Ultralow-Strain Zn-Substituted Layered Oxide Cathode with Suppressed P2–O2 Transition for Stable Sodium Ion Storage

Wang, Yanxia; Wang, Liguang; Zhu, He; Chu, Jun; Fang, Yongjin; Wu, Lina; Huang, Ling; Ren, Yang; Sun, Cheng‐Jun; Liu, Qi; Ai, Xinping; Yang, Hanxi; Cao, Yuliang

doi:10.1002/adfm.201910327

Title: Ultralow-Strain Zn-Substituted Layered Oxide Cathode with Suppressed P2–O2 Transition for Stable Sodium Ion Storage

Abstract

Layered transition metal oxides have drawn much attention as a promising candidate cathode material for sodium-ion batteries. However, their performance degradation originating from strains and lattice phase transitions remains a critical challenge. Herein, a high-concentration Zn-substituted Na_xMnO₂ cathode with strongly suppressed P2–O2 transition is investigated, which exhibits a volume change as low as 1.0% in the charge/discharge process. Additionally, such ultralow strain characteristics ensure a stable host for sodium ion storage, which significantly improves the cycling stability and rate capability of the cathode material. Also, the strong coupling between the highly reversible capacity and the doping content of Zn in Na_xMnO₂ is investigated. It is suggested that a reversible anionic redox reaction can be effectively triggered by Zn ions and is also highly dependent on the Zn content. Such an ion doping strategy could shed light on the design and construction of stable and high-capacity sodium ion host.

Authors:

Wang, Yanxia ^[1]; Wang, Liguang ^[2]; Zhu, He ^[2]; Chu, Jun ^[1]; Fang, Yongjin ^[1]; Wu, Lina ^[3]; Huang, Ling ^[3]; Ren, Yang ^[4]; Sun, Cheng‐Jun ^[4]; Liu, Qi ^[5]; Ai, Xinping ^[1]; Yang, Hanxi ^[1];

^[1]

Wuhan Univ. (China). Hubei Key Lab. of Electrochemical Power Sources
City Univ. of Hong Kong (Hong Kong)
Xiamen Univ. (China)
Argonne National Lab. (ANL), Lemont, IL (United States)
City Univ. of Hong Kong (Hong Kong); City Univ. of Hong Kong (Hong Kong). Shenzhen Research Inst.

Publication Date:: Wed Feb 12 00:00:00 EST 2020

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China

OSTI Identifier:: 1763386

Alternate Identifier(s):: OSTI ID: 1599465

Grant/Contract Number:: AC02-06CH11357; 21673165; 21972108; 2016YFB0901500; 9610399; DE‐AC02‐06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Volume: 30; Journal Issue: 13; Journal ID: ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; sodium ion batteries; ultralow strain; substitution; phase transition

Citation Formats


                    Wang, Yanxia, Wang, Liguang, Zhu, He, Chu, Jun, Fang, Yongjin, Wu, Lina, Huang, Ling, Ren, Yang, Sun, Cheng‐Jun, Liu, Qi, Ai, Xinping, Yang, Hanxi, and Cao, Yuliang. Ultralow-Strain Zn-Substituted Layered Oxide Cathode with Suppressed P2–O2 Transition for Stable Sodium Ion Storage.  United States: N. p., 2020. 
Web.  doi:10.1002/adfm.201910327.

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                    Wang, Yanxia, Wang, Liguang, Zhu, He, Chu, Jun, Fang, Yongjin, Wu, Lina, Huang, Ling, Ren, Yang, Sun, Cheng‐Jun, Liu, Qi, Ai, Xinping, Yang, Hanxi, & Cao, Yuliang. Ultralow-Strain Zn-Substituted Layered Oxide Cathode with Suppressed P2–O2 Transition for Stable Sodium Ion Storage.  United States.  https://doi.org/10.1002/adfm.201910327

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                    Wang, Yanxia, Wang, Liguang, Zhu, He, Chu, Jun, Fang, Yongjin, Wu, Lina, Huang, Ling, Ren, Yang, Sun, Cheng‐Jun, Liu, Qi, Ai, Xinping, Yang, Hanxi, and Cao, Yuliang. Wed .  
"Ultralow-Strain Zn-Substituted Layered Oxide Cathode with Suppressed P2–O2 Transition for Stable Sodium Ion Storage".  United States.  https://doi.org/10.1002/adfm.201910327.  https://www.osti.gov/servlets/purl/1763386.

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@article{osti_1763386,

  title        = {Ultralow-Strain Zn-Substituted Layered Oxide Cathode with Suppressed P2–O2 Transition for Stable Sodium Ion Storage},

  author       = {Wang, Yanxia and Wang, Liguang and Zhu, He and Chu, Jun and Fang, Yongjin and Wu, Lina and Huang, Ling and Ren, Yang and Sun, Cheng‐Jun and Liu, Qi and Ai, Xinping and Yang, Hanxi and Cao, Yuliang},

  abstractNote = {Layered transition metal oxides have drawn much attention as a promising candidate cathode material for sodium-ion batteries. However, their performance degradation originating from strains and lattice phase transitions remains a critical challenge. Herein, a high-concentration Zn-substituted NaxMnO2 cathode with strongly suppressed P2–O2 transition is investigated, which exhibits a volume change as low as 1.0% in the charge/discharge process. Additionally, such ultralow strain characteristics ensure a stable host for sodium ion storage, which significantly improves the cycling stability and rate capability of the cathode material. Also, the strong coupling between the highly reversible capacity and the doping content of Zn in NaxMnO2 is investigated. It is suggested that a reversible anionic redox reaction can be effectively triggered by Zn ions and is also highly dependent on the Zn content. Such an ion doping strategy could shed light on the design and construction of stable and high-capacity sodium ion host.},

  doi          = {10.1002/adfm.201910327},

  journal      = {Advanced Functional Materials},

  number       = 13,

  volume       = 30,

  place        = {United States},

  year         = {Wed Feb 12 00:00:00 EST 2020},

  month        = {Wed Feb 12 00:00:00 EST 2020}

}

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Title: Ultralow-Strain Zn-Substituted Layered Oxide Cathode with Suppressed P2–O2 Transition for Stable Sodium Ion Storage

Abstract

Citation Formats

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Routes to High Energy Cathodes of Sodium-Ion Batteries
journal, December 2015

Exploring Oxygen Activity in the High Energy P2-Type Na _0.78 Ni _0.23 Mn _0.69 O ₂ Cathode Material for Na-Ion Batteries
journal, March 2017

Sodium and Manganese Stoichiometry of P2-Type Na _2/3 MnO ₂
journal, September 2016

MXene encapsulated titanium oxide nanospheres for ultra-stable and fast sodium storage
journal, September 2018

Deformation and stress in electrode materials for Li-ion batteries
journal, June 2014

Recent Progress of Layered Transition Metal Oxide Cathodes for Sodium‐Ion Batteries
journal, February 2019

P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012

X-ray absorption near-edge structures of LiMn ₂ O ₄ and LiNi _0.5 Mn _1.5 O ₄ spinel oxides for lithium-ion batteries: the first-principles calculation study
journal, January 2016

Design Strategies to Enable the Efficient Use of Sodium Metal Anodes in High‐Energy Batteries
journal, October 2019

P′2-Na _2/3 Mn _0.9 Me _0.1 O ₂ (Me = Mg, Ti, Co, Ni, Cu, and Zn): Correlation between Orthorhombic Distortion and Electrochemical Property
journal, October 2017

Electrochemical and thermal properties of P2-type Na2/3Fe1/3Mn2/3O2 for Na-ion batteries
journal, October 2014

Structure–Electrochemical Evolution of a Mn-Rich P2 Na _2/3 Fe _0.2 Mn _0.8 O ₂ Na-Ion Battery Cathode
journal, August 2017

Realizing Three-Electron Redox Reactions in NASICON-Structured Na 3 MnTi(PO 4 ) 3 for Sodium-Ion Batteries
journal, January 2019

Sodium-ion batteries: present and future
journal, January 2017

Recent Advances in Sodium-Ion Battery Materials
journal, June 2018

Structural classification and properties of the layered oxides
journal, January 1980

Highly Reversible Oxygen-Redox Chemistry at 4.1 V in Na _4/7− _x [□ _1/7 Mn _6/7 ]O ₂ (□: Mn Vacancy)
journal, April 2018

High Performance Li ₂ Ru _{1– y} Mn _y O ₃ (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding
journal, March 2013

Research Development on Sodium-Ion Batteries
journal, October 2014