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Title: Spectral, Compositional, and Physical Properties of the Upper Murray Formation and Vera Rubin Ridge, Gale Crater, Mars

Abstract

During 2018 and 2019, the Mars Science Laboratory Curiosity rover investigated the chemistry, morphology, and stratigraphy of Vera Rubin ridge (VRR). Using orbital data from the Compact Reconnaissance Imaging Spectrometer for Mars, scientists attributed the strong 860 nm signal associated with VRR to the presence of red crystalline hematite. However, Mastcam multispectral data and CheMin X-ray diffraction (XRD) measurements show that the depth of the 860 nm absorption is negatively correlated with the abundance of red crystalline hematite, suggesting that other mineralogical or physical parameters are also controlling the 860 nm absorption. Here, we examine Mastcam and ChemCam passive reflectance spectra from VRR and other locations to link the depth, position, and presence or absence of iron-related mineralogic absorption features to the XRD-derived rock mineralogy. Correlating CheMin mineralogy to spectral parameters showed that the ~860 nm absorption has a strong positive correlation with the abundance of ferric phyllosilicates. New laboratory reflectance measurements of powdered mineral mixtures can reproduce trends found in Gale crater. We hypothesize that variations in the 860 nm absorption feature in Mastcam and ChemCam observations of VRR materials are a result of three factors: (1) variations in ferric phyllosilicate abundance due to its ~800–1,000 nm absorption; (2)more » variations in clinopyroxene abundance because of its band maximum at ~860 nm; and (3) the presence of red crystalline hematite because of its absorption centered at 860 nm. We also show that relatively small changes in Ca-sulfate abundance is one potential cause of the erosional resistance and geomorphic expression of VRR.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5];  [6]; ORCiD logo [7]; ORCiD logo [8]; ORCiD logo [9]; ORCiD logo [10]
  1. Arizona State Univ., Tempe, AZ (United States)
  2. NASA Goddard Space Flight Center (GSFC), Greenbelt, MD (United States)
  3. California Inst. of Technology (CalTech), Pasadena, CA (United States)
  4. Purdue Univ., West Lafayette, IN (United States)
  5. Johns Hopkins Univ., Baltimore, MD (United States)
  6. Institut de Recherche en Astrophysique et Planetologie, Toulouse (France)
  7. NASA Neil A. Armstrong Flight Research Center, Edwards, CA (United States)
  8. NASA Johnson Space Center, Houston, TX (United States)
  9. Univ. of New Brunswick, Fredericton NB (Canada)
  10. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); National Aeronautics and Space Administration (NASA)
OSTI Identifier:
1760573
Report Number(s):
LA-UR-19-32335
Journal ID: ISSN 2169-9097
Grant/Contract Number:  
89233218CNA000001; 1546033
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Geophysical Research. Planets
Additional Journal Information:
Journal Volume: 125; Journal Issue: 11; Journal ID: ISSN 2169-9097
Publisher:
American Geophysical Union
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; Planetary Sciences; Mastcam; multispectral; laboratory; phyllosilicates; hematite; ferric iron

Citation Formats

Jacob, S. R., Wellington, D. F., Bell III, James F., Achilles, Cherie N., Fraeman, Abigail A., Horgan, B., Johnson, Jeffrey R., Maurice, Sylvestre, Peters, G. H., Rampe, E. B., Thompson, L. M., and Wiens, Roger Craig. Spectral, Compositional, and Physical Properties of the Upper Murray Formation and Vera Rubin Ridge, Gale Crater, Mars. United States: N. p., 2020. Web. doi:10.1029/2019je006290.
Jacob, S. R., Wellington, D. F., Bell III, James F., Achilles, Cherie N., Fraeman, Abigail A., Horgan, B., Johnson, Jeffrey R., Maurice, Sylvestre, Peters, G. H., Rampe, E. B., Thompson, L. M., & Wiens, Roger Craig. Spectral, Compositional, and Physical Properties of the Upper Murray Formation and Vera Rubin Ridge, Gale Crater, Mars. United States. https://doi.org/10.1029/2019je006290
Jacob, S. R., Wellington, D. F., Bell III, James F., Achilles, Cherie N., Fraeman, Abigail A., Horgan, B., Johnson, Jeffrey R., Maurice, Sylvestre, Peters, G. H., Rampe, E. B., Thompson, L. M., and Wiens, Roger Craig. Fri . "Spectral, Compositional, and Physical Properties of the Upper Murray Formation and Vera Rubin Ridge, Gale Crater, Mars". United States. https://doi.org/10.1029/2019je006290. https://www.osti.gov/servlets/purl/1760573.
@article{osti_1760573,
title = {Spectral, Compositional, and Physical Properties of the Upper Murray Formation and Vera Rubin Ridge, Gale Crater, Mars},
author = {Jacob, S. R. and Wellington, D. F. and Bell III, James F. and Achilles, Cherie N. and Fraeman, Abigail A. and Horgan, B. and Johnson, Jeffrey R. and Maurice, Sylvestre and Peters, G. H. and Rampe, E. B. and Thompson, L. M. and Wiens, Roger Craig},
abstractNote = {During 2018 and 2019, the Mars Science Laboratory Curiosity rover investigated the chemistry, morphology, and stratigraphy of Vera Rubin ridge (VRR). Using orbital data from the Compact Reconnaissance Imaging Spectrometer for Mars, scientists attributed the strong 860 nm signal associated with VRR to the presence of red crystalline hematite. However, Mastcam multispectral data and CheMin X-ray diffraction (XRD) measurements show that the depth of the 860 nm absorption is negatively correlated with the abundance of red crystalline hematite, suggesting that other mineralogical or physical parameters are also controlling the 860 nm absorption. Here, we examine Mastcam and ChemCam passive reflectance spectra from VRR and other locations to link the depth, position, and presence or absence of iron-related mineralogic absorption features to the XRD-derived rock mineralogy. Correlating CheMin mineralogy to spectral parameters showed that the ~860 nm absorption has a strong positive correlation with the abundance of ferric phyllosilicates. New laboratory reflectance measurements of powdered mineral mixtures can reproduce trends found in Gale crater. We hypothesize that variations in the 860 nm absorption feature in Mastcam and ChemCam observations of VRR materials are a result of three factors: (1) variations in ferric phyllosilicate abundance due to its ~800–1,000 nm absorption; (2) variations in clinopyroxene abundance because of its band maximum at ~860 nm; and (3) the presence of red crystalline hematite because of its absorption centered at 860 nm. We also show that relatively small changes in Ca-sulfate abundance is one potential cause of the erosional resistance and geomorphic expression of VRR.},
doi = {10.1029/2019je006290},
journal = {Journal of Geophysical Research. Planets},
number = 11,
volume = 125,
place = {United States},
year = {Fri Aug 28 00:00:00 EDT 2020},
month = {Fri Aug 28 00:00:00 EDT 2020}
}

Works referenced in this record:

Visible to near-infrared MSL/Mastcam multispectral imaging: Initial results from select high-interest science targets within Gale Crater, Mars
journal, June 2017

  • Wellington, Danika F.; Bell, James F.; Johnson, Jeffrey R.
  • American Mineralogist, Vol. 102, Issue 6
  • DOI: 10.2138/am-2017-5760CCBY

Clay mineral diversity and abundance in sedimentary rocks of Gale crater, Mars
journal, June 2018

  • Bristow, Thomas F.; Rampe, Elizabeth B.; Achilles, Cherie N.
  • Science Advances, Vol. 4, Issue 6
  • DOI: 10.1126/sciadv.aar3330

Hematite, pyroxene, and phyllosilicates on Mars: Implications from oxidized impact melt rocks from Manicouagan Crater, Quebec, Canada
journal, January 1995

  • Morris, Richard V.; Golden, D. C.; Bell, James F.
  • Journal of Geophysical Research, Vol. 100, Issue E3
  • DOI: 10.1029/94JE01500

Evidence for Multiple Diagenetic Episodes in Ancient Fluvial‐Lacustrine Sedimentary Rocks in Gale Crater, Mars
journal, August 2020

  • Achilles, C. N.; Rampe, E. B.; Downs, R. T.
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 8
  • DOI: 10.1029/2019JE006295

Synergistic Ground and Orbital Observations of Iron Oxides on Mt. Sharp and Vera Rubin Ridge
journal, September 2020

  • Fraeman, A. A.; Johnson, J. R.; Arvidson, R. E.
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 9
  • DOI: 10.1029/2019JE006294

Visible/near-infrared spectral diversity from in situ observations of the Bagnold Dune Field sands in Gale Crater, Mars: VIS/NIR SPECTRA OF BAGNOLD SANDS
journal, December 2017

  • Johnson, Jeffrey R.; Achilles, Cherie; Bell, James F.
  • Journal of Geophysical Research: Planets, Vol. 122, Issue 12
  • DOI: 10.1002/2016JE005187

A hematite-bearing layer in Gale Crater, Mars: Mapping and implications for past aqueous conditions
journal, July 2013

  • Fraeman, A. A.; Arvidson, R. E.; Catalano, J. G.
  • Geology, Vol. 41, Issue 10
  • DOI: 10.1130/G34613.1

Mineralogy of an ancient lacustrine mudstone succession from the Murray formation, Gale crater, Mars
journal, August 2017


ChemCam: Chemostratigraphy by the First Mars Microprobe
journal, February 2015


Mineralogic and compositional properties of Martian soil and dust: Results from Mars Pathfinder
journal, January 2000

  • Bell, J. F.; McSween, H. Y.; Crisp, J. A.
  • Journal of Geophysical Research: Planets, Vol. 105, Issue E1
  • DOI: 10.1029/1999JE001060

Distinct hematite populations from simultaneous fitting of Mössbauer spectra from Meridiani Planum, Mars
journal, January 2010

  • Fleischer, I.; Agresti, D. G.; Klingelhöfer, G.
  • Journal of Geophysical Research, Vol. 115
  • DOI: 10.1029/2010JE003622

Characterization and Calibration of the CheMin Mineralogical Instrument on Mars Science Laboratory
journal, June 2012


Mineralogy of Vera Rubin Ridge From the Mars Science Laboratory CheMin Instrument
journal, September 2020

  • Rampe, E. B.; Bristow, T. F.; Morris, R. V.
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 9
  • DOI: 10.1029/2019JE006306

Constraints on the origin and evolution of the layered mound in Gale Crater, Mars using Mars Reconnaissance Orbiter data
journal, August 2011


Constraints on the Mineralogy and Geochemistry of Vera Rubin Ridge, Gale Crater, Mars, From Mars Science Laboratory Sample Analysis at Mars Evolved Gas Analyses
journal, November 2020

  • McAdam, Amy C.; Sutter, Brad; Archer, P. Douglas
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 11
  • DOI: 10.1029/2019JE006309

Uniaxial Compressive Strengths of Rocks Drilled at Gale Crater, Mars
journal, January 2018

  • Peters, G. H.; Carey, E. M.; Anderson, R. C.
  • Geophysical Research Letters, Vol. 45, Issue 1
  • DOI: 10.1002/2017GL075965

Pre-flight calibration and initial data processing for the ChemCam laser-induced breakdown spectroscopy instrument on the Mars Science Laboratory rover
journal, April 2013

  • Wiens, R. C.; Maurice, S.; Lasue, J.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 82
  • DOI: 10.1016/j.sab.2013.02.003

Evidence for pigmentary hematite on Mars based on optical, magnetic, and Mossbauer studies of superparamagnetic (nanocrystalline) hematite
journal, March 1989

  • Morris, Richard V.; Agresti, David G.; Lauer, Howard V.
  • Journal of Geophysical Research: Solid Earth, Vol. 94, Issue B3
  • DOI: 10.1029/JB094iB03p02760

The stratigraphy and evolution of lower Mount Sharp from spectral, morphological, and thermophysical orbital data sets: Stratigraphy and Evolution of Mount Sharp
journal, September 2016

  • Fraeman, A. A.; Ehlmann, B. L.; Arvidson, R. E.
  • Journal of Geophysical Research: Planets, Vol. 121, Issue 9
  • DOI: 10.1002/2016JE005095

Deposition, exhumation, and paleoclimate of an ancient lake deposit, Gale crater, Mars
journal, October 2015


Mars Science Laboratory Mission and Science Investigation
journal, July 2012

  • Grotzinger, John P.; Crisp, Joy; Vasavada, Ashwin R.
  • Space Science Reviews, Vol. 170, Issue 1-4
  • DOI: 10.1007/s11214-012-9892-2

APXS‐Derived Compositional Characteristics of Vera Rubin Ridge and Murray Formation, Gale Crater, Mars: Geochemical Implications for the Origin of the Ridge
journal, October 2020

  • Thompson, L. M.; Berger, J. A.; Spray, J. G.
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 10
  • DOI: 10.1029/2019JE006319

Visible/near-infrared spectrogoniometric observations and modeling of dust-coated rocks
journal, October 2004


Calibration of the Mars Science Laboratory Alpha Particle X-ray Spectrometer
journal, April 2012

  • Campbell, John L.; Perrett, Glynis M.; Gellert, Ralf
  • Space Science Reviews, Vol. 170, Issue 1-4
  • DOI: 10.1007/s11214-012-9873-5

Collecting Samples in Gale Crater, Mars; an Overview of the Mars Science Laboratory Sample Acquisition, Sample Processing and Handling System
journal, June 2012


Curiosity’s Mars Hand Lens Imager (MAHLI) Investigation
journal, July 2012

  • Edgett, Kenneth S.; Yingst, R. Aileen; Ravine, Michael A.
  • Space Science Reviews, Vol. 170, Issue 1-4
  • DOI: 10.1007/s11214-012-9910-4

The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Science Objectives and Mast Unit Description
journal, July 2012


The effect of systematic diagenetic changes on the mechanical behavior of a quartz-cemented sandstone
journal, March 2015

  • Cook, Jennie E.; Goodwin, Laurel B.; Boutt, David F.
  • GEOPHYSICS, Vol. 80, Issue 2
  • DOI: 10.1190/geo2014-0026.1

Wind-blown sandstones cemented by sulfate and clay minerals in Gale Crater, Mars
journal, February 2014

  • Milliken, R. E.; Ewing, R. C.; Fischer, W. W.
  • Geophysical Research Letters, Vol. 41, Issue 4
  • DOI: 10.1002/2013GL059097

High spectral resolution reflectance spectroscopy of minerals
journal, January 1990

  • Clark, Roger N.; King, Trude V. V.; Klejwa, Matthew
  • Journal of Geophysical Research, Vol. 95, Issue B8
  • DOI: 10.1029/JB095iB08p12653

Observational evidence of crystalline iron oxides on Mars
journal, January 1990

  • Bell, James F.; McCord, Thomas B.; Owensby, Pamela D.
  • Journal of Geophysical Research, Vol. 95, Issue B9
  • DOI: 10.1029/JB095iB09p14447

Paleoclimate of Mars as captured by the stratigraphic record in Gale Crater: STRATIGRAPHY OF GALE CRATER
journal, February 2010

  • Milliken, R. E.; Grotzinger, J. P.; Thomson, B. J.
  • Geophysical Research Letters, Vol. 37, Issue 4
  • DOI: 10.1029/2009GL041870

Ceramic ChemCam Calibration Targets on Mars Science Laboratory
journal, May 2012


Redox stratification of an ancient lake in Gale crater, Mars
journal, June 2017


The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Body Unit and Combined System Tests
journal, June 2012

  • Wiens, Roger C.; Maurice, Sylvestre; Barraclough, Bruce
  • Space Science Reviews, Vol. 170, Issue 1-4
  • DOI: 10.1007/s11214-012-9902-4

Overview of the Mars Science Laboratory mission: Bradbury Landing to Yellowknife Bay and beyond: MARS SCIENCE LABORATORY MISSION OVERVIEW
journal, June 2014

  • Vasavada, A. R.; Grotzinger, J. P.; Arvidson, R. E.
  • Journal of Geophysical Research: Planets, Vol. 119, Issue 6
  • DOI: 10.1002/2014JE004622

The Mars Science Laboratory (MSL) Mast cameras and Descent imager: Investigation and instrument descriptions: MSL Mastcam/MARDI Descriptions
journal, August 2017

  • Malin, Michal C.; Ravine, Michael A.; Caplinger, Michael A.
  • Earth and Space Science, Vol. 4, Issue 8
  • DOI: 10.1002/2016EA000252

Strength of mineral absorption features in the transmitted component of near-infrared reflected light: First results from RELAB
journal, November 1983


Diagenesis of Vera Rubin Ridge, Gale Crater, Mars, From Mastcam Multispectral Images
journal, October 2020

  • Horgan, Briony H. N.; Johnson, Jeffrey R.; Fraeman, Abigail A.
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 11
  • DOI: 10.1029/2019JE006322

ChemCam passive reflectance spectroscopy of surface materials at the Curiosity landing site, Mars
journal, March 2015


The Chemostratigraphy of the Murray Formation and Role of Diagenesis at Vera Rubin Ridge in Gale Crater, Mars, as Observed by the ChemCam Instrument
journal, September 2020

  • Frydenvang, J.; Mangold, N.; Wiens, R. C.
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 9
  • DOI: 10.1029/2019JE006320

USGS Spectral Library Version 7
report, April 2017

  • Kokaly, Raymond F.; Clark, Roger N.; Swayze, Gregg A.
  • U.S. Geological Survey Data Series 1035
  • DOI: 10.3133/ds1035

Low-temperature reflectivity spectra of red hematite and the color of Mars
journal, April 1997

  • Morris, Richard V.; Golden, D. C.; Bell, James F.
  • Journal of Geophysical Research: Planets, Vol. 102, Issue E4
  • DOI: 10.1029/96JE03993

Evidence for a Diagenetic Origin of Vera Rubin Ridge, Gale Crater, Mars: Summary and Synthesis of Curiosity 's Exploration Campaign
journal, December 2020

  • Fraeman, A. A.; Edgar, L. A.; Rampe, E. B.
  • Journal of Geophysical Research: Planets, Vol. 125, Issue 12
  • DOI: 10.1029/2020JE006527