In situ polymerized succinonitrile-based solid polymer electrolytes for lithium ion batteries

Liu, Kai; Zhang, Qingqing; Thapa, Bishnu; Sun, Xiao-Guang; Ding, Fei; Liu, Xingjiang; Zhang, Jinli; Dai, Sheng

doi:10.1016/j.ssi.2019.115159

Title: In situ polymerized succinonitrile-based solid polymer electrolytes for lithium ion batteries

Journal Article · 16 December 2019 · Solid State Ionics

DOI: https://doi.org/10.1016/j.ssi.2019.115159 · OSTI ID:1761672

Liu, Kai ^[1]; Zhang, Qingqing ^[2]; Thapa, Bishnu ^[3];

^[4]; Ding, Fei ^[5]; Liu, Xingjiang ^[6]; Zhang, Jinli ^[7];

^[3]

Tianjin Univ. (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Tianjin Univ. (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Key Laboratory of Science and Technology on Power Sources, Tianjin (China)
Tianjin Univ. (China); National Key Laboratory of Science and Technology on Power Sources, Tianjin (China)
Tianjin Univ. (China); Shihezi Univ. (China)

Novel solid polymer electrolytes based on succinonitrile (SN) plastic crystal electrolyte (SN-PCE) and polymerized ionic liquid (PIL) has been successfully synthesized via an in-situ method. The fabricated electrolyte (PIL-SN-PCE) is uniformly inlayed into the supporting matrix of polyimide, which effectively ameliorates the mechanical properties of the electrolyte. PIL can effectively enhance the thermal stability of electrolytes up to 300 °C and mitigate the parasitic reactions between the electrolytes and the electrodes. PIL-SN-PCE exhibits a remarkable oxidation ability up to 5.4 V vs Li/Li⁺ and a high room temperature ionic conductivity of 6.54 × 10^-4 S cm^-1. Furthermore, in-situ formed interface in PIL-SN-PCE guarantee an excellent compatibility with different electrodes, which can effectively improve the cycle stability and rate performances of both half-cells and full cells. Finally, PIL-SN-PCE is considered as a promising electrolyte for high energy density lithium-ion batteries.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: Foundation of National Key Laboratory of Science and Technology on Power Sources; National Natural Science Foundation of China (NNSFC); Program for Chang jiang Scholars and Innovative Research Team in University; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1761672

Journal Information:: Solid State Ionics, Journal Name: Solid State Ionics Journal Issue: 1 Vol. 345; ISSN 0167-2738

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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