DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Cryogenic mechanical behaviors of CrMnFeCoNi high-entropy alloy

Abstract

The CrMnFeCoNi high-entropy alloy (HEA) exhibits higher yield strength, ultimate strength and ductility at lower temperature. To further clarify the effect of the testing temperature on microstructure evolution, in this study in-situ synchrotron-based high-energy X-ray diffraction tensile tests were carried out from 298 K down to 123 K. The enhanced yield strength of the alloy at cryogenic temperatures can be attributed to the greater lattice distortion prior to plastic deformation. Higher strain hardening rate leads to the simultaneously enhanced strength and ductility of the studied HEA below room temperature. Both dynamic Hall-Petch hardening (twinning) and dislocation hardening provide high work hardening capacity for this alloy during the plastic deformation at cryogenic temperatures. The increased dislocation density and nano-twins at cryogenic temperatures can be attributed to the decrease in the stacking fault energy as the deformation temperature decreases. These studies could provide an in-depth understanding for the strengthening mechanisms of the HEA in different temperature conditions and guide the exploration of HEAs with superb mechanical properties at cryogenic environments.

Authors:
 [1];  [2];  [1];  [3];  [1];  [1];  [4];  [1];  [1];  [1]
  1. Harbin Inst. of Technology (China)
  2. Xi'an Space Engine Company Limited (China)
  3. China Univ. of Petroleum, Beijing, (China)
  4. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC); National Natural Science Foundation of China (NSFC)
OSTI Identifier:
1774493
Grant/Contract Number:  
AC02-06CH11357; 51871076; 51671070; 51827801
Resource Type:
Accepted Manuscript
Journal Name:
Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing
Additional Journal Information:
Journal Volume: 789; Journal ID: ISSN 0921-5093
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; cryogenic temperature; high energy x-ray diffraction; high-entropy alloy; nano-twins; stacking faults

Citation Formats

Fu, Wujing, Zheng, Wei, Huang, Yongjiang, Guo, Fangmin, Jiang, Songshan, Xue, Peng, Ren, Yang, Fan, Hongbo, Ning, Zhiliang, and Sun, Jianfei. Cryogenic mechanical behaviors of CrMnFeCoNi high-entropy alloy. United States: N. p., 2020. Web. doi:10.1016/j.msea.2020.139579.
Fu, Wujing, Zheng, Wei, Huang, Yongjiang, Guo, Fangmin, Jiang, Songshan, Xue, Peng, Ren, Yang, Fan, Hongbo, Ning, Zhiliang, & Sun, Jianfei. Cryogenic mechanical behaviors of CrMnFeCoNi high-entropy alloy. United States. https://doi.org/10.1016/j.msea.2020.139579
Fu, Wujing, Zheng, Wei, Huang, Yongjiang, Guo, Fangmin, Jiang, Songshan, Xue, Peng, Ren, Yang, Fan, Hongbo, Ning, Zhiliang, and Sun, Jianfei. Fri . "Cryogenic mechanical behaviors of CrMnFeCoNi high-entropy alloy". United States. https://doi.org/10.1016/j.msea.2020.139579. https://www.osti.gov/servlets/purl/1774493.
@article{osti_1774493,
title = {Cryogenic mechanical behaviors of CrMnFeCoNi high-entropy alloy},
author = {Fu, Wujing and Zheng, Wei and Huang, Yongjiang and Guo, Fangmin and Jiang, Songshan and Xue, Peng and Ren, Yang and Fan, Hongbo and Ning, Zhiliang and Sun, Jianfei},
abstractNote = {The CrMnFeCoNi high-entropy alloy (HEA) exhibits higher yield strength, ultimate strength and ductility at lower temperature. To further clarify the effect of the testing temperature on microstructure evolution, in this study in-situ synchrotron-based high-energy X-ray diffraction tensile tests were carried out from 298 K down to 123 K. The enhanced yield strength of the alloy at cryogenic temperatures can be attributed to the greater lattice distortion prior to plastic deformation. Higher strain hardening rate leads to the simultaneously enhanced strength and ductility of the studied HEA below room temperature. Both dynamic Hall-Petch hardening (twinning) and dislocation hardening provide high work hardening capacity for this alloy during the plastic deformation at cryogenic temperatures. The increased dislocation density and nano-twins at cryogenic temperatures can be attributed to the decrease in the stacking fault energy as the deformation temperature decreases. These studies could provide an in-depth understanding for the strengthening mechanisms of the HEA in different temperature conditions and guide the exploration of HEAs with superb mechanical properties at cryogenic environments.},
doi = {10.1016/j.msea.2020.139579},
journal = {Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing},
number = ,
volume = 789,
place = {United States},
year = {Fri May 29 00:00:00 EDT 2020},
month = {Fri May 29 00:00:00 EDT 2020}
}

Works referenced in this record:

Stacking fault energy in austenitic steels determined by using in situ X-ray diffraction during bending
journal, May 2014

  • Rafaja, D.; Krbetschek, C.; Ullrich, C.
  • Journal of Applied Crystallography, Vol. 47, Issue 3
  • DOI: 10.1107/S1600576714007109

Effect of stacking fault energy on mechanical behavior of bulk nanocrystalline Cu and Cu alloys
journal, August 2011


Cooperative deformation in high-entropy alloys at ultralow temperatures
journal, March 2020


Mechanical properties and deformation twinning behavior of as-cast CoCrFeMnNi high-entropy alloy at low and high temperatures
journal, January 2018


Temperature dependent stacking fault energy of FeCrCoNiMn high entropy alloy
journal, November 2015


Ductile-brittle transition of carbon alloyed Fe40Mn40Co10Cr10 high entropy alloys
journal, February 2019


In-situ neutron diffraction study of deformation behavior of a multi-component high-entropy alloy
journal, February 2014

  • Wu, Y.; Liu, W. H.; Wang, X. L.
  • Applied Physics Letters, Vol. 104, Issue 5
  • DOI: 10.1063/1.4863748

Tensile properties of high- and medium-entropy alloys
journal, August 2013


Transformation-enhanced strength and ductility in a FeCoCrNiMn dual phase high-entropy alloy
journal, April 2020


Microstructural development in equiatomic multicomponent alloys
journal, July 2004


High temperature deformation behavior of carbon-containing FeCoCrNiMn high entropy alloy
journal, May 2018


Refractory high-entropy alloys
journal, September 2010


The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy
journal, September 2013


Processing two-dimensional X-ray diffraction and small-angle scattering data in DAWN 2
journal, May 2017

  • Filik, J.; Ashton, A. W.; Chang, P. C. Y.
  • Journal of Applied Crystallography, Vol. 50, Issue 3
  • DOI: 10.1107/S1600576717004708

First In Situ Lattice Strains Measurements Under Load at VULCAN
journal, October 2010

  • An, Ke; Skorpenske, Harley D.; Stoica, Alexandru D.
  • Metallurgical and Materials Transactions A, Vol. 42, Issue 1
  • DOI: 10.1007/s11661-010-0495-9

Sluggish diffusion in Co–Cr–Fe–Mn–Ni high-entropy alloys
journal, August 2013


Deformation mechanisms of Mo alloyed FeCoCrNi high entropy alloy: In situ neutron diffraction
journal, April 2017


Microstructures and properties of high-entropy alloys
journal, April 2014


High-Entropy Alloys: A Critical Review
journal, April 2014


The fcc solid solution stability in the Co-Cr-Fe-Mn-Ni multi-component system
journal, April 2017


Densities and character of dislocations and size-distribution of subgrains in deformed metals by X-ray diffraction profile analysis
journal, December 2001


Mechanical Properties and Stacking Fault Energies of NiFeCrCoMn High-Entropy Alloy
journal, October 2013


Abnormal temperature dependence of impact toughness in Al CoCrFeNi system high entropy alloys
journal, May 2018


Recrystallization and phase transitions in a γ-TiAl-based alloy as observed by ex situ and in situ high-energy X-ray diffraction
journal, August 2006


Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off
journal, May 2016

  • Li, Zhiming; Pradeep, Konda Gokuldoss; Deng, Yun
  • Nature, Vol. 534, Issue 7606
  • DOI: 10.1038/nature17981

The effect of dislocation contrast on x‐ray line broadening: A new approach to line profile analysis
journal, November 1996

  • Ungár, T.; Borbély, A.
  • Applied Physics Letters, Vol. 69, Issue 21
  • DOI: 10.1063/1.117951

Data Analysis WorkbeNch ( DAWN )
journal, April 2015

  • Basham, Mark; Filik, Jacob; Wharmby, Michael T.
  • Journal of Synchrotron Radiation, Vol. 22, Issue 3
  • DOI: 10.1107/S1600577515002283

Effect of grain size on fatigue cracking at twin boundaries in a CoCrFeMnNi high-entropy alloy
journal, February 2020


A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014


Single‐ and Double‐Deformation Faults in Face‐Centered Cubic Crystals
journal, July 1963


Voigt-function modeling in Fourier analysis of size- and strain-broadened X-ray diffraction peaks
journal, February 1993


The contrast factors of dislocations in cubic crystals: the dislocation model of strain anisotropy in practice
journal, October 1999

  • Ungár, T.; Dragomir, I.; Révész, Á.
  • Journal of Applied Crystallography, Vol. 32, Issue 5
  • DOI: 10.1107/S0021889899009334

In situ neutron diffraction study on temperature dependent deformation mechanisms of ultrafine grained austenitic Fe–14Cr–16Ni alloy
journal, February 2014


EXPGUI , a graphical user interface for GSAS
journal, April 2001


Dislocation density evolution of AA 7020-T6 investigated by in-situ synchrotron diffraction under tensile load
journal, October 2015


Inter- and intragranular stresses in cyclically-deformed 316 stainless steel
journal, June 2005

  • Wang, X. -L.; Wang, Y. D.; Stoica, A. D.
  • Materials Science and Engineering: A, Vol. 399, Issue 1-2
  • DOI: 10.1016/j.msea.2005.02.030

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004

  • Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
  • Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
  • DOI: 10.1002/adem.200300567

A critical review of high entropy alloys and related concepts
journal, January 2017


The influence of strain rate, deformation temperature and stacking fault energy on the mechanical properties of Cu alloys
journal, October 2013


Microstructure and mechanical properties of Fe CoCrNiMn high-entropy alloys
journal, October 2019


Stacking faults in face-centred cubic metals and alloys
journal, May 1957


Relationship between stacking‐fault energy and x‐ray measurements of stacking‐fault probability and microstrain
journal, November 1974

  • Reed, R. P.; Schramm, R. E.
  • Journal of Applied Physics, Vol. 45, Issue 11
  • DOI: 10.1063/1.1663122

On the strain rate-dependent deformation mechanism of CoCrFeMnNi high-entropy alloy at liquid nitrogen temperature
journal, May 2017


Stacking fault energy of face-centered-cubic high entropy alloys
journal, February 2018


Use of Rietveld refinement for elastic macrostrain determination and for evaluation of plastic strain history from diffraction spectra
journal, August 1997

  • Daymond, M. R.; Bourke, M. A. M.; Von Dreele, R. B.
  • Journal of Applied Physics, Vol. 82, Issue 4
  • DOI: 10.1063/1.365956

In-situ neutron diffraction studies on high-temperature deformation behavior in a CoCrFeMnNi high entropy alloy
journal, July 2015


Cryogenic-deformation-induced phase transformation in an FeCoCrNi high-entropy alloy
journal, February 2018


Competition between slip and twinning in face-centered cubic metals
journal, October 2014

  • Cai, T.; Zhang, Z. J.; Zhang, P.
  • Journal of Applied Physics, Vol. 116, Issue 16
  • DOI: 10.1063/1.4898319

Microstructure evolution and critical stress for twinning in the CrMnFeCoNi high-entropy alloy
journal, October 2016