Extraction of the trivalent transplutonium actinides americium through einsteinium by the sulfur donor Cyanex 301

Bessen, Nathan; Yan, Qiang; Pu, Ning; Chen, Jing; Xu, Chao; Shafer, Jenifer

doi:10.1039/D1QI00076D

Title: Extraction of the trivalent transplutonium actinides americium through einsteinium by the sulfur donor Cyanex 301

Journal Article · 14 September 2021 · Inorganic Chemistry Frontiers (Online)

DOI: https://doi.org/10.1039/D1QI00076D · OSTI ID:1782763

^[1];

^[2]; Pu, Ning ^[2]; Chen, Jing ^[2];

^[2];

^[1]

Colorado School of Mines, 1500 Illinois St, Golden, CO 80401, USA
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

When extracting metals with the sulfur donor ligand, Cyanex 301 (bis(2,4,4-trimethylpentyl)dithiophosphinic acid), a transition in the coordination mode of extracted complexes has been observed between Eu and Gd, but not within the actinide series.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0020189

OSTI ID:: 1782763

Journal Information:: Inorganic Chemistry Frontiers (Online), Journal Name: Inorganic Chemistry Frontiers (Online) Journal Issue: 18 Vol. 8; ISSN ICFNAW; ISSN 2052-1553

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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