Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries
Abstract
A novel redox-active quinone-based organic building block 1,4-dicyano-2,3,5,6-tetrahydroxybenzene (LH4) has been synthesized and used as a bridging ligand to form a new 1D copper-benzoquinoid coordination polymer [CuL(DMF)2]n. The compound is able to deliver an initial capacity as high as 268 mA h g-1 at 30 mA g-1 (~C/2.5) when used as the cathode in Li batteries. Ex situ XPS and FT-IR reveal the involvement of both Cu and organic moieties in the multi-electron redox reaction. Cu K-edge XANES and EXAFS measurements confirm the change in the oxidation state and coordination environment of Cu during the discharge–charge process. In situ generated metallic nanoparticles have been observed by TEM. The obtained mechanistic understanding of the metal–organic electrode materials for Li-based batteries may pave the way for the design of next-generation energy-storage systems.
- Authors:
-
[3];
[2];
[4];
[2]
- Tamkang Univ., Taipei (Taiwan)
- National Cheng Kung Univ., Tainan City (Taiwan)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
- National Taiwan Normal Univ., Taipei (Taiwan)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1777812
- Alternate Identifier(s):
- OSTI ID: 1557902
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 41; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Chang, Cheng-Han, Li, An-Che, Popovs, Ilja, Kaveevivitchai, Watchareeya, Chen, Jeng-Lung, Chou, Kai-Chun, Kuo, Ting-Shen, and Chen, Teng-Hao. Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries. United States: N. p., 2019.
Web. doi:10.1039/c9ta05244e.
Chang, Cheng-Han, Li, An-Che, Popovs, Ilja, Kaveevivitchai, Watchareeya, Chen, Jeng-Lung, Chou, Kai-Chun, Kuo, Ting-Shen, & Chen, Teng-Hao. Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries. United States. https://doi.org/10.1039/c9ta05244e
Chang, Cheng-Han, Li, An-Che, Popovs, Ilja, Kaveevivitchai, Watchareeya, Chen, Jeng-Lung, Chou, Kai-Chun, Kuo, Ting-Shen, and Chen, Teng-Hao. Fri .
"Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries". United States. https://doi.org/10.1039/c9ta05244e. https://www.osti.gov/servlets/purl/1777812.
@article{osti_1777812,
title = {Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries},
author = {Chang, Cheng-Han and Li, An-Che and Popovs, Ilja and Kaveevivitchai, Watchareeya and Chen, Jeng-Lung and Chou, Kai-Chun and Kuo, Ting-Shen and Chen, Teng-Hao},
abstractNote = {A novel redox-active quinone-based organic building block 1,4-dicyano-2,3,5,6-tetrahydroxybenzene (LH4) has been synthesized and used as a bridging ligand to form a new 1D copper-benzoquinoid coordination polymer [CuL(DMF)2]n. The compound is able to deliver an initial capacity as high as 268 mA h g-1 at 30 mA g-1 (~C/2.5) when used as the cathode in Li batteries. Ex situ XPS and FT-IR reveal the involvement of both Cu and organic moieties in the multi-electron redox reaction. Cu K-edge XANES and EXAFS measurements confirm the change in the oxidation state and coordination environment of Cu during the discharge–charge process. In situ generated metallic nanoparticles have been observed by TEM. The obtained mechanistic understanding of the metal–organic electrode materials for Li-based batteries may pave the way for the design of next-generation energy-storage systems.},
doi = {10.1039/c9ta05244e},
journal = {Journal of Materials Chemistry. A},
number = 41,
volume = 7,
place = {United States},
year = {Fri Aug 09 00:00:00 EDT 2019},
month = {Fri Aug 09 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 24 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Recent Progress in Organic Electrodes for Li and Na Rechargeable Batteries
journal, March 2018
- Lee, Sechan; Kwon, Giyun; Ku, Kyojin
- Advanced Materials, Vol. 30, Issue 42
High-capacity zinc-ion storage in an open-tunnel oxide for aqueous and nonaqueous Zn-ion batteries
journal, January 2016
- Kaveevivitchai, Watchareeya; Manthiram, Arumugam
- Journal of Materials Chemistry A, Vol. 4, Issue 48
Coordination Polymers for High-Capacity Li-Ion Batteries: Metal-Dependent Solid-State Reversibility
journal, June 2018
- Lee, Hyun Ho; Lee, Jae Bin; Park, Yuwon
- ACS Applied Materials & Interfaces, Vol. 10, Issue 26
Organic small molecules and polymers as an electrode material for rechargeable lithium ion batteries
journal, January 2018
- Bhosale, Manik E.; Chae, Sudong; Kim, Ji Man
- Journal of Materials Chemistry A, Vol. 6, Issue 41
Coordination Polymers of 2,5-Dihydroxybenzoquinone and Chloranilic Acid with the (10,3)- a Topology
journal, July 2011
- Abrahams, Brendan F.; Hudson, Timothy A.; McCormick, Laura J.
- Crystal Growth & Design, Vol. 11, Issue 7
Nanostructured Conjugated Polymers: Toward High-Performance Organic Electrodes for Rechargeable Batteries
journal, August 2017
- Xie, Jian; Gu, Peiyang; Zhang, Qichun
- ACS Energy Letters, Vol. 2, Issue 9
Structural Control of Copper(I) Coordination Polymers: Construction of One-, Two-, and Three-Dimensional Frameworks of Tetrahedral Copper(I) Ions Bridged by Dicyanobenzene Derivatives
journal, December 1997
- Kuroda-Sowa, Takayoshi; Horino, Takashi; Yamamoto, Mikiko
- Inorganic Chemistry, Vol. 36, Issue 27
A H-bond stabilized quinone electrode material for Li–organic batteries: the strength of weak bonds
journal, January 2019
- Sieuw, Louis; Jouhara, Alia; Quarez, Éric
- Chemical Science, Vol. 10, Issue 2
Harnessing Structural Dynamics in a 2D Manganese–Benzoquinoid Framework To Dramatically Accelerate Metal Transport in Diffusion-Limited Metal Exchange Reactions
journal, July 2018
- Liu, Lujia; Li, Liang; DeGayner, Jordan A.
- Journal of the American Chemical Society, Vol. 140, Issue 36
Construction of Copper(I) Coordination Polymers of 1,2,4,5-Tetracyanobenzene with Zigzag Sheet and Porous Frameworks
journal, October 1998
- Munakata, Megumu; Ning, Gui Ling; Kuroda-Sowa, Takayoshi
- Inorganic Chemistry, Vol. 37, Issue 21
High Capacity Microporous Molybdenum–Vanadium Oxide Electrodes for Rechargeable Lithium Batteries
journal, June 2013
- Kaveevivitchai, Watchareeya; Jacobson, Allan J.
- Chemistry of Materials, Vol. 25, Issue 13
Molecular Engineering with Organic Carbonyl Electrode Materials for Advanced Stationary and Redox Flow Rechargeable Batteries
journal, April 2017
- Zhao, Qing; Zhu, Zhiqiang; Chen, Jun
- Advanced Materials, Vol. 29, Issue 48
Materials Challenges and Opportunities of Lithium Ion Batteries
journal, January 2011
- Manthiram, Arumugam
- The Journal of Physical Chemistry Letters, Vol. 2, Issue 3
A Novel Hybrid Supramolecular Network Assembled from Perfect ??? Stacking of an Anionic Inorganic Layer and a Cationic Hydronium-Ion-Mediated Organic Layer
journal, November 2004
- Luo, Tzuoo-Tsair; Liu, Yen-Hsiang; Tsai, Hui-Lien
- European Journal of Inorganic Chemistry, Vol. 2004, Issue 21
Transition-Metal-Triggered High-Efficiency Lithium Ion Storage via Coordination Interactions with Redox-Active Croconate in One-Dimensional Metal–Organic Anode Materials
journal, February 2018
- Zhang, Lin; Cheng, Fangyi; Shi, Wei
- ACS Applied Materials & Interfaces, Vol. 10, Issue 7
One-Dimensional Zinc-Based Coordination Polymer as a Higher Capacity Anode Material for Lithium Ion Batteries
journal, September 2017
- Song, Yidan; Yu, Lili; Gao, Yuanrui
- Inorganic Chemistry, Vol. 56, Issue 19
Comparing Crystallizations in Three Dimensions and Two Dimensions: Behavior of Isomers of [2,2′-Bipyridine]dicarbonitrile and [1,10-Phenanthroline]dicarbonitrile
journal, August 2017
- Peter, Aneeshma; Mohan, Midhun; Maris, Thierry
- Crystal Growth & Design, Vol. 17, Issue 10
A Ferric Semiquinoid Single-Chain Magnet via Thermally-Switchable Metal–Ligand Electron Transfer
journal, May 2018
- DeGayner, Jordan A.; Wang, Kunyu; Harris, T. David
- Journal of the American Chemical Society, Vol. 140, Issue 21
Carbonyls: Powerful Organic Materials for Secondary Batteries
journal, April 2015
- Häupler, Bernhard; Wild, Andreas; Schubert, Ulrich S.
- Advanced Energy Materials, Vol. 5, Issue 11
A Novel Coordination Polymer as Positive Electrode Material for Lithium Ion Battery
journal, January 2008
- Xiang, Jiangfeng; Chang, Caixian; Li, Ming
- Crystal Growth & Design, Vol. 8, Issue 1
Preparation, Characterization and Scanned Conductance Microscopy Studies of DNA-Templated One-Dimensional Copper Nanostructures
journal, February 2010
- Watson, Scott M. D.; Wright, Nicholas G.; Horrocks, Benjamin R.
- Langmuir, Vol. 26, Issue 3
Rational Design of a Novel Intercalation System. Layer-Gap Control of Crystalline Coordination Polymers, {[Cu(CA)(H 2 O) m ](G)} n ( m = 2, G = 2,5-Dimethylpyrazine and Phenazine; m = 1, G = 1,2,3,4,6,7,8,9-Octahydrophenazine)
journal, January 1996
- Kawata, Satoshi; Kitagawa, Susumu; Kumagai, Hitoshi
- Inorganic Chemistry, Vol. 35, Issue 15
Critical review on lithium-ion batteries: are they safe? Sustainable?
journal, June 2017
- Mauger, A.; Julien, C. M.
- Ionics, Vol. 23, Issue 8
Pristine Metal-Organic Frameworks and their Composites for Energy Storage and Conversion
journal, November 2017
- Liang, Zibin; Qu, Chong; Guo, Wenhan
- Advanced Materials, Vol. 30, Issue 37
Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
journal, January 2019
- Wu, Zhenzhen; Xie, Jian; Xu, Zhichuan J.
- Journal of Materials Chemistry A, Vol. 7, Issue 9
Two Distinct Redox Intercalation Reactions of Hydroquinone with Porous Vanadium Benzenedicarboxylate MIL-47
journal, January 2015
- Kaveevivitchai, Watchareeya; Wang, Xiqu; Liu, Lumei
- Inorganic Chemistry, Vol. 54, Issue 4
2D Conductive Iron-Quinoid Magnets Ordering up to T c = 105 K via Heterogenous Redox Chemistry
journal, March 2017
- DeGayner, Jordan A.; Jeon, Ie-Rang; Sun, Lei
- Journal of the American Chemical Society, Vol. 139, Issue 11
Application of quinonic cathode compounds for quasi-solid lithium batteries
journal, January 2013
- Hanyu, Yuki; Ganbe, Yoshiyuki; Honma, Itaru
- Journal of Power Sources, Vol. 221
A quinone-based oligomeric lithium salt for superior Li–organic batteries
journal, January 2014
- Song, Zhiping; Qian, Yumin; Liu, Xizheng
- Energy Environ. Sci., Vol. 7, Issue 12
Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework
journal, December 2015
- Darago, Lucy E.; Aubrey, Michael L.; Yu, Chung Jui
- Journal of the American Chemical Society, Vol. 137, Issue 50
Discovery of a “Bipolar Charging” Mechanism in the Solid-State Electrochemical Process of a Flexible Metal–Organic Framework
journal, February 2016
- Zhang, Zhongyue; Yoshikawa, Hirofumi; Awaga, Kunio
- Chemistry of Materials, Vol. 28, Issue 5
Photo-reduced Cu/CuO nanoclusters on TiO2 nanotube arrays as highly efficient and reusable catalyst
journal, January 2017
- Jin, Zhao; Liu, Chang; Qi, Kun
- Scientific Reports, Vol. 7, Issue 1
Two-Dimensional Conductive and Redox-Active Nanostructures Synthesized by Crystal-Controlled Polymerization for Electrochemical Applications
journal, July 2018
- Sato, Kosuke; Imai, Hiroaki; Oaki, Yuya
- ACS Applied Nano Materials, Vol. 1, Issue 8
Copper(I) oligomers and polymers with dicyanobenzene and cyanopyridine ligands
journal, August 2016
- Broderick, Mark K.; Yang, Congqi; Pike, Robert D.
- Polyhedron, Vol. 114
Reversible redox switching of magnetic order and electrical conductivity in a 2D manganese benzoquinoid framework
journal, January 2019
- Liu, Lujia; DeGayner, Jordan A.; Sun, Lei
- Chemical Science, Vol. 10, Issue 17
Design Strategies for Promising Organic Positive Electrodes in Lithium-Ion Batteries: Quinones and Carbon Materials
journal, October 2017
- Kim, Ki Chul
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 42
Voltammetry of Electroinactive Species Using Quinone/Hydroquinone Redox: A Known Redox System Viewed in a New Perspective
journal, July 2007
- Rafiee, Mohammad; Nematollahi, Davood
- Electroanalysis, Vol. 19, Issue 13
Multiple N—H...NC, C—H...NC and nitrile...π interactions in 4,4′-bipyridine-1,1′-diium bis(1,1,3,3-tetracyano-2-ethoxypropenide): structure determination and DFT calculations of anion...π cation interaction energies
journal, July 2015
- Setifi, Fatima; Geiger, David K.; Abdul Razak, Ibrahim
- Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 8
Copper ferrites@reduced graphene oxide anode materials for advanced lithium storage applications
journal, August 2017
- Wang, Junyong; Deng, Qinglin; Li, Mengjiao
- Scientific Reports, Vol. 7, Issue 1
A Coordination Chemistry Approach for Lithium-Ion Batteries: The Coexistence of Metal and Ligand Redox Activities in a One-Dimensional Metal–Organic Material
journal, April 2016
- Li, Gaihua; Yang, Hao; Li, Fengcai
- Inorganic Chemistry, Vol. 55, Issue 10
A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T c = 26 to 80 K
journal, December 2015
- Jeon, Ie-Rang; Negru, Bogdan; Van Duyne, Richard P.
- Journal of the American Chemical Society, Vol. 137, Issue 50
Monitoring the Solid-State Electrochemistry of Cu(2,7-AQDC) (AQDC = Anthraquinone Dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal–Organic Framework
journal, November 2014
- Zhang, Zhongyue; Yoshikawa, Hirofumi; Awaga, Kunio
- Journal of the American Chemical Society, Vol. 136, Issue 46
Fabrication of infinite two- and three-dimensional copper coordination polymers of chloranilic acid and its derivatives. Crystal structures and magnetic properties
journal, April 1995
- Kawata, S.; Kitagawa, S.; Kondo, M.
- Synthetic Metals, Vol. 71, Issue 1-3
Redox-active metal–organic frameworks as electrode materials for batteries
journal, November 2016
- Zhang, Zhongyue; Awaga, Kunio
- MRS Bulletin, Vol. 41, Issue 11
Fabrication of infinite two-dimensional sheets of tetragonal metal(II) lattices
journal, September 2002
- Kumagai, Hitoshi; Kawata, Satoshi; Kitagawa, Susumu
- Inorganica Chimica Acta, Vol. 337
Substituent effects on the redox potentials of dihydroxybenzenes: theoretical and experimental study
journal, November 2014
- Liu, Tao; Liu, Meng-Meng; Zheng, Xiao-Wen
- Tetrahedron, Vol. 70, Issue 47
Super-light Cu@Ni nanowires/graphene oxide composites for significantly enhanced microwave absorption performance
journal, May 2017
- Wang, Xiaoxia; Zhang, Baoqin; Zhang, Wei
- Scientific Reports, Vol. 7, Issue 1
Fabrication of infinite two- and three-dimensional copper coordination polymers of chloranilic acid and its derivatives. crystal structures and magnetic properties
conference, January 1994
- Kawata, S.; Kitagawa, S.; Kondo, M.
- International Conference on Science and Technology of Synthetic Metals
Works referencing / citing this record:
2D-metal–organic coordination polymers of lanthanides (La( iii ), Pr( iii ) and Nd( iii )) with redox-active dioxolene bridging ligands
journal, January 2020
- Kharitonov, Alexandr D.; Trofimova, Olesya Y.; Meshcheryakova, Irina N.
- CrystEngComm, Vol. 22, Issue 28