Magnetoelastic distortion of multiferroic BiFeO3 in the canted antiferromagnetic state

Rõõm, T.; Viirok, J.; Peedu, L.; Nagel, U.; Farkas, D. G.; Szaller, D.; Kocsis, V.; Bordács, S.; Kézsmárki, I.; Kamenskyi, D. L.; Engelkamp, H.; Ozerov, M.; Smirnov, D.; Krzystek, J.; Thirunavukkuarasu, K.; Ozaki, Y.; Tomioka, Y.; Ito, T.; Datta, T.; Fishman, R. S.

doi:10.1103/physrevb.102.214410

Title: Magnetoelastic distortion of multiferroic BiFeO₃ in the canted antiferromagnetic state

Abstract

Using THz spectroscopy, here we show that the spin-wave spectrum of multiferroic BiFeO₃ in its high-field canted antiferromagnetic state is well described by a spin model that violates rhombohedral symmetry. We demonstrate that the monoclinic distortion of the canted antiferromagnetic state is induced by the single-ion magnetoelastic coupling between the lattice and the two nearly antiparallel spins. The revised spin model for BiFeO₃ contains two new single-ion anisotropy terms that violate rhombohedral symmetry and depend on the direction of the magnetic field.

Authors:

^[1]; Viirok, J. ^[1]; Peedu, L. ^[1];

^[1]; Farkas, D. G. ^[2];

^[3]; Kocsis, V. ^[4]; Bordács, S. ^[2]; Kézsmárki, I. ^[5]; Kamenskyi, D. L. ^[6];

^[6]; Ozerov, M. ^[7]; Smirnov, D. ^[7];

^[7]; Thirunavukkuarasu, K. ^[8]; Ozaki, Y. ^[9]; Tomioka, Y. ^[9]; Ito, T. ^[9];

^[10];

^[11]

National Inst. of Chemical Physics and Biophysics, Tallinn (Estonia)
Budapest Univ. of Technology and Economics (Hungary); Hungarian Academy of Sciences, Budapest (Hungary)
Budapest Univ. of Technology and Economics (Hungary); Vienna Univ. of Technology (Austria)
Budapest Univ. of Technology and Economics (Hungary); RIKEN Center for Emergent Matter Science (CEMS), Wako (Japan)
Budapest Univ. of Technology and Economics (Hungary); Univ. of Augsburg (Germany)
Radboud Univ., Nijmegen (Netherlands)
Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)
Florida A & M University, Tallahassee, FL (United States)
National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)
Augusta Univ., GA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division

Publication Date:: 2020-12-09

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; European Regional Development Fund; Estonian Ministry of Education and Research Council Grants; Estonian Academy of Science; Hungarian Academy of Science; Hungarian Innovation Office (NKFIH); BME; Austrian Science Fund (FWF); German Research Foundation (DFG); SYSU; National Science Foundation (NSF)

OSTI Identifier:: 1755293

Grant/Contract Number:: AC05-00OR22725; TK134; IUT23-03; PRG736; SNK-64/2013; K-124176; ANN-122879; BME-FIKP-NAT; 2816-N27; TRR-80; OEMT-2017-KF-06; DMR-1644779

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review. B

Additional Journal Information:: Journal Volume: 102; Journal Issue: 21; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ferroelectricity; magnetic anisotropy; magnetic order; magnetoelastic effect; spin dynamics; spin waves; spin-orbit coupling; ferroelectrics; multiferroics; terahertz spectroscopy

Citation Formats


                    Rõõm, T., Viirok, J., Peedu, L., Nagel, U., Farkas, D. G., Szaller, D., Kocsis, V., Bordács, S., Kézsmárki, I., Kamenskyi, D. L., Engelkamp, H., Ozerov, M., Smirnov, D., Krzystek, J., Thirunavukkuarasu, K., Ozaki, Y., Tomioka, Y., Ito, T., Datta, T., and Fishman, R. S. Magnetoelastic distortion of multiferroic BiFeO3 in the canted antiferromagnetic state.  United States: N. p., 2020. 
Web.  doi:10.1103/physrevb.102.214410.

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                    Rõõm, T., Viirok, J., Peedu, L., Nagel, U., Farkas, D. G., Szaller, D., Kocsis, V., Bordács, S., Kézsmárki, I., Kamenskyi, D. L., Engelkamp, H., Ozerov, M., Smirnov, D., Krzystek, J., Thirunavukkuarasu, K., Ozaki, Y., Tomioka, Y., Ito, T., Datta, T., & Fishman, R. S. Magnetoelastic distortion of multiferroic BiFeO3 in the canted antiferromagnetic state.  United States.  https://doi.org/10.1103/physrevb.102.214410

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                    Rõõm, T., Viirok, J., Peedu, L., Nagel, U., Farkas, D. G., Szaller, D., Kocsis, V., Bordács, S., Kézsmárki, I., Kamenskyi, D. L., Engelkamp, H., Ozerov, M., Smirnov, D., Krzystek, J., Thirunavukkuarasu, K., Ozaki, Y., Tomioka, Y., Ito, T., Datta, T., and Fishman, R. S. Wed .  
"Magnetoelastic distortion of multiferroic BiFeO3 in the canted antiferromagnetic state".  United States.  https://doi.org/10.1103/physrevb.102.214410.  https://www.osti.gov/servlets/purl/1755293.

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@article{osti_1755293,

  title        = {Magnetoelastic distortion of multiferroic BiFeO3 in the canted antiferromagnetic state},

  author       = {Rõõm, T. and Viirok, J. and Peedu, L. and Nagel, U. and Farkas, D. G. and Szaller, D. and Kocsis, V. and Bordács, S. and Kézsmárki, I. and Kamenskyi, D. L. and Engelkamp, H. and Ozerov, M. and Smirnov, D. and Krzystek, J. and Thirunavukkuarasu, K. and Ozaki, Y. and Tomioka, Y. and Ito, T. and Datta, T. and Fishman, R. S.},

  abstractNote = {Using THz spectroscopy, here we show that the spin-wave spectrum of multiferroic BiFeO3 in its high-field canted antiferromagnetic state is well described by a spin model that violates rhombohedral symmetry. We demonstrate that the monoclinic distortion of the canted antiferromagnetic state is induced by the single-ion magnetoelastic coupling between the lattice and the two nearly antiparallel spins. The revised spin model for BiFeO3 contains two new single-ion anisotropy terms that violate rhombohedral symmetry and depend on the direction of the magnetic field.},

  doi          = {10.1103/physrevb.102.214410},

  journal      = {Physical Review. B},

  number       = 21,

  volume       = 102,

  place        = {United States},

  year         = {2020},

  month        = {12}

}

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Works referenced in this record:

Magnetic field induced antiferromagnetic cone structure in multiferroic ${BiFeO}_{3}$
journal, March 2020

Matsuda, M.; Dissanayake, S. E.; Hong, T.
Physical Review Materials, Vol. 4, Issue 3
DOI: 10.1103/PhysRevMaterials.4.034412

Growth of Highly Insulating Bulk Single Crystals of Multiferroic BiFeO ₃ and Their Inherent Internal Strains in the Domain-Switching Process
journal, November 2011

Ito, Toshimitsu; Ushiyama, Tomoharu; Yanagisawa, Yuji
Crystal Growth & Design, Vol. 11, Issue 11
DOI: 10.1021/cg201068m

Flexomagnetoelectric interaction in multiferroics
journal, August 2009

Pyatakov, A. P.; Zvezdin, A. K.
The European Physical Journal B, Vol. 71, Issue 3
DOI: 10.1140/epjb/e2009-00281-5

BiFeO ₃ Thin Films: A Playground for Exploring Electric-Field Control of Multifunctionalities
journal, July 2015

Yang, Jan-Chi; He, Qing; Yu, Pu
Annual Review of Materials Research, Vol. 45, Issue 1
DOI: 10.1146/annurev-matsci-070214-020837

High Field Neutron Diffraction Studies on Metamagnetic Transition of Multiferroic BiFeO ₃
journal, December 2011

Ohoyama, Kenji; Lee, Seongsu; Yoshii, Shunsuke
Journal of the Physical Society of Japan, Vol. 80, Issue 12
DOI: 10.1143/JPSJ.80.125001

Temperature-dependent properties of the magnetic order in single-crystal BiFeO $_{3}$
journal, May 2011

Ramazanoglu, M.; Ratcliff, W.; Choi, Y. J.
Physical Review B, Vol. 83, Issue 17
DOI: 10.1103/PhysRevB.83.174434

Nanoscale Electrostatic Manipulation of Magnetic Flux Quanta in Ferroelectric/Superconductor ${BiFeO}_{3} / {YBa}_{2} {Cu}_{3} O_{7 - δ}$ Heterostructures
journal, December 2011

Crassous, Arnaud; Bernard, Rozenn; Fusil, Stéphane
Physical Review Letters, Vol. 107, Issue 24, Article No. 247002
DOI: 10.1103/PhysRevLett.107.247002

Successive field-induced transitions in ${BiFeO}_{3}$ around room temperature
journal, July 2017

Kawachi, Shiro; Miyake, Atsushi; Ito, Toshimitsu
Physical Review Materials, Vol. 1, Issue 2
DOI: 10.1103/PhysRevMaterials.1.024408

Atomic displacements in BiFeO ₃ as a function of temperature: neutron diffraction study
journal, July 2007

Palewicz, A.; Przeniosło, R.; Sosnowska, I.
Acta Crystallographica Section B Structural Science, Vol. 63, Issue 4
DOI: 10.1107/S0108768107023956

Scalable energy-efficient magnetoelectric spin–orbit logic
journal, December 2018

Manipatruni, Sasikanth; Nikonov, Dmitri E.; Lin, Chia-Ching
Nature, Vol. 565, Issue 7737
DOI: 10.1038/s41586-018-0770-2

The microscopic model of BiFeO3
journal, May 2018

Fishman, R. S.
Physica B: Condensed Matter, Vol. 536
DOI: 10.1016/j.physb.2017.09.103

Antiferromagnetic transitions in tetragonal-like BiFeO $_{3}$
journal, March 2012

MacDougall, G. J.; Christen, H. M.; Siemons, W.
Physical Review B, Vol. 85, Issue 10
DOI: 10.1103/PhysRevB.85.100406

High field studies on BiFeO 3 single crystals grown by the laser-diode heating floating zone method
journal, June 2015

Tokunaga, M.; Akaki, M.; Miyake, A.
Journal of Magnetism and Magnetic Materials, Vol. 383
DOI: 10.1016/j.jmmm.2014.10.026

Advances in magnetoelectric multiferroics
journal, February 2019

Spaldin, N. A.; Ramesh, R.
Nature Materials, Vol. 18, Issue 3
DOI: 10.1038/s41563-018-0275-2

Spin Wave Measurements over the Full Brillouin Zone of Multiferroic ${BiFeO}_{3}$
journal, February 2012

Jeong, Jaehong; Goremychkin, E. A.; Guidi, T.
Physical Review Letters, Vol. 108, Issue 7
DOI: 10.1103/PhysRevLett.108.077202

Magnetoelectric Feedback among Magnetic Order, Polarization, and Lattice in Multiferroic BiFeO ₃
journal, November 2011

Park, Junghwan; Lee, Sang-Hyun; Lee, Seongsu
Journal of the Physical Society of Japan, Vol. 80, Issue 11
DOI: 10.1143/JPSJ.80.114714

Spin state and spectroscopic modes of multiferroic BiFeO $_{3}$
journal, April 2013

Fishman, Randy S.; Haraldsen, Jason T.; Furukawa, Nobuo
Physical Review B, Vol. 87, Issue 13
DOI: 10.1103/PhysRevB.87.134416

Optical Diode Effect at Spin-Wave Excitations of the Room-Temperature Multiferroic ${BiFeO}_{3}$
journal, September 2015

Kézsmárki, I.; Nagel, U.; Bordács, S.
Physical Review Letters, Vol. 115, Issue 12
DOI: 10.1103/PhysRevLett.115.127203

Long-wavelength magnetic and magnetoelectric excitations in the ferroelectric antiferromagnet BiFeO $_{3}$
journal, March 2011

Talbayev, D.; Trugman, S. A.; Lee, Seongsu
Physical Review B, Vol. 83, Issue 9
DOI: 10.1103/PhysRevB.83.094403

Static Magnetoelastic Coupling in Cubic Crystals
journal, January 1963

Callen, Earl R.; Callen, Herbert B.
Physical Review, Vol. 129, Issue 2
DOI: 10.1103/PhysRev.129.578

Dielectric Properties of Solid Solutions of BiFeO ₃ with Pb(Ti, Zr)O ₃ at High Temperature and High Frequency
journal, January 1968

Smith, Robert T.; Achenbach, Gary D.; Gerson, Robert
Journal of Applied Physics, Vol. 39, Issue 1
DOI: 10.1063/1.1655783

Electric field control of the magnetic state in BiFeO3 single crystals
journal, May 2008

Lee, Seoungsu; Ratcliff, W.; Cheong, S-W.
Applied Physics Letters, Vol. 92, Issue 19
DOI: 10.1063/1.2930678

Spiral magnetic ordering in bismuth ferrite
journal, August 1982

Sosnowska, I.; Neumaier, T. P.; Steichele, E.
Journal of Physics C: Solid State Physics, Vol. 15, Issue 23
DOI: 10.1088/0022-3719/15/23/020

High-field study of multiferroic BiFeO ₃
journal, January 2010

Tokunaga, M.; Azuma, M.; Shimakawa, Y.
Journal of Physics: Conference Series, Vol. 200, Issue 1
DOI: 10.1088/1742-6596/200/1/012206

Polarized Raman spectroscopy of nearly tetragonal ${BiFeO}_{3}$ thin films
journal, July 2010

Iliev, M. N.; Abrashev, M. V.; Mazumdar, D.
Physical Review B, Vol. 82, Issue 1
DOI: 10.1103/PhysRevB.82.014107

Magnetostriction
journal, February 1968

Callen, Earl
Journal of Applied Physics, Vol. 39, Issue 2
DOI: 10.1063/1.2163507

Direct coupling of ferromagnetic moment and ferroelectric polarization in ${BiFeO}_{3}$
journal, October 2019

Kawachi, Shiro; Miyahara, Shin; Ito, Toshimitsu
Physical Review B, Vol. 100, Issue 14
DOI: 10.1103/PhysRevB.100.140412

Beyond CMOS computing with spin and polarization
journal, April 2018

Manipatruni, Sasikanth; Nikonov, Dmitri E.; Young, Ian A.
Nature Physics, Vol. 14, Issue 4
DOI: 10.1038/s41567-018-0101-4

Structural distortion and magnetism of BiFeO ₃ epitaxial thin films: A Raman spectroscopy and neutron diffraction study
journal, March 2007

Béa, H.; Bibes, M.; Petit, S.
Philosophical Magazine Letters, Vol. 87, Issue 3-4
DOI: 10.1080/09500830701235802

Neutron diffraction study of the BiFeO ₃ spin cycloid at low temperature
journal, June 2010

Herrero-Albillos, Julia; Catalan, Gustau; Rodriguez-Velamazan, José Alberto
Journal of Physics: Condensed Matter, Vol. 22, Issue 25
DOI: 10.1088/0953-8984/22/25/256001

Stabilization of weak ferromagnetism by strong magnetic response to epitaxial strain in multiferroic BiFeO3
journal, August 2015

Dixit, Hemant; Hee Lee, Jun; Krogel, Jaron T.
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep12969

Temperature-Dependent Interplay of Dzyaloshinskii-Moriya Interaction and Single-Ion Anisotropy in Multiferroic ${BiFeO}_{3}$
journal, September 2014

Jeong, Jaehong; Le, Manh Duc; Bourges, P.
Physical Review Letters, Vol. 113, Issue 10
DOI: 10.1103/PhysRevLett.113.107202

Pinning, rotation, and metastability of ${BiFeO}_{3}$ cycloidal domains in a magnetic field
journal, January 2018

Fishman, Randy S.
Physical Review B, Vol. 97, Issue 1
DOI: 10.1103/PhysRevB.97.014405

Local Weak Ferromagnetism in Single-Crystalline Ferroelectric ${BiFeO}_{3}$
journal, November 2011

Ramazanoglu, M.; Laver, M.; Ratcliff, W.
Physical Review Letters, Vol. 107, Issue 20
DOI: 10.1103/PhysRevLett.107.207206

The atomic structure of BiFeO3
journal, May 1969

Michel, Christian; Moreau, Jean-Michel; Achenbach, Gary D.
Solid State Communications, Vol. 7, Issue 9
DOI: 10.1016/0038-1098(69)90597-3

Space-time parity violation and magnetoelectric interactions in antiferromagnets
journal, June 2004

Kadomtseva, A. M.; Zvezdin, A. K.; Popov, Yu. F.
Journal of Experimental and Theoretical Physics Letters, Vol. 79, Issue 11
DOI: 10.1134/1.1787107

Theory of Spin-Orbit Enhanced Electric-Field Control of Magnetism in Multiferroic ${BiFeO}_{3}$
journal, June 2013

de Sousa, Rogério; Allen, Marc; Cazayous, Maximilien
Physical Review Letters, Vol. 110, Issue 26
DOI: 10.1103/PhysRevLett.110.267202

Effect of spatial spin modulation on the relaxation and NMR frequencies of 57Fe nuclei in a ferroelectric antiferromagnet BiFeO3
journal, July 2002

Zalesskii, A. V.; Frolov, A. A.; Zvezdin, A. K.
Journal of Experimental and Theoretical Physics, Vol. 95, Issue 1
DOI: 10.1134/1.1499907

Complex strain evolution of polar and magnetic order in multiferroic BiFeO3 thin films
journal, September 2018

Chen, Zuhuang; Chen, Zhanghui; Kuo, Chang-Yang
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-06190-5

Photovoltaic effects in BiFeO3
journal, August 2009

Yang, S. Y.; Martin, L. W.; Byrnes, S. J.
Applied Physics Letters, Vol. 95, Issue 6
DOI: 10.1063/1.3204695

Low-temperature evolution of the modulated magnetic structure in the ferroelectric antiferromagnet BiFeO $_{3}$
journal, October 2011

Sosnowska, I.; Przeniosło, R.
Physical Review B, Vol. 84, Issue 14
DOI: 10.1103/PhysRevB.84.144404

Electric-Field-Induced Spin Flop in ${BiFeO}_{3}$ Single Crystals at Room Temperature
journal, June 2008

Lebeugle, D.; Colson, D.; Forget, A.
Physical Review Letters, Vol. 100, Issue 22
DOI: 10.1103/PhysRevLett.100.227602

Magnetostriction in rare-earth based antiferromagnets
journal, January 2005

Doerr *, M.; Rotter, M.; Lindbaum, A.
Advances in Physics, Vol. 54, Issue 1
DOI: 10.1080/00018730500037264

Ferroelectric BiFeO3 X-ray and neutron diffraction study
journal, January 1971

Moreau, J. M.; Michel, C.; Gerson, R.
Journal of Physics and Chemistry of Solids, Vol. 32, Issue 6
DOI: 10.1016/S0022-3697(71)80189-0

Monoclinic Deformation of Crystal Lattice of Bulk α-BiFeO ₃ : High Resolution Synchrotron Radiation Studies
journal, April 2012

Sosnowska, Izabela; PrzeniosŁo, Radosław; Palewicz, Andrzej
Journal of the Physical Society of Japan, Vol. 81, Issue 4
DOI: 10.1143/JPSJ.81.044604

Thermal evolution of the full three-dimensional magnetic excitations in the multiferroic BiFeO $_{3}$
journal, November 2012

Xu, Zhijun; Wen, Jinsheng; Berlijn, Tom
Physical Review B, Vol. 86, Issue 17
DOI: 10.1103/PhysRevB.86.174419

Origin of the long period magnetic ordering in BiFeO3
journal, February 1995

Sosnowska, I.; Zvezdin, A. K.
Journal of Magnetism and Magnetic Materials, Vol. 140-144
DOI: 10.1016/0304-8853(94)01120-6

Magnetic-field-induced phase transition in ${BiFeO}_{3}$ observed by high-field electron spin resonance: Cycloidal to homogeneous spin order
journal, February 2004

Ruette, Benjamin; Zvyagin, S.; Pyatakov, A. P.
Physical Review B, Vol. 69, Issue 6
DOI: 10.1103/PhysRevB.69.064114

Magnetoelastic Spin Hamiltonians: Applications to Garnets
journal, October 1969

Alben, Richard; Callen, Earl
Physical Review, Vol. 186, Issue 2
DOI: 10.1103/PhysRev.186.522

Electric-field control of spin waves at room temperature in multiferroic BiFeO3
journal, November 2010

Rovillain, P.; de Sousa, R.; Gallais, Y.
Nature Materials, Vol. 9, Issue 12
DOI: 10.1038/nmat2899

Destruction of spin cycloid in (111)c-oriented BiFeO3 thin films by epitiaxial constraint: Enhanced polarization and release of latent magnetization
journal, January 2005

Bai, Feiming; Wang, Junling; Wuttig, M.
Applied Physics Letters, Vol. 86, Issue 3
DOI: 10.1063/1.1851612

High-Field Study of Strong Magnetoelectric Coupling in Single-Domain Crystals of BiFeO ₃
journal, June 2010

Tokunaga, Masashi; Azuma, Masaki; Shimakawa, Yuichi
Journal of the Physical Society of Japan, Vol. 79, Issue 6
DOI: 10.1143/JPSJ.79.064713

Spin-induced polarizations and nonreciprocal directional dichroism of the room-temperature multiferroic ${BiFeO}_{3}$
journal, September 2015

Fishman, Randy S.; Lee, Jun Hee; Bordács, Sándor
Physical Review B, Vol. 92, Issue 9
DOI: 10.1103/PhysRevB.92.094422

57Fe NMR study of a spatially modulated magnetic structure in BiFeO3
journal, June 2000

Zalesskii, A. V.; Zvezdin, A. K.; Frolov, A. A.
Journal of Experimental and Theoretical Physics Letters, Vol. 71, Issue 11
DOI: 10.1134/1.1307994

Toward Intrinsic Ferroelectric Switching in Multiferroic ${BiFeO}_{3}$
journal, August 2020

Parsonnet, Eric; Huang, Yen-Lin; Gosavi, Tanay
Physical Review Letters, Vol. 125, Issue 6
DOI: 10.1103/PhysRevLett.125.067601

Bond electronic polarization induced by spin
journal, December 2006

Jia, Chenglong; Onoda, Shigeki; Nagaosa, Naoto
Physical Review B, Vol. 74, Issue 22
DOI: 10.1103/PhysRevB.74.224444

BiFeO ₃ Crystal Structure at Low Temperatures
journal, February 2010

Palewicz, A.; Sosnowska, I.; Przeniosło, R.
Acta Physica Polonica A, Vol. 117, Issue 2
DOI: 10.12693/APhysPolA.117.296

Magnetic control of transverse electric polarization in BiFeO3
journal, January 2015

Tokunaga, M.; Akaki, M.; Ito, T.
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms6878

On the Structure of α-BiFeO ₃
journal, February 2013

Wang, Hui; Yang, Chengxu; Lu, Jun
Inorganic Chemistry, Vol. 52, Issue 5
DOI: 10.1021/ic302047z

Magnetic Dispersion and Anisotropy in Multiferroic ${BiFeO}_{3}$
journal, August 2012

Matsuda, M.; Fishman, R. S.; Hong, T.
Physical Review Letters, Vol. 109, Issue 6
DOI: 10.1103/PhysRevLett.109.067205

Dielectric hysteresis in single crystal BiFeO3
journal, July 1970

Teague, James R.; Gerson, Robert; James, W. J.
Solid State Communications, Vol. 8, Issue 13
DOI: 10.1016/0038-1098(70)90262-0

Spiral magnetic ordering in bismuth ferrite
journal, August 1982

Sosnowska, I.; Neumaier, T. P.; Steichele, E.
Journal of Physics C: Solid State Physics, Vol. 15, Issue 23
DOI: 10.1088/0022-3719/15/23/020

Static Magnetoelastic Coupling in Cubic Crystals
journal, June 1963

Callen, Earl R.; Callen, Herbert B.
Physical Review, Vol. 130, Issue 6
DOI: 10.1103/physrev.130.2600

Magnetostriction, Forced Magnetostriction, and Anomalous Thermal Expansion in Ferromagnets
journal, July 1965

Callen, Earl; Callen, Herbert B.
Physical Review, Vol. 139, Issue 2A
DOI: 10.1103/physrev.139.a455

Field-induced phase transitions and phase diagrams in BiFeO $_{3}$ -like multiferroics
journal, June 2013

Gareeva, Z. V.; Popkov, A. F.; Soloviov, S. V.
Physical Review B, Vol. 87, Issue 21
DOI: 10.1103/physrevb.87.214413

Possible Observation of Cycloidal Electromagnons in ${BiFeO}_{3}$
journal, July 2008

Cazayous, M.; Gallais, Y.; Sacuto, A.
Physical Review Letters, Vol. 101, Issue 3
DOI: 10.1103/physrevlett.101.037601

Terahertz Spectroscopy of Spin Waves in Multiferroic ${BiFeO}_{3}$ in High Magnetic Fields
journal, June 2013

Nagel, U.; Fishman, Randy S.; Katuwal, T.
Physical Review Letters, Vol. 110, Issue 25
DOI: 10.1103/physrevlett.110.257201

Magnetic Field Control of Cycloidal Domains and Electric Polarization in Multiferroic ${BiFeO}_{3}$
journal, April 2018

Bordács, S.; Farkas, D. G.; White, J. S.
Physical Review Letters, Vol. 120, Issue 14
DOI: 10.1103/physrevlett.120.147203

Structure of a ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3
journal, December 1990

Kubel, F.; Schmid, H.
Acta Crystallographica Section B Structural Science, Vol. 46, Issue 6
DOI: 10.1107/s0108768190006887

Long wavelength magnetic and magnetoelectric excitations in the ferroelectric antiferromagnet BiFeO3
text, January 2011

Talbayev, D.; Trugman, S. A.; Lee, Seongsu
arXiv
DOI: 10.48550/arxiv.1102.2552

The Spin State and Spectroscopic Modes of Multiferroic BiFeO3
text, January 2013

Fishman, Randy S.; Haraldsen, Jason T.; Furukawa, Nobuo
arXiv
DOI: 10.48550/arxiv.1302.4365

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Magnetic and structural properties of BiFeO{sub 3} thin films grown epitaxially on SrTiO{sub 3}/Si substrates

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The integration of oxides with semiconductors is important for the technological advancement of the next generation electronics. Concomitant ferroelectric and antiferromagnetic (AF) behavior is demonstrated in single crystal BiFeO{sub 3} (BFO) films grown on 20 nm SrTiO{sub 3} (STO) virtual substrates on Si(100) using molecular beam epitaxy (MBE). STO thin films are grown in an oxide MBE chamber by co-deposition of Sr, Ti, and molecular O{sub 2}. Careful control of the O{sub 2} during nucleation produced commensurate growth of STO on Si. The sequence of the steps allows for the suppression of an amorphous SiO{sub 2} layer. This STO(20 nm)/Simore »« less
https://doi.org/10.1063/1.4796150
Evidence of improved ferroelectric phase stabilization in Nd and Sc co-substituted BiFeO{sub 3}

Journal Article Durga Rao, T. ; Asthana, Saket - Journal of Applied Physics

Polycrystalline BiFeO{sub 3} and Bi{sub 0.9}Nd{sub 0.1}Fe{sub 1−x}Sc{sub x}O{sub 3} (x = 0, 0.05, and 0.10) multiferroic compounds were prepared using conventional solid-state route. X-ray diffraction studies and Raman measurements indicated that the compounds were crystallized in rhombohedral structure with R3c space group. Weak ferromagnetism was induced due to the suppression of canted spin structure in the substituted compounds. Both remanent magnetization (M{sub r}) and coercive field (H{sub c}) were enhanced in Nd and Sc substituted compounds. Further, Néel temperature T{sub N} was decreased from 644 K for BiFeO{sub 3} to 550 K for Bi{sub 0.9}Nd{sub 0.1}Fe{sub 0.9}Sc{sub 0.1}O{sub 3} compound due to weakeningmore »« less
https://doi.org/10.1063/1.4898805
Successive field-induced transitions in ${BiFeO}_{3}$ around room temperature

Journal Article Kawachi, Shiro ; Miyake, Atsushi ; Ito, Toshimitsu ; ... - Physical Review Materials

The effects of high magnetic fields applied perpendicular to the spontaneous ferroelectric polarization on single crystals of BiFeO₃ were investigated in this paper through magnetization, magnetostriction, and neutron diffraction measurements. The magnetostriction measurements revealed lattice distortion of 2 x 10^-5 during the reorientation process of the cycloidal spin order by applied magnetic fields. Furthermore, anomalous changes in magnetostriction and electric polarization at a larger field demonstrate an intermediate phase between cycloidal and canted antiferromagnetic states, where a large magnetoelectric effect was observed. Neutron diffraction measurements clarified that incommensurate spin modulation along the [110]_hex direction in the cycloidal phase becomes Qmore »« less
Cited by 21
https://doi.org/10.1103/PhysRevMaterials.1.024408

Full Text Available
Magnetic interactions in BiFeO₃: A first-principles study

Journal Article Xu, Changsong ; Xu, Bin ; Dupé, Bertrand ; ... - Physical Review B

First-principles calculations, in combination with the four-state energy mapping method, are performed to extract the magnetic interaction parameters of multiferroic BiFeO₃. Such parameters include the symmetric exchange (SE) couplings and the Dzyaloshinskii-Moriya (DM) interactions up to second-nearest neighbors, as well as the single-ion anisotropy (SIA). Here, all magnetic parameters are obtained not only for the R3c structural ground state, but also for the R3m and R¯3c phases in order to determine the effects of ferroelectricity and antiferrodistortion distortions, respectively, on these magnetic parameters. In particular, two different second-nearest-neighbor couplings are identified and their origins are discussed in details. Moreover, Montemore »« less
Cited by 31
https://doi.org/10.1103/physrevb.99.104420

Full Text Available

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Title: Magnetoelastic distortion of multiferroic BiFeO3 in the canted antiferromagnetic state

Abstract

Citation Formats

Magnetic field induced antiferromagnetic cone structure in multiferroic BiFeO 3 journal, March 2020

Growth of Highly Insulating Bulk Single Crystals of Multiferroic BiFeO 3 and Their Inherent Internal Strains in the Domain-Switching Process journal, November 2011

Flexomagnetoelectric interaction in multiferroics journal, August 2009

BiFeO 3 Thin Films: A Playground for Exploring Electric-Field Control of Multifunctionalities journal, July 2015

High Field Neutron Diffraction Studies on Metamagnetic Transition of Multiferroic BiFeO 3 journal, December 2011

Temperature-dependent properties of the magnetic order in single-crystal BiFeO 3 journal, May 2011

Nanoscale Electrostatic Manipulation of Magnetic Flux Quanta in Ferroelectric/Superconductor BiFeO 3 / YBa 2 Cu 3 O 7 − δ Heterostructures journal, December 2011

Successive field-induced transitions in BiFeO 3 around room temperature journal, July 2017

Atomic displacements in BiFeO 3 as a function of temperature: neutron diffraction study journal, July 2007

Scalable energy-efficient magnetoelectric spin–orbit logic journal, December 2018

The microscopic model of BiFeO3 journal, May 2018

Antiferromagnetic transitions in tetragonal-like BiFeO 3 journal, March 2012

High field studies on BiFeO 3 single crystals grown by the laser-diode heating floating zone method journal, June 2015

Advances in magnetoelectric multiferroics journal, February 2019

Spin Wave Measurements over the Full Brillouin Zone of Multiferroic BiFeO 3 journal, February 2012

Magnetoelectric Feedback among Magnetic Order, Polarization, and Lattice in Multiferroic BiFeO 3 journal, November 2011

Spin state and spectroscopic modes of multiferroic BiFeO 3 journal, April 2013

Optical Diode Effect at Spin-Wave Excitations of the Room-Temperature Multiferroic BiFeO 3 journal, September 2015

Long-wavelength magnetic and magnetoelectric excitations in the ferroelectric antiferromagnet BiFeO 3 journal, March 2011

Static Magnetoelastic Coupling in Cubic Crystals journal, January 1963

Dielectric Properties of Solid Solutions of BiFeO 3 with Pb(Ti, Zr)O 3 at High Temperature and High Frequency journal, January 1968

Electric field control of the magnetic state in BiFeO3 single crystals journal, May 2008

Spiral magnetic ordering in bismuth ferrite journal, August 1982

High-field study of multiferroic BiFeO 3 journal, January 2010

Polarized Raman spectroscopy of nearly tetragonal BiFeO 3 thin films journal, July 2010

Magnetostriction journal, February 1968

Direct coupling of ferromagnetic moment and ferroelectric polarization in BiFeO 3 journal, October 2019

Beyond CMOS computing with spin and polarization journal, April 2018

Structural distortion and magnetism of BiFeO 3 epitaxial thin films: A Raman spectroscopy and neutron diffraction study journal, March 2007

Neutron diffraction study of the BiFeO 3 spin cycloid at low temperature journal, June 2010

Stabilization of weak ferromagnetism by strong magnetic response to epitaxial strain in multiferroic BiFeO3 journal, August 2015

Temperature-Dependent Interplay of Dzyaloshinskii-Moriya Interaction and Single-Ion Anisotropy in Multiferroic BiFeO 3 journal, September 2014

Pinning, rotation, and metastability of BiFeO 3 cycloidal domains in a magnetic field journal, January 2018

Local Weak Ferromagnetism in Single-Crystalline Ferroelectric BiFeO 3 journal, November 2011

The atomic structure of BiFeO3 journal, May 1969

Space-time parity violation and magnetoelectric interactions in antiferromagnets journal, June 2004

Theory of Spin-Orbit Enhanced Electric-Field Control of Magnetism in Multiferroic BiFeO 3 journal, June 2013

Effect of spatial spin modulation on the relaxation and NMR frequencies of 57Fe nuclei in a ferroelectric antiferromagnet BiFeO3 journal, July 2002

Complex strain evolution of polar and magnetic order in multiferroic BiFeO3 thin films journal, September 2018

Photovoltaic effects in BiFeO3 journal, August 2009

Low-temperature evolution of the modulated magnetic structure in the ferroelectric antiferromagnet BiFeO 3 journal, October 2011

Electric-Field-Induced Spin Flop in BiFeO 3 Single Crystals at Room Temperature journal, June 2008

Magnetostriction in rare-earth based antiferromagnets journal, January 2005

Ferroelectric BiFeO3 X-ray and neutron diffraction study journal, January 1971

Monoclinic Deformation of Crystal Lattice of Bulk α-BiFeO 3 : High Resolution Synchrotron Radiation Studies journal, April 2012

Thermal evolution of the full three-dimensional magnetic excitations in the multiferroic BiFeO 3 journal, November 2012

Origin of the long period magnetic ordering in BiFeO3 journal, February 1995

Magnetic-field-induced phase transition in BiFeO 3 observed by high-field electron spin resonance: Cycloidal to homogeneous spin order journal, February 2004

Magnetoelastic Spin Hamiltonians: Applications to Garnets journal, October 1969

Electric-field control of spin waves at room temperature in multiferroic BiFeO3 journal, November 2010

Destruction of spin cycloid in (111)c-oriented BiFeO3 thin films by epitiaxial constraint: Enhanced polarization and release of latent magnetization journal, January 2005

High-Field Study of Strong Magnetoelectric Coupling in Single-Domain Crystals of BiFeO 3 journal, June 2010

Spin-induced polarizations and nonreciprocal directional dichroism of the room-temperature multiferroic BiFeO 3 journal, September 2015

57Fe NMR study of a spatially modulated magnetic structure in BiFeO3 journal, June 2000

Toward Intrinsic Ferroelectric Switching in Multiferroic BiFeO 3 journal, August 2020

Bond electronic polarization induced by spin journal, December 2006

BiFeO 3 Crystal Structure at Low Temperatures journal, February 2010

Magnetic control of transverse electric polarization in BiFeO3 journal, January 2015

On the Structure of α-BiFeO 3 journal, February 2013

Magnetic Dispersion and Anisotropy in Multiferroic BiFeO 3 journal, August 2012

Dielectric hysteresis in single crystal BiFeO3 journal, July 1970

Spiral magnetic ordering in bismuth ferrite journal, August 1982

Static Magnetoelastic Coupling in Cubic Crystals journal, June 1963

Magnetostriction, Forced Magnetostriction, and Anomalous Thermal Expansion in Ferromagnets journal, July 1965

Field-induced phase transitions and phase diagrams in BiFeO 3 -like multiferroics journal, June 2013

Possible Observation of Cycloidal Electromagnons in BiFeO 3 journal, July 2008

Terahertz Spectroscopy of Spin Waves in Multiferroic BiFeO 3 in High Magnetic Fields journal, June 2013

Magnetic Field Control of Cycloidal Domains and Electric Polarization in Multiferroic BiFeO 3 journal, April 2018

Structure of a ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3 journal, December 1990

Long wavelength magnetic and magnetoelectric excitations in the ferroelectric antiferromagnet BiFeO3 text, January 2011

The Spin State and Spectroscopic Modes of Multiferroic BiFeO3 text, January 2013

Title: Magnetoelastic distortion of multiferroic BiFeO₃ in the canted antiferromagnetic state

Magnetic field induced antiferromagnetic cone structure in multiferroic ${BiFeO}_{3}$
journal, March 2020

Growth of Highly Insulating Bulk Single Crystals of Multiferroic BiFeO ₃ and Their Inherent Internal Strains in the Domain-Switching Process
journal, November 2011

Flexomagnetoelectric interaction in multiferroics
journal, August 2009

BiFeO ₃ Thin Films: A Playground for Exploring Electric-Field Control of Multifunctionalities
journal, July 2015

High Field Neutron Diffraction Studies on Metamagnetic Transition of Multiferroic BiFeO ₃
journal, December 2011

Temperature-dependent properties of the magnetic order in single-crystal BiFeO $_{3}$
journal, May 2011

Nanoscale Electrostatic Manipulation of Magnetic Flux Quanta in Ferroelectric/Superconductor ${BiFeO}_{3} / {YBa}_{2} {Cu}_{3} O_{7 - δ}$ Heterostructures
journal, December 2011

Successive field-induced transitions in ${BiFeO}_{3}$ around room temperature
journal, July 2017

Atomic displacements in BiFeO ₃ as a function of temperature: neutron diffraction study
journal, July 2007

Scalable energy-efficient magnetoelectric spin–orbit logic
journal, December 2018

The microscopic model of BiFeO3
journal, May 2018

Antiferromagnetic transitions in tetragonal-like BiFeO $_{3}$
journal, March 2012

High field studies on BiFeO 3 single crystals grown by the laser-diode heating floating zone method
journal, June 2015

Advances in magnetoelectric multiferroics
journal, February 2019

Spin Wave Measurements over the Full Brillouin Zone of Multiferroic ${BiFeO}_{3}$
journal, February 2012

Magnetoelectric Feedback among Magnetic Order, Polarization, and Lattice in Multiferroic BiFeO ₃
journal, November 2011

Spin state and spectroscopic modes of multiferroic BiFeO $_{3}$
journal, April 2013

Optical Diode Effect at Spin-Wave Excitations of the Room-Temperature Multiferroic ${BiFeO}_{3}$
journal, September 2015

Long-wavelength magnetic and magnetoelectric excitations in the ferroelectric antiferromagnet BiFeO $_{3}$
journal, March 2011

Static Magnetoelastic Coupling in Cubic Crystals
journal, January 1963

Dielectric Properties of Solid Solutions of BiFeO ₃ with Pb(Ti, Zr)O ₃ at High Temperature and High Frequency
journal, January 1968

Electric field control of the magnetic state in BiFeO3 single crystals
journal, May 2008

Spiral magnetic ordering in bismuth ferrite
journal, August 1982

High-field study of multiferroic BiFeO ₃
journal, January 2010

Polarized Raman spectroscopy of nearly tetragonal ${BiFeO}_{3}$ thin films
journal, July 2010

Magnetostriction
journal, February 1968

Direct coupling of ferromagnetic moment and ferroelectric polarization in ${BiFeO}_{3}$
journal, October 2019

Beyond CMOS computing with spin and polarization
journal, April 2018

Structural distortion and magnetism of BiFeO ₃ epitaxial thin films: A Raman spectroscopy and neutron diffraction study
journal, March 2007

Neutron diffraction study of the BiFeO ₃ spin cycloid at low temperature
journal, June 2010

Stabilization of weak ferromagnetism by strong magnetic response to epitaxial strain in multiferroic BiFeO3
journal, August 2015

Temperature-Dependent Interplay of Dzyaloshinskii-Moriya Interaction and Single-Ion Anisotropy in Multiferroic ${BiFeO}_{3}$
journal, September 2014

Pinning, rotation, and metastability of ${BiFeO}_{3}$ cycloidal domains in a magnetic field
journal, January 2018

Local Weak Ferromagnetism in Single-Crystalline Ferroelectric ${BiFeO}_{3}$
journal, November 2011

The atomic structure of BiFeO3
journal, May 1969

Space-time parity violation and magnetoelectric interactions in antiferromagnets
journal, June 2004

Theory of Spin-Orbit Enhanced Electric-Field Control of Magnetism in Multiferroic ${BiFeO}_{3}$
journal, June 2013

Effect of spatial spin modulation on the relaxation and NMR frequencies of 57Fe nuclei in a ferroelectric antiferromagnet BiFeO3
journal, July 2002

Complex strain evolution of polar and magnetic order in multiferroic BiFeO3 thin films
journal, September 2018

Photovoltaic effects in BiFeO3
journal, August 2009

Low-temperature evolution of the modulated magnetic structure in the ferroelectric antiferromagnet BiFeO $_{3}$
journal, October 2011

Electric-Field-Induced Spin Flop in ${BiFeO}_{3}$ Single Crystals at Room Temperature
journal, June 2008

Magnetostriction in rare-earth based antiferromagnets
journal, January 2005

Ferroelectric BiFeO3 X-ray and neutron diffraction study
journal, January 1971

Monoclinic Deformation of Crystal Lattice of Bulk α-BiFeO ₃ : High Resolution Synchrotron Radiation Studies
journal, April 2012

Thermal evolution of the full three-dimensional magnetic excitations in the multiferroic BiFeO $_{3}$
journal, November 2012

Origin of the long period magnetic ordering in BiFeO3
journal, February 1995

Magnetic-field-induced phase transition in ${BiFeO}_{3}$ observed by high-field electron spin resonance: Cycloidal to homogeneous spin order
journal, February 2004

Magnetoelastic Spin Hamiltonians: Applications to Garnets
journal, October 1969

Electric-field control of spin waves at room temperature in multiferroic BiFeO3
journal, November 2010

Destruction of spin cycloid in (111)c-oriented BiFeO3 thin films by epitiaxial constraint: Enhanced polarization and release of latent magnetization
journal, January 2005

High-Field Study of Strong Magnetoelectric Coupling in Single-Domain Crystals of BiFeO ₃
journal, June 2010

Spin-induced polarizations and nonreciprocal directional dichroism of the room-temperature multiferroic ${BiFeO}_{3}$
journal, September 2015

57Fe NMR study of a spatially modulated magnetic structure in BiFeO3
journal, June 2000

Toward Intrinsic Ferroelectric Switching in Multiferroic ${BiFeO}_{3}$
journal, August 2020

Bond electronic polarization induced by spin
journal, December 2006

BiFeO ₃ Crystal Structure at Low Temperatures
journal, February 2010

Magnetic control of transverse electric polarization in BiFeO3
journal, January 2015

On the Structure of α-BiFeO ₃
journal, February 2013

Magnetic Dispersion and Anisotropy in Multiferroic ${BiFeO}_{3}$
journal, August 2012

Dielectric hysteresis in single crystal BiFeO3
journal, July 1970

Spiral magnetic ordering in bismuth ferrite
journal, August 1982

Static Magnetoelastic Coupling in Cubic Crystals
journal, June 1963

Magnetostriction, Forced Magnetostriction, and Anomalous Thermal Expansion in Ferromagnets
journal, July 1965

Field-induced phase transitions and phase diagrams in BiFeO $_{3}$ -like multiferroics
journal, June 2013

Possible Observation of Cycloidal Electromagnons in ${BiFeO}_{3}$
journal, July 2008

Terahertz Spectroscopy of Spin Waves in Multiferroic ${BiFeO}_{3}$ in High Magnetic Fields
journal, June 2013

Magnetic Field Control of Cycloidal Domains and Electric Polarization in Multiferroic ${BiFeO}_{3}$
journal, April 2018

Structure of a ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3
journal, December 1990

Long wavelength magnetic and magnetoelectric excitations in the ferroelectric antiferromagnet BiFeO3
text, January 2011

The Spin State and Spectroscopic Modes of Multiferroic BiFeO3
text, January 2013