Rapid build up of nanooptomechanical transduction in single crystals of a ruthenium-based SO 2 linkage photoisomer
Abstract
Single-crystal nanooptomechanical transduction occurs in [Ru(SO2)(NH3)4(H2O)]chlorobenzenesulfonate2, reaching maximal levels within 40 s at 100 K when photostimulated by 505 nm light. Its in situ light-induced crystal structure reveals the molecular origins of this optical actuation: 26.0(3)% of the η1-SO2 ligand photoconverts into an η1-OSO photoisomer which, in turn, induces a 49.6(9)° arene ring rotation in its neighbouring counter ion.
- Authors:
-
[1];
[2];
[1];
[3];
- Cavendish Laboratory, Department of Physics, University of Cambridge, J. J. Thomson Avenue, Cambridge
- Argonne National Laboratory, 9700 South Cass Avenue, Lemont, USA
- NSF's ChemMatCARS Beamline, The University of Chicago, Advanced Photon Source, Lemont, USA
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1765406
- Alternate Identifier(s):
- OSTI ID: 1777146
- Grant/Contract Number:
- AC02-06CH11357; CHE-1346572; CHE-1834750; DMR-1531283
- Resource Type:
- Published Article
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm Journal Volume: 57 Journal Issue: 11; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Cole, Jacqueline M., Gosztola, David J., Velazquez-Garcia, Jose de J., Grass Wang, SuYin, and Chen, Yu-Sheng. Rapid build up of nanooptomechanical transduction in single crystals of a ruthenium-based SO 2 linkage photoisomer. United Kingdom: N. p., 2021.
Web. doi:10.1039/D0CC06755E.
Cole, Jacqueline M., Gosztola, David J., Velazquez-Garcia, Jose de J., Grass Wang, SuYin, & Chen, Yu-Sheng. Rapid build up of nanooptomechanical transduction in single crystals of a ruthenium-based SO 2 linkage photoisomer. United Kingdom. https://doi.org/10.1039/D0CC06755E
Cole, Jacqueline M., Gosztola, David J., Velazquez-Garcia, Jose de J., Grass Wang, SuYin, and Chen, Yu-Sheng. Thu .
"Rapid build up of nanooptomechanical transduction in single crystals of a ruthenium-based SO 2 linkage photoisomer". United Kingdom. https://doi.org/10.1039/D0CC06755E.
@article{osti_1765406,
title = {Rapid build up of nanooptomechanical transduction in single crystals of a ruthenium-based SO 2 linkage photoisomer},
author = {Cole, Jacqueline M. and Gosztola, David J. and Velazquez-Garcia, Jose de J. and Grass Wang, SuYin and Chen, Yu-Sheng},
abstractNote = {Single-crystal nanooptomechanical transduction occurs in [Ru(SO2)(NH3)4(H2O)]chlorobenzenesulfonate2, reaching maximal levels within 40 s at 100 K when photostimulated by 505 nm light. Its in situ light-induced crystal structure reveals the molecular origins of this optical actuation: 26.0(3)% of the η1-SO2 ligand photoconverts into an η1-OSO photoisomer which, in turn, induces a 49.6(9)° arene ring rotation in its neighbouring counter ion.},
doi = {10.1039/D0CC06755E},
journal = {ChemComm},
number = 11,
volume = 57,
place = {United Kingdom},
year = {Thu Feb 11 00:00:00 EST 2021},
month = {Thu Feb 11 00:00:00 EST 2021}
}
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