Tetraarylborate polymer networks as single-ion conducting solid electrolytes
Abstract
A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. Sonogashira polymerizations using tetrakis(4-iodophenyl)borate, tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl)borate and tetrakis(4-bromo-2,3,5,6-tetrafluorophenyl)borate delivered highly cross-linked polymer networks with both 1,4-diethynylbeznene and a tri(ethylene glycol) substituted derivative. Promising initial conductivity metrics have been observed, including high room temperature conductivities (up to 2.7 × 10-4 S cm-1), moderate activation energies (0.25–0.28 eV), and high lithium ion transport numbers (up to tLi+ = 0.93). Initial investigations into the effects of important materials parameters such as bulk morphology, porosity, fluorination, and other chemical modification, provide starting design parameters for further development of this new class of solid electrolytes.
- Authors:
-
[4];
- Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA 02139
- Department of Chemistry, University of California, Berkeley, USA 94720-1462
- Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, USA 14853-1301
- Centre for Surface Chemistry and Catalysis, University of Leuven, 3001 Leuven, Belgium
- Department of Chemistry, University of California, Berkeley, USA 94720-1462, Division of Materials Sciences
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1771814
- Alternate Identifier(s):
- OSTI ID: 1214440
- Grant/Contract Number:
- SC0001015; unassigned; CHE-1413862
- Resource Type:
- Published Article
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Name: Chemical Science Journal Volume: 6 Journal Issue: 10; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Van Humbeck, Jeffrey F., Aubrey, Michael L., Alsbaiee, Alaaeddin, Ameloot, Rob, Coates, Geoffrey W., Dichtel, William R., and Long, Jeffrey R. Tetraarylborate polymer networks as single-ion conducting solid electrolytes. United Kingdom: N. p., 2015.
Web. doi:10.1039/C5SC02052B.
Van Humbeck, Jeffrey F., Aubrey, Michael L., Alsbaiee, Alaaeddin, Ameloot, Rob, Coates, Geoffrey W., Dichtel, William R., & Long, Jeffrey R. Tetraarylborate polymer networks as single-ion conducting solid electrolytes. United Kingdom. https://doi.org/10.1039/C5SC02052B
Van Humbeck, Jeffrey F., Aubrey, Michael L., Alsbaiee, Alaaeddin, Ameloot, Rob, Coates, Geoffrey W., Dichtel, William R., and Long, Jeffrey R. Mon .
"Tetraarylborate polymer networks as single-ion conducting solid electrolytes". United Kingdom. https://doi.org/10.1039/C5SC02052B.
@article{osti_1771814,
title = {Tetraarylborate polymer networks as single-ion conducting solid electrolytes},
author = {Van Humbeck, Jeffrey F. and Aubrey, Michael L. and Alsbaiee, Alaaeddin and Ameloot, Rob and Coates, Geoffrey W. and Dichtel, William R. and Long, Jeffrey R.},
abstractNote = {A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. Sonogashira polymerizations using tetrakis(4-iodophenyl)borate, tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl)borate and tetrakis(4-bromo-2,3,5,6-tetrafluorophenyl)borate delivered highly cross-linked polymer networks with both 1,4-diethynylbeznene and a tri(ethylene glycol) substituted derivative. Promising initial conductivity metrics have been observed, including high room temperature conductivities (up to 2.7 × 10-4 S cm-1), moderate activation energies (0.25–0.28 eV), and high lithium ion transport numbers (up to tLi+ = 0.93). Initial investigations into the effects of important materials parameters such as bulk morphology, porosity, fluorination, and other chemical modification, provide starting design parameters for further development of this new class of solid electrolytes.},
doi = {10.1039/C5SC02052B},
journal = {Chemical Science},
number = 10,
volume = 6,
place = {United Kingdom},
year = {Mon Sep 14 00:00:00 EDT 2015},
month = {Mon Sep 14 00:00:00 EDT 2015}
}
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