Long-lived charge separation in two-dimensional ligand-perovskite heterostructures

Deng, Shibin; Snaider, Jordan M.; Gao, Yao; Shi, Enzheng; Jin, Linrui; Schaller, Richard D.; Dou, Letian; Huang, Libai

doi:10.1063/1.5131801

Title: Long-lived charge separation in two-dimensional ligand-perovskite heterostructures

Journal Article · 26 January 2020 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/1.5131801 · OSTI ID:1755186

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^[1]; Shi, Enzheng ^[1]; Jin, Linrui ^[1]; Schaller, Richard D. ^[2];

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Purdue Univ., West Lafayette, IN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)

Rational design of heterojunctions using nanostructured materials is a useful strategy for achieving efficient interfacial charge separation in photovoltaics. Heterojunctions can be constructed between organic ligands and inorganic layer in two-dimensional (2D) perovskites, taking advantage of their highly programmable structures. We investigate electron and hole transfer at the interface between the thiophene-based semiconducting ligands and the lead halide inorganic sublattices using time-resolved photoluminescence and transient reflection spectroscopy in single 2D perovskite crystals. Here, these measurements demonstrate charge transfer time of ~ 10 ps and long-lived charge-separated state over the nanosecond timescale in 2D ligand-perovskite heterostructures. The efficient charge transfer processes with slow charge recombination suggest the potential for improving exciton dissociation and charge transport in 2D perovskite solar cells.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: US Department of the Navy, Office of Naval Research (ONR); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0016356

OSTI ID:: 1755186

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 4 Vol. 152; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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