Uncharted Waters: Super-Concentrated Electrolytes

Borodin, Oleg; Self, Julian; Persson, Kristin A.; Wang, Chunsheng; Xu, Kang

doi:10.1016/j.joule.2019.12.007

Title: Uncharted Waters: Super-Concentrated Electrolytes

Journal Article · 31 December 2019 · Joule

DOI: https://doi.org/10.1016/j.joule.2019.12.007 · OSTI ID:1766109

Borodin, Oleg; Self, Julian; Persson, Kristin A.; Wang, Chunsheng; Xu, Kang

Not Available

View Journal Article

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1766109

Journal Information:: Joule, Journal Name: Joule Journal Issue: 1 Vol. 4; ISSN 2542-4351

Publisher:: Elsevier - Cell PressCopyright Statement

Country of Publication:: United States

Language:: English

References (110)

Flexible Aqueous Li-Ion Battery with High Energy and Power Densities Yang, Chongyin; Ji, Xiao; Fan, Xiulin Advanced Materials, Vol. 29, Issue 44 https://doi.org/10.1002/adma.201701972	journal	October 2017
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes Kim, Hyea; Wu, Feixiang; Lee, Jung Tae Advanced Energy Materials, Vol. 5, Issue 6 https://doi.org/10.1002/aenm.201401792	journal	December 2014
“Water-in-Salt” Electrolyte Makes Aqueous Sodium-Ion Battery Safe, Green, and Long-Lasting Suo, Liumin; Borodin, Oleg; Wang, Yuesheng Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201701189	journal	July 2017
Advanced High-Voltage Aqueous Lithium-Ion Battery Enabled by “Water-in-Bisalt” Electrolyte Suo, Liumin; Borodin, Oleg; Sun, Wei Angewandte Chemie International Edition, Vol. 55, Issue 25 https://doi.org/10.1002/anie.201602397	journal	April 2016
Fading Mechanisms and Voltage Hysteresis in FeF ₂ -NiF ₂ Solid Solution Cathodes for Lithium and Lithium-Ion Batteries Huang, Qiao; Pollard, Travis P.; Ren, Xiaolei Small, Vol. 15, Issue 6 https://doi.org/10.1002/smll.201804670	journal	January 2019
Li + Transport Mechanism in Oligo(Ethylene Oxide)s Compared to Carbonates Borodin, Oleg; Smith, G. D. Journal of Solution Chemistry, Vol. 36, Issue 6 https://doi.org/10.1007/s10953-007-9146-1	journal	April 2007
Lithium batteries: a 50-year perspective, 1959–2009 Vincent, C. Solid State Ionics, Vol. 134, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00723-2	journal	October 2000
Cathodically Stable Li-O2 Battery Operations Using Water-in-Salt Electrolyte Dong, Qi; Yao, Xiahui; Zhao, Yanyan Chem, Vol. 4, Issue 6 https://doi.org/10.1016/j.chempr.2018.02.015	journal	June 2018
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries Ren, Xiaodi; Chen, Shuru; Lee, Hongkyung Chem, Vol. 4, Issue 8 https://doi.org/10.1016/j.chempr.2018.05.002	journal	August 2018
Understanding Thermodynamic and Kinetic Contributions in Expanding the Stability Window of Aqueous Electrolytes Zheng, Jiaxin; Tan, Guoyu; Shan, Peng Chem, Vol. 4, Issue 12 https://doi.org/10.1016/j.chempr.2018.09.004	journal	December 2018
Challenges with prediction of battery electrolyte electrochemical stability window and guiding the electrode – electrolyte stabilization Borodin, Oleg Current Opinion in Electrochemistry, Vol. 13 https://doi.org/10.1016/j.coelec.2018.10.015	journal	February 2019
Electrodeposition of rhenium with suppressed hydrogen evolution from water-in-salt electrolyte Huang, Q.; Lyons, T. W. Electrochemistry Communications, Vol. 93 https://doi.org/10.1016/j.elecom.2018.06.003	journal	August 2018
Towards stable lithium-sulfur batteries: Mechanistic insights into electrolyte decomposition on lithium metal anode Chen, Xiang; Hou, Ting-Zheng; Li, Bo Energy Storage Materials, Vol. 8 https://doi.org/10.1016/j.ensm.2017.01.003	journal	July 2017
4.0 V Aqueous Li-Ion Batteries Yang, Chongyin; Chen, Ji; Qing, Tingting Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.08.009	journal	September 2017
Hybrid Aqueous/Non-aqueous Electrolyte for Safe and High-Energy Li-Ion Batteries Wang, Fei; Borodin, Oleg; Ding, Michael S. Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.02.011	journal	May 2018
Toward True Lithium-Air Batteries Wu, Feixiang; Yu, Yan Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.04.019	journal	May 2018
High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes Chen, Shuru; Zheng, Jianming; Yu, Lu Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.002	journal	August 2018
Stretchable Lithium Metal Anode with Improved Mechanical and Electrochemical Cycling Stability Liu, Kai; Kong, Biao; Liu, Wei Joule, Vol. 2, Issue 9 https://doi.org/10.1016/j.joule.2018.06.003	journal	September 2018
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions Ren, Xiaodi; Zou, Lianfeng; Cao, Xia Joule, Vol. 3, Issue 7 https://doi.org/10.1016/j.joule.2019.05.006	journal	July 2019
High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes Yang, Yangyuchen; Davies, Daniel M.; Yin, Yijie Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.06.008	journal	August 2019
New glyme–cyclic imide lithium salt complexes as thermally stable electrolytes for lithium batteries Tamura, Takashi; Hachida, Takeshi; Yoshida, Kazuki Journal of Power Sources, Vol. 195, Issue 18 https://doi.org/10.1016/j.jpowsour.2009.11.061	journal	September 2010
Combined quantum chemical/Raman spectroscopic analyses of Li+ cation solvation: Cyclic carbonate solvents—Ethylene carbonate and propylene carbonate Allen, Joshua L.; Borodin, Oleg; Seo, Daniel M. Journal of Power Sources, Vol. 267 https://doi.org/10.1016/j.jpowsour.2014.05.107	journal	December 2014
Natural abundance 17O, 6Li NMR and molecular modeling studies of the solvation structures of lithium bis(fluorosulfonyl)imide/1,2-dimethoxyethane liquid electrolytes Wan, Chuan; Hu, Mary Y.; Borodin, Oleg Journal of Power Sources, Vol. 307 https://doi.org/10.1016/j.jpowsour.2015.12.120	journal	March 2016
A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries Alvarado, Judith; Schroeder, Marshall A.; Zhang, Minghao Materials Today, Vol. 21, Issue 4 https://doi.org/10.1016/j.mattod.2018.02.005	journal	May 2018
Toward a low-cost high-voltage sodium aqueous rechargeable battery Lee, Myeong Hwan; Kim, Sung Joo; Chang, Donghee Materials Today, Vol. 29 https://doi.org/10.1016/j.mattod.2019.02.004	journal	October 2019
PEO/garnet composite electrolytes for solid-state lithium batteries: From “ceramic-in-polymer” to “polymer-in-ceramic” Chen, Long; Li, Yutao; Li, Shuai-Peng Nano Energy, Vol. 46 https://doi.org/10.1016/j.nanoen.2017.12.037	journal	April 2018
Cyclic and differential pulse voltammetric behavior of reactants confined to the electrode surface Brown, Alan P.; Anson, Fred C. Analytical Chemistry, Vol. 49, Issue 11 https://doi.org/10.1021/ac50019a033	journal	September 1977
Modeling Insight into Battery Electrolyte Electrochemical Stability and Interfacial Structure Borodin, Oleg; Ren, Xiaoming; Vatamanu, Jenel Accounts of Chemical Research, Vol. 50, Issue 12 https://doi.org/10.1021/acs.accounts.7b00486	journal	November 2017
Before Li Ion Batteries Winter, Martin; Barnett, Brian; Xu, Kang Chemical Reviews, Vol. 118, Issue 23 https://doi.org/10.1021/acs.chemrev.8b00422	journal	November 2018
Theoretical Analysis of Carrier Ion Diffusion in Superconcentrated Electrolyte Solutions for Sodium-Ion Batteries Okoshi, Masaki; Chou, Chien-Pin; Nakai, Hiromi The Journal of Physical Chemistry B, Vol. 122, Issue 9 https://doi.org/10.1021/acs.jpcb.7b10589	journal	February 2018
Polarizable Molecular Dynamics and Experiments of 1,2-Dimethoxyethane Electrolytes with Lithium and Sodium Salts: Structure and Transport Properties Liyana-Arachchi, Thilanga P.; Haskins, Justin B.; Burke, Colin M. The Journal of Physical Chemistry B, Vol. 122, Issue 36 https://doi.org/10.1021/acs.jpcb.8b03445	journal	August 2018
Charge Transport in [Li(tetraglyme)][bis(trifluoromethane) sulfonimide] Solvate Ionic Liquids: Insight from Molecular Dynamics Simulations Dong, Dengpan; Bedrov, Dmitry The Journal of Physical Chemistry B, Vol. 122, Issue 43 https://doi.org/10.1021/acs.jpcb.8b06913	journal	October 2018
Direct Evidence for Li Ion Hopping Conduction in Highly Concentrated Sulfolane-Based Liquid Electrolytes Dokko, Kaoru; Watanabe, Daiki; Ugata, Yosuke The Journal of Physical Chemistry B, Vol. 122, Issue 47 https://doi.org/10.1021/acs.jpcb.8b09439	journal	November 2018
Anion Solvation in Carbonate-Based Electrolytes von Wald Cresce, Arthur; Gobet, Mallory; Borodin, Oleg The Journal of Physical Chemistry C, Vol. 119, Issue 49 https://doi.org/10.1021/acs.jpcc.5b08895	journal	November 2015
Novel Na ⁺ Ion Diffusion Mechanism in Mixed Organic–Inorganic Ionic Liquid Electrolyte Leading to High Na ⁺ Transference Number and Stable, High Rate Electrochemical Cycling of Sodium Cells. Forsyth, Maria; Yoon, Hyungook; Chen, Fangfang The Journal of Physical Chemistry C, Vol. 120, Issue 8 https://doi.org/10.1021/acs.jpcc.5b11746	journal	February 2016
Spectroscopic and Density Functional Theory Characterization of Common Lithium Salt Solvates in Carbonate Electrolytes for Lithium Batteries Chapman, Navid; Borodin, Oleg; Yoon, Taeho The Journal of Physical Chemistry C, Vol. 121, Issue 4 https://doi.org/10.1021/acs.jpcc.6b12234	journal	January 2017
Highly Concentrated Electrolytes Containing a Phosphoric Acid Ester Amide with Self-Extinguishing Properties for Use in Lithium Batteries Shiga, Tohru; Okuda, Chika-aki; Kato, Yuichi The Journal of Physical Chemistry C, Vol. 122, Issue 18 https://doi.org/10.1021/acs.jpcc.7b12461	journal	April 2018
Insights into the Structure and Transport of the Lithium, Sodium, Magnesium, and Zinc Bis(trifluoromethansulfonyl)imide Salts in Ionic Liquids Borodin, Oleg; Giffin, Guinevere A.; Moretti, Arianna The Journal of Physical Chemistry C, Vol. 122, Issue 35 https://doi.org/10.1021/acs.jpcc.8b05573	journal	August 2018
Sulfolane-Based Highly Concentrated Electrolytes of Lithium Bis(trifluoromethanesulfonyl)amide: Ionic Transport, Li-Ion Coordination, and Li–S Battery Performance Nakanishi, Azusa; Ueno, Kazuhide; Watanabe, Daiki The Journal of Physical Chemistry C, Vol. 123, Issue 23 https://doi.org/10.1021/acs.jpcc.9b02625	journal	May 2019
Ramifications of Water-in-Salt Interfacial Structure at Charged Electrodes for Electrolyte Electrochemical Stability Vatamanu, Jenel; Borodin, Oleg The Journal of Physical Chemistry Letters, Vol. 8, Issue 18 https://doi.org/10.1021/acs.jpclett.7b01879	journal	August 2017
Theory of the Double Layer in Water-in-Salt Electrolytes McEldrew, Michael; Goodwin, Zachary A. H.; Kornyshev, Alexei A. The Journal of Physical Chemistry Letters, Vol. 9, Issue 19 https://doi.org/10.1021/acs.jpclett.8b02543	journal	September 2018
Probing Electric Double-Layer Composition via in Situ Vibrational Spectroscopy and Molecular Simulations Raberg, Jonathan H.; Vatamanu, Jenel; Harris, Stephen J. The Journal of Physical Chemistry Letters, Vol. 10, Issue 12 https://doi.org/10.1021/acs.jpclett.9b00879	journal	May 2019
Tuning the Hydrogen Evolution Reaction on Metals by Lithium Salt Guha, Anku; Narayanaru, Sreekanth; Narayanan, Tharangattu N. ACS Applied Energy Materials, Vol. 1, Issue 12 https://doi.org/10.1021/acsaem.8b01546	journal	October 2018
Unusual Passivation Ability of Superconcentrated Electrolytes toward Hard Carbon Negative Electrodes in Sodium-Ion Batteries Takada, Koji; Yamada, Yuki; Watanabe, Eriko ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b08414	journal	April 2017
Directing the Lithium–Sulfur Reaction Pathway via Sparingly Solvating Electrolytes for High Energy Density Batteries Lee, Chang-Wook; Pang, Quan; Ha, Seungbum ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00123	journal	May 2017
High-Voltage Aqueous Magnesium Ion Batteries Wang, Fei; Fan, Xiulin; Gao, Tao ACS Central Science, Vol. 3, Issue 10 https://doi.org/10.1021/acscentsci.7b00361	journal	September 2017
A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal Batteries Yu, Lu; Chen, Shuru; Lee, Hongkyung ACS Energy Letters, Vol. 3, Issue 9 https://doi.org/10.1021/acsenergylett.8b00935	journal	July 2018
Transport in Superconcentrated LiPF ₆ and LiBF ₄ /Propylene Carbonate Electrolytes Self, Julian; Fong, Kara D.; Persson, Kristin A. ACS Energy Letters, Vol. 4, Issue 12 https://doi.org/10.1021/acsenergylett.9b02118	journal	October 2019
Liquid Structure with Nano-Heterogeneity Promotes Cationic Transport in Concentrated Electrolytes Borodin, Oleg; Suo, Liumin; Gobet, Mallory ACS Nano, Vol. 11, Issue 10 https://doi.org/10.1021/acsnano.7b05664	journal	October 2017
General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes Yamada, Yuki; Usui, Kenji; Chiang, Ching Hua ACS Applied Materials & Interfaces, Vol. 6, Issue 14, p. 10892-10899 https://doi.org/10.1021/am5001163	journal	March 2014
Ion transport in solvent-free polymers Ratner, Mark A.; Shriver, Duward F. Chemical Reviews, Vol. 88, Issue 1 https://doi.org/10.1021/cr00083a006	journal	January 1988
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes Yoshida, Kazuki; Nakamura, Megumi; Kazue, Yuichi Journal of the American Chemical Society, Vol. 133, Issue 33, p. 13121-13129 https://doi.org/10.1021/ja203983r	journal	August 2011
Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046 https://doi.org/10.1021/ja412807w	journal	March 2014
How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes Suo, Liumin; Oh, Dahyun; Lin, Yuxiao Journal of the American Chemical Society, Vol. 139, Issue 51 https://doi.org/10.1021/jacs.7b10688	journal	December 2017
Temperature Dependence of Self-Diffusion Coefficients of Ions and Solvents in Ethylene Carbonate, Propylene Carbonate, and Diethyl Carbonate Single Solutions and Ethylene Carbonate + Diethyl Carbonate Binary Solutions of LiPF ₆ Studied by NMR Hayamizu, Kikuko Journal of Chemical & Engineering Data, Vol. 57, Issue 7 https://doi.org/10.1021/je3003089	journal	June 2012
LiTFSI Structure and Transport in Ethylene Carbonate from Molecular Dynamics Simulations Borodin, Oleg; Smith, Grant D. The Journal of Physical Chemistry B, Vol. 110, Issue 10 https://doi.org/10.1021/jp056249q	journal	March 2006
Glyme−Lithium Salt Phase Behavior Henderson, Wesley A. The Journal of Physical Chemistry B, Vol. 110, Issue 26 https://doi.org/10.1021/jp061516t	journal	July 2006
Electrochemical Lithium Intercalation into Graphite in Dimethyl Sulfoxide-Based Electrolytes: Effect of Solvation Structure of Lithium Ion Yamada, Yuki; Takazawa, Yasuyuki; Miyazaki, Kohei The Journal of Physical Chemistry C, Vol. 114, Issue 26 https://doi.org/10.1021/jp1037427	journal	June 2010
Change from Glyme Solutions to Quasi-ionic Liquids for Binary Mixtures Consisting of Lithium Bis(trifluoromethanesulfonyl)amide and Glymes Yoshida, Kazuki; Tsuchiya, Mizuho; Tachikawa, Naoki The Journal of Physical Chemistry C, Vol. 115, Issue 37 https://doi.org/10.1021/jp206881t	journal	August 2011
Molecular Dynamics Simulation Studies of the Structure of a Mixed Carbonate/LiPF ₆ Electrolyte near Graphite Surface as a Function of Electrode Potential Vatamanu, Jenel; Borodin, Oleg; Smith, Grant D. The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp2101539	journal	December 2011
Correlating Li ⁺ Solvation Sheath Structure with Interphasial Chemistry on Graphite von Wald Cresce, Arthur; Borodin, Oleg; Xu, Kang The Journal of Physical Chemistry C, Vol. 116, Issue 50 https://doi.org/10.1021/jp303610t	journal	December 2012
Glyme–Lithium Salt Equimolar Molten Mixtures: Concentrated Solutions or Solvate Ionic Liquids? Ueno, Kazuhide; Yoshida, Kazuki; Tsuchiya, Mizuho The Journal of Physical Chemistry B, Vol. 116, Issue 36 https://doi.org/10.1021/jp307378j	journal	August 2012
Influence of Solvent on Ion Aggregation and Transport in PY ₁₅ TFSI Ionic Liquid–Aprotic Solvent Mixtures Borodin, Oleg; Henderson, Wesley A.; Fox, Eric T. The Journal of Physical Chemistry B, Vol. 117, Issue 36 https://doi.org/10.1021/jp406541e	journal	August 2013
Sacrificial Anion Reduction Mechanism for Electrochemical Stability Improvement in Highly Concentrated Li-Salt Electrolyte Sodeyama, Keitaro; Yamada, Yuki; Aikawa, Koharu The Journal of Physical Chemistry C, Vol. 118, Issue 26, p. 14091-14097 https://doi.org/10.1021/jp501178n	journal	June 2014
Chelate Effects in Glyme/Lithium Bis(trifluoromethanesulfonyl)amide Solvate Ionic Liquids. I. Stability of Solvate Cations and Correlation with Electrolyte Properties Zhang, Ce; Ueno, Kazuhide; Yamazaki, Azusa The Journal of Physical Chemistry B, Vol. 118, Issue 19 https://doi.org/10.1021/jp501319e	journal	May 2014
Quantum Chemistry and Molecular Dynamics Simulation Study of Dimethyl Carbonate: Ethylene Carbonate Electrolytes Doped with LiPF ₆ Borodin, Oleg; Smith, Grant D. The Journal of Physical Chemistry B, Vol. 113, Issue 6 https://doi.org/10.1021/jp809614h	journal	February 2009
Pulse-Gradient Spin-Echo ¹ H, ⁷ Li, and ¹⁹ F NMR Diffusion and Ionic Conductivity Measurements of 14 Organic Electrolytes Containing LiN(SO ₂ CF ₃ ) ₂ Hayamizu, Kikuko; Aihara, Yuichi; Arai, Shigemasa The Journal of Physical Chemistry B, Vol. 103, Issue 3 https://doi.org/10.1021/jp9825664	journal	January 1999
In Situ and Quantitative Characterization of Solid Electrolyte Interphases Cresce, Arthur v.; Russell, Selena M.; Baker, David R. Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl404471v	journal	February 2014
Rubbery solid electrolytes with dominant cationic transport and high ambient conductivity Angell, C. A.; Liu, C.; Sanchez, E. Nature, Vol. 362, Issue 6416 https://doi.org/10.1038/362137a0	journal	March 1993
Superconcentrated electrolytes for a high-voltage lithium-ion battery Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12032	journal	June 2016
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries Suo, Liumin; Hu, Yong-Sheng; Li, Hong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2513	journal	February 2013
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Hydrate-melt electrolytes for high-energy-density aqueous batteries Yamada, Yuki; Usui, Kenji; Sodeyama, Keitaro Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.129	journal	August 2016
Batteries: Widening voltage windows Xu, Kang; Wang, Chunsheng Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.161	journal	October 2016
An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes Son, Seoung-Bum; Gao, Tao; Harvey, Steve P. Nature Chemistry, Vol. 10, Issue 5 https://doi.org/10.1038/s41557-018-0019-6	journal	April 2018
Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization Cao, Xia; Ren, Xiaodi; Zou, Lianfeng Nature Energy, Vol. 4, Issue 9 https://doi.org/10.1038/s41560-019-0464-5	journal	September 2019
All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents Fan, Xiulin; Ji, Xiao; Chen, Long Nature Energy, Vol. 4, Issue 10 https://doi.org/10.1038/s41560-019-0474-3	journal	October 2019
Highly reversible zinc metal anode for aqueous batteries Wang, Fei; Borodin, Oleg; Gao, Tao Nature Materials, Vol. 17, Issue 6 https://doi.org/10.1038/s41563-018-0063-z	journal	April 2018
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries Fan, Xiulin; Chen, Long; Borodin, Oleg Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0183-2	journal	July 2018
Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite Yang, Chongyin; Chen, Ji; Ji, Xiao Nature, Vol. 569, Issue 7755 https://doi.org/10.1038/s41586-019-1175-6	journal	May 2019
Quantifying inactive lithium in lithium metal batteries Fang, Chengcheng; Li, Jinxing; Zhang, Minghao Nature, Vol. 572, Issue 7770 https://doi.org/10.1038/s41586-019-1481-z	journal	August 2019
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms McOwen, Dennis W.; Seo, Daniel M.; Borodin, Oleg Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42351D	journal	January 2014
“Solvent-in-salt” systems for design of new materials in chemistry, biology and energy research Azov, Vladimir A.; Egorova, Ksenia S.; Seitkalieva, Marina M. Chemical Society Reviews, Vol. 47, Issue 4 https://doi.org/10.1039/C7CS00547D	journal	January 2018
A ZnCl ₂ water-in-salt electrolyte for a reversible Zn metal anode Zhang, Chong; Holoubek, John; Wu, Xianyong Chemical Communications, Vol. 54, Issue 100 https://doi.org/10.1039/C8CC07730D	journal	January 2018
How efficient is Li ⁺ ion transport in solvate ionic liquids under anion-blocking conditions in a battery? Dong, Dengpan; Sälzer, Fabian; Roling, Bernhard Physical Chemistry Chemical Physics, Vol. 20, Issue 46 https://doi.org/10.1039/C8CP06214E	journal	January 2018
The role of the hydrogen evolution reaction in the solid–electrolyte interphase formation mechanism for “ Water-in-Salt ” electrolytes Dubouis, Nicolas; Lemaire, Pierre; Mirvaux, Boris Energy & Environmental Science, Vol. 11, Issue 12 https://doi.org/10.1039/C8EE02456A	journal	January 2018
Bisalt ether electrolytes: a pathway towards lithium metal batteries with Ni-rich cathodes Alvarado, Judith; Schroeder, Marshall A.; Pollard, Travis P. Energy & Environmental Science, Vol. 12, Issue 2 https://doi.org/10.1039/C8EE02601G	journal	January 2019
A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions Bernal, J. D.; Fowler, R. H. The Journal of Chemical Physics, Vol. 1, Issue 8 https://doi.org/10.1063/1.1749327	journal	August 1933
Ionic conduction and self-diffusion near infinitesimal concentration in lithium salt-organic solvent electrolytes Aihara, Yuichi; Sugimoto, Kyoko; Price, William S. The Journal of Chemical Physics, Vol. 113, Issue 5 https://doi.org/10.1063/1.482004	journal	August 2000
Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility Yang, Chongyin; Suo, Liumin; Borodin, Oleg Proceedings of the National Academy of Sciences, Vol. 114, Issue 24 https://doi.org/10.1073/pnas.1703937114	journal	May 2017
Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery Fan, Xiulin; Ji, Xiao; Han, Fudong Science Advances, Vol. 4, Issue 12 https://doi.org/10.1126/sciadv.aau9245	journal	December 2018
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Electrochemical Intercalation of Lithium Ion within Graphite from Propylene Carbonate Solutions Jeong, Soon-Ki; Inaba, Minoru; Iriyama, Yasutoshi Electrochemical and Solid-State Letters, Vol. 6, Issue 1 https://doi.org/10.1149/1.1526781	journal	January 2003
Ion Transport Properties of Six Lithium Salts Dissolved in γ-Butyrolactone Studied by Self-Diffusion and Ionic Conductivity Measurements Aihara, Yuichi; Bando, Toshinori; Nakagawa, Hiroe Journal of The Electrochemical Society, Vol. 151, Issue 1 https://doi.org/10.1149/1.1630592	journal	January 2004
Sulfamides and Glymes as Aprotic Solvents for Lithium Batteries Choquette, Yves Journal of The Electrochemical Society, Vol. 145, Issue 10 https://doi.org/10.1149/1.1838834	journal	January 1998
How to Reduce the Cointercalation of Propylene Carbonate in Li x ZrS2 and Other Layered Compounds McKinnon, W. R.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 132, Issue 2 https://doi.org/10.1149/1.2113839	journal	February 1985
Physicochemical and Electrochemical Properties of Glyme-LiN(SO2F)2 Complex for Safe Lithium-ion Secondary Battery Electrolyte Seki, Shiro; Takei, Katsuhito; Miyashiro, Hajime Journal of The Electrochemical Society, Vol. 158, Issue 6 https://doi.org/10.1149/1.3582822	journal	January 2011
Electrolyte Solvation and Ionic Association: V. Acetonitrile-Lithium Bis(fluorosulfonyl)imide (LiFSI) Mixtures Han, Sang-Don; Borodin, Oleg; Seo, Daniel M. Journal of The Electrochemical Society, Vol. 161, Issue 14 https://doi.org/10.1149/2.0101414jes	journal	January 2014
Electrolyte Solvation and Ionic Association III. Acetonitrile-Lithium Salt Mixtures–Transport Properties Seo, Daniel M.; Borodin, Oleg; Balogh, Daniel Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.018308jes	journal	January 2013
Electrodeposition of Superconducting Rhenium with Water-in-Salt Electrolyte Huang, Q.; Hu, Y. Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0261816jes	journal	January 2018
Perspective—Fluorinating Interphases Wang, Chunsheng; Meng, Ying Shirley; Xu, Kang Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0281903jes	journal	December 2018
Electrolyte Solvation and Ionic Association II. Acetonitrile-Lithium Salt Mixtures: Highly Dissociated Salts Seo, Daniel M.; Borodin, Oleg; Han, Sang-Don Journal of The Electrochemical Society, Vol. 159, Issue 9 https://doi.org/10.1149/2.035209jes	journal	January 2012
Li ⁺ Transference Numbers in Liquid Electrolytes Obtained by Very-Low-Frequency Impedance Spectroscopy at Variable Electrode Distances Wohde, F.; Balabajew, M.; Roling, B. Journal of The Electrochemical Society, Vol. 163, Issue 5 https://doi.org/10.1149/2.0811605jes	journal	January 2016
Electrolyte Solvation and Ionic Association: VI. Acetonitrile-Lithium Salt Mixtures: Highly Associated Salts Revisited Borodin, Oleg; Han, Sang-Don; Daubert, James S. Journal of The Electrochemical Society, Vol. 162, Issue 4 https://doi.org/10.1149/2.0891503jes	journal	January 2015
Controlling Ionic Transport through the PEO-LiTFSI/LLZTO Interface Gupta, Arushi; Sakamoto, Jeff The Electrochemical Society Interface, Vol. 28, Issue 2 https://doi.org/10.1149/2.F06192if	journal	January 2019
Electrolyte Solvation and Ionic Association Seo, Daniel M.; Borodin, Oleg; Han, Sang-Don Journal of The Electrochemical Society, Vol. 159, Issue 5 https://doi.org/10.1149/2.jes112264	journal	January 2012
Physicochemical Properties of Glyme–Li Salt Complexes as a New Family of Room-temperature Ionic Liquids Tamura, Takashi; Yoshida, Kazuki; Hachida, Takeshi Chemistry Letters, Vol. 39, Issue 7 https://doi.org/10.1246/cl.2010.753	journal	July 2010

Similar Records

ACTIVITY OF WATER AND ELECTROLYTES IN CONCENTRATED ELECTROLYTE SOLUTIONS.

Journal Article · 1969 · Z. Phys. Chem. (Leipzig) 245: No. 5-6, 431-5(1970). · OSTI ID:4690714

Kalman, E

Ion Transport in (Localized) High Concentration Electrolytes for Li-Based Batteries

Journal Article · 2024 · ACS Energy Letters · OSTI ID:2278901

Bergstrom, Helen K.; McCloskey, Bryan D.

INFLUENCE OF IMPURITIES ON THE ELECTROLYTIC CONCENTRATION OF HEAVY WATER

Journal Article · 1956 · Kgl. Norske Videnskab. Selskabs. Forh. · OSTI ID:4234750

Brun, J; Gundersen, W; Varberg, Th

Related Subjects

25 ENERGY STORAGE
electrolytes
ion transportinter
phaseliquid structure
super-concentration

Title: Uncharted Waters: Super-Concentrated Electrolytes

Citation Formats

References (110)

Similar Records

Related Subjects