Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries
Abstract
Development of advanced high energy density lithium ion batteries is important for promoting electromobility. Making electric vehicles attractive and competitive compared to conventional automobiles depends on the availability of reliable, safe, high power, and highly energetic batteries whose components are abundant and cost effective. Nickel rich Li[NixCoyMn1–x–y]O2 layered cathode materials (x > 0.5) are of interest because they can provide very high specific capacity without pushing charging potentials to levels that oxidize the electrolyte solutions. However, these cathode materials suffer from stability problems. In this work, we discovered that doping these materials with tungsten (1 mol%) remarkably increases their stability due to a partial layered to cubic (rock salt) phase transition. We demonstrate herein highly stable Li ion battery prototypes consisting of tungsten-stabilized Ni rich cathode materials (x > 0.9) with specific capacities >220 mA h g-1. This development can increase the energy density of Li ion batteries more than 30% above the state of the art without compromising durability.
- Authors:
-
[1];
[3];
[4];
[5];
[6];
[7];
[1]
- Hanyang Univ., Seoul (South Korea)
- Freie Univ., Berlin (Germany)
- Freie Univ., Berlin (Germany); Forschungszentrum Juelich (Germany)
- Bar-Ilan Univ., Ramat-Gan (Israel)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Pohang Accelerator Lab. (PAL) (South Korea)
- Pusan National Univ., Busan (Korea, Republic of)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE; Ministry of Trade; China Scholarship Council (CSC); Federal Ministry of Education and Research (BMBF); Israel Committee for High Education; Israel Prime Minister Office
- OSTI Identifier:
- 1757972
- Report Number(s):
- PNNL-SA-129318
Journal ID: ISSN 1754-5692
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 5; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Kim, Un-Hyuck, Jun, Do-Wook, Park, Kang-Joon, Zhang, Q., Kaghazchi, Payam, Aurbach, Doron, Major, Dan T., Goobes, Gil, Dixit, Mudit, Leifer, Nicole, Wang, Chongmin, Yan, Pengfei, Ahn, Docheon, Kim, Kwang Ho, Yoon, Chong S., and Sun, Yang-Kook. Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries. United States: N. p., 2018.
Web. doi:10.1039/c8ee00227d.
Kim, Un-Hyuck, Jun, Do-Wook, Park, Kang-Joon, Zhang, Q., Kaghazchi, Payam, Aurbach, Doron, Major, Dan T., Goobes, Gil, Dixit, Mudit, Leifer, Nicole, Wang, Chongmin, Yan, Pengfei, Ahn, Docheon, Kim, Kwang Ho, Yoon, Chong S., & Sun, Yang-Kook. Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries. United States. https://doi.org/10.1039/c8ee00227d
Kim, Un-Hyuck, Jun, Do-Wook, Park, Kang-Joon, Zhang, Q., Kaghazchi, Payam, Aurbach, Doron, Major, Dan T., Goobes, Gil, Dixit, Mudit, Leifer, Nicole, Wang, Chongmin, Yan, Pengfei, Ahn, Docheon, Kim, Kwang Ho, Yoon, Chong S., and Sun, Yang-Kook. Mon .
"Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries". United States. https://doi.org/10.1039/c8ee00227d. https://www.osti.gov/servlets/purl/1757972.
@article{osti_1757972,
title = {Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries},
author = {Kim, Un-Hyuck and Jun, Do-Wook and Park, Kang-Joon and Zhang, Q. and Kaghazchi, Payam and Aurbach, Doron and Major, Dan T. and Goobes, Gil and Dixit, Mudit and Leifer, Nicole and Wang, Chongmin and Yan, Pengfei and Ahn, Docheon and Kim, Kwang Ho and Yoon, Chong S. and Sun, Yang-Kook},
abstractNote = {Development of advanced high energy density lithium ion batteries is important for promoting electromobility. Making electric vehicles attractive and competitive compared to conventional automobiles depends on the availability of reliable, safe, high power, and highly energetic batteries whose components are abundant and cost effective. Nickel rich Li[NixCoyMn1–x–y]O2 layered cathode materials (x > 0.5) are of interest because they can provide very high specific capacity without pushing charging potentials to levels that oxidize the electrolyte solutions. However, these cathode materials suffer from stability problems. In this work, we discovered that doping these materials with tungsten (1 mol%) remarkably increases their stability due to a partial layered to cubic (rock salt) phase transition. We demonstrate herein highly stable Li ion battery prototypes consisting of tungsten-stabilized Ni rich cathode materials (x > 0.9) with specific capacities >220 mA h g-1. This development can increase the energy density of Li ion batteries more than 30% above the state of the art without compromising durability.},
doi = {10.1039/c8ee00227d},
journal = {Energy & Environmental Science},
number = 5,
volume = 11,
place = {United States},
year = {Mon Mar 12 00:00:00 EDT 2018},
month = {Mon Mar 12 00:00:00 EDT 2018}
}
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