Crystalline Mesoporous Complex Oxides: Porosity-Controlled Electromagnetic Response
Abstract
Abstract A colloidal‐amphiphile‐templated growth is developed to synthesize mesoporous complex oxides with highly crystalline frameworks. Organosilane‐containing colloidal templates can convert into thermally stable silica that prevents the overgrowth of crystalline grains and the collapse of the mesoporosity. Using ilmenite CoTiO 3 as an example, the high crystallinity and the extraordinary thermal stability of its mesoporosity are demonstrated at 800 °C for 48 h under air. This synthetic approach is general and applicable to a series of complex oxides that are not reported with mesoporosity and high crystallinity, such as NiTiO 3 , FeTiO 3 , ZnTiO 3 , Co 2 TiO 4 , Zn 2 TiO 4 , MgTi 2 O 5 , and FeTi 2 O 5 . Those novel materials make it possible to build up correlations between mesoscale porosity and surface‐sensitive physicochemical properties, e.g., electromagnetic response. For mesoporous CoTiO 3 , there is a 3 K increase of its antiferromagnetic ordering temperature, compared with that of nonporous one. This finding provides a general guideline to design mesoporous complex oxides that allow exploring their unique properties different from bulk materials.
- Authors:
-
[1];
[4]
- Univ. of Connecticut, Storrs, CT (United States)
- Univ. of Connecticut, Storrs, CT (United States). Institute of Material Science
- Brown Univ., Providence, RI (United States)
- Univ. of Connecticut, Storrs, CT (United States). Institute of Materials Science
- Publication Date:
- Research Org.:
- Univ. of Connecticut, Storrs, CT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1775525
- Alternate Identifier(s):
- OSTI ID: 1599925
- Grant/Contract Number:
- FG02-86ER13622
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 30; Journal Issue: 15; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Jin, Lei, Su, Xingsong, Shi, Jianhang, Shih, Kuo‐Chih, Cintron, Daniel, Cai, Tong, Nieh, Mu‐Ping, Chen, Ou, Suib, Steven L., Jain, Menka, and He, Jie. Crystalline Mesoporous Complex Oxides: Porosity-Controlled Electromagnetic Response. United States: N. p., 2020.
Web. doi:10.1002/adfm.201909491.
Jin, Lei, Su, Xingsong, Shi, Jianhang, Shih, Kuo‐Chih, Cintron, Daniel, Cai, Tong, Nieh, Mu‐Ping, Chen, Ou, Suib, Steven L., Jain, Menka, & He, Jie. Crystalline Mesoporous Complex Oxides: Porosity-Controlled Electromagnetic Response. United States. https://doi.org/10.1002/adfm.201909491
Jin, Lei, Su, Xingsong, Shi, Jianhang, Shih, Kuo‐Chih, Cintron, Daniel, Cai, Tong, Nieh, Mu‐Ping, Chen, Ou, Suib, Steven L., Jain, Menka, and He, Jie. Sun .
"Crystalline Mesoporous Complex Oxides: Porosity-Controlled Electromagnetic Response". United States. https://doi.org/10.1002/adfm.201909491. https://www.osti.gov/servlets/purl/1775525.
@article{osti_1775525,
title = {Crystalline Mesoporous Complex Oxides: Porosity-Controlled Electromagnetic Response},
author = {Jin, Lei and Su, Xingsong and Shi, Jianhang and Shih, Kuo‐Chih and Cintron, Daniel and Cai, Tong and Nieh, Mu‐Ping and Chen, Ou and Suib, Steven L. and Jain, Menka and He, Jie},
abstractNote = {Abstract A colloidal‐amphiphile‐templated growth is developed to synthesize mesoporous complex oxides with highly crystalline frameworks. Organosilane‐containing colloidal templates can convert into thermally stable silica that prevents the overgrowth of crystalline grains and the collapse of the mesoporosity. Using ilmenite CoTiO 3 as an example, the high crystallinity and the extraordinary thermal stability of its mesoporosity are demonstrated at 800 °C for 48 h under air. This synthetic approach is general and applicable to a series of complex oxides that are not reported with mesoporosity and high crystallinity, such as NiTiO 3 , FeTiO 3 , ZnTiO 3 , Co 2 TiO 4 , Zn 2 TiO 4 , MgTi 2 O 5 , and FeTi 2 O 5 . Those novel materials make it possible to build up correlations between mesoscale porosity and surface‐sensitive physicochemical properties, e.g., electromagnetic response. For mesoporous CoTiO 3 , there is a 3 K increase of its antiferromagnetic ordering temperature, compared with that of nonporous one. This finding provides a general guideline to design mesoporous complex oxides that allow exploring their unique properties different from bulk materials.},
doi = {10.1002/adfm.201909491},
journal = {Advanced Functional Materials},
number = 15,
volume = 30,
place = {United States},
year = {Sun Feb 16 00:00:00 EST 2020},
month = {Sun Feb 16 00:00:00 EST 2020}
}
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