DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: New reflections on hard X-ray photon-in/photon-out spectroscopy

Abstract

Analysis of the electronic structure and local coordination of an element is an important aspect in the study of the chemical and physical properties of materials. This is particularly relevant at the nanoscale where new phases of matter may emerge below a critical size. X-ray emission spectroscopy (XES) at synchrotron radiation sources and free electron lasers has enriched the field of X-ray spectroscopy. Additionally, the spectroscopic techniques derived from the combination of X-ray absorption and emission spectroscopy (XAS–XES), such as resonant inelastic X-ray scattering (RIXS) and high energy resolution fluorescence detected (HERFD) XAS, are an ideal tool for the study of nanomaterials. New installations and beamline upgrades now often include wavelength dispersive instruments for the analysis of the emitted X-rays. With the growing use of XAS–XES, scientists are learning about the possibilities and pitfalls. We discuss some experimental aspects, assess the feasibility of measuring weak fluorescence lines in dilute, radiation sensitive samples, and present new experimental approaches for studying magnetic properties of colloidal nanoparticles directly in the liquid phase.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2];  [2];  [2]; ORCiD logo [1]
  1. European Synchrotron Radiation Facility (ESRF), Grenoble (France)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1782156
Alternate Identifier(s):
OSTI ID: 1643720
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 12; Journal Issue: 30; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
47 OTHER INSTRUMENTATION

Citation Formats

Lafuerza, Sara, Retegan, Marius, Detlefs, Blanka, Chatterjee, Ruchira, Yachandra, Vittal, Yano, Junko, and Glatzel, Pieter. New reflections on hard X-ray photon-in/photon-out spectroscopy. United States: N. p., 2020. Web. doi:10.1039/d0nr01983f.
Lafuerza, Sara, Retegan, Marius, Detlefs, Blanka, Chatterjee, Ruchira, Yachandra, Vittal, Yano, Junko, & Glatzel, Pieter. New reflections on hard X-ray photon-in/photon-out spectroscopy. United States. https://doi.org/10.1039/d0nr01983f
Lafuerza, Sara, Retegan, Marius, Detlefs, Blanka, Chatterjee, Ruchira, Yachandra, Vittal, Yano, Junko, and Glatzel, Pieter. Fri . "New reflections on hard X-ray photon-in/photon-out spectroscopy". United States. https://doi.org/10.1039/d0nr01983f. https://www.osti.gov/servlets/purl/1782156.
@article{osti_1782156,
title = {New reflections on hard X-ray photon-in/photon-out spectroscopy},
author = {Lafuerza, Sara and Retegan, Marius and Detlefs, Blanka and Chatterjee, Ruchira and Yachandra, Vittal and Yano, Junko and Glatzel, Pieter},
abstractNote = {Analysis of the electronic structure and local coordination of an element is an important aspect in the study of the chemical and physical properties of materials. This is particularly relevant at the nanoscale where new phases of matter may emerge below a critical size. X-ray emission spectroscopy (XES) at synchrotron radiation sources and free electron lasers has enriched the field of X-ray spectroscopy. Additionally, the spectroscopic techniques derived from the combination of X-ray absorption and emission spectroscopy (XAS–XES), such as resonant inelastic X-ray scattering (RIXS) and high energy resolution fluorescence detected (HERFD) XAS, are an ideal tool for the study of nanomaterials. New installations and beamline upgrades now often include wavelength dispersive instruments for the analysis of the emitted X-rays. With the growing use of XAS–XES, scientists are learning about the possibilities and pitfalls. We discuss some experimental aspects, assess the feasibility of measuring weak fluorescence lines in dilute, radiation sensitive samples, and present new experimental approaches for studying magnetic properties of colloidal nanoparticles directly in the liquid phase.},
doi = {10.1039/d0nr01983f},
journal = {Nanoscale},
number = 30,
volume = 12,
place = {United States},
year = {Fri Jul 17 00:00:00 EDT 2020},
month = {Fri Jul 17 00:00:00 EDT 2020}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 14 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Oxidation and Luminescence Quenching of Europium in BaMgAl 10 O 17 Blue Phosphors
journal, November 2017


Radiation damages during synchrotron X-ray micro-analyses of Prussian blue and zinc white historic paintings: detection, mitigation and integration
journal, September 2015


Advances in element speciation analysis of biomedical samples using synchrotron-based techniques
journal, July 2018

  • Porcaro, Francesco; Roudeau, Stéphane; Carmona, Asuncion
  • TrAC Trends in Analytical Chemistry, Vol. 104
  • DOI: 10.1016/j.trac.2017.09.016

Insights into the Geometric and Electronic Structure of Transition Metal Centers from Valence-to-Core X-ray Emission Spectroscopy
journal, September 2015


Hard-X-ray-Induced Excited-Spin-State Trapping
journal, July 2007

  • Vankó, György; Renz, Franz; Molnár, Gábor
  • Angewandte Chemie International Edition, Vol. 46, Issue 28
  • DOI: 10.1002/anie.200604432

Effect of silica capping on the oxidation of Fe 3 O 4 nanoparticles in dispersion revealed by x-ray absorption spectroscopy
journal, June 2012


High-Resolution Mn EXAFS of the Oxygen-Evolving Complex in Photosystem II:  Structural Implications for the Mn 4 Ca Cluster
journal, November 2005

  • Yano, Junko; Pushkar, Yulia; Glatzel, Pieter
  • Journal of the American Chemical Society, Vol. 127, Issue 43
  • DOI: 10.1021/ja054873a

Absence of Mn-Centered Oxidation in the S2 → S3 Transition:  Implications for the Mechanism of Photosynthetic Water Oxidation
journal, July 2001

  • Messinger, Johannes; Robblee, John H.; Bergmann, Uwe
  • Journal of the American Chemical Society, Vol. 123, Issue 32
  • DOI: 10.1021/ja004307+

Quantitative Speciation of Heavy Metals in Soils and Sediments by Synchrotron X-ray Techniques
journal, January 2002

  • Manceau, A.; Marcus, M. A.; Tamura, N.
  • Reviews in Mineralogy and Geochemistry, Vol. 49, Issue 1
  • DOI: 10.2138/gsrmg.49.1.341

Johann-type laboratory-scale x-ray absorption spectrometer with versatile detection modes
journal, March 2019

  • Honkanen, Ari-Pekka; Ollikkala, Sami; Ahopelto, Taru
  • Review of Scientific Instruments, Vol. 90, Issue 3
  • DOI: 10.1063/1.5084049

Towards accurate structural characterization of metal centres in protein crystals: the structures of Ni and Cu T 6 bovine insulin derivatives
journal, December 2013

  • Frankaer, Christian Grundahl; Mossin, Susanne; Ståhl, Kenny
  • Acta Crystallographica Section D Biological Crystallography, Vol. 70, Issue 1
  • DOI: 10.1107/S1399004713029040

High-Energy-Resolution Fluorescence-Detected X-ray Absorption of the Q Intermediate of Soluble Methane Monooxygenase
journal, November 2017

  • Castillo, Rebeca G.; Banerjee, Rahul; Allpress, Caleb J.
  • Journal of the American Chemical Society, Vol. 139, Issue 49
  • DOI: 10.1021/jacs.7b09560

Nanoscale Distribution of Magnetic Anisotropies in Bimagnetic Soft Core-Hard Shell MnFe 2 O 4 @CoFe 2 O 4 Nanoparticles
journal, September 2017

  • Daffé, Niéli; Sikora, Marcin; Rovezzi, Mauro
  • Advanced Materials Interfaces, Vol. 4, Issue 22
  • DOI: 10.1002/admi.201700599

On the correlation between the X-ray absorption chemical shift and the formal valence state in mixed-valence manganites
journal, April 2010

  • García, Joaquín; Subías, Gloria; Cuartero, Vera
  • Journal of Synchrotron Radiation, Vol. 17, Issue 3
  • DOI: 10.1107/S0909049510010277

Structural changes caused by radiation-induced reduction and radiolysis: the effect of X-ray absorbed dose in a fungal multicopper oxidase
journal, April 2012

  • De la Mora, Eugenio; Lovett, Janet E.; Blanford, Christopher F.
  • Acta Crystallographica Section D Biological Crystallography, Vol. 68, Issue 5
  • DOI: 10.1107/S0907444912005343

Valence to Core X-ray Emission Spectroscopy
journal, May 2014


High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information
journal, January 2005


Five-element Johann-type x-ray emission spectrometer with a single-photon-counting pixel detector
journal, June 2011

  • Kleymenov, Evgeny; van Bokhoven, Jeroen A.; David, Christian
  • Review of Scientific Instruments, Vol. 82, Issue 6
  • DOI: 10.1063/1.3600452

Small particles, big impacts: A review of the diverse applications of nanofluids
journal, January 2013

  • Taylor, Robert; Coulombe, Sylvain; Otanicar, Todd
  • Journal of Applied Physics, Vol. 113, Issue 1
  • DOI: 10.1063/1.4754271

A practical superconducting-microcalorimeter X-ray spectrometer for beamline and laboratory science
journal, May 2017

  • Doriese, W. B.; Abbamonte, P.; Alpert, B. K.
  • Review of Scientific Instruments, Vol. 88, Issue 5
  • DOI: 10.1063/1.4983316

A laboratory-based hard x-ray monochromator for high-resolution x-ray emission spectroscopy and x-ray absorption near edge structure measurements
journal, November 2014

  • Seidler, G. T.; Mortensen, D. R.; Remesnik, A. J.
  • Review of Scientific Instruments, Vol. 85, Issue 11
  • DOI: 10.1063/1.4901599

Laboratory von Hámos X-ray spectroscopy for routine sample characterization
journal, October 2016

  • Németh, Zoltán; Szlachetko, Jakub; Bajnóczi, Éva G.
  • Review of Scientific Instruments, Vol. 87, Issue 10
  • DOI: 10.1063/1.4964098

Structure and bonding in Au( i ) chloride species: a critical examination of X-ray absorption spectroscopy (XAS) data
journal, January 2015

  • Chang, Sin-Yuen; Uehara, Akihiro; Booth, Samuel G.
  • RSC Advances, Vol. 5, Issue 9
  • DOI: 10.1039/C4RA13087A

Solving self-absorption in fluorescence
journal, May 2019


Synergistic interplay of Zn and Rh-Cr promoters on Ga 2 O 3 based photocatalysts for water splitting
journal, January 2018

  • Borges Ordoño, Marta; Yasumura, Shunsaku; Glatzel, Pieter
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 36
  • DOI: 10.1039/C8CP03987A

Metal oxidation states in biological water splitting
journal, January 2015

  • Krewald, Vera; Retegan, Marius; Cox, Nicholas
  • Chemical Science, Vol. 6, Issue 3
  • DOI: 10.1039/C4SC03720K

A feasibility study of “range-extended” EXAFS measurement at the Pt L 3 -edge of Pt/Al 2 O 3 in the presence of Au 2 O 3
journal, January 2018

  • Asakura, Hiroyuki; Kawamura, Naomi; Mizumaki, Masaichiro
  • Journal of Analytical Atomic Spectrometry, Vol. 33, Issue 1
  • DOI: 10.1039/C7JA00309A

Selective magnetometry of superparamagnetic iron oxide nanoparticles in liquids
journal, January 2020

  • Kuciakowski, Juliusz; Kmita, Angelika; Lachowicz, Dorota
  • Nanoscale, Vol. 12, Issue 31
  • DOI: 10.1039/d0nr02866e

Structural Changes of the Oxygen-evolving Complex in Photosystem II during the Catalytic Cycle
journal, June 2013

  • Glöckner, Carina; Kern, Jan; Broser, Matthias
  • Journal of Biological Chemistry, Vol. 288, Issue 31
  • DOI: 10.1074/jbc.M113.476622

Multiple excitations in the K fluorescence emission of Mn, Fe and Ni compounds
conference, January 2003

  • Glatzel, P.
  • X-RAY AND INNER-SHELL PROCESSES, AIP Conference Proceedings
  • DOI: 10.1063/1.1536383

A Johann-type X-ray emission spectrometer at the Rossendorf beamline
journal, April 2016

  • Kvashnina, Kristina O.; Scheinost, Andreas C.
  • Journal of Synchrotron Radiation, Vol. 23, Issue 3
  • DOI: 10.1107/S1600577516004483

Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode
journal, November 2012

  • Alonso-Mori, R.; Kern, J.; Gildea, R. J.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 47, p. 19103-19107
  • DOI: 10.1073/pnas.1211384109

Elongated magnetite nanoparticle formation from a solid ferrous precursor in a magnetotactic bacterium
journal, November 2016

  • Baumgartner, Jens; Menguy, Nicolas; Gonzalez, Teresa Perez
  • Journal of The Royal Society Interface, Vol. 13, Issue 124
  • DOI: 10.1098/rsif.2016.0665

Double-channel excitation in the X-ray absorption spectrum of Fe3+ water solutions
journal, September 2002


A laboratory spectrometer for high throughput X-ray emission spectroscopy in catalysis research
journal, November 2018

  • Malzer, Wolfgang; Grötzsch, Daniel; Gnewkow, Richard
  • Review of Scientific Instruments, Vol. 89, Issue 11
  • DOI: 10.1063/1.5035171

Chemical Forms of Mercury in Human Hair Reveal Sources of Exposure
journal, September 2016

  • Manceau, Alain; Enescu, Mironel; Simionovici, Alexandre
  • Environmental Science & Technology, Vol. 50, Issue 19
  • DOI: 10.1021/acs.est.6b03468

A new method of directly determining the core–hole effect in the Ce L3 XAS of mixed valence Ce compounds—An application of resonant X-ray emission spectroscopy
journal, April 2011

  • Kotani, A.; Kvashnina, K. O.; Butorin, S. M.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 184, Issue 3-6
  • DOI: 10.1016/j.elspec.2010.12.028

A tool to plan photon-in/photon-out experiments: count rates, dips and self-absorption
journal, October 2012


High Resolution X-Ray Resonant Raman Scattering
journal, May 1995


Kβ X‐Ray Emission Spectroscopic Study of a Second‐Row Transition Metal (Mo) and Its Application to Nitrogenase‐Related Model Complexes
journal, May 2020

  • Castillo, Rebeca G.; Henthorn, Justin T.; McGale, Jeremy
  • Angewandte Chemie International Edition, Vol. 59, Issue 31
  • DOI: 10.1002/anie.202003621

Bent crystal spectrometer for both frequency and wavenumber resolved x-ray scattering at a seeded free-electron laser
journal, September 2014

  • Zastrau, Ulf; Fletcher, Luke B.; Förster, Eckhart
  • Review of Scientific Instruments, Vol. 85, Issue 9
  • DOI: 10.1063/1.4894821

High energy-resolution x-ray spectroscopy at ultra-high dilution with spherically bent crystal analyzers of 0.5 m radius
journal, January 2017

  • Rovezzi, Mauro; Lapras, Christophe; Manceau, Alain
  • Review of Scientific Instruments, Vol. 88, Issue 1
  • DOI: 10.1063/1.4974100

Real Time Observation of X-ray-Induced Surface Modification Using Simultaneous XANES and XEOL-XANES
journal, September 2013

  • Adriaens, Annemie; Quinn, Paul; Nikitenko, Sergey
  • Analytical Chemistry, Vol. 85, Issue 20
  • DOI: 10.1021/ac401646q

Direct Detection of Oxygen Ligation to the Mn4Ca Cluster of Photosystem II by X-ray Emission Spectroscopy
journal, December 2009

  • Pushkar, Yulia; Long, Xi; Glatzel, Pieter
  • Angewandte Chemie International Edition, Vol. 49, Issue 4
  • DOI: 10.1002/anie.200905366

Ceria Nanocubes: Dependence of the Electronic Structure on Synthetic and Experimental Conditions
journal, May 2013

  • Revoy, Michelle N.; Scott, Robert W. J.; Grosvenor, Andrew P.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 19
  • DOI: 10.1021/jp3124814

Strong K -edge Magnetic Circular Dichroism Observed in Photon-in–Photon-out Spectroscopy
journal, July 2010


X-Ray-Induced Lysis of the Fe−CO Bond in Carbonmonoxy-Myoglobin
journal, November 2010

  • Della Longa, Stefano; Arcovito, Alessandro
  • Inorganic Chemistry, Vol. 49, Issue 21
  • DOI: 10.1021/ic101186m

Reflections on hard X-ray photon-in/photon-out spectroscopy for electronic structure studies
journal, June 2013

  • Glatzel, Pieter; Weng, Tsu-Chien; Kvashnina, Kristina
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 188
  • DOI: 10.1016/j.elspec.2012.09.004

Tailoring the Local Conductivity of TiO 2 by X‐Ray Nanobeam Irradiation
journal, May 2019

  • Mino, Lorenzo; Bonino, Valentina; Picollo, Federico
  • Advanced Electronic Materials, Vol. 5, Issue 6
  • DOI: 10.1002/aelm.201900129

Elimination of self-absorption in fluorescence hard-x-ray absorption spectra
journal, October 1999


Mn 4 Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen
journal, March 2014

  • Yano, Junko; Yachandra, Vittal
  • Chemical Reviews, Vol. 114, Issue 8
  • DOI: 10.1021/cr4004874

Introduction to XAFS
book, January 2010


Range-extended EXAFS at the L edge of rare earths using high-energy-resolution fluorescence detection: A study of La in LaOCl
journal, July 2005


A novel von Hamos spectrometer for efficient X-ray emission spectroscopy in the laboratory
journal, May 2014

  • Anklamm, Lars; Schlesiger, Christopher; Malzer, Wolfgang
  • Review of Scientific Instruments, Vol. 85, Issue 5
  • DOI: 10.1063/1.4875986

TEXS: in-vacuum tender X-ray emission spectrometer with 11 Johansson crystal analyzers
journal, April 2020

  • Rovezzi, Mauro; Harris, Alistair; Detlefs, Blanka
  • Journal of Synchrotron Radiation, Vol. 27, Issue 3
  • DOI: 10.1107/S160057752000243X

X-ray damage to the Mn4Ca complex in single crystals of photosystem II: A case study for metalloprotein crystallography
journal, August 2005

  • Yano, J.; Kern, J.; Irrgang, K. -D.
  • Proceedings of the National Academy of Sciences, Vol. 102, Issue 34
  • DOI: 10.1073/pnas.0505207102

A multi-crystal wavelength dispersive x-ray spectrometer
journal, July 2012

  • Alonso-Mori, Roberto; Kern, Jan; Sokaras, Dimosthenis
  • Review of Scientific Instruments, Vol. 83, Issue 7
  • DOI: 10.1063/1.4737630

The Structure and Behavior of Platinum in SnO 2 ‐Based Sensors under Working Conditions
journal, March 2011

  • Hübner, Michael; Koziej, Dorota; Bauer, Matthias
  • Angewandte Chemie International Edition, Vol. 50, Issue 12
  • DOI: 10.1002/anie.201004499

Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy
journal, November 1991


The beamline ID32 at the ESRF for soft X-ray high energy resolution resonant inelastic X-ray scattering and polarisation dependent X-ray absorption spectroscopy
journal, September 2018

  • Brookes, N. B.; Yakhou-Harris, F.; Kummer, K.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 903
  • DOI: 10.1016/j.nima.2018.07.001

A wavelength‐dispersive X‐ray spectrometer for in/ex situ resonant inelastic X‐ray scattering studies
journal, April 2019

  • Mei, Bingbao; Gu, Songqi; Du, Xianlong
  • X-Ray Spectrometry, Vol. 49, Issue 1
  • DOI: 10.1002/xrs.3132

Full correction of the self-absorption in soft-fluorescence extended x-ray-absorption fine structure
journal, August 1992


1s2p resonant inelastic x-ray scattering-magnetic circular dichroism: A sensitive probe of 3 d magnetic moments using hard x-ray photons
journal, April 2012

  • Sikora, M.; Juhin, A.; Simon, G.
  • Journal of Applied Physics, Vol. 111, Issue 7
  • DOI: 10.1063/1.3670064

A Review of Clinical Translation of Inorganic Nanoparticles
journal, May 2015


Distinction between Intrinsic and X-ray-Induced Oxidized Oxygen States in Li-Rich 3d Layered Oxides and LiAlO 2
journal, May 2019

  • Lebens-Higgins, Zachary W.; Vinckeviciute, Julija; Wu, Jinpeng
  • The Journal of Physical Chemistry C, Vol. 123, Issue 21
  • DOI: 10.1021/acs.jpcc.9b01298

An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research
journal, February 2019

  • Jahrman, Evan P.; Holden, William M.; Ditter, Alexander S.
  • Review of Scientific Instruments, Vol. 90, Issue 2
  • DOI: 10.1063/1.5049383

Magnetic Nanoparticles: Design and Characterization, Toxicity and Biocompatibility, Pharmaceutical and Biomedical Applications
journal, September 2012

  • Reddy, L. Harivardhan; Arias, José L.; Nicolas, Julien
  • Chemical Reviews, Vol. 112, Issue 11
  • DOI: 10.1021/cr300068p

Minimizing experimental artefacts in synchrotron-based X-ray analyses of Fe speciation in tissues of rice plants
journal, June 2019

  • Wang, Peng; McKenna, Brigid A.; Menzies, Neal W.
  • Journal of Synchrotron Radiation, Vol. 26, Issue 4
  • DOI: 10.1107/S1600577519004351

Manganese Kβ X-ray Emission Spectroscopy As a Probe of Metal–Ligand Interactions
journal, September 2011

  • Beckwith, Martha A.; Roemelt, Michael; Collomb, Marie-Noëlle
  • Inorganic Chemistry, Vol. 50, Issue 17
  • DOI: 10.1021/ic200970t

Iron (Fe) speciation in xylem sap by XANES at a high brilliant synchrotron X-ray source: opportunities and limitations
journal, April 2013

  • Terzano, Roberto; Mimmo, Tanja; Vekemans, Bart
  • Analytical and Bioanalytical Chemistry, Vol. 405, Issue 16
  • DOI: 10.1007/s00216-013-6959-1

Progress in the preparation of magnetic nanoparticles for applications in biomedicine
journal, November 2009


Quantitative Evaluation of Radiation Damage to Polyethylene Terephthalate by Soft X-rays and High-energy Electrons
journal, February 2009

  • Wang, Jian; Botton, Gianluigi A.; West, Marcia M.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 7
  • DOI: 10.1021/jp808289e

A versatile Johansson-type tender x-ray emission spectrometer
journal, March 2020

  • Nowak, S. H.; Armenta, R.; Schwartz, C. P.
  • Review of Scientific Instruments, Vol. 91, Issue 3
  • DOI: 10.1063/1.5121853

A seven-crystal Johann-type hard x-ray spectrometer at the Stanford Synchrotron Radiation Lightsource
journal, May 2013

  • Sokaras, D.; Weng, T. -C.; Nordlund, D.
  • Review of Scientific Instruments, Vol. 84, Issue 5
  • DOI: 10.1063/1.4803669

Magnetite nanoparticles for cancer diagnosis, treatment, and treatment monitoring: recent advances
journal, April 2016


Magnetic Iron Oxide Nanoparticles: Synthesis, Stabilization, Vectorization, Physicochemical Characterizations, and Biological Applications
journal, April 2010

  • Laurent, Sophie; Forge, Delphine; Port, Marc
  • Chemical Reviews, Vol. 110, Issue 4
  • DOI: 10.1021/cr900197g

A close look at dose: Toward L-edge XAS spectral uniformity, dose quantification and prediction of metal ion photoreduction
journal, January 2015


High energy resolution five-crystal spectrometer for high quality fluorescence and absorption measurements on an x-ray absorption spectroscopy beamline
journal, June 2012

  • Llorens, Isabelle; Lahera, Eric; Delnet, William
  • Review of Scientific Instruments, Vol. 83, Issue 6
  • DOI: 10.1063/1.4728414

Revealing the Chemical Form of “Invisible” Gold in Natural Arsenian Pyrite and Arsenopyrite with High Energy-Resolution X-ray Absorption Spectroscopy
journal, July 2019


Absence of Ce 3+ Sites in Chemically Active Colloidal Ceria Nanoparticles
journal, November 2013

  • Cafun, Jean-Daniel; Kvashnina, Kristina O.; Casals, Eudald
  • ACS Nano, Vol. 7, Issue 12
  • DOI: 10.1021/nn403542p

Critical absorbed dose of resinous adhesive material towards non-destructive chemical-state analysis using soft X-rays
journal, April 2019

  • Yamane, Hiroyuki; Oura, Masaki; Sawada, Kei
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 232
  • DOI: 10.1016/j.elspec.2018.12.005