Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys

Hua, Nengbin; Wang, Wenjie; Wang, Qianting; Ye, Youxiong; Lin, Sihan; Zhang, Lei; Guo, Qiaohang; Brechtl, Jamieson; Liaw, Peter K.

doi:10.1016/j.jallcom.2020.157997

Title: Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys

Journal Article · 20 November 2021 · Journal of Alloys and Compounds

DOI: https://doi.org/10.1016/j.jallcom.2020.157997 · OSTI ID:1769231

Hua, Nengbin ^[1]; Wang, Wenjie ^[1]; Wang, Qianting ^[1]; Ye, Youxiong ^[2]; Lin, Sihan ^[1]; Zhang, Lei ^[1]; Guo, Qiaohang ^[1]; Brechtl, Jamieson ^[2]; Liaw, Peter K. ^[2]

Fujian Univ. of Technology, Fuzhou (China)
Univ. of Tennessee, Knoxville, TN (United States)

The microstructures, mechanical, corrosion, and wear behaviors of the Ti_xZrNbTaMo (x = 0.5, 1, 1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied in this work. It was found that the Ti–Zr–Nb–Ta–Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti_0.5ZrNbTaMo HEA exhibited a high hardness of about 500 HV, high compressive strength approaching 2,600 MPa, and large plastic strain of over 30%. Furthermore, the highly-protective oxide films formed on the surface of Ti–Zr–Nb–Ta–Mo HEAs in the phosphate buffer saline (PBS) solution, which resulted in the high corrosion resistance of the HEAs. The Ti–Zr–Nb–Ta–Mo HEAs exhibited the greater dry- and wet-wear resistance than that of the traditional biomedical Ti6Al4V alloy. The results also indicated that with the decrease in the Ti content, the wear resistance of the Ti–Zr–Nb–Ta–Mo HEAs in the PBS solution improved. Finally, the Ti_0.5ZrNbTaMo alloy presented the highest corrosive wear resistance among the four HEAs owing to its combination of good mechanical properties and high chemical stability.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; National Natural Science Foundation of China (NSFC); Natural Science Foundation of Fujian Province; New Century Excellent Talents in University of Fujian Province; National Science Foundation (NSF); US Army Research Office (ARO)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1769231

Journal Information:: Journal of Alloys and Compounds, Journal Name: Journal of Alloys and Compounds Journal Issue: 1 Vol. 861; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (62)

Enhanced mechanical properties of HfMoTaTiZr and HfMoNbTaTiZr refractory high-entropy alloys Juan, Chien-Chang; Tsai, Ming-Hung; Tsai, Che-Wei Intermetallics, Vol. 62 https://doi.org/10.1016/j.intermet.2015.03.013	journal	July 2015
Correlations between the wear resistance and properties of bulk metallic glasses Liao, Zhenlong; Hua, Nengbin; Chen, Wenzhe Intermetallics, Vol. 93 https://doi.org/10.1016/j.intermet.2017.10.008	journal	February 2018
Corrosion-wear of β-Ti alloy TMZF (Ti-12Mo-6Zr-2Fe) in simulated body fluid Yang, Xueyuan; Hutchinson, Christopher R. Acta Biomaterialia, Vol. 42 https://doi.org/10.1016/j.actbio.2016.07.008	journal	September 2016
Phase stability and transformation in a light-weight high-entropy alloy Feng, Rui; Gao, Michael C.; Zhang, Chuan Acta Materialia, Vol. 146 https://doi.org/10.1016/j.actamat.2017.12.061	journal	March 2018
Tribological properties of Ti40Zr25Ni8Cu9Be18 bulk metallic glasses under different conditions Duan, H. T.; Tu, J. S.; Du, S. M. Materials & Design, Vol. 32, Issue 8-9 https://doi.org/10.1016/j.matdes.2011.04.018	journal	September 2011
Review on the Research and Development of Ti-Based Bulk Metallic Glasses Gong, Pan; Deng, Lei; Jin, Junsong Metals, Vol. 6, Issue 11 https://doi.org/10.3390/met6110264	journal	November 2016
Corrosion-Resistant High-Entropy Alloys: A Review Shi, Yunzhu; Yang, Bin; Liaw, Peter Metals, Vol. 7, Issue 2 https://doi.org/10.3390/met7020043	journal	February 2017
Long-term corrosion resistance of new Ti–Ta–Zr alloy in simulated physiological fluids by electrochemical and surface analysis methods Vasilescu, C.; Drob, S. I.; Calderon Moreno, J. M. Corrosion Science, Vol. 93 https://doi.org/10.1016/j.corsci.2015.01.038	journal	April 2015
A refractory Hf25Nb25Ti25Zr25 high-entropy alloy with excellent structural stability and tensile properties Wu, Y. D.; Cai, Y. H.; Wang, T. Materials Letters, Vol. 130 https://doi.org/10.1016/j.matlet.2014.05.134	journal	September 2014
Microstructural, mechanical and electrochemical characterization of TiZrTaHfNb and Ti1.5ZrTa0.5Hf0.5Nb0.5 refractory high-entropy alloys for biomedical applications Motallebzadeh, Amir; Peighambardoust, Naeimeh Sadat; Sheikh, Saad Intermetallics, Vol. 113 https://doi.org/10.1016/j.intermet.2019.106572	journal	October 2019
Composition dependence of the microstructure and the mechanical properties of nano/ultrafine-structured Ti–Cu–Ni–Sn–Nb alloys He, G.; Eckert, J.; Löser, W. Acta Materialia, Vol. 52, Issue 10 https://doi.org/10.1016/j.actamat.2004.03.006	journal	June 2004
Metallic implant biomaterials Chen, Qizhi; Thouas, George A. Materials Science and Engineering: R: Reports, Vol. 87 https://doi.org/10.1016/j.mser.2014.10.001	journal	January 2015
Contact and Rubbing of Flat Surfaces Archard, J. F. Journal of Applied Physics, Vol. 24, Issue 8 https://doi.org/10.1063/1.1721448	journal	August 1953
Wear-Corrosion Synergism in a CoCrMo Hip Bearing Alloy Is Influenced by Proteins Mathew, Mathew T.; Jacobs, Joshua J.; Wimmer, Markus A. Clinical Orthopaedics & Related Research, Vol. 470, Issue 11 https://doi.org/10.1007/s11999-012-2563-5	journal	January 2012
Microabrasion–corrosion of cast CoCrMo alloy in simulated body fluids Sun, D.; Wharton, J. A.; Wood, R. J. K. Tribology International, Vol. 42, Issue 1 https://doi.org/10.1016/j.triboint.2008.05.005	journal	January 2009
Wear Characteristics of Metallic Biomaterials: A Review Hussein, Mohamed; Mohammed, Abdul; Al-Aqeeli, Naser Materials, Vol. 8, Issue 5 https://doi.org/10.3390/ma8052749	journal	May 2015
Effects of noble elements on the glass-forming ability, mechanical property, electrochemical behavior and tribocorrosion resistance of Ni- and Cu-free Zr-Al-Co bulk metallic glass Hua, Nengbin; Liao, Zhenlong; Chen, Wenzhe Journal of Alloys and Compounds, Vol. 725 https://doi.org/10.1016/j.jallcom.2017.07.167	journal	November 2017
Mechanical, corrosion, and wear performances of a biocompatible Ti-based glassy alloy Hua, Nengbin; Hong, Xiaoshi; Lin, Liyuan Journal of Non-Crystalline Solids, Vol. 543 https://doi.org/10.1016/j.jnoncrysol.2020.120116	journal	September 2020
Probing deformation mechanisms of a FeCoCrNi high-entropy alloy at 293 and 77 K using in situ neutron diffraction Wang, Yiqiang; Liu, Bin; Yan, Kun Acta Materialia, Vol. 154 https://doi.org/10.1016/j.actamat.2018.05.013	journal	August 2018
Fundamental electronic structure and multiatomic bonding in 13 biocompatible high-entropy alloys Ching, Wai-Yim; San, Saro; Brechtl, Jamieson npj Computational Materials, Vol. 6, Issue 1 https://doi.org/10.1038/s41524-020-0321-x	journal	May 2020
New Ti-based Ti–Cu–Zr–Fe–Sn–Si–Ag bulk metallic glass for biomedical applications Pang, Shujie; Liu, Ying; Li, Haifei Journal of Alloys and Compounds, Vol. 625 https://doi.org/10.1016/j.jallcom.2014.07.021	journal	March 2015
Effects of environmental temperature and sliding speed on the tribological behaviour of a Ti-based metallic glass Rahaman, M. L.; Zhang, L. C.; Ruan, H. H. Intermetallics, Vol. 52 https://doi.org/10.1016/j.intermet.2014.03.011	journal	September 2014
Corrosion behavior of Hf0.5Nb0.5Ta0.5Ti1.5Zr refractory high-entropy in aqueous chloride solutions Zhou, Qiongyu; Sheikh, Saad; Ou, Ping Electrochemistry Communications, Vol. 98 https://doi.org/10.1016/j.elecom.2018.11.009	journal	January 2019
Reciprocating sliding wear behavior of high entropy alloys in dry and marine environments Ayyagari, Aditya; Barthelemy, Chloe; Gwalani, Bharat Materials Chemistry and Physics, Vol. 210 https://doi.org/10.1016/j.matchemphys.2017.07.031	journal	May 2018
Fretting-corrosion between 316L SS and PMMA: Influence of ionic strength, protein and electrochemical conditions on material wear. Application to orthopaedic implants Pellier, J.; Geringer, J.; Forest, B. Wear, Vol. 271, Issue 9-10 https://doi.org/10.1016/j.wear.2011.01.082	journal	July 2011
Dry sliding and tribocorrosion behaviour of hot pressed CoCrMo biomedical alloy as compared with the cast CoCrMo and Ti6Al4V alloys Doni, Z.; Alves, A. C.; Toptan, F. Materials & Design (1980-2015), Vol. 52 https://doi.org/10.1016/j.matdes.2013.05.032	journal	December 2013
Microstructural origins of high strength and high ductility in an AlCoCrFeNi2.1 eutectic high-entropy alloy Gao, Xuzhou; Lu, Yiping; Zhang, Bo Acta Materialia, Vol. 141 https://doi.org/10.1016/j.actamat.2017.07.041	journal	December 2017
A novel quaternary equiatomic Ti-Zr-Nb-Ta medium entropy alloy (MEA) Nguyen, V. T.; Qian, M.; Shi, Z. Intermetallics, Vol. 101 https://doi.org/10.1016/j.intermet.2018.07.008	journal	October 2018
Ti based biomaterials, the ultimate choice for orthopaedic implants – A review Geetha, M.; Singh, A. K.; Asokamani, R. Progress in Materials Science, Vol. 54, Issue 3 https://doi.org/10.1016/j.pmatsci.2008.06.004	journal	May 2009
Microstructure and wear properties of nitrided AlCoCrFeNi high-entropy alloy Wang, Yongxiang; Yang, Yaojun; Yang, Huijun Materials Chemistry and Physics, Vol. 210 https://doi.org/10.1016/j.matchemphys.2017.05.029	journal	May 2018
Formation, structure and properties of biocompatible TiZrHfNbTa high-entropy alloys Yuan, Yuan; Wu, Yuan; Yang, Zhi Materials Research Letters, Vol. 7, Issue 6 https://doi.org/10.1080/21663831.2019.1584592	journal	March 2019
The role of fracture toughness in the wear of metals Hornbogen, E. Wear, Vol. 33, Issue 2 https://doi.org/10.1016/0043-1648(75)90280-X	journal	July 1975
Novel TiNbTaZrMo high-entropy alloys for metallic biomaterials Todai, Mitsuharu; Nagase, Takeshi; Hori, Takao Scripta Materialia, Vol. 129 https://doi.org/10.1016/j.scriptamat.2016.10.028	journal	March 2017
Electrochemical properties, chemical composition and thickness of passive film formed on novel Ti–20Nb–10Zr–5Ta alloy Milošev, Ingrid; Žerjav, Gregor; Calderon Moreno, Jose Maria Electrochimica Acta, Vol. 99 https://doi.org/10.1016/j.electacta.2013.03.086	journal	June 2013
A fracture-resistant high-entropy alloy for cryogenic applications Gludovatz, B.; Hohenwarter, A.; Catoor, D. Science, Vol. 345, Issue 6201 https://doi.org/10.1126/science.1254581	journal	September 2014
Corrosive wear behaviors and mechanisms of a biocompatible Fe-based bulk metallic glass Hua, Nengbin; Hong, Xiaoshi; Liao, Zhenlong Journal of Non-Crystalline Solids, Vol. 542 https://doi.org/10.1016/j.jnoncrysol.2020.120088	journal	August 2020
High-entropy alloys George, Easo P.; Raabe, Dierk; Ritchie, Robert O. Nature Reviews Materials, Vol. 4, Issue 8 https://doi.org/10.1038/s41578-019-0121-4	journal	June 2019
Tribocorrosion behaviors of a biodegradable Mg65Zn30Ca5 bulk metallic glass for potential biomedical implant applications Hua, Nengbin; Chen, Wenzhe; Wang, Qianting Journal of Alloys and Compounds, Vol. 745 https://doi.org/10.1016/j.jallcom.2018.02.138	journal	May 2018
Tribo-corrosion properties of cobalt-based medical implant alloys in simulated biological environments Yan, Yu; Neville, Anne; Dowson, Duncan Wear, Vol. 263, Issue 7-12 https://doi.org/10.1016/j.wear.2007.01.114	journal	September 2007
Microstructural features and dry - Sliding wear response of MoTaNbZrTi high entropy alloy Mathiou, C.; Poulia, A.; Georgatis, E. Materials Chemistry and Physics, Vol. 210 https://doi.org/10.1016/j.matchemphys.2017.08.036	journal	May 2018
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes Yeh, J.-W.; Chen, S.-K.; Lin, S.-J. Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303 https://doi.org/10.1002/adem.200300567	journal	May 2004
Bio-corrosion behavior and in vitro biocompatibility of equimolar TiZrHfNbTa high-entropy alloy Yang, Wei; Liu, Ying; Pang, Shujie Intermetallics, Vol. 124 https://doi.org/10.1016/j.intermet.2020.106845	journal	September 2020
The corrosion/wear mechanisms of Ti–6Al–4V alloy for different scratching rates Komotori, Jun; Hisamori, Noriyuki; Ohmori, Yosuke Wear, Vol. 263, Issue 1-6 https://doi.org/10.1016/j.wear.2006.11.025	journal	September 2007
Microstructure and tribological properties of TiTaHfNbZr high entropy alloy coatings deposited on Ti 6Al 4V substrates Tüten, N.; Canadinc, D.; Motallebzadeh, A. Intermetallics, Vol. 105 https://doi.org/10.1016/j.intermet.2018.11.015	journal	February 2019
Friction and wear behavior of a single-phase equiatomic TiZrHfNb high-entropy alloy studied using a nanoscratch technique Ye, Y. X.; Liu, C. Z.; Wang, H. Acta Materialia, Vol. 147 https://doi.org/10.1016/j.actamat.2018.01.014	journal	April 2018
Tribo-electrochemical characterization of metallic biomaterials for total joint replacement Diomidis, N.; Mischler, S.; More, N. S. Acta Biomaterialia, Vol. 8, Issue 2 https://doi.org/10.1016/j.actbio.2011.09.034	journal	February 2012
A critical review of high entropy alloys and related concepts Miracle, D. B.; Senkov, O. N. Acta Materialia, Vol. 122 https://doi.org/10.1016/j.actamat.2016.08.081	journal	January 2017
Tribological behaviors of a Ni-free Ti-based bulk metallic glass in air and a simulated physiological environment Liu, Ying; Pang, Shujie; Yang, Wei Journal of Alloys and Compounds, Vol. 766 https://doi.org/10.1016/j.jallcom.2018.07.023	journal	October 2018
An assessment on the future development of high-entropy alloys: Summary from a recent workshop Lu, Z. P.; Wang, H.; Chen, M. W. Intermetallics, Vol. 66 https://doi.org/10.1016/j.intermet.2015.06.021	journal	November 2015
Effects of Al addition on structural evolution and tensile properties of the FeCoNiCrMn high-entropy alloy system He, J. Y.; Liu, W. H.; Wang, H. Acta Materialia, Vol. 62 https://doi.org/10.1016/j.actamat.2013.09.037	journal	January 2014
The chemical wear (corrosion-wear) of novel Cr based hard coated 316L austenitic stainless steels in aqueous saline solution Dearnley, P. A.; Mallia, B. Wear, Vol. 306, Issue 1-2 https://doi.org/10.1016/j.wear.2012.09.002	journal	August 2013
Cytotoxicity evaluation of 43 metal salts using murine fibroblasts and osteoblastic cells Yamamoto, A.; Honma, R.; Sumita, M. Journal of Biomedical Materials Research, Vol. 39, Issue 2 https://doi.org/10.1002/(SICI)1097-4636(199802)39:2<331::AID-JBM22>3.0.CO;2-E	journal	February 1998
Bimodal structured Ti-base alloy with large elasticity and low Young's modulus He, G.; Hagiwara, M. Materials Science and Engineering: C, Vol. 25, Issue 3 https://doi.org/10.1016/j.msec.2005.03.001	journal	May 2005
Biomedical materials and techniques to improve the tribological, mechanical and biomedical properties of orthopedic implants – A review article Ibrahim, Mahmoud Z.; Sarhan, Ahmed A. D.; Yusuf, Farazila Journal of Alloys and Compounds, Vol. 714 https://doi.org/10.1016/j.jallcom.2017.04.231	journal	August 2017
Pin-on-disk wear behavior in a like-on-like configuration in a biological environment of high carbon cast and low carbon forged Co–29Cr–6Mo alloys Chiba, Akihiko; Kumagai, Kazushige; Nomura, Naoyuki Acta Materialia, Vol. 55, Issue 4 https://doi.org/10.1016/j.actamat.2006.10.005	journal	February 2007
Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes Lei, Zhifeng; Liu, Xiongjun; Wu, Yuan Nature, Vol. 563, Issue 7732 https://doi.org/10.1038/s41586-018-0685-y	journal	November 2018
Wear behavior of high entropy alloys containing soft dispersoids (Pb, Bi) Yadav, Surekha; Kumar, Arvind; Biswas, Krishanu Materials Chemistry and Physics, Vol. 210 https://doi.org/10.1016/j.matchemphys.2017.06.020	journal	May 2018
TiZrNbTaMo high-entropy alloy designed for orthopedic implants: As-cast microstructure and mechanical properties Wang, Shao-Ping; Xu, Jian Materials Science and Engineering: C, Vol. 73 https://doi.org/10.1016/j.msec.2016.12.057	journal	April 2017
Microstructure and mechanical properties of refractory MoNbHfZrTi high-entropy alloy Guo, N. N.; Wang, L.; Luo, L. S. Materials & Design, Vol. 81 https://doi.org/10.1016/j.matdes.2015.05.019	journal	September 2015
Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy Senkov, O. N.; Scott, J. M.; Senkova, S. V. Journal of Alloys and Compounds, Vol. 509, Issue 20 https://doi.org/10.1016/j.jallcom.2011.02.171	journal	May 2011
Wear and corrosion behaviour of Ti–13Nb–13Zr and Ti–6Al–4V alloys in simulated physiological solution Cvijović-Alagić, I.; Cvijović, Z.; Mitrović, S. Corrosion Science, Vol. 53, Issue 2 https://doi.org/10.1016/j.corsci.2010.11.014	journal	February 2011
Ultrafine composite microstructure in a bulk Ti alloy for high strength, strain hardening and tensile ductility Sun, B. B.; Sui, M. L.; Wang, Y. M. Acta Materialia, Vol. 54, Issue 5 https://doi.org/10.1016/j.actamat.2005.11.011	journal	March 2006

Similar Records

Computational exploration of biomedical HfNbTaTiZr and Hf_0.5Nb_0.5Ta_0.5Ti_1.5Zr refractory high-entropy alloys

Journal Article · 2021 · Materials Research Express (Online) · OSTI ID:1865397

Bhandari, Uttam; Ghadimi, Hamed; Zhang, Congyan; +3 more

Sliding Wear of Spark Plasma Sintered CrFeCoNiCu High-Entropy Alloy Coatings: Effect of Aluminum Addition

Journal Article · 2018 · Journal of Materials Engineering and Performance · OSTI ID:22863209

Ji, Xiulin; Alavi, S. Habib; Harimkar, Sandip P.; +1 more

PROGRESS RELATING TO CIVILIAN APPLICATIONS DURING APRIL 1959

Technical Report · 1959 · OSTI ID:4232002

Dayton, R. W.; Tipton, Jr., C. R.

Related Subjects

36 MATERIALS SCIENCE
High entropy alloys
Wear
Corrosive wear
Polarization
Mechanical properties

Title: Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys

Citation Formats

References (62)

Similar Records

Related Subjects