; Mendes, Álvaro
  • Journal of Aerospace Technology and Management, Vol. 7, Issue 4
  • DOI: 10.5028/jatm.v7i4.466

Modeling the measured effect of a nitroplasticizer (BDNPA/F) on cookoff of a plastic bonded explosive (PBX 9501)
journal, November 2016


Thermal conductivity of energetic materials
journal, October 2019

  • Lawless, Zachary D.; Hobbs, Michael L.; Kaneshige, Michael J.
  • Journal of Energetic Materials, Vol. 38, Issue 2
  • DOI: 10.1080/07370652.2019.1679285