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Title: Influence of Coordination Environment of Anchored Single-Site Cobalt Catalyst on CO2 Hydrogenation

Authors:
 [1];  [1];  [1];  [2];  [3]; ORCiD logo [1]
  1. Univ. of South Carolina, Columbia, SC (United States)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Argonne National Lab. (ANL), Lemont, IL (United States); Illinois Institute of Technology, Chicago, IL (United States). Center for Synchrotron Research and Instrumentation
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1763652
Alternate Identifier(s):
OSTI ID: 1579470
Grant/Contract Number:  
AC02-06CH11357; DGE-1250052
Resource Type:
Accepted Manuscript
Journal Name:
ChemCatChem
Additional Journal Information:
Journal Volume: 12; Journal Issue: 3; Journal ID: ISSN 1867-3880
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CO2 methanation; Cobalt single-site catalysts; XAFS; XPS; CO2 hydrogenation; Cobalt; Ensemble effects; Ostwald Ripening

Citation Formats

Jimenez, Juan D., Wen, Cun, Royko, Michael M., Kropf, Arthur J., Segre, Carlo, and Lauterbach, Jochen. Influence of Coordination Environment of Anchored Single-Site Cobalt Catalyst on CO2 Hydrogenation. United States: N. p., 2019. Web. doi:10.1002/cctc.201901676.
Jimenez, Juan D., Wen, Cun, Royko, Michael M., Kropf, Arthur J., Segre, Carlo, & Lauterbach, Jochen. Influence of Coordination Environment of Anchored Single-Site Cobalt Catalyst on CO2 Hydrogenation. United States. doi:https://doi.org/10.1002/cctc.201901676
Jimenez, Juan D., Wen, Cun, Royko, Michael M., Kropf, Arthur J., Segre, Carlo, and Lauterbach, Jochen. Mon . "Influence of Coordination Environment of Anchored Single-Site Cobalt Catalyst on CO2 Hydrogenation". United States. doi:https://doi.org/10.1002/cctc.201901676. https://www.osti.gov/servlets/purl/1763652.
@article{osti_1763652,
title = {Influence of Coordination Environment of Anchored Single-Site Cobalt Catalyst on CO2 Hydrogenation},
author = {Jimenez, Juan D. and Wen, Cun and Royko, Michael M. and Kropf, Arthur J. and Segre, Carlo and Lauterbach, Jochen},
abstractNote = {},
doi = {10.1002/cctc.201901676},
journal = {ChemCatChem},
number = 3,
volume = 12,
place = {United States},
year = {2019},
month = {12}
}

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Works referenced in this record:

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005


Unveiling Active Sites of CO 2 Reduction on Nitrogen-Coordinated and Atomically Dispersed Iron and Cobalt Catalysts
journal, March 2018


Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Synthesis and Characterization of Cobalt Hydroxide, Cobalt Oxyhydroxide, and Cobalt Oxide Nanodiscs
journal, November 2009

  • Yang, Jing; Liu, Hongwei; Martens, Wayde N.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 1
  • DOI: 10.1021/jp908548f

Design of highly active cobalt catalysts for CO 2 hydrogenation via the tailoring of surface orientation of nanostructures
journal, January 2019

  • Jimenez, Juan D.; Wen, Cun; Lauterbach, Jochen
  • Catalysis Science & Technology, Vol. 9, Issue 8
  • DOI: 10.1039/C9CY00402E

Production of synthetic natural gas (SNG) from coal and dry biomass – A technology review from 1950 to 2009
journal, August 2010


A study on the effect of support's reducibility on the reverse water-gas shift reaction over Pt catalysts
journal, May 2012


UV–visible, XANES and EXAFS investigations of a cobalt complex grafted in micelle templated silica
journal, January 1999

  • Be´land, ois; Badiei, Ali-Reza; Rönning, Magnus
  • Physical Chemistry Chemical Physics, Vol. 1, Issue 4
  • DOI: 10.1039/a807630h

The effects of bimetallic Co–Ru nanoparticles on Co/RuO 2 /Al 2 O 3 catalysts for the water gas shift and methanation
journal, September 2014


Catalytic N−H Bond Activation and Breaking by a Well-Defined Co II 1 O 4 Site of a Heterogeneous Catalyst
journal, January 2018

  • Khivantsev, Konstantin; Biancardi, Alessandro; Fathizadeh, Mahdi
  • ChemCatChem, Vol. 10, Issue 4
  • DOI: 10.1002/cctc.201701268

Design of Single-Atom Co–N 5 Catalytic Site: A Robust Electrocatalyst for CO 2 Reduction with Nearly 100% CO Selectivity and Remarkable Stability
journal, February 2018

  • Pan, Yuan; Lin, Rui; Chen, Yinjuan
  • Journal of the American Chemical Society, Vol. 140, Issue 12
  • DOI: 10.1021/jacs.8b00814

Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
journal, March 2017


Remarkable Effect of the Preparation Technique on the State of Cobalt Ions in BEA Zeolites Evidenced by FTIR Spectroscopy of Adsorbed CO and NO, TPR and XRD
journal, October 2006

  • Mihaylova, Angelina; Hadjiivanov, Konstantin; Dzwigaj, Stanislaw
  • The Journal of Physical Chemistry B, Vol. 110, Issue 39
  • DOI: 10.1021/jp0634398

CO 2 Reduction on Supported Ru/Al 2 O 3 Catalysts: Cluster Size Dependence of Product Selectivity
journal, October 2013

  • Kwak, Ja Hun; Kovarik, Libor; Szanyi, János
  • ACS Catalysis, Vol. 3, Issue 11
  • DOI: 10.1021/cs400381f

Evidence of Highly Active Cobalt Oxide Catalyst for the Fischer–Tropsch Synthesis and CO 2 Hydrogenation
journal, January 2014

  • Melaet, Gérôme; Ralston, Walter T.; Li, Cheng-Shiuan
  • Journal of the American Chemical Society, Vol. 136, Issue 6
  • DOI: 10.1021/ja412447q

Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening?
journal, April 2013

  • Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R.
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar3002427

Combining in Situ NEXAFS Spectroscopy and CO 2 Methanation Kinetics To Study Pt and Co Nanoparticle Catalysts Reveals Key Insights into the Role of Platinum in Promoted Cobalt Catalysis
journal, July 2014

  • Beaumont, Simon K.; Alayoglu, Selim; Specht, Colin
  • Journal of the American Chemical Society, Vol. 136, Issue 28
  • DOI: 10.1021/ja505286j

Novel aspects of the physical chemistry of Co/SiO2 Fischer–Tropsch catalyst preparations
journal, September 2006


Photocatalytic water oxidation by very small cobalt domains on a silica surface
journal, January 2013

  • Ahn, Hyun S.; Yano, Junko; Tilley, T. Don
  • Energy & Environmental Science, Vol. 6, Issue 10
  • DOI: 10.1039/c3ee42067a

The kinetics of precipitation from supersaturated solid solutions
journal, April 1961


Carbon Dioxide Hydrogenation over a Metal-Free Carbon-Based Catalyst
journal, June 2017


Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015


Quantum Mechanical Screening of Single-Atom Bimetallic Alloys for the Selective Reduction of CO 2 to C 1 Hydrocarbons
journal, October 2016


Preparation of silica- and carbon-supported cobalt by electrostatic adsorption of Co(III) hexaammines
journal, June 2007


Quantification of Zinc Atoms in a Surface Alloy on Copper in an Industrial-Type Methanol Synthesis Catalyst
journal, April 2014

  • Kuld, Sebastian; Conradsen, Christian; Moses, Poul Georg
  • Angewandte Chemie International Edition, Vol. 53, Issue 23
  • DOI: 10.1002/anie.201311073

Supported Cobalt Nanorod Catalysts for Carbon Dioxide Hydrogenation
journal, February 2017

  • Jimenez, Juan; Bird, Ashley; Santos Santiago, Maryorie
  • Energy Technology, Vol. 5, Issue 6
  • DOI: 10.1002/ente.201600575

Hydrogenation of CO2 on group VIII metals II. Kinetics and mechanism of CO2 hydrogenation on nickel
journal, October 1982


Formation of Dimers That Contain Unbridged W(IV)/W(IV) Double Bonds
journal, August 2004

  • Lopez, Lourdes Pia H.; Schrock, Richard R.
  • Journal of the American Chemical Society, Vol. 126, Issue 31
  • DOI: 10.1021/ja0400988

Water Oxidation by Cobalt Centers on Various Oxide Surfaces: The Effects of Oxide Surface Acidity and Oxygen Atom Affinity on Catalysis
journal, March 2015

  • Ahn, Hyun S.; Yano, Junko; Tilley, T. Don
  • ACS Catalysis, Vol. 5, Issue 4
  • DOI: 10.1021/cs502120f

CO 2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity
journal, May 2016

  • Kattel, Shyam; Yu, Weiting; Yang, Xiaofang
  • Angewandte Chemie, Vol. 128, Issue 28
  • DOI: 10.1002/ange.201601661

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations
journal, March 2012

  • Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D.
  • Science, Vol. 335, Issue 6073
  • DOI: 10.1126/science.1215864

Chemical reactions at silica surfaces
journal, April 1990


Cobalt Particle Size Effects in the Fischer−Tropsch Reaction Studied with Carbon Nanofiber Supported Catalysts
journal, March 2006

  • Bezemer, G. Leendert; Bitter, Johannes H.; Kuipers, Herman P. C. E.
  • Journal of the American Chemical Society, Vol. 128, Issue 12
  • DOI: 10.1021/ja058282w

Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011

  • Wang, Wei; Wang, Shengping; Ma, Xinbin
  • Chemical Society Reviews, Vol. 40, Issue 7
  • DOI: 10.1039/c1cs15008a

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014


Surface science of single-site heterogeneous olefin polymerization catalysts
journal, October 2006

  • Kim, S. H.; Somorjai, G. A.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 42
  • DOI: 10.1073/pnas.0602346103

Direct Low-Temperature Deposition of Crystallized CoOOH Films by Potentiostatic Electrolysis
journal, January 2005

  • Pauporté, T.; Mendoza, L.; Cassir, M.
  • Journal of The Electrochemical Society, Vol. 152, Issue 2
  • DOI: 10.1149/1.1842044

Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998


Controllable Synthesis of Mesoporous Co 3 O 4 Nanostructures with Tunable Morphology for Application in Supercapacitors
journal, May 2009

  • Xiong, Shenglin; Yuan, Changzhou; Zhang, Xiaogang
  • Chemistry - A European Journal, Vol. 15, Issue 21
  • DOI: 10.1002/chem.200802671

Self-healing catalysts: Co 3 O 4 nanorods for Fischer–Tropsch synthesis
journal, January 2014

  • Wen, Cun; Dunbar, Darrius; Zhang, Xin
  • Chem. Commun., Vol. 50, Issue 35
  • DOI: 10.1039/C4CC01021C

Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts
journal, August 2000


Single-Site Heterogeneous Catalysts
journal, October 2005

  • Thomas, John Meurig; Raja, Robert; Lewis, Dewi W.
  • Angewandte Chemie International Edition, Vol. 44, Issue 40, p. 6456-6482
  • DOI: 10.1002/anie.200462473

Low-temperature oxidation of CO catalysed by Co3O4 nanorods
journal, April 2009

  • Xie, Xiaowei; Li, Yong; Liu, Zhi-Quan
  • Nature, Vol. 458, Issue 7239, p. 746-749
  • DOI: 10.1038/nature07877

Co-Support Compound Formation in Alumina-Supported Cobalt Catalysts
journal, November 2001

  • Jongsomjit, Bunjerd; Panpranot, Joongjai; Goodwin, James G.
  • Journal of Catalysis, Vol. 204, Issue 1
  • DOI: 10.1006/jcat.2001.3387

Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism
journal, February 2015


X-ray nanoscopy of cobalt Fischer–Tropsch catalysts at work
journal, January 2013

  • Cats, Korneel H.; Gonzalez-Jimenez, Ines D.; Liu, Yijin
  • Chemical Communications, Vol. 49, Issue 41
  • DOI: 10.1039/c3cc00160a

Titania-Supported Cobalt and Cobalt–Phosphorus Catalysts: Characterization and Performances in Ethane Oxidative Dehydrogenation
journal, August 2001

  • Brik, Younes; Kacimi, Mohamed; Ziyad, Mahfoud
  • Journal of Catalysis, Vol. 202, Issue 1
  • DOI: 10.1006/jcat.2001.3262

Low-Temperature Restructuring of CeO 2 -Supported Ru Nanoparticles Determines Selectivity in CO 2 Catalytic Reduction
journal, September 2018

  • Aitbekova, Aisulu; Wu, Liheng; Wrasman, Cody J.
  • Journal of the American Chemical Society, Vol. 140, Issue 42
  • DOI: 10.1021/jacs.8b07615

IFEFFIT  : interactive XAFS analysis and FEFF fitting
journal, March 2001


A combined in situ XAS-XRPD-Raman study of Fischer–Tropsch synthesis over a carbon supported Co catalyst
journal, April 2013


Heterogeneous Catalysis on Atomically Dispersed Supported Metals: CO 2 Reduction on Multifunctional Pd Catalysts
journal, August 2013

  • Kwak, Ja Hun; Kovarik, Libor; Szanyi, János
  • ACS Catalysis, Vol. 3, Issue 9
  • DOI: 10.1021/cs4001392

Catalysis mechanisms of CO 2 and CO methanation
journal, January 2016

  • Miao, Bin; Ma, Su Su Khine; Wang, Xin
  • Catalysis Science & Technology, Vol. 6, Issue 12
  • DOI: 10.1039/C6CY00478D

The synthesis of highly dispersed noble and base metals on silica via strong electrostatic adsorption: I. Amorphous silica
journal, December 2008


Size-Controlled Model Co Nanoparticle Catalysts for CO 2 Hydrogenation: Synthesis, Characterization, and Catalytic Reactions
journal, May 2012

  • Iablokov, Viacheslav; Beaumont, Simon K.; Alayoglu, Selim
  • Nano Letters, Vol. 12, Issue 6
  • DOI: 10.1021/nl300973b

Synthesis, characterization and in situ DRIFTS during the CO2 hydrogenation reaction over supported cobalt catalysts
journal, November 2011