Recent Developments and Challenges in Hybrid Solid Electrolytes for Lithium-Ion Batteries

Han, Lu; Lehmann, Michelle L.; Zhu, Jiadeng; Liu, Tianyi; Zhou, Zhengping; Tang, Xiaomin; Heish, Chien-Te; Sokolov, Alexei P.; Cao, Pengfei; Chen, Xi Chelsea; Saito, Tomonori

doi:10.3389/fenrg.2020.00202

Title: Recent Developments and Challenges in Hybrid Solid Electrolytes for Lithium-Ion Batteries

Abstract

Lithium-ion batteries (LIBs) have attracted worldwide research interest due to their high energy density and long cycle life. Solid-state LIBs improve the safety of conventional liquid-based LIBs by replacing the flammable organic electrolytes with a solid electrolyte. Among the various types of solid electrolytes, hybrid solid electrolytes (HSEs) demonstrate great promise to achieve high ionic conductivity, reduced interfacial resistance between the electrolyte and electrodes, mechanical robustness, and excellent processability due to the combined advantages of both polymer and inorganic electrolyte. This article summarizes recent developments in HSEs for LIBs. Approaches for the preparation of hybrid electrolytes and current understanding of ion-transport mechanisms are discussed. The main challenges including unsatisfactory ionic conductivity and perspectives of HSEs for LIBs are highlighted for future development. The present review provides insights into HSE development to allow a more efficient and target-oriented future endeavor on achieving high-performance solid-state LIBs.

Authors:

Han, Lu ^[1]; Lehmann, Michelle L. ^[2]; Zhu, Jiadeng ^[1]; Liu, Tianyi ^[3];

^[1];

^[1]; Heish, Chien-Te ^[4];

^[2];

^[1];

^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Yuan Ze Univ., Taoyuan (Taiwan); Univ. of Tennessee, Knoxville, TN (United States)

Publication Date:: Wed Sep 02 00:00:00 EDT 2020

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1766409

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Frontiers in Energy Research

Additional Journal Information:: Journal Volume: 8; Journal Issue: 0; Journal ID: ISSN 2296-598X

Publisher:: Frontiers Research Foundation

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; lithium-ion batteries (LIBs); hybrid solid electrolytes (HSEs); solid electrolytes; polymer electrolytes; inorganic electrolytes; ionic conductivity; ion-transport mechanisms

Citation Formats


                    Han, Lu, Lehmann, Michelle L., Zhu, Jiadeng, Liu, Tianyi, Zhou, Zhengping, Tang, Xiaomin, Heish, Chien-Te, Sokolov, Alexei P., Cao, Pengfei, Chen, Xi Chelsea, and Saito, Tomonori. Recent Developments and Challenges in Hybrid Solid Electrolytes for Lithium-Ion Batteries.  United States: N. p., 2020. 
Web.  doi:10.3389/fenrg.2020.00202.

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                    Han, Lu, Lehmann, Michelle L., Zhu, Jiadeng, Liu, Tianyi, Zhou, Zhengping, Tang, Xiaomin, Heish, Chien-Te, Sokolov, Alexei P., Cao, Pengfei, Chen, Xi Chelsea, & Saito, Tomonori. Recent Developments and Challenges in Hybrid Solid Electrolytes for Lithium-Ion Batteries.  United States.  https://doi.org/10.3389/fenrg.2020.00202

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                    Han, Lu, Lehmann, Michelle L., Zhu, Jiadeng, Liu, Tianyi, Zhou, Zhengping, Tang, Xiaomin, Heish, Chien-Te, Sokolov, Alexei P., Cao, Pengfei, Chen, Xi Chelsea, and Saito, Tomonori. Wed .  
"Recent Developments and Challenges in Hybrid Solid Electrolytes for Lithium-Ion Batteries".  United States.  https://doi.org/10.3389/fenrg.2020.00202.  https://www.osti.gov/servlets/purl/1766409.

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@article{osti_1766409,

  title        = {Recent Developments and Challenges in Hybrid Solid Electrolytes for Lithium-Ion Batteries},

  author       = {Han, Lu and Lehmann, Michelle L. and Zhu, Jiadeng and Liu, Tianyi and Zhou, Zhengping and Tang, Xiaomin and Heish, Chien-Te and Sokolov, Alexei P. and Cao, Pengfei and Chen, Xi Chelsea and Saito, Tomonori},

  abstractNote = {Lithium-ion batteries (LIBs) have attracted worldwide research interest due to their high energy density and long cycle life. Solid-state LIBs improve the safety of conventional liquid-based LIBs by replacing the flammable organic electrolytes with a solid electrolyte. Among the various types of solid electrolytes, hybrid solid electrolytes (HSEs) demonstrate great promise to achieve high ionic conductivity, reduced interfacial resistance between the electrolyte and electrodes, mechanical robustness, and excellent processability due to the combined advantages of both polymer and inorganic electrolyte. This article summarizes recent developments in HSEs for LIBs. Approaches for the preparation of hybrid electrolytes and current understanding of ion-transport mechanisms are discussed. The main challenges including unsatisfactory ionic conductivity and perspectives of HSEs for LIBs are highlighted for future development. The present review provides insights into HSE development to allow a more efficient and target-oriented future endeavor on achieving high-performance solid-state LIBs.},

  doi          = {10.3389/fenrg.2020.00202},

  journal      = {Frontiers in Energy Research},

  number       = 0,

  volume       = 8,

  place        = {United States},

  year         = {Wed Sep 02 00:00:00 EDT 2020},

  month        = {Wed Sep 02 00:00:00 EDT 2020}

}

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“Water–in–Eutectogel” Electrolytes for Quasi–Solid–State Aqueous Lithium–Ion Batteries

Journal Article Hou, Xu ; Pollard, Travis P. ; He, Xin ; ... - Advanced Energy Materials

The development of high safety lithium-ion batteries (LIBs) is greatly impeded by the flammability and leakage concerns of typical organic solvent-based electrolytes. As one of the alternative classes of electrolytes, hydrogel electrolytes exhibit high safety, high flexibility, low cost, and are benign to the environment. However, the narrow electrochemical stability window (ESW) of typical hydrogel electrolytes restricts the operating voltage of battery cells. Here, a new class of “water-in-eutectogel (WiETG)” electrolyte is reported, fabricated by combining a hydrogel with a “deep eutectic solvent” (LiTFSI in acetamide). The obtained WiETG electrolyte exhibits non-flammability, high ionic conductivity, and a wide ESW. LiMn₂O₄||Li₄Ti₅O₁₂more »« less
https://doi.org/10.1002/aenm.202200401

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Title: Recent Developments and Challenges in Hybrid Solid Electrolytes for Lithium-Ion Batteries

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Lithium-Salt-Rich PEO/Li 0.3 La 0.557 TiO 3 Interpenetrating Composite Electrolyte with Three-Dimensional Ceramic Nano-Backbone for All-Solid-State Lithium-Ion Batteries journal, July 2018

Electrochemical and Structural Analysis in All‐Solid‐State Lithium Batteries by Analytical Electron Microscopy: Progress and Perspectives journal, October 2019

Synthesis and Properties of Polyimide Composites Containing Graphene Oxide Via In-Situ Polymerization journal, October 2012

Fast Na+-ion transport in skeleton structures journal, February 1976

Electrospun ZnO–SnO2 composite nanofibers with enhanced electrochemical performance as lithium-ion anodes journal, July 2016

PEO-based composite polymer electrolytes journal, July 1998

Enhancement of ion dynamics in PMMA-based gels with addition of TiO2 nano-particles journal, June 2003

Solvation of lithium salts within single-phase dimethyl siloxane bisphenol-A carbonate block copolymer journal, April 2000

Effect of reduced graphene oxide reduction degree on the performance of polysulfide rejection in lithium-sulfur batteries journal, January 2018

Thermal, electrical, and mechanical properties of composite polymer electrolytes based on cross-linked poly(ethylene oxide-co-propylene oxide) and ceramic filler journal, May 2003

Nitrogen-doped carbon nanofibers derived from polyacrylonitrile for use as anode material in sodium-ion batteries journal, November 2015

A review of lithium and non-lithium based solid state batteries journal, May 2015

Empirical parameters for donor and acceptor properties of solvents journal, September 1976

From colloidal to composite electrolytes: properties, peculiarities, and possibilities journal, September 2004

Poly(ethylene oxide)-based electrolytes for lithium-ion batteries journal, January 2015

Selective Transporting of Lithium Ion by Shape Selective Molecular Sieves ZSM-5 in PEO-Based Composite Polymer Electrolyte journal, November 2004

Multinuclear in situ magnetic resonance imaging of electrochemical double-layer capacitors journal, August 2014

Polycondensation as a Versatile Synthetic Route to Aliphatic Polycarbonates for Solid Polymer Electrolytes journal, May 2017

Designing solid-state electrolytes for safe, energy-dense batteries journal, February 2020

Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts journal, September 1983

Elastic Single-Ion Conducting Polymer Electrolytes: Toward a Versatile Approach for Intrinsically Stretchable Functional Polymers journal, April 2020

Rubbery Block Copolymer Electrolytes for Solid-State Rechargeable Lithium Batteries journal, January 1999

Carbon-Coated Magnesium Ferrite Nanofibers for Lithium-Ion Battery Anodes with Enhanced Cycling Performance journal, March 2017

Study of segmental dynamics and ion transport in polymer–ceramic composite electrolytes by quasi-elastic neutron scattering journal, January 2019

Porous one-dimensional carbon/iron oxide composite for rechargeable lithium-ion batteries with high and stable capacity journal, July 2016

Effect of modified SiO2 on the properties of PEO-based polymer electrolytes journal, October 2003

Ion conduction and relaxation in PEO-LiTFSI-Al 2 O 3 polymer nanocomposite electrolytes journal, May 2015

Miscibility studies of high Tg polyester and polycarbonate blends journal, May 1994

A star-shaped single lithium-ion conducting copolymer by grafting a POSS nanoparticle journal, August 2017

Challenges and opportunities towards fast-charging battery materials journal, June 2019

Lithium ion conductive glass ceramics in the system Li1.4Al0.4(Ge1?xTix)1.6(PO4)3 (x=0?1.0) journal, July 2004

Grain boundary resistance of fast lithium ion conductors: Comparison between a lithium-ion conductive Li–Al–Ti–P–O-type glass ceramic and a Li1.5Al0.5Ge1.5P3O12 ceramic journal, January 2012

Ion-conductive properties of polyether-based composite electrolytes filled with mesoporous silica, alumina and titania journal, December 2013

A novel separator coated by carbon for achieving exceptional high performance lithium-sulfur batteries journal, February 2016

Transport and interfacial properties of composite polymer electrolytes journal, January 2000

Sulfur gradient-distributed CNF composite: a self-inhibiting cathode for binder-free lithium–sulfur batteries journal, January 2014

A three-dimensional interconnected polymer/ceramic composite as a thin film solid electrolyte journal, April 2020

Engineering a flexible and mechanically strong composite electrolyte for solid-state lithium batteries journal, July 2020

Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12 journal, October 2007

Synthesis and properties of organic/inorganic hybrid branched-graft copolymers and their application to solid-state electrolytes for high-temperature lithium-ion batteries journal, January 2014

Crystal Chemistry and Stability of “Li7La3Zr2O12 ” Garnet: A Fast Lithium-Ion Conductor journal, February 2011

Reversible monoclinic-rhombohedral transformation in LiSn2(PO4)3 with NASICON-type structure journal, October 1995

Polymer electrolytes based on polycarbonates and their electrochemical and thermal properties journal, September 2012

Examination of the fundamental relation between ionic transport and segmental relaxation in polymer electrolytes journal, August 2014

Investigation of mechanical properties of polyvinyl chloride–polyethylene oxide (PVC–PEO) based polymer electrolytes for lithium polymer cells journal, May 2007

Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte journal, June 2019

A New All-Solid-State Hyperbranched Star Polymer Electrolyte for Lithium Ion Batteries: Synthesis and Electrochemical Properties journal, September 2016

Bi-layer lithium phosphorous oxynitride/aluminium substituted lithium lanthanum titanate as a promising solid electrolyte for long-life rechargeable lithium–oxygen batteries journal, January 2015

Hierarchical multi-component nanofiber separators for lithium polysulfide capture in lithium–sulfur batteries: an experimental and molecular modeling study journal, January 2016

Remarkable Conductivity of a Self-Healing Single-Ion Conducting Polymer Electrolyte, Poly(ethylene- co -acrylic lithium (fluoro sulfonyl)imide), for All-Solid-State Li-Ion Batteries journal, June 2019

In Situ Synthesis of a Hierarchical All-Solid-State Electrolyte Based on Nitrile Materials for High-Performance Lithium-Ion Batteries journal, May 2015

Influence of zeolite on electrochemical and physicochemical properties of polyethylene oxide solid electrolyte journal, September 1995

Enhancement of ionic conductivity of composite membranes for all-solid-state lithium rechargeable batteries incorporating tetragonal Li7La3Zr2O12 into a polyethylene oxide matrix journal, January 2015

Lithium Ion Solvation and Diffusion in Bulk Organic Electrolytes from First-Principles and Classical Reactive Molecular Dynamics journal, January 2015

Decoupling Ionic Conductivity from Structural Relaxation: A Way to Solid Polymer Electrolytes? journal, June 2011

Perspectives for Polymer Electrolytes: A View from Fundamentals of Ionic Conductivity journal, April 2020

Multifunctional polyimide/graphene oxide composites via in situ polymerization journal, December 2013

Polymer electrolytes based on acrylonitrile–butyl acrylate copolymers and lithium bis(trifluoromethanesulfone)imide journal, August 2005

Effect of LiClO 4 on the Structure and Mobility of PEO-Based Solid Polymer Electrolytes journal, March 2009

Sulfide solid electrolytes for all-solid-state lithium batteries: Structure, conductivity, stability and application journal, September 2018

Electrochemical study of polymethacrylonitrile electrolytes journal, February 2002

Composite polyether based solid electrolytes. The Lewis acid-base approach journal, May 1996

Free-standing sulfide/polymer composite solid electrolyte membranes with high conductance for all-solid-state lithium batteries journal, March 2020

UV-cross-linked poly(ethylene oxide carbonate) as free standing solid polymer electrolyte for lithium batteries journal, April 2019

High-Performance 3-D Fiber Network Composite Electrolyte Enabled with Li-Ion Conducting Nanofibers and Amorphous PEO-Based Cross-Linked Polymer for Ambient All-Solid-State Lithium-Metal Batteries journal, July 2019

Polymer-ceramic ion-conducting composites journal, July 1996

Toward High‐Energy‐Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytes journal, January 2020

Effect of silane-functionalized mesoporous silica SBA-15 on performance of PEO-based composite polymer electrolytes journal, June 2006

Interface-Enabled Ion Conduction in Li 10 GeP 2 S 12 –Poly(ethylene Oxide) Hybrid Electrolytes journal, January 2019

All solid-state polymer electrolytes for high-performance lithium ion batteries journal, October 2016

Polymer-in-Salt Electrolytes Based on Acrylonitrile/Butyl Acrylate Copolymers and Lithium Salts journal, September 2004

High ionic conductivity in lithium lanthanum titanate journal, June 1993

Integrated Interface Strategy toward Room Temperature Solid-State Lithium Batteries journal, April 2018

A continuum percolation model for dispersed ionic conductors journal, April 1990

Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes journal, January 2018

High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO 2 Nanospheres in Poly(ethylene oxide) journal, December 2015

Understanding glass fiber membrane used as a novel separator for lithium–sulfur batteries journal, April 2016

Lithium-Salt-Rich PEO/Li _0.3 La _0.557 TiO ₃ Interpenetrating Composite Electrolyte with Three-Dimensional Ceramic Nano-Backbone for All-Solid-State Lithium-Ion Batteries
journal, July 2018

Electrochemical and Structural Analysis in All‐Solid‐State Lithium Batteries by Analytical Electron Microscopy: Progress and Perspectives
journal, October 2019

Synthesis and Properties of Polyimide Composites Containing Graphene Oxide Via In-Situ Polymerization
journal, October 2012

Fast Na+-ion transport in skeleton structures
journal, February 1976

Electrospun ZnO–SnO2 composite nanofibers with enhanced electrochemical performance as lithium-ion anodes
journal, July 2016

PEO-based composite polymer electrolytes
journal, July 1998

Enhancement of ion dynamics in PMMA-based gels with addition of TiO2 nano-particles
journal, June 2003

Solvation of lithium salts within single-phase dimethyl siloxane bisphenol-A carbonate block copolymer
journal, April 2000

Effect of reduced graphene oxide reduction degree on the performance of polysulfide rejection in lithium-sulfur batteries
journal, January 2018

Thermal, electrical, and mechanical properties of composite polymer electrolytes based on cross-linked poly(ethylene oxide-co-propylene oxide) and ceramic filler
journal, May 2003

Nitrogen-doped carbon nanofibers derived from polyacrylonitrile for use as anode material in sodium-ion batteries
journal, November 2015

A review of lithium and non-lithium based solid state batteries
journal, May 2015

Empirical parameters for donor and acceptor properties of solvents
journal, September 1976

From colloidal to composite electrolytes: properties, peculiarities, and possibilities
journal, September 2004

Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
journal, January 2015

Selective Transporting of Lithium Ion by Shape Selective Molecular Sieves ZSM-5 in PEO-Based Composite Polymer Electrolyte
journal, November 2004

Multinuclear in situ magnetic resonance imaging of electrochemical double-layer capacitors
journal, August 2014

Polycondensation as a Versatile Synthetic Route to Aliphatic Polycarbonates for Solid Polymer Electrolytes
journal, May 2017

Designing solid-state electrolytes for safe, energy-dense batteries
journal, February 2020

Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts
journal, September 1983

Elastic Single-Ion Conducting Polymer Electrolytes: Toward a Versatile Approach for Intrinsically Stretchable Functional Polymers
journal, April 2020

Rubbery Block Copolymer Electrolytes for Solid-State Rechargeable Lithium Batteries
journal, January 1999

Carbon-Coated Magnesium Ferrite Nanofibers for Lithium-Ion Battery Anodes with Enhanced Cycling Performance
journal, March 2017

Study of segmental dynamics and ion transport in polymer–ceramic composite electrolytes by quasi-elastic neutron scattering
journal, January 2019

Porous one-dimensional carbon/iron oxide composite for rechargeable lithium-ion batteries with high and stable capacity
journal, July 2016

Effect of modified SiO2 on the properties of PEO-based polymer electrolytes
journal, October 2003

Ion conduction and relaxation in PEO-LiTFSI-Al ₂ O ₃ polymer nanocomposite electrolytes
journal, May 2015

Miscibility studies of high Tg polyester and polycarbonate blends
journal, May 1994

A star-shaped single lithium-ion conducting copolymer by grafting a POSS nanoparticle
journal, August 2017

Challenges and opportunities towards fast-charging battery materials
journal, June 2019

Lithium ion conductive glass ceramics in the system Li1.4Al0.4(Ge1?xTix)1.6(PO4)3 (x=0?1.0)
journal, July 2004

Grain boundary resistance of fast lithium ion conductors: Comparison between a lithium-ion conductive Li–Al–Ti–P–O-type glass ceramic and a Li1.5Al0.5Ge1.5P3O12 ceramic
journal, January 2012

Ion-conductive properties of polyether-based composite electrolytes filled with mesoporous silica, alumina and titania
journal, December 2013

A novel separator coated by carbon for achieving exceptional high performance lithium-sulfur batteries
journal, February 2016

Transport and interfacial properties of composite polymer electrolytes
journal, January 2000

Sulfur gradient-distributed CNF composite: a self-inhibiting cathode for binder-free lithium–sulfur batteries
journal, January 2014

A three-dimensional interconnected polymer/ceramic composite as a thin film solid electrolyte
journal, April 2020

Engineering a flexible and mechanically strong composite electrolyte for solid-state lithium batteries
journal, July 2020

Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂
journal, October 2007

Synthesis and properties of organic/inorganic hybrid branched-graft copolymers and their application to solid-state electrolytes for high-temperature lithium-ion batteries
journal, January 2014

Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor
journal, February 2011

Reversible monoclinic-rhombohedral transformation in LiSn2(PO4)3 with NASICON-type structure
journal, October 1995

Polymer electrolytes based on polycarbonates and their electrochemical and thermal properties
journal, September 2012

Examination of the fundamental relation between ionic transport and segmental relaxation in polymer electrolytes
journal, August 2014

Investigation of mechanical properties of polyvinyl chloride–polyethylene oxide (PVC–PEO) based polymer electrolytes for lithium polymer cells
journal, May 2007

Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte
journal, June 2019

A New All-Solid-State Hyperbranched Star Polymer Electrolyte for Lithium Ion Batteries: Synthesis and Electrochemical Properties
journal, September 2016

Bi-layer lithium phosphorous oxynitride/aluminium substituted lithium lanthanum titanate as a promising solid electrolyte for long-life rechargeable lithium–oxygen batteries
journal, January 2015

Hierarchical multi-component nanofiber separators for lithium polysulfide capture in lithium–sulfur batteries: an experimental and molecular modeling study
journal, January 2016

Remarkable Conductivity of a Self-Healing Single-Ion Conducting Polymer Electrolyte, Poly(ethylene- co -acrylic lithium (fluoro sulfonyl)imide), for All-Solid-State Li-Ion Batteries
journal, June 2019

In Situ Synthesis of a Hierarchical All-Solid-State Electrolyte Based on Nitrile Materials for High-Performance Lithium-Ion Batteries
journal, May 2015

Influence of zeolite on electrochemical and physicochemical properties of polyethylene oxide solid electrolyte
journal, September 1995

Enhancement of ionic conductivity of composite membranes for all-solid-state lithium rechargeable batteries incorporating tetragonal Li7La3Zr2O12 into a polyethylene oxide matrix
journal, January 2015

Lithium Ion Solvation and Diffusion in Bulk Organic Electrolytes from First-Principles and Classical Reactive Molecular Dynamics
journal, January 2015

Decoupling Ionic Conductivity from Structural Relaxation: A Way to Solid Polymer Electrolytes?
journal, June 2011

Perspectives for Polymer Electrolytes: A View from Fundamentals of Ionic Conductivity
journal, April 2020

Multifunctional polyimide/graphene oxide composites via in situ polymerization
journal, December 2013

Polymer electrolytes based on acrylonitrile–butyl acrylate copolymers and lithium bis(trifluoromethanesulfone)imide
journal, August 2005

Effect of LiClO ₄ on the Structure and Mobility of PEO-Based Solid Polymer Electrolytes
journal, March 2009

Sulfide solid electrolytes for all-solid-state lithium batteries: Structure, conductivity, stability and application
journal, September 2018

Electrochemical study of polymethacrylonitrile electrolytes
journal, February 2002

Composite polyether based solid electrolytes. The Lewis acid-base approach
journal, May 1996

Free-standing sulfide/polymer composite solid electrolyte membranes with high conductance for all-solid-state lithium batteries
journal, March 2020

UV-cross-linked poly(ethylene oxide carbonate) as free standing solid polymer electrolyte for lithium batteries
journal, April 2019

High-Performance 3-D Fiber Network Composite Electrolyte Enabled with Li-Ion Conducting Nanofibers and Amorphous PEO-Based Cross-Linked Polymer for Ambient All-Solid-State Lithium-Metal Batteries
journal, July 2019

Polymer-ceramic ion-conducting composites
journal, July 1996

Toward High‐Energy‐Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytes
journal, January 2020

Effect of silane-functionalized mesoporous silica SBA-15 on performance of PEO-based composite polymer electrolytes
journal, June 2006

Interface-Enabled Ion Conduction in Li ₁₀ GeP ₂ S ₁₂ –Poly(ethylene Oxide) Hybrid Electrolytes
journal, January 2019

All solid-state polymer electrolytes for high-performance lithium ion batteries
journal, October 2016

Polymer-in-Salt Electrolytes Based on Acrylonitrile/Butyl Acrylate Copolymers and Lithium Salts
journal, September 2004

High ionic conductivity in lithium lanthanum titanate
journal, June 1993

Integrated Interface Strategy toward Room Temperature Solid-State Lithium Batteries
journal, April 2018

A continuum percolation model for dispersed ionic conductors
journal, April 1990

Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes
journal, January 2018

High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO ₂ Nanospheres in Poly(ethylene oxide)
journal, December 2015

Understanding glass fiber membrane used as a novel separator for lithium–sulfur batteries
journal, April 2016

Molecular Transport in Liquids and Glasses
journal, November 1959

Tailored crosslinking of Poly(ethylene oxide) enables mechanical robustness and improved sodium-ion conductivity
journal, September 2019

Facile and scalable fabrication of polymer-ceramic composite electrolyte with high ceramic loadings
journal, June 2018