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Title: Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys

Abstract

The microstructures, mechanical, corrosion, and wear behaviors of the TixZrNbTaMo (x = 0.5, 1, 1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied in this work. It was found that the Ti–Zr–Nb–Ta–Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti0.5ZrNbTaMo HEA exhibited a high hardness of about 500 HV, high compressive strength approaching 2,600 MPa, and large plastic strain of over 30%. Furthermore, the highly-protective oxide films formed on the surface of Ti–Zr–Nb–Ta–Mo HEAs in the phosphate buffer saline (PBS) solution, which resulted in the high corrosion resistance of the HEAs. The Ti–Zr–Nb–Ta–Mo HEAs exhibited the greater dry- and wet-wear resistance than that of the traditional biomedical Ti6Al4V alloy. The results also indicated that with the decrease in the Ti content, the wear resistance of the Ti–Zr–Nb–Ta–Mo HEAs in the PBS solution improved. Finally, the Ti0.5ZrNbTaMo alloy presented the highest corrosive wear resistance among the four HEAs owing to its combination of good mechanical properties and high chemical stability.

Authors:
 [1];  [1];  [1];  [2];  [1];  [1];  [1];  [2];  [2]
  1. Fujian Univ. of Technology, Fuzhou (China)
  2. Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE; National Natural Science Foundation of China (NNSFC); Natural Science Foundation of Fujian Province; New Century Excellent Talents in University of Fujian Province; National Science Foundation (NSF); US Army Research Office (ARO)
OSTI Identifier:
1769231
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Alloys and Compounds
Additional Journal Information:
Journal Volume: 861; Journal Issue: 1; Journal ID: ISSN 0925-8388
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; High entropy alloys; Wear; Corrosive wear; Polarization; Mechanical properties

Citation Formats

Hua, Nengbin, Wang, Wenjie, Wang, Qianting, Ye, Youxiong, Lin, Sihan, Zhang, Lei, Guo, Qiaohang, Brechtl, Jamieson, and Liaw, Peter K. Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys. United States: N. p., 2021. Web. doi:10.1016/j.jallcom.2020.157997.
Hua, Nengbin, Wang, Wenjie, Wang, Qianting, Ye, Youxiong, Lin, Sihan, Zhang, Lei, Guo, Qiaohang, Brechtl, Jamieson, & Liaw, Peter K. Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys. United States. https://doi.org/10.1016/j.jallcom.2020.157997
Hua, Nengbin, Wang, Wenjie, Wang, Qianting, Ye, Youxiong, Lin, Sihan, Zhang, Lei, Guo, Qiaohang, Brechtl, Jamieson, and Liaw, Peter K. Sun . "Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys". United States. https://doi.org/10.1016/j.jallcom.2020.157997.
@article{osti_1769231,
title = {Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys},
author = {Hua, Nengbin and Wang, Wenjie and Wang, Qianting and Ye, Youxiong and Lin, Sihan and Zhang, Lei and Guo, Qiaohang and Brechtl, Jamieson and Liaw, Peter K.},
abstractNote = {The microstructures, mechanical, corrosion, and wear behaviors of the TixZrNbTaMo (x = 0.5, 1, 1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied in this work. It was found that the Ti–Zr–Nb–Ta–Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti0.5ZrNbTaMo HEA exhibited a high hardness of about 500 HV, high compressive strength approaching 2,600 MPa, and large plastic strain of over 30%. Furthermore, the highly-protective oxide films formed on the surface of Ti–Zr–Nb–Ta–Mo HEAs in the phosphate buffer saline (PBS) solution, which resulted in the high corrosion resistance of the HEAs. The Ti–Zr–Nb–Ta–Mo HEAs exhibited the greater dry- and wet-wear resistance than that of the traditional biomedical Ti6Al4V alloy. The results also indicated that with the decrease in the Ti content, the wear resistance of the Ti–Zr–Nb–Ta–Mo HEAs in the PBS solution improved. Finally, the Ti0.5ZrNbTaMo alloy presented the highest corrosive wear resistance among the four HEAs owing to its combination of good mechanical properties and high chemical stability.},
doi = {10.1016/j.jallcom.2020.157997},
journal = {Journal of Alloys and Compounds},
number = 1,
volume = 861,
place = {United States},
year = {2021},
month = {11}
}

Journal Article:
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Works referenced in this record:

Tribo-electrochemical characterization of metallic biomaterials for total joint replacement
journal, February 2012


Effects of environmental temperature and sliding speed on the tribological behaviour of a Ti-based metallic glass
journal, September 2014


Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes
journal, November 2018


Corrosion-Resistant High-Entropy Alloys: A Review
journal, February 2017


Wear Characteristics of Metallic Biomaterials: A Review
journal, May 2015

  • Hussein, Mohamed; Mohammed, Abdul; Al-Aqeeli, Naser
  • Materials, Vol. 8, Issue 5
  • DOI: 10.3390/ma8052749

Microstructure and tribological properties of TiTaHfNbZr high entropy alloy coatings deposited on Ti 6Al 4V substrates
journal, February 2019


Novel TiNbTaZrMo high-entropy alloys for metallic biomaterials
journal, March 2017


Metallic implant biomaterials
journal, January 2015


Enhanced mechanical properties of HfMoTaTiZr and HfMoNbTaTiZr refractory high-entropy alloys
journal, July 2015


Electrochemical properties, chemical composition and thickness of passive film formed on novel Ti–20Nb–10Zr–5Ta alloy
journal, June 2013


Wear and corrosion behaviour of Ti–13Nb–13Zr and Ti–6Al–4V alloys in simulated physiological solution
journal, February 2011


Formation, structure and properties of biocompatible TiZrHfNbTa high-entropy alloys
journal, March 2019


New Ti-based Ti–Cu–Zr–Fe–Sn–Si–Ag bulk metallic glass for biomedical applications
journal, March 2015


Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy
journal, May 2011


Fundamental electronic structure and multiatomic bonding in 13 biocompatible high-entropy alloys
journal, May 2020


Tribological behaviors of a Ni-free Ti-based bulk metallic glass in air and a simulated physiological environment
journal, October 2018


Corrosion behavior of Hf0.5Nb0.5Ta0.5Ti1.5Zr refractory high-entropy in aqueous chloride solutions
journal, January 2019


Phase stability and transformation in a light-weight high-entropy alloy
journal, March 2018


Microstructure and mechanical properties of refractory MoNbHfZrTi high-entropy alloy
journal, September 2015


The corrosion/wear mechanisms of Ti–6Al–4V alloy for different scratching rates
journal, September 2007


High-entropy alloys
journal, June 2019


TiZrNbTaMo high-entropy alloy designed for orthopedic implants: As-cast microstructure and mechanical properties
journal, April 2017


Wear behavior of high entropy alloys containing soft dispersoids (Pb, Bi)
journal, May 2018


Ti based biomaterials, the ultimate choice for orthopaedic implants – A review
journal, May 2009


Ultrafine composite microstructure in a bulk Ti alloy for high strength, strain hardening and tensile ductility
journal, March 2006


Tribo-corrosion properties of cobalt-based medical implant alloys in simulated biological environments
journal, September 2007


A novel quaternary equiatomic Ti-Zr-Nb-Ta medium entropy alloy (MEA)
journal, October 2018


Review on the Research and Development of Ti-Based Bulk Metallic Glasses
journal, November 2016


Tribological properties of Ti40Zr25Ni8Cu9Be18 bulk metallic glasses under different conditions
journal, September 2011


A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014


Corrosion-wear of β-Ti alloy TMZF (Ti-12Mo-6Zr-2Fe) in simulated body fluid
journal, September 2016


Microstructure and wear properties of nitrided AlCoCrFeNi high-entropy alloy
journal, May 2018


An assessment on the future development of high-entropy alloys: Summary from a recent workshop
journal, November 2015


Wear-Corrosion Synergism in a CoCrMo Hip Bearing Alloy Is Influenced by Proteins
journal, January 2012

  • Mathew, Mathew T.; Jacobs, Joshua J.; Wimmer, Markus A.
  • Clinical Orthopaedics & Related Research, Vol. 470, Issue 11
  • DOI: 10.1007/s11999-012-2563-5

A refractory Hf25Nb25Ti25Zr25 high-entropy alloy with excellent structural stability and tensile properties
journal, September 2014


Contact and Rubbing of Flat Surfaces
journal, August 1953


Microabrasion–corrosion of cast CoCrMo alloy in simulated body fluids
journal, January 2009


Bimodal structured Ti-base alloy with large elasticity and low Young's modulus
journal, May 2005


Mechanical, corrosion, and wear performances of a biocompatible Ti-based glassy alloy
journal, September 2020


Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004

  • Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
  • Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
  • DOI: 10.1002/adem.200300567

Microstructural origins of high strength and high ductility in an AlCoCrFeNi2.1 eutectic high-entropy alloy
journal, December 2017


A critical review of high entropy alloys and related concepts
journal, January 2017


Cytotoxicity evaluation of 43 metal salts using murine fibroblasts and osteoblastic cells
journal, February 1998


Corrosive wear behaviors and mechanisms of a biocompatible Fe-based bulk metallic glass
journal, August 2020


Biomedical materials and techniques to improve the tribological, mechanical and biomedical properties of orthopedic implants – A review article
journal, August 2017


The role of fracture toughness in the wear of metals
journal, July 1975


Microstructural features and dry - Sliding wear response of MoTaNbZrTi high entropy alloy
journal, May 2018


Reciprocating sliding wear behavior of high entropy alloys in dry and marine environments
journal, May 2018


Tribocorrosion behaviors of a biodegradable Mg65Zn30Ca5 bulk metallic glass for potential biomedical implant applications
journal, May 2018


Dry sliding and tribocorrosion behaviour of hot pressed CoCrMo biomedical alloy as compared with the cast CoCrMo and Ti6Al4V alloys
journal, December 2013


Correlations between the wear resistance and properties of bulk metallic glasses
journal, February 2018


Bio-corrosion behavior and in vitro biocompatibility of equimolar TiZrHfNbTa high-entropy alloy
journal, September 2020