Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Experimental considerations to study Li-excess disordered rock salt cathode materials

Journal Article · · Journal of Materials Chemistry. A
DOI: https://doi.org/10.1039/D0TA07836K · OSTI ID:1755470
 [1];  [2];  [1];  [1];  [3]; ORCiD logo [3];  [1];  [1]; ORCiD logo [2];  [3]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Nanoengineering, University of California San Diego, La Jolla, USA
  2. Department of Physics, Applied Physics and Astronomy, Binghamton University, Binghamton, USA
  3. Department of Chemistry, Stony Brook University, Stony Brook, USA
+ Show Author Affiliations

Synthesis parameters, storage conditions, and electrolyte chemistry are all critical parameters limiting the cycling performances of disordered rock salt cathodes.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0012583; SC0012704
OSTI ID:
1755470
Journal Information:
Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 3 Vol. 9; ISSN JMCAET; ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (57)

The Configurational Space of Rocksalt-Type Oxides for High-Capacity Lithium Battery Electrodes journal May 2014
Disordered Lithium-Rich Oxyfluoride as a Stable Host for Enhanced Li + Intercalation Storage journal February 2015
Review on Challenges and Recent Advances in the Electrochemical Performance of High Capacity Li- and Mn-Rich Cathode Materials for Li-Ion Batteries journal December 2017
Understanding Performance Degradation in Cation‐Disordered Rock‐Salt Oxide Cathodes journal July 2019
Anion Reactivity in Cation‐Disordered Rocksalt Cathode Materials: The Influence of Fluorine Substitution journal August 2020
Modified High-Nickel Cathodes with Stable Surface Chemistry Against Ambient Air for Lithium-Ion Batteries journal April 2018
Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen journal April 2018
The quantitative analysis of surfaces by XPS: A review journal December 1980
Phase stability of iron germanate, FeGeO3, to 127 GPa journal November 2017
Thermal analysis study of LiFeO2 formation from Li2CO3–Fe2O3 mechanically activated reagents journal March 2018
Recent advances in magnetic structure determination by neutron powder diffraction journal October 1993
A disordered rock-salt Li-excess cathode material with high capacity and substantial oxygen redox activity: Li 1.25 Nb 0.25 Mn 0.5 O 2 journal November 2015
Surface chemistry of metal oxide coated lithium manganese nickel oxide thin film cathodes studied by XPS journal February 2013
XPS analysis of nanostructured materials and biological surfaces journal May 2010
Phase transformation and exchange bias effects in mechanically alloyed Fe/magnetite powders journal June 2011
Synthesis and electrochemical performance of Li3NbO4-based cation-disordered rock-salt cathode materials for Li-ion batteries journal August 2019
Influence of electrolyte additives on the cathode electrolyte interphase (CEI) formation on LiNi1/3Mn1/3Co1/3O2 in half cells with Li metal counter electrode journal October 2016
Mechanisms for electrochemical performance enhancement by the salt-type electrolyte additive, lithium difluoro(oxalato)borate, in high-voltage lithium-ion batteries journal July 2017
The Li 3 Ru y Nb 1– y O 4 (0 ≤ y ≤ 1) System: Structural Diversity and Li Insertion and Extraction Capabilities journal May 2017
Reaction Heterogeneity in LiNi 0.8 Co 0.15 Al 0.05 O 2 Induced by Surface Layer journal August 2017
Cathode Electrolyte Interphase Formation and Electrolyte Oxidation Mechanism for Ni-Rich Cathode Materials journal April 2020
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights journal October 2015
Quantification of Surface Oxygen Depletion and Solid Carbonate Evolution on the First Cycle of LiNi 0.6 Mn 0.2 Co 0.2 O 2 Electrodes journal April 2019
Correlating Lithium Hydroxyl Accumulation with Capacity Retention in V 2 O 5 Aerogel Cathodes journal April 2016
Design and Tuning of the Electrochemical Properties of Vanadium-Based Cation-Disordered Rock-Salt Oxide Positive Electrode Material for Lithium-Ion Batteries journal September 2019
Investigations on the Fundamental Process of Cathode Electrolyte Interphase Formation and Evolution of High-Voltage Cathodes journal December 2019
Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO 2 to CoO 2 Investigated by XPS journal January 2008
Probing the Origin of Enhanced Stability of “AlPO4” Nanoparticle Coated LiCoO2 during Cycling to High Voltages: Combined XRD and XPS Studies journal October 2009
Understanding the Roles of Anionic Redox and Oxygen Release during Electrochemical Cycling of Lithium-Rich Layered Li 4 FeSbO 6 journal April 2015
Residual Lithium Carbonate Predominantly Accounts for First Cycle CO 2 and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides journal November 2017
Composition and Growth Behavior of the Surface and Electrolyte Decomposition Layer of/on a Commercial Lithium Ion Battery Li x Ni 1/3 Mn 1/3 Co 1/3 O 2 Cathode Determined by Sputter Depth Profile X-ray Photoelectron Spectroscopy journal December 2013
Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries journal July 2016
Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries journal December 2016
A new active Li–Mn–O compound for high energy density Li-ion batteries journal November 2015
In situ click chemistry generation of cyclooxygenase-2 inhibitors journal February 2017
Advances and issues in developing salt-concentrated battery electrolytes journal March 2019
Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials journal April 2018
Synthesis and electrochemical properties of Li 1.3 Nb 0.3 V 0.4 O 2 as a positive electrode material for rechargeable lithium batteries journal January 2016
Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries journal January 2016
Enabling multi-electron reaction of ε-VOPO 4 to reach theoretical capacity for lithium-ion batteries journal January 2018
Design principles for high transition metal capacity in disordered rocksalt Li-ion cathodes journal January 2018
Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li 1.25 Nb 0.25 Mn 0.5 O 2 journal January 2019
Cation-disordered rocksalt transition metal oxides and oxyfluorides for high energy lithium-ion cathodes journal January 2020
Revisiting the charge compensation mechanisms in LiNi 0.8 Co 0.2−y Al y O 2 systems journal January 2019
Film-forming electrolyte additives for rechargeable lithium-ion batteries: progress and outlook journal January 2019
Identifying the anionic redox activity in cation-disordered Li 1.25 Nb 0.25 Fe 0.50 O 2 /C oxide cathodes for Li-ion batteries journal January 2020
Disordered lithium niobate rock-salt materials prepared by hydrothermal synthesis journal January 2010
High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure journal June 2015
A versatile sample-environment cell for non-ambient X-ray scattering experiments journal July 2008
GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal March 2013
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries journal January 2014
On the Surface Chemistry of LiMO[sub 2] Cathode Materials (M=[MnNi] and [MnNiCo]): Electrochemical, Spectroscopic, and Calorimetric Studies journal January 2010
Ambient Storage Derived Surface Contamination of NCM811 and NCM111: Performance Implications and Mitigation Strategies journal January 2019
XPS-Surface Analysis of SEI Layers on Li-Ion Cathodes: Part II. SEI-Composition and Formation inside Composite Electrodes journal January 2018
Editors' Choice—Growth of Ambient Induced Surface Impurity Species on Layered Positive Electrode Materials and Impact on Electrochemical Performance journal January 2017
Solid-state Redox Reaction of Oxide Ions for Rechargeable Batteries journal April 2017
Enhanced Cycling Stability of Cation Disordered Rock-Salt Li1.2Ti0.4Mn0.4O2 Material by Surface Modification With Al2O3 journal March 2019

Similar Records

Related Subjects