Synthesis of MgCo2O4-coated Li4Ti5O12 composite anodes using co-precipitation method for lithium-ion batteries
Abstract
In the present work, we report synthesis of MgCo2O4 (MCO)/Li4Ti5O12 (LTO) composites for Li-ion battery anodes by a co-precipitation method. The objective here is to replace expensive Co with Mg and also to exploit advantages of both MCO and LTO. Three samples of MCO/LTO particles with different MCO proportion have various average particle sizes of 38.1, 56.9, and 58.5 nm, confirmed by scanning electron microscopy. Electrochemical studies show that a MCO/LTO anode offers a discharge capacity of ca. 300 mAh g-1, which is two times higher than that achieved by pristine LTO. The MCO/LTO anode also retains 75% of its initial capacity, even if the discharge rate is increased to 5 C. Cyclic stability test reveals that the composite anode still maintains nearly 85.5% of its initial capacity after 150 cycles. Electrochemical impedance spectroscopy indicates that the equivalent series resistance of MCO/LTO electrodes is significantly lower than that of LTO, i.e., from 35.5 to 9.9 Ω. The enhanced performance of the composite electrodes can be attributed to its improved conductivity as well as to the surface modification of LTO particles by MCO nanoparticle deposition which leads to increased number of active sites on the former.
- Authors:
-
- Xiamen Univ. of Technology (China)
- Yuan Ze Univ., Taoyuan (Taiwan)
- Univ. of Saskatchewan, Saskatoon, SK (Canada)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1761758
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Solid State Electrochemistry
- Additional Journal Information:
- Journal Volume: 23; Journal Issue: 11; Journal ID: ISSN 1432-8488
- Publisher:
- Springer Nature
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Lithium-ion battery; Spinel structure; Composite anodes; Magnesiumcobaltite; Lithiumtitanate
Citation Formats
Gu, Siyong, Hsieh, Chien-Te, Huq, Mohammad Mahmudul, Hsu, Jo-Pei, and Li, Jianlin. Synthesis of MgCo2O4-coated Li4Ti5O12 composite anodes using co-precipitation method for lithium-ion batteries. United States: N. p., 2019.
Web. doi:10.1007/s10008-019-04416-0.
Gu, Siyong, Hsieh, Chien-Te, Huq, Mohammad Mahmudul, Hsu, Jo-Pei, & Li, Jianlin. Synthesis of MgCo2O4-coated Li4Ti5O12 composite anodes using co-precipitation method for lithium-ion batteries. United States. https://doi.org/10.1007/s10008-019-04416-0
Gu, Siyong, Hsieh, Chien-Te, Huq, Mohammad Mahmudul, Hsu, Jo-Pei, and Li, Jianlin. Thu .
"Synthesis of MgCo2O4-coated Li4Ti5O12 composite anodes using co-precipitation method for lithium-ion batteries". United States. https://doi.org/10.1007/s10008-019-04416-0. https://www.osti.gov/servlets/purl/1761758.
@article{osti_1761758,
title = {Synthesis of MgCo2O4-coated Li4Ti5O12 composite anodes using co-precipitation method for lithium-ion batteries},
author = {Gu, Siyong and Hsieh, Chien-Te and Huq, Mohammad Mahmudul and Hsu, Jo-Pei and Li, Jianlin},
abstractNote = {In the present work, we report synthesis of MgCo2O4 (MCO)/Li4Ti5O12 (LTO) composites for Li-ion battery anodes by a co-precipitation method. The objective here is to replace expensive Co with Mg and also to exploit advantages of both MCO and LTO. Three samples of MCO/LTO particles with different MCO proportion have various average particle sizes of 38.1, 56.9, and 58.5 nm, confirmed by scanning electron microscopy. Electrochemical studies show that a MCO/LTO anode offers a discharge capacity of ca. 300 mAh g-1, which is two times higher than that achieved by pristine LTO. The MCO/LTO anode also retains 75% of its initial capacity, even if the discharge rate is increased to 5 C. Cyclic stability test reveals that the composite anode still maintains nearly 85.5% of its initial capacity after 150 cycles. Electrochemical impedance spectroscopy indicates that the equivalent series resistance of MCO/LTO electrodes is significantly lower than that of LTO, i.e., from 35.5 to 9.9 Ω. The enhanced performance of the composite electrodes can be attributed to its improved conductivity as well as to the surface modification of LTO particles by MCO nanoparticle deposition which leads to increased number of active sites on the former.},
doi = {10.1007/s10008-019-04416-0},
journal = {Journal of Solid State Electrochemistry},
number = 11,
volume = 23,
place = {United States},
year = {Thu Oct 31 00:00:00 EDT 2019},
month = {Thu Oct 31 00:00:00 EDT 2019}
}
Works referenced in this record:
Influence of Li addition on charge/discharge behavior of spinel lithium titanate
journal, September 2010
- Hsieh, Chien-Te; Lin, Jia-Yi
- Journal of Alloys and Compounds, Vol. 506, Issue 1
Graphene-Wrapped Fe3O4 Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries
journal, September 2010
- Zhou, Guangmin; Wang, Da-Wei; Li, Feng
- Chemistry of Materials, Vol. 22, Issue 18, p. 5306-5313
Enhancing the reversible capacity of nanostructured TiO 2 (anatase) by Zr-doping using a sol–gel template method
journal, October 2015
- Opra, Denis P.; Gnedenkov, Sergey V.; Sokolov, Alexander A.
- Scripta Materialia, Vol. 107
Nanophase ZnCo2O4 as a High Performance Anode Material for Li-Ion Batteries
journal, October 2007
- Sharma, Y.; Sharma, N.; Subba Rao, G. V.
- Advanced Functional Materials, Vol. 17, Issue 15
Electrospun porous ZnCo2O4 nanotubes as a high-performance anode material for lithium-ion batteries
journal, January 2012
- Luo, Wei; Hu, Xianluo; Sun, Yongming
- Journal of Materials Chemistry, Vol. 22, Issue 18
Kinetics of electrochemical lithium intercalation into thin tungsten (VI) oxide layers
journal, May 2008
- Churikov, A. V.; Ivanishchev, A. V.; Ivanishcheva, I. A.
- Russian Journal of Electrochemistry, Vol. 44, Issue 5
Li4Ti5O12 electrodes operated under hurdle conditions and SiO2 incorporation effect
journal, September 2013
- Jiang, Simin; Zhao, Bote; Chen, Yubo
- Journal of Power Sources, Vol. 238
Challenges of Spinel Li 4 Ti 5 O 12 for Lithium-Ion Battery Industrial Applications
journal, January 2017
- Yuan, Tao; Tan, Zhuopeng; Ma, Chunrong
- Advanced Energy Materials, Vol. 7, Issue 12
Nano-particle Li4Ti5O12 spinel as electrode for electrochemical generators
journal, June 2003
- Guerfi, A.; Sévigny, S.; Lagacé, M.
- Journal of Power Sources, Vol. 119-121
Co3O4 Nanocages for High-Performance Anode Material in Lithium-Ion Batteries
journal, March 2012
- Yan, Nan; Hu, Lin; Li, Yan
- The Journal of Physical Chemistry C, Vol. 116, Issue 12, p. 7227-7235
Metal Oxide Hollow Nanostructures for Lithium-ion Batteries
journal, March 2012
- Wang, Zhiyu; Zhou, Liang; David Lou, Xiong Wen
- Advanced Materials, Vol. 24, Issue 14, p. 1903-1911
Enhanced methane combustion over Co3O4 catalysts prepared by a facile precipitation method: Effect of aging time
journal, July 2017
- Pu, Zhiying; Zhou, Huan; Zheng, Yifan
- Applied Surface Science, Vol. 410
A comprehensive review of Li 4 Ti 5 O 12 -based electrodes for lithium-ion batteries: The latest advancements and future perspectives
journal, December 2015
- Zhao, Bote; Ran, Ran; Liu, Meilin
- Materials Science and Engineering: R: Reports, Vol. 98
Enhanced Performance of “Flower-like” Li 4 Ti 5 O 12 Motifs as Anode Materials for High-Rate Lithium-Ion Batteries
journal, July 2015
- Wang, Lei; Zhang, Yiman; Scofield, Megan E.
- ChemSusChem, Vol. 8, Issue 19
Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries
journal, January 2011
- Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz
- Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699
Mesoporous NiCo 2 O 4 Nanowire Arrays Grown on Carbon Textiles as Binder-Free Flexible Electrodes for Energy Storage
journal, December 2013
- Shen, Laifa; Che, Qian; Li, Hongsen
- Advanced Functional Materials, Vol. 24, Issue 18
Preparation of Ce- and La-Doped Li4Ti5O12 Nanosheets and Their Electrochemical Performance in Li Half Cell and Li4Ti5O12/LiFePO4 Full Cell Batteries
journal, June 2017
- Qin, Meng; Li, Yueming; Lv, Xiao-Jun
- Nanomaterials, Vol. 7, Issue 6
Binder strategy towards improving the rate performance of nanosheet-assembled SnO2 hollow microspheres
journal, January 2012
- Zhao, Xinyu; Cao, Minhua; Hu, Changwen
- RSC Advances, Vol. 2, Issue 31
Titanium-Based Anode Materials for Safe Lithium-Ion Batteries
journal, July 2012
- Chen, Zonghai; Belharouak, Ilias; Sun, Y. -K.
- Advanced Functional Materials, Vol. 23, Issue 8
Insertion Electrode Materials for Rechargeable Lithium Batteries
journal, July 1998
- Winter, Martin; Besenhard, Jürgen O.; Spahr, Michael E.
- Advanced Materials, Vol. 10, Issue 10
Coaxial Carbon/Metal Oxide/Aligned Carbon Nanotube Arrays as High-Performance Anodes for Lithium Ion Batteries
journal, February 2014
- Lou, Fengliu; Zhou, Haitao; Tran, Trung Dung
- ChemSusChem, Vol. 7, Issue 5
Structural and electrical properties of Li4Ti5O12 anode material for lithium-ion batteries
journal, June 2018
- Vikram Babu, B.; Vijaya Babu, K.; Tewodros Aregai, G.
- Results in Physics, Vol. 9
Intercalation and Push-Out Process with Spinel-to-Rocksalt Transition on Mg Insertion into Spinel Oxides in Magnesium Batteries
journal, June 2015
- Okamoto, Shinya; Ichitsubo, Tetsu; Kawaguchi, Tomoya
- Advanced Science, Vol. 2, Issue 8
Highly Porous NiCo 2 O 4 Nanoflakes and Nanobelts as Anode Materials for Lithium-Ion Batteries with Excellent Rate Capability
journal, August 2014
- Mondal, Anjon Kumar; Su, Dawei; Chen, Shuangqiang
- ACS Applied Materials & Interfaces, Vol. 6, Issue 17
Mg and Al substituted cobalt spinels as catalysts for low temperature deN2O—Evidence for octahedral cobalt active sites
journal, March 2014
- Stelmachowski, P.; Maniak, G.; Kaczmarczyk, J.
- Applied Catalysis B: Environmental, Vol. 146
Characteristics of Lignin Fractions from Dilute Acid Pretreated Switchgrass and Their Effect on Cellobiohydrolase from Trichoderma longibrachiatum
journal, February 2018
- Yao, Lan; Yang, Haitao; Yoo, Chang Geun
- Frontiers in Energy Research, Vol. 6
Hollow MnCo 2 O 4 Submicrospheres with Multilevel Interiors: From Mesoporous Spheres to Yolk-in-Double-Shell Structures
journal, December 2013
- Li, Jingfa; Wang, Jiazhao; Liang, Xin
- ACS Applied Materials & Interfaces, Vol. 6, Issue 1
Lithium recycling behaviour of nano-phase-CuCo2O4 as anode for lithium-ion batteries
journal, November 2007
- Sharma, Yogesh; Sharma, N.; Rao, G. V. Subba
- Journal of Power Sources, Vol. 173, Issue 1
Lithium iron oxide as alternative anode for li-ion batteries
journal, September 2000
- Prosini, Pier Paolo; Carewska, Maria; Loreti, Stefano
- International Journal of Inorganic Materials, Vol. 2, Issue 4
Studies on spinel cobaltites, FeCo2O4 and MgCo2O4 as anodes for Li-ion batteries
journal, June 2008
- Sharma, Y.; Sharma, N.; Subbarao, G.
- Solid State Ionics, Vol. 179, Issue 15-16
Enhanced electrochemical performance of La 2 O 3 -modified Li 4 Ti 5 O 12 anode material for Li-ion batteries
journal, August 2017
- Wei, Aijia; Li, Wen; Zhang, Lihui
- IOP Conference Series: Materials Science and Engineering, Vol. 231
Design of porous Co3O4 nanosheets via one-step synthesis as high-performance anode materials for lithium-ion batteries
journal, September 2018
- Guo, Shihang; Feng, Yi; Ding, Weiqiang
- Journal of Solid State Electrochemistry, Vol. 23, Issue 1
Composition analysis of the passive film on the carbon electrode of a lithium-ion battery with an EC-based electrolyte
journal, March 1998
- Yang, C. R.; Wang, Y. Y.; Wan, C. C.
- Journal of Power Sources, Vol. 72, Issue 1
Template-free synthesis of mesoporous spinel lithium titanate microspheres and their application in high-rate lithium ion batteries
journal, January 2009
- Tang, Yufeng; Yang, Li; Qiu, Zheng
- Journal of Materials Chemistry, Vol. 19, Issue 33
Nanostructured TiO2-TiOF2 composite synthesized by the original method of pulsed high-voltage discharge as anode material for Li-ion battery
journal, May 2015
- Gnedenkov, S. V.; Opra, D. P.; Kuryavyi, V. G.
- Nanotechnologies in Russia, Vol. 10, Issue 5-6
Gassing in Li4Ti5O12-based batteries and its remedy
journal, December 2012
- He, Yan-Bing; Li, Baohua; Liu, Ming
- Scientific Reports, Vol. 2, Issue 1
Morphology-tuned Synthesis of MgCo2O4 Arrays on Graphene Coated Nickel Foam for High-Rate Supercapacitor Electrode
journal, March 2018
- Guan, Xiangfeng
- International Journal of Electrochemical Science
Li 4 Ti 5 O 12 /Co 3 O 4 Composite for Improved Performance in Lithium-Ion Batteries
journal, January 2015
- Hong, Jung-Eui; Oh, Rye-Gyeong; Ryu, Kwang-Sun
- Journal of The Electrochemical Society, Vol. 162, Issue 10
Effect of Hf-doping on electrochemical performance of anatase TiO 2 as an anode material for lithium storage
journal, June 2018
- Gnedenkov, Sergey V.; Sinebryukhov, Sergey L.; Zheleznov, Veniamin V.
- Royal Society Open Science, Vol. 5, Issue 6
Recent Advances in Metal Oxide-based Electrode Architecture Design for Electrochemical Energy Storage
journal, August 2012
- Jiang, Jian; Li, Yuanyuan; Liu, Jinping
- Advanced Materials, Vol. 24, Issue 38
Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011
- Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
- Energy & Environmental Science, Vol. 4, Issue 9
Facile Synthesis of Two-Dimensional Porous MgCo2O4 Nanosheets as Anode for Lithium-Ion Batteries
journal, December 2017
- Wang, Fei; Liu, Yong; Zhao, Yuanfang
- Applied Sciences, Vol. 8, Issue 1
Synthesis of Spherical Silver-coated Li4Ti5O12 Anode Material by a Sol-Gel-assisted Hydrothermal Method
journal, October 2017
- Li, Jun; Huang, Si; Xu, Shuaijun
- Nanoscale Research Letters, Vol. 12, Issue 1
Review on recent progress of nanostructured anode materials for Li-ion batteries
journal, July 2014
- Goriparti, Subrahmanyam; Miele, Ermanno; De Angelis, Francesco
- Journal of Power Sources, Vol. 257
Li 2 ZrO 3 -coated Li 4 Ti 5 O 12 with nanoscale interface for high performance lithium-ion batteries
journal, April 2016
- Zhang, Han; Liu, Yang; Wang, Ting
- Applied Surface Science, Vol. 368
Synthesis, Characterization, and Li-Electrochemical Performance of Highly Porous Co 3 O 4 Powders
journal, June 2007
- Binotto, G.; Larcher, D.; Prakash, A. S.
- Chemistry of Materials, Vol. 19, Issue 12
Electrochemical performance of ZnO-coated Li 4 Ti 5 O 12 composite electrodes for lithium-ion batteries with the voltage ranging from 3 to 0.01 V
journal, October 2018
- Wang, Ying; Ren, Ya; Dai, Xinyi
- Royal Society Open Science, Vol. 5, Issue 10
Preparation and characterization of high-density spherical Li4Ti5O12 anode material for lithium secondary batteries
journal, April 2006
- Gao, Jian; Jiang, Changyin; Ying, Jierong
- Journal of Power Sources, Vol. 155, Issue 2
TinO2n−1-Coated Li4Ti5O12 Composite Anode Material for Lithium-Ion Batteries
journal, January 2018
- Zhang, Xiaoyan; Xu, Wen; Liu, Wanying
- JOM, Vol. 70, Issue 8
Influencing factors of low- and high-temperature behavior of Co-doped Zn2SnO4–graphene–carbon nanocomposite as anode material for lithium-ion batteries
journal, April 2017
- Gao, Zhenhai; Zhang, Xiaoting; Hu, Hongyu
- Journal of Electroanalytical Chemistry, Vol. 791
Morphologically Robust NiFe 2 O 4 Nanofibers as High Capacity Li-Ion Battery Anode Material
journal, October 2013
- Cherian, Christie Thomas; Sundaramurthy, Jayaraman; Reddy, M. V.
- ACS Applied Materials & Interfaces, Vol. 5, Issue 20
Facile synthesis of MgCo2O4 nanowires as binder-free flexible anode materials for high-performance Li-ion batteries
journal, August 2015
- Wang, Xiujuan; Zhai, Gaohong; Wang, Hui
- Journal of Nanoparticle Research, Vol. 17, Issue 8
Coaxial Carbon/Metal Oxide/Aligned Carbon Nanotube Arrays as High-Performance Anodes for Lithium Ion Batteries
journal, May 2014
- Lou, Fengliu; Zhou, Haitao; Tran, Trung Dung
- ChemSusChem, Vol. 7, Issue 5