Monolayer and Bilayer Perfluoropentacene on Cu(111)

Smalley, S.; Darancet, P.; Guest, J. R.; Smerdon, J. A.

doi:10.1021/acs.jpcc.9b09670

Title: Monolayer and Bilayer Perfluoropentacene on Cu(111)

Journal Article · 17 December 2019 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.9b09670 · OSTI ID:1774347

Smalley, S. ^[1];

^[2];

^[1]

University of Central Lancashire, Preston (United Kingdom)
Argonne National Lab. (ANL), Argonne, IL (United States)

Perfluoropentacene (PFP), an n-type organic semiconductor, is deposited at monolayer and bilayer coverages on Cu(111). Scanning tunneling microscopy at various bias voltages is used to investigate the geometric and electronic structures of the layer. The appearances of the first layer and second layer differ, likely due to perturbation of the first layer electronic structure by the substrate. This has been previously observed for pentacene (Pn), the isostructural p-type organic semiconductor. The PFP film has a unit cell of (4, -3,3 4) relative to the substrate, which is larger than that of Pn/Cu(111), representing a half-integer increment in each direction.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; Royal Society United Kingdom

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1774347

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 1 Vol. 124; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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