Tuning the dynamics of imidazolium-based ionic liquids via hydrogen bonding. I. The viscous regime

Thomann, C. A.; Münzner, P.; Moch, K.; Jacquemin, J.; Goodrich, P.; Sokolov, Alexei P.; Böhmer, R.; Gainaru, C.

doi:10.1063/5.0026144

Title: Tuning the dynamics of imidazolium-based ionic liquids via hydrogen bonding. I. The viscous regime

Journal Article · 17 November 2020 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/5.0026144 · OSTI ID:1767846

Thomann, C. A. ^[1];

^[1]; Moch, K. ^[1];

^[2]; Goodrich, P. ^[3];

^[4];

^[1];

^[1]

Dortmund Univ. of Technology (Germany)
Univ. de Tours (France); Queen's Univ., Belfast, Northern Ireland (United Kingdom)
Queen's Univ., Belfast, Northern Ireland (United Kingdom)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Combining results from impedance spectroscopy and oscillatory shear rheology, this study focuses on the relation between the mass and charge flows and on how these are affected by the H-bonding in viscous ionic liquids (ILs). In particular, we compare the relaxational behaviors of the paradigmatic IL 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM-TFSI) and its OH-functionalized counterpart 1-(2-hydroxyethyl)-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (OHEMIM-TFSI). Our results and their analysis demonstrate that the presence of cationic OH-groups bears a strong impact on the overall dynamics of OHEMIM-TFSI, although no signatures of suprastructural relaxation modes could be identified in their dielectric and mechanical responses. To check whether at the origin of this strong variation is the H-bonding or merely the difference between the corresponding cation sizes (controlling both the hydrodynamic volume and the inter-charge distance), the present study includes 1-propyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (PMIM-TFSI), mixtures of EMIM-TFSI and PMIM-TFSI with lithium bis(trifluoromethylsulfonyl)imide (Li-TFSI), and mixtures of OHEMIM-TFSI with PMIM-TFSI. Their investigation clearly reveals that the dynamical changes induced by H-bonding are significantly larger than those that can be attributed to the change in the ion size. Moreover, in the mixtures of OHEMIM-TFSI with PMIM-TFSI, a dilution of the OH-groups leads to strong deviations from ideal mixing behavior, thus highlighting the common phenomenological ground of hydroxy-functionalized ILs and other H-bonded liquids.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); German Research Foundation (DFG)

Grant/Contract Number:: AC05-00OR22725; GA2680/1-1; CHE-1764409

OSTI ID:: 1767846

Journal Information:: Journal of Chemical Physics, Vol. 153, Issue 19; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (93)

On the relation between reorientation and diffusion in glass-forming ionic liquids with micro-heterogeneous structures Becher, Manuel; Steinrücken, Elisa; Vogel, Michael The Journal of Chemical Physics, Vol. 151, Issue 19 https://doi.org/10.1063/1.5128420	journal	November 2019
Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye Böhmer, Roland; Gainaru, Catalin; Richert, Ranko Physics Reports, Vol. 545, Issue 4 https://doi.org/10.1016/j.physrep.2014.07.005	journal	December 2014
Structure and dynamics of short-chain polymerized ionic liquids Wieland, F.; Bocharova, V.; Münzner, P. The Journal of Chemical Physics, Vol. 151, Issue 3 https://doi.org/10.1063/1.5109228	journal	July 2019
Broadband dynamics in neat 4-methyl-3-heptanol and in mixtures with 2-ethyl-1-hexanol Bauer, S.; Wittkamp, H.; Schildmann, S. The Journal of Chemical Physics, Vol. 139, Issue 13 https://doi.org/10.1063/1.4821229	journal	October 2013
The influence of hydrogen bonding on the physical properties of ionic liquids Fumino, Koichi; Peppel, Tim; Geppert-Rybczyńska, Monika Physical Chemistry Chemical Physics, Vol. 13, Issue 31 https://doi.org/10.1039/c1cp20732f	journal	January 2011
Experimental studies of Debye-like process and structural relaxation in mixtures of 2-ethyl-1-hexanol and 2-ethyl-1-hexyl bromide Preuß, M.; Gainaru, C.; Hecksher, T. The Journal of Chemical Physics, Vol. 137, Issue 14 https://doi.org/10.1063/1.4755754	journal	October 2012
Physical and electrochemical properties of 1-(2-hydroxyethyl)-3-methyl imidazolium and N-(2-hydroxyethyl)-N-methyl morpholinium ionic liquids Yeon, Sun-Hwa; Kim, Ki-Sub; Choi, Sukjeong Electrochimica Acta, Vol. 50, Issue 27 https://doi.org/10.1016/j.electacta.2005.03.020	journal	September 2005
Highly decoupled ionic and protonic solid electrolyte systems, in relation to other relaxing systems and their energy landscapes Mizuno, F.; Belieres, J. -P.; Kuwata, N. Journal of Non-Crystalline Solids, Vol. 352, Issue 42-49 https://doi.org/10.1016/j.jnoncrysol.2006.06.006	journal	November 2006
Spectral shape simplicity of viscous materials Gainaru, Catalin Physical Review E, Vol. 100, Issue 2 https://doi.org/10.1103/physreve.100.020601	journal	August 2019
Protic Ionic Liquids: Solvents with Tunable Phase Behavior and Physicochemical Properties Greaves, Tamar L.; Weerawardena, Asoka; Fong, Celesta The Journal of Physical Chemistry B, Vol. 110, Issue 45 https://doi.org/10.1021/jp0634048	journal	November 2006
Thermal Conductivity of Ionic Liquids: Measurement and Prediction Fröba, A. P.; Rausch, M. H.; Krzeminski, K. International Journal of Thermophysics, Vol. 31, Issue 11-12 https://doi.org/10.1007/s10765-010-0889-3	journal	December 2010
Role of choline formate ionic liquid in the polymerization of vinyl and methacrylic monomers Sundar, D. Sathish; Vijayaraghavan, R.; Subramaniam, J. Journal of Applied Polymer Science, Vol. 120, Issue 6 https://doi.org/10.1002/app.33609	journal	February 2011
Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols Bauer, S.; Burlafinger, K.; Gainaru, C. The Journal of Chemical Physics, Vol. 138, Issue 9 https://doi.org/10.1063/1.4793469	journal	March 2013
Energetic Nitrogen-Rich Salts and Ionic Liquids Singh, Rajendra P.; Verma, Rajendar D.; Meshri, Dayal T. Angewandte Chemie International Edition, Vol. 45, Issue 22 https://doi.org/10.1002/anie.200504236	journal	May 2006
Fundamental parameters governing ion conductivity in polymer electrolytes Kisliuk, A.; Bocharova, V.; Popov, I. Electrochimica Acta, Vol. 299 https://doi.org/10.1016/j.electacta.2018.12.143	journal	March 2019
Ion-Pair Formation in the Ionic Liquid 1-Ethyl-3-methylimidazolium Bis(triflyl)imide as a Function of Temperature and Concentration Köddermann, Thorsten; Wertz, Christiane; Heintz, Andreas ChemPhysChem, Vol. 7, Issue 9 https://doi.org/10.1002/cphc.200600034	journal	September 2006
Communication: Slow supramolecular mode in amine and thiol derivatives of 2-ethyl-1-hexanol revealed by combined dielectric and shear-mechanical studies Adrjanowicz, K.; Jakobsen, B.; Hecksher, T. The Journal of Chemical Physics, Vol. 143, Issue 18 https://doi.org/10.1063/1.4935510	journal	November 2015
Interactions and dynamics in electrolyte solutions by dielectric spectroscopy Buchner, Richard; Hefter, Glenn Physical Chemistry Chemical Physics, Vol. 11, Issue 40 https://doi.org/10.1039/b906555p	journal	January 2009
Photoinduced Electron Transfer in an Imidazolium Ionic Liquid and in Its Binary Mixtures with Water, Methanol, and 2-Propanol: Appearance of Marcus-Type of Inversion Sarkar, Souravi; Mandal, Sarthak; Ghatak, Chiranjib The Journal of Physical Chemistry B, Vol. 116, Issue 4 https://doi.org/10.1021/jp2075995	journal	January 2012
Influence of Chain Rigidity and Dielectric Constant on the Glass Transition Temperature in Polymerized Ionic Liquids Bocharova, V.; Wojnarowska, Z.; Cao, Peng-Fei The Journal of Physical Chemistry B, Vol. 121, Issue 51 https://doi.org/10.1021/acs.jpcb.7b09423	journal	December 2017
Intermolecular Dynamics, Interactions, and Solvation in Ionic Liquids Castner, Edward W.; Wishart, James F.; Shirota, Hideaki Accounts of Chemical Research, Vol. 40, Issue 11 https://doi.org/10.1021/ar700169g	journal	November 2007
Importance of reorientational dynamics for the charge transport in ionic liquids Sippel, P.; Krohns, S.; Reuter, D. Physical Review E, Vol. 98, Issue 5 https://doi.org/10.1103/physreve.98.052605	journal	November 2018
Ion transport in glass: Influence of glassy structure on spatial extent of nonrandom ion hopping Roling, B.; Martiny, C.; Brückner, S. Physical Review B, Vol. 63, Issue 21 https://doi.org/10.1103/physrevb.63.214203	journal	May 2001
Mechanism of Conductivity Relaxation in Liquid and Polymeric Electrolytes: Direct Link between Conductivity and Diffusivity Gainaru, C.; Stacy, E. W.; Bocharova, V. The Journal of Physical Chemistry B, Vol. 120, Issue 42 https://doi.org/10.1021/acs.jpcb.6b08567	journal	October 2016
Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts ^† Bonhôte, Pierre; Dias, Ana-Paula; Papageorgiou, Nicholas Inorganic Chemistry, Vol. 35, Issue 5 https://doi.org/10.1021/ic951325x	journal	January 1996
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Welton, Thomas Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084 https://doi.org/10.1021/cr980032t	journal	August 1999
Electrode polarization in dielectric measurements: a review Ishai, Paul Ben; Talary, Mark S.; Caduff, Andreas Measurement Science and Technology, Vol. 24, Issue 10 https://doi.org/10.1088/0957-0233/24/10/102001	journal	August 2013
Local and global dynamics of the viscous ion conductors 2Ca(NO ₃ ) ₂ -3KNO ₃ and 2Ca(NO ₃ ) ₂ -3RbNO ₃ probed by ⁸⁷ Rb nuclear magnetic resonance and shear rheology Beerwerth, Joachim; Bierwirth, S. Peter; Adam, Jens The Journal of Chemical Physics, Vol. 150, Issue 19 https://doi.org/10.1063/1.5093973	journal	May 2019
A short history of ionic liquids—from molten salts to neoteric solvents Wilkes, John S. Green Chemistry, Vol. 4, Issue 2 https://doi.org/10.1039/b110838g	journal	March 2002
A Rayleighian approach for modeling kinetics of ionic transport in polymeric media Kumar, Rajeev; Mahalik, Jyoti P.; Bocharova, Vera The Journal of Chemical Physics, Vol. 146, Issue 6 https://doi.org/10.1063/1.4975309	journal	February 2017
Spectroscopic Evidence for an Enhanced Anion-Cation Interaction from Hydrogen Bonding in Pure Imidazolium Ionic Liquids Wulf, Alexander; Fumino, Koichi; Ludwig, Ralf Angewandte Chemie International Edition, Vol. 49, Issue 2 https://doi.org/10.1002/anie.200905437	journal	December 2009
Room temperature ionic liquids and their mixtures—a review Marsh, K. N.; Boxall, J. A.; Lichtenthaler, R. Fluid Phase Equilibria, Vol. 219, Issue 1 https://doi.org/10.1016/j.fluid.2004.02.003	journal	May 2004
Bio ionic liquids: room temperature ionic liquids composed wholly of biomaterials Fukaya, Yukinobu; Iizuka, Yoshiki; Sekikawa, Kenta Green Chemistry, Vol. 9, Issue 11 https://doi.org/10.1039/b706571j	journal	January 2007
Generic Primary Mechanical Response of Viscous Liquids Bierwirth, S. Peter; Böhmer, Roland; Gainaru, Catalin Physical Review Letters, Vol. 119, Issue 24 https://doi.org/10.1103/physrevlett.119.248001	journal	December 2017
Deeply supercooled aqueous LiCl solution studied by frequency-resolved shear rheology Münzner, Philipp; Hoffmann, Lars; Böhmer, Roland The Journal of Chemical Physics, Vol. 150, Issue 23 https://doi.org/10.1063/1.5100600	journal	June 2019
Diffusion in ionic liquids: the interplay between molecular structure and dynamics Sangoro, J. R.; Iacob, C.; Naumov, S. Soft Matter, Vol. 7, Issue 5 https://doi.org/10.1039/c0sm01404d	journal	January 2011
Free Radical Polymerization of n -Butyl Methacrylate in Ionic Liquids Strehmel, Veronika; Laschewsky, André; Wetzel, Hendrik Macromolecules, Vol. 39, Issue 3 https://doi.org/10.1021/ma0516945	journal	February 2006
Mesoscale Organization and Dynamics in Binary Ionic Liquid Mixtures Cosby, Tyler; Kapoor, Utkarsh; Shah, Jindal K. The Journal of Physical Chemistry Letters, Vol. 10, Issue 20 https://doi.org/10.1021/acs.jpclett.9b02478	journal	September 2019
Mobile ion concentrations in solid electrolytes from an analysis of a.c. conductivity Almond, D.; West, A. Solid State Ionics, Vol. 9-10 https://doi.org/10.1016/0167-2738(83)90247-3	journal	December 1983
Dynamics of Glassy, Crystalline and Liquid Ionic Conductors: Experiments, Theories, Simulations Habasaki, Junko; Leon, Carlos; Ngai, K. L. Topics in Applied Physics https://doi.org/10.1007/978-3-319-42391-3	book	January 2017
The lithium ion conductor β-spodumene: an orientational glass Böhmer, R.; Lunkenheimer, P.; Lotze, M. Zeitschrift für Physik B Condensed Matter, Vol. 100, Issue 4 https://doi.org/10.1007/s002570050165	journal	December 1996
Dielectric and conductivity relaxation in mixtures of glycerol with LiCl Köhler, M.; Lunkenheimer, P.; Loidl, A. The European Physical Journal E, Vol. 27, Issue 2 https://doi.org/10.1140/epje/i2008-10357-8	journal	August 2008
Diluting the hydrogen bonds in viscous solutions of n-butanol with n-bromobutane: II. A comparison of rotational and translational motions Lederle, Christina; Hiller, Wolf; Gainaru, Catalin The Journal of Chemical Physics, Vol. 134, Issue 6 https://doi.org/10.1063/1.3549123	journal	February 2011
A review on the transport properties of ionic liquids Wang, Xiaojing; Chi, Yanling; Mu, Tiancheng Journal of Molecular Liquids, Vol. 193 https://doi.org/10.1016/j.molliq.2014.03.011	journal	May 2014
Upon the structure of room temperature halogenoaluminate ionic liquids Abdul-Sada, Ala'a K.; Greenway, Anthony M.; Hitchcock, Peter B. Journal of the Chemical Society, Chemical Communications, Issue 24 https://doi.org/10.1039/c39860001753	journal	January 1986
Molecular Dynamics Changes Induced by Hydrostatic Pressure in a Supercooled Primary Alcohol Pawlus, Sebastian; Paluch, Marian; Dzida, Marzena The Journal of Physical Chemistry Letters, Vol. 1, Issue 21 https://doi.org/10.1021/jz101288v	journal	October 2010
Changes of relaxation dynamics of a hydrogen-bonded glass former after removal of the hydrogen bonds Grzybowska, K.; Pawlus, S.; Mierzwa, M. The Journal of Chemical Physics, Vol. 125, Issue 14 https://doi.org/10.1063/1.2354492	journal	October 2006
Synthesis and physical-chemical properties of ionic liquids based on 1-n-butyl-3-methylimidazolium cation Suarez, P. A. Z.; Einloft, S.; Dullius, J. E. L. Journal de Chimie Physique et de Physico-Chimie Biologique, Vol. 95, Issue 7 https://doi.org/10.1051/jcp:1998103	journal	July 1998
Scaling vs. Vogel–Fulcher-type structural relaxation in deeply supercooled materials Richert, Ranko Physica A: Statistical Mechanics and its Applications, Vol. 287, Issue 1-2 https://doi.org/10.1016/s0378-4371(00)00451-9	journal	November 2000
Solid-like mean-square displacement in glass-forming liquids Schrøder, Thomas B.; Dyre, Jeppe C. The Journal of Chemical Physics, Vol. 152, Issue 14 https://doi.org/10.1063/5.0004093	journal	April 2020
Fundamental Limitations of Ionic Conductivity in Polymerized Ionic Liquids Stacy, Eric W.; Gainaru, Catalin P.; Gobet, Mallory Macromolecules, Vol. 51, Issue 21 https://doi.org/10.1021/acs.macromol.8b01221	journal	October 2018
IR and NMR Properties of Ionic Liquids: Do They Tell Us the Same Thing? Wulf, Alexander; Fumino, Koichi; Michalik, Dirk ChemPhysChem, Vol. 8, Issue 15 https://doi.org/10.1002/cphc.200700508	journal	October 2007
Temperature dependence of hydrogen bonding in alcohols Huelsekopf, M.; Ludwig, R. Journal of Molecular Liquids, Vol. 85, Issue 1-2 https://doi.org/10.1016/s0167-7322(99)00168-3	journal	April 2000
Dynamic processes in ionic glasses Angell, C. Austin Chemical Reviews, Vol. 90, Issue 3 https://doi.org/10.1021/cr00101a006	journal	May 1990
Importance of liquid fragility for energy applications of ionic liquids Sippel, P.; Lunkenheimer, P.; Krohns, S. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep13922	journal	September 2015
Relaxation and Diffusion in Complex Systems Ngai, K. L. Partially Ordered Systems https://doi.org/10.1007/978-1-4419-7649-9	book	January 2011
Heterogeneity at the Glass Transition: Translational and Rotational Self-Diffusion Chang, Inyong; Sillescu, Hans The Journal of Physical Chemistry B, Vol. 101, Issue 43 https://doi.org/10.1021/jp9640989	journal	October 1997
Dynamics of glass-forming liquids. IX. Structural versus dielectric relaxation in monohydroxy alcohols Wang, Li-Min; Richert, Ranko The Journal of Chemical Physics, Vol. 121, Issue 22 https://doi.org/10.1063/1.1811072	journal	January 2004
Comments on the electric modulus function Hodge, I. M.; Ngai, K. L.; Moynihan, C. T. Journal of Non-Crystalline Solids, Vol. 351, Issue 2 https://doi.org/10.1016/j.jnoncrysol.2004.07.089	journal	January 2005
Effect of hydrogen bond cooperativity on the behavior of water Stokely, K.; Mazza, M. G.; Stanley, H. E. Proceedings of the National Academy of Sciences, Vol. 107, Issue 4 https://doi.org/10.1073/pnas.0912756107	journal	January 2010
Biological Activity of Ionic Liquids and Their Application in Pharmaceutics and Medicine Egorova, Ksenia S.; Gordeev, Evgeniy G.; Ananikov, Valentine P. Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.6b00562	journal	January 2017
Ion Dynamics under Pressure in an Ionic Liquid Rivera-Calzada, A.; Kaminski, K.; Leon, C. The Journal of Physical Chemistry B, Vol. 112, Issue 10 https://doi.org/10.1021/jp710479b	journal	March 2008
Factors Controlling the Diffusion of Ions in Ionic Liquids Tsuzuki, Seiji ChemPhysChem, Vol. 13, Issue 7 https://doi.org/10.1002/cphc.201100870	journal	April 2012
Self polymerising ionic liquid gel Winther-Jensen, Orawan; Vijayaraghavan, R.; Sun, Jiazeng Chemical Communications, Issue 21 https://doi.org/10.1039/b822905h	journal	January 2009
Controlling “like–likes–like” charge attraction in hydroxy-functionalized ionic liquids by polarizability of the cations, interaction strength of the anions and varying alkyl chain length Niemann, Thomas; Zaitsau, Dzmitry H.; Strate, Anne Physical Chemistry Chemical Physics, Vol. 22, Issue 5 https://doi.org/10.1039/c9cp06481h	journal	January 2020
Fundamental questions relating to ion conduction in disordered solids Dyre, Jeppe C.; Maass, Philipp; Roling, Bernhard Reports on Progress in Physics, Vol. 72, Issue 4 https://doi.org/10.1088/0034-4885/72/4/046501	journal	March 2009
Spectroscopic Evidence for Clusters of Like-Charged Ions in Ionic Liquids Stabilized by Cooperative Hydrogen Bonding Knorr, Anne; Stange, Peter; Fumino, Koichi ChemPhysChem, Vol. 17, Issue 4 https://doi.org/10.1002/cphc.201501134	journal	January 2016
Cationic clustering influences the phase behaviour of ionic liquids Niemann, Thomas; Zaitsau, Dimitri; Strate, Anne Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-33176-6	journal	October 2018
Ab Initio Calculations of Cooperativity Effects on Clusters of Methanol, Ethanol, 1-Propanol, and Methanethiol Sum, Amadeu K.; Sandler, Stanley I. The Journal of Physical Chemistry A, Vol. 104, Issue 6 https://doi.org/10.1021/jp993094b	journal	February 2000
Counting cations involved in cationic clusters of hydroxy-functionalized ionic liquids by means of infrared and solid-state NMR spectroscopy Strate, Anne; Neumann, Jan; Niemann, Thomas Physical Chemistry Chemical Physics, Vol. 22, Issue 13 https://doi.org/10.1039/d0cp00303d	journal	January 2020
Hydrogen Bonding Behaviors of Binary Systems Containing the Ionic Liquid 1-Butyl-3-methylimidazolium Trifluoroacetate and Water/Methanol Zhang, Qing-Guo; Wang, Nan-Nan; Wang, Shuang-Long The Journal of Physical Chemistry B, Vol. 115, Issue 38 https://doi.org/10.1021/jp204305g	journal	September 2011
How Strong Is Hydrogen Bonding in Ionic Liquids? Combined X-ray Crystallographic, Infrared/Raman Spectroscopic, and Density Functional Theory Study Katsyuba, Sergey A.; Vener, Mikhail V.; Zvereva, Elena E. The Journal of Physical Chemistry B, Vol. 117, Issue 30 https://doi.org/10.1021/jp405255w	journal	July 2013
When Like Charged Ions Attract in Ionic Liquids: Controlling the Formation of Cationic Clusters by the Interaction Strength of the Counterions Strate, Anne; Niemann, Thomas; Michalik, Dirk Angewandte Chemie International Edition, Vol. 56, Issue 2 https://doi.org/10.1002/anie.201609799	journal	December 2016
Hydrogen-Bonding Interactions in Pyridinium-Based Ionic Liquids and Dimethyl Sulfoxide Binary Systems: A Combined Experimental and Computational Study Zhang, Yaqin; He, Hongyan; Zhang, Suojiang ACS Omega, Vol. 3, Issue 2 https://doi.org/10.1021/acsomega.7b01805	journal	February 2018
Diluting the hydrogen bonds in viscous solutions of n-butanol with n-bromobutane: A dielectric study El Goresy, T.; Böhmer, R. The Journal of Chemical Physics, Vol. 128, Issue 15 https://doi.org/10.1063/1.2903403	journal	April 2008
Why Does a Reduction in Hydrogen Bonding Lead to an Increase in Viscosity for the 1-Butyl-2,3-dimethyl-imidazolium-Based Ionic Liquids? ^† Hunt, Patricia A. The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp067182p	journal	May 2007
On the molecular mechanisms of α and β relaxations in ionic liquids Steinrücken, Elisa; Becher, Manuel; Vogel, Michael The Journal of Chemical Physics, Vol. 153, Issue 10 https://doi.org/10.1063/5.0019271	journal	September 2020
Broadband Dielectric Spectroscopy Kremer, Friedrich; Schönhals, Andreas https://doi.org/10.1007/978-3-642-56120-7	book	January 2003
The phase behaviour of 1-alkyl-3-methylimidazolium tetrafluoroborates; ionic liquids and ionic liquid crystals Holbrey, John D.; Seddon, Kenneth R. Journal of the Chemical Society, Dalton Transactions, Issue 13 https://doi.org/10.1039/a902818h	journal	January 1999
ac complex conductivity in NaCl: No new universality Macdonald, J. Ross Journal of Applied Physics, Vol. 75, Issue 2 https://doi.org/10.1063/1.356487	journal	January 1994
Density and viscosity of pyridinium-based ionic liquids and their binary mixtures with water at several temperatures Mokhtarani, Babak; Sharifi, Ali; Mortaheb, Hamid Reza The Journal of Chemical Thermodynamics, Vol. 41, Issue 3 https://doi.org/10.1016/j.jct.2008.09.001	journal	March 2009
Charge Transport and Glassy Dynamics in Ionic Liquids Sangoro, Joshua R.; Kremer, Friedrich Accounts of Chemical Research, Vol. 45, Issue 4 https://doi.org/10.1021/ar2001809	journal	November 2011
Scaling and Universality of ac Conduction in Disordered Solids Schrøder, Thomas B.; Dyre, Jeppe C. Physical Review Letters, Vol. 84, Issue 2 https://doi.org/10.1103/physrevlett.84.310	journal	January 2000
Dielectric Relaxation of Aqueous NaCl Solutions Buchner, Richard; Hefter, Glenn T.; May, Peter M. The Journal of Physical Chemistry A, Vol. 103, Issue 1 https://doi.org/10.1021/jp982977k	journal	January 1999
Characterization of the diffusion process in oxide glasses based on the correlation between electric conduction and dielectric relaxation Namikawa, Hiroshi Journal of Non-Crystalline Solids, Vol. 18, Issue 2 https://doi.org/10.1016/0022-3093(75)90019-8	journal	September 1975
Anomalous Component Dynamics of a Binary Mixture of Associating Glass-Forming Liquids Wang, Li-Min; Tian, Yongjun; Liu, Riping The Journal of Physical Chemistry B, Vol. 115, Issue 4 https://doi.org/10.1021/jp1101362	journal	February 2011
Oscillatory shear and high-pressure dielectric study of 5-methyl-3-heptanol Gainaru, C.; Wikarek, M.; Pawlus, S. Colloid and Polymer Science, Vol. 292, Issue 8 https://doi.org/10.1007/s00396-014-3274-0	journal	June 2014
ac Hopping Conduction at Extreme Disorder Takes Place on the Percolating Cluster Schrøder, Thomas B.; Dyre, Jeppe C. Physical Review Letters, Vol. 101, Issue 2 https://doi.org/10.1103/physrevlett.101.025901	journal	July 2008
Hydrogen bonding in ionic liquids Hunt, Patricia A.; Ashworth, Claire R.; Matthews, Richard P. Chemical Society Reviews, Vol. 44, Issue 5 https://doi.org/10.1039/c4cs00278d	journal	January 2015
Viscosity of binary mixtures of 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid with four organic solvents Ciocirlan, Oana; Croitoru, Oana; Iulian, Olga The Journal of Chemical Thermodynamics, Vol. 101 https://doi.org/10.1016/j.jct.2016.06.015	journal	October 2016
Hydrogen bonding in protic ionic liquids: structural correlations, vibrational spectroscopy, and rotational dynamics of liquid ethylammonium nitrate Zentel, Tobias; Overbeck, Viviane; Michalik, Dirk Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 51, Issue 3 https://doi.org/10.1088/1361-6455/aa9a9e	journal	January 2018
Mixed Debye-type liquids studied by dielectric, shear mechanical, nuclear magnetic resonance, and near-infrared spectroscopy Bauer, S.; Moch, K.; Münzner, P. Journal of Non-Crystalline Solids, Vol. 407 https://doi.org/10.1016/j.jnoncrysol.2014.07.018	journal	January 2015
Ionic conduction in solids: Comparing conductivity and modulus representations with regard to scaling properties Sidebottom, D. L.; Roling, B.; Funke, K. Physical Review B, Vol. 63, Issue 2 https://doi.org/10.1103/physrevb.63.024301	journal	December 2000

Similar Records

Impact of Hydrogen Bonding on the Dynamics and Structure of Protic Ionic Liquid/Water Binary Mixtures

Journal Article · 2017 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1797301

Bailey, Heather E.; Wang, Yong-Lei; Fayer, Michael D.

Effect of Ionic Liquid Components on the Coil Dimensions of PEO

Journal Article · 2019 · Macromolecules · OSTI ID:1523530

Kharel, Aakriti; Lodge, Timothy P.

Molecular dynamics simulations of uranyl and plutonyl cations in a task-specific ionic liquid

Journal Article · 2024 · Journal of Chemical Physics · OSTI ID:2475570

Maerzke, Katie A.; Goff, George S.; Runde, Wolfgang H.; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Glass transitions
Dielectric properties
Ionic liquids
Electrical conductivity
Rheology and fluid dynamics

Title: Tuning the dynamics of imidazolium-based ionic liquids via hydrogen bonding. I. The viscous regime

Citation Formats

References (93)

Similar Records

Related Subjects