Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (Co x Rh 100− x @SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates
Abstract
Abstract The synthesis, characterization, and catalytic properties of bimetallic cobalt‐rhodium nanoparticles of defined Co:Rh ratios immobilized in an imidazolium‐based supported ionic liquid phase (Co x Rh 100− x @SILP) are described. Following an organometallic approach, precise control of the Co:Rh ratios is accomplished. Electron microscopy and X‐ray absorption spectroscopy confirm the formation of small, well‐dispersed, and homogeneously alloyed zero‐valent bimetallic nanoparticles in all investigated materials. Benzylideneacetone and various bicyclic heteroaromatics are used as chemical probes to investigate the hydrogenation performances of the Co x Rh 100− x @SILP materials. The Co:Rh ratio of the nanoparticles is found to have a critical influence on observed activity and selectivity, with clear synergistic effects arising from the combination of the noble metal and its 3d congener. In particular, the ability of Co x Rh 100− x @SILP catalysts to hydrogenate 6‐membered aromatic rings is found to experience a remarkable sharp switch in a narrow composition range between Co 25 Rh 75 (full ring hydrogenation) and Co 30 Rh 70 (no ring hydrogenation).
- Authors:
-
[2];
[1]
- Max Planck Institute for Chemical Energy Conversion Stiftstrasse 34–36 Mülheim an der Ruhr 45470 Germany, Institut für Technische und Makromolekulare Chemie RWTH Aachen University Worringerweg 2 Aachen 52074 Germany
- Max Planck Institute for Chemical Energy Conversion Stiftstrasse 34–36 Mülheim an der Ruhr 45470 Germany
- Laboratoire de Physique et Chimie des Nano‐Objets Université de Toulouse INSA UPS LPCNO CNRS‐UMR5215 135 Avenue de Rangueil Toulouse 31077 France
- Institut für Technische und Makromolekulare Chemie RWTH Aachen University Worringerweg 2 Aachen 52074 Germany
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1737726
- Alternate Identifier(s):
- OSTI ID: 1786580
- Resource Type:
- Published Article
- Journal Name:
- Small
- Additional Journal Information:
- Journal Name: Small Journal Volume: 17 Journal Issue: 5; Journal ID: ISSN 1613-6810
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Rengshausen, Simon, Van Stappen, Casey, Levin, Natalia, Tricard, Simon, Luska, Kylie L., DeBeer, Serena, Chaudret, Bruno, Bordet, Alexis, and Leitner, Walter. Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (Co x Rh 100− x @SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates. Germany: N. p., 2020.
Web. doi:10.1002/smll.202006683.
Rengshausen, Simon, Van Stappen, Casey, Levin, Natalia, Tricard, Simon, Luska, Kylie L., DeBeer, Serena, Chaudret, Bruno, Bordet, Alexis, & Leitner, Walter. Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (Co x Rh 100− x @SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates. Germany. https://doi.org/10.1002/smll.202006683
Rengshausen, Simon, Van Stappen, Casey, Levin, Natalia, Tricard, Simon, Luska, Kylie L., DeBeer, Serena, Chaudret, Bruno, Bordet, Alexis, and Leitner, Walter. Mon .
"Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (Co x Rh 100− x @SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates". Germany. https://doi.org/10.1002/smll.202006683.
@article{osti_1737726,
title = {Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (Co x Rh 100− x @SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates},
author = {Rengshausen, Simon and Van Stappen, Casey and Levin, Natalia and Tricard, Simon and Luska, Kylie L. and DeBeer, Serena and Chaudret, Bruno and Bordet, Alexis and Leitner, Walter},
abstractNote = {Abstract The synthesis, characterization, and catalytic properties of bimetallic cobalt‐rhodium nanoparticles of defined Co:Rh ratios immobilized in an imidazolium‐based supported ionic liquid phase (Co x Rh 100− x @SILP) are described. Following an organometallic approach, precise control of the Co:Rh ratios is accomplished. Electron microscopy and X‐ray absorption spectroscopy confirm the formation of small, well‐dispersed, and homogeneously alloyed zero‐valent bimetallic nanoparticles in all investigated materials. Benzylideneacetone and various bicyclic heteroaromatics are used as chemical probes to investigate the hydrogenation performances of the Co x Rh 100− x @SILP materials. The Co:Rh ratio of the nanoparticles is found to have a critical influence on observed activity and selectivity, with clear synergistic effects arising from the combination of the noble metal and its 3d congener. In particular, the ability of Co x Rh 100− x @SILP catalysts to hydrogenate 6‐membered aromatic rings is found to experience a remarkable sharp switch in a narrow composition range between Co 25 Rh 75 (full ring hydrogenation) and Co 30 Rh 70 (no ring hydrogenation).},
doi = {10.1002/smll.202006683},
journal = {Small},
number = 5,
volume = 17,
place = {Germany},
year = {Mon Dec 21 00:00:00 EST 2020},
month = {Mon Dec 21 00:00:00 EST 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/smll.202006683
https://doi.org/10.1002/smll.202006683
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices
journal, March 2000
- Sun, S.
- Science, Vol. 287, Issue 5460
Bimetallic Nanocrystals: Syntheses, Properties, and Applications
journal, July 2016
- Gilroy, Kyle D.; Ruditskiy, Aleksey; Peng, Hsin-Chieh
- Chemical Reviews, Vol. 116, Issue 18
Colloidal Au–Cu alloy nanoparticles: synthesis, optical properties and applications
journal, January 2018
- Thota, Sravan; Wang, Yongchen; Zhao, Jing
- Materials Chemistry Frontiers, Vol. 2, Issue 6
Synthesis and Magnetism of Co x Rh 1 - x and Co x Ru 1 - x Nanoparticles
journal, July 2003
- Zitoun, D.; Amiens, C.; Chaudret, B.
- The Journal of Physical Chemistry B, Vol. 107, Issue 29
Synthesis and Optical Properties of Fe@Au, Ni@Au Bimetallic Core–Shell Nanoparticles
journal, April 2018
- Soloveva, A. Yu.; Eremenko, N. K.; Obraztsova, I. I.
- Russian Journal of Inorganic Chemistry, Vol. 63, Issue 4
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts
journal, September 2016
- Matsubu, John C.; Zhang, Shuyi; DeRita, Leo
- Nature Chemistry, Vol. 9, Issue 2
Dendrimer-Stabilized Metal Nanoparticles as Efficient Catalysts for Reversible Dehydrogenation/Hydrogenation of N-Heterocycles
journal, November 2017
- Deraedt, Christophe; Ye, Rong; Ralston, Walter T.
- Journal of the American Chemical Society, Vol. 139, Issue 49
Catalytic hydrogenation of benzene to cyclohexene on Ru(0001) from density functional theory investigations☆
journal, February 2011
- Fan, Chen; Zhu, Yi-An; Zhou, Xing-Gui
- Catalysis Today, Vol. 160, Issue 1
Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles
journal, November 2008
- Tao, F.; Grass, M. E.; Zhang, Y.
- Science, Vol. 322, Issue 5903
Synthesis of ultrasmall, homogeneously alloyed, bimetallic nanoparticles on silica supports
journal, November 2017
- Wong, A.; Liu, Q.; Griffin, S.
- Science, Vol. 358, Issue 6369
Synthesis of Monodisperse FeAu Nanoparticles with Tunable Magnetic and Optical Properties
journal, April 2007
- Chiang, I-C.; Chen, D. -H.
- Advanced Functional Materials, Vol. 17, Issue 8
Étude de l'effet des additifs Fe, Co, Ni sur l'interaction Rh–toluène sur Rh/Al2O3
journal, June 2004
- Benseradj, Fadhéla; Sadi, Farida; Chater, Mohamed
- Comptes Rendus Chimie, Vol. 7, Issue 6-7
Magneto-Plasmonic Au-Fe Alloy Nanoparticles Designed for Multimodal SERS-MRI-CT Imaging
journal, March 2014
- Amendola, Vincenzo; Scaramuzza, Stefano; Litti, Lucio
- Small, Vol. 10, Issue 12
Catalytic Hydrogenolysis of Substituted Diaryl Ethers by Using Ruthenium Nanoparticles on an Acidic Supported Ionic Liquid Phase (Ru@SILP-SO3H)
journal, February 2019
- Rengshausen, Simon; Etscheidt, Fabian; Großkurth, Johannes
- Synlett, Vol. 30, Issue 04
A general synthesis approach for supported bimetallic nanoparticles via surface inorganometallic chemistry
journal, November 2018
- Ding, Kunlun; Cullen, David A.; Zhang, Laibao
- Science, Vol. 362, Issue 6414
Surface Chemistry on Colloidal Metals. Reversible Adsorbate-Induced Surface Composition Changes in Colloidal Palladium-Copper Alloys
journal, March 1995
- Bradley, John S.; Hill, Ernestine W.; Chaudret, Bruno
- Langmuir, Vol. 11, Issue 3
Bimetallic Nanoparticles in Supported Ionic Liquid Phases as Multifunctional Catalysts for the Selective Hydrodeoxygenation of Aromatic Substrates
journal, September 2018
- Offner-Marko, Lisa; Bordet, Alexis; Moos, Gilles
- Angewandte Chemie International Edition, Vol. 57, Issue 39
Bimetallic Nanocrystals: Liquid-Phase Synthesis and Catalytic Applications
journal, January 2011
- Wang, Dingsheng; Li, Yadong
- Advanced Materials, Vol. 23, Issue 9
Hydrogenation of arenes, N-heteroaromatic compounds, and alkenes catalyzed by rhodium nanoparticles supported on magnesium oxide
journal, May 2014
- Sánchez, Antonio; Fang, Minfeng; Ahmed, Atif
- Applied Catalysis A: General, Vol. 477
Chemoselective reduction of heteroarenes with a reduced graphene oxide supported rhodium nanoparticle catalyst
journal, January 2018
- Karakulina, Alena; Gopakumar, Aswin; Fei, Zhaofu
- Catalysis Science & Technology, Vol. 8, Issue 19
Molecular Control of the Catalytic Properties of Rhodium Nanoparticles in Supported Ionic Liquid Phase (SILP) Systems
journal, November 2020
- Bordet, Alexis; Moos, Gilles; Welsh, Calum
- ACS Catalysis, Vol. 10, Issue 23
Tuning the structure and magnetic behavior of Ni–Ir-based nanoparticles in ionic liquids
journal, January 2018
- M. da Silva, Kácris I.; Bernardi, Fabiano; Abarca, Gabriel
- Physical Chemistry Chemical Physics, Vol. 20, Issue 15
Raney Ni-Sn Catalyst for H2 Production from Biomass-Derived Hydrocarbons
journal, June 2003
- Huber, G. W.
- Science, Vol. 300, Issue 5628
Cobalt–rhodium heterobimetallic nanoparticle-catalyzed reactions
journal, January 2008
- Park, Ji Hoon; Chung, Young Keun
- Dalton Transactions, Issue 18
Synthesis of supported bimetallic nanoparticles with controlled size and composition distributions for active site elucidation
journal, August 2015
- Hakim, Sikander H.; Sener, Canan; Alba-Rubio, Ana C.
- Journal of Catalysis, Vol. 328
Structural Models and Atomic Distribution of Bimetallic Nanoparticles as Investigated by X-ray Absorption Spectroscopy
journal, August 2005
- Hwang, Bing-Joe; Sarma, Loka Subramanyam; Chen, Jiun-Ming
- Journal of the American Chemical Society, Vol. 127, Issue 31
Bimetallic synergy in cobalt–palladium nanocatalysts for CO oxidation
journal, December 2018
- Wu, Cheng Hao; Liu, Chang; Su, Dong
- Nature Catalysis, Vol. 2, Issue 1
Enhancing the Catalytic Properties of Ruthenium Nanoparticle-SILP Catalysts by Dilution with Iron
journal, May 2016
- Luska, Kylie L.; Bordet, Alexis; Tricard, Simon
- ACS Catalysis, Vol. 6, Issue 6
A General and Highly Selective Cobalt-Catalyzed Hydrogenation of N-Heteroarenes under Mild Reaction Conditions
journal, February 2017
- Adam, Rosa; Cabrero-Antonino, Jose R.; Spannenberg, Anke
- Angewandte Chemie International Edition, Vol. 56, Issue 12
Bifunctional nanoparticle–SILP catalysts (NPs@SILP) for the selective deoxygenation of biomass substrates
journal, January 2014
- Luska, Kylie L.; Julis, Jennifer; Stavitski, Eli
- Chem. Sci., Vol. 5, Issue 12
Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co–Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions
journal, October 2016
- Choi, Isaac; Chung, Hyunho; Park, Jang Won
- Organic Letters, Vol. 18, Issue 21
Selective Hydrogenation of Benzofurans Using Ruthenium Nanoparticles in Lewis Acid-Modified Ruthenium-Supported Ionic Liquid Phases
journal, January 2020
- El Sayed, Sami; Bordet, Alexis; Weidenthaler, Claudia
- ACS Catalysis, Vol. 10, Issue 3
Organometallic Synthesis of β-CoAl Nanoparticles and β-CoAl/Al Nanoparticles and Their Behaviour upon Air Exposure
journal, February 2010
- Cokoja, Mirza; Parala, Harish; Birkner, Alexander
- European Journal of Inorganic Chemistry, Vol. 2010, Issue 11
Optical and Magnetic Properties of Ag–Ni Bimetallic Nanoparticles Assembled via Pulsed Laser-Induced Dewetting
journal, July 2020
- Garfinkel, David A.; Pakeltis, Grace; Tang, Nan
- ACS Omega, Vol. 5, Issue 30
Designing bimetallic catalysts for a green and sustainable future
journal, January 2012
- Sankar, Meenakshisundaram; Dimitratos, Nikolaos; Miedziak, Peter J.
- Chemical Society Reviews, Vol. 41, Issue 24
Characterization of supported cobalt and cobalt-rhodium catalysts III. Temperature-Programmed Reduction (TPR), Oxidation (TPO), and EXAFS of Co$z.sbnd;Rh/SiO2
journal, January 1986
- Vantblik, H.
- Journal of Catalysis, Vol. 97, Issue 1
Selective hydrodeoxygenation of hydroxyacetophenones to ethyl-substituted phenol derivatives using a FeRu@SILP catalyst
journal, January 2020
- Goclik, Lisa; Offner-Marko, Lisa; Bordet, Alexis
- Chemical Communications, Vol. 56, Issue 66
Cookie-like Au/NiO Nanoparticles with Optical Gas-Sensing Properties
journal, February 2007
- Mattei, G.; Mazzoldi, P.; Post, M. L.
- Advanced Materials, Vol. 19, Issue 4
Alcohol synthesis by catalytic hydrogenation of CO2 over Rh-Co/SiO2
journal, January 2000
- Kusama, Hitoshi; Okabe, Kiyomi; Sayama, Kazuhiro
- Applied Organometallic Chemistry, Vol. 14, Issue 12
Aqueous-phase hydrogenation and hydrodeoxygenation of biomass-derived oxygenates with bimetallic catalysts
journal, January 2014
- Lee, Jechan; Kim, Yong Tae; Huber, George W.
- Green Chemistry, Vol. 16, Issue 2
Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO 2 Catalysts
journal, January 2006
- Enache, Dan I.; Edwards, Jennifer K.; Landon, Philip
- Science, Vol. 311, Issue 5759
Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms
journal, September 2019
- Zhang, Leilei; Zhou, Maoxiang; Wang, Aiqin
- Chemical Reviews, Vol. 120, Issue 2
Selective Hydrogenation and Hydrodeoxygenation of Aromatic Ketones to Cyclohexane Derivatives Using a Rh@SILP Catalyst
journal, May 2020
- Moos, Gilles; Emondts, Meike; Bordet, Alexis
- Angewandte Chemie International Edition, Vol. 59, Issue 29
The Role of Atomic Ensembles in the Reactivity of Bimetallic Electrocatalysts
journal, September 2001
- Maroun, F.
- Science, Vol. 293, Issue 5536
Supported ionic liquid phase rhodium nanoparticle hydrogenation catalysts
journal, January 2007
- Gelesky, Marcos A.; Chiaro, Sandra S. X.; Pavan, Flávio A.
- Dalton Transactions, Issue 47
Asymmetric Hydrogenation of Heteroarenes and Arenes
journal, November 2011
- Wang, Duo-Sheng; Chen, Qing-An; Lu, Sheng-Mei
- Chemical Reviews, Vol. 112, Issue 4, p. 2557-2590
Grain boundaries modulating active sites in RhCo porous nanospheres for efficient CO2 hydrogenation
journal, May 2018
- Zheng, Xusheng; Lin, Yue; Pan, Haibin
- Nano Research, Vol. 11, Issue 5
A Rhodium Nanoparticle-Lewis Acidic Ionic Liquid Catalyst for the Chemoselective Reduction of Heteroarenes
journal, November 2015
- Karakulina, Alena; Gopakumar, Aswin; Akçok, İsmail
- Angewandte Chemie International Edition, Vol. 55, Issue 1
Synergistic Interaction within Bifunctional Ruthenium Nanoparticle/SILP Catalysts for the Selective Hydrodeoxygenation of Phenols
journal, November 2015
- Luska, Kylie L.; Migowski, Pedro; El Sayed, Sami
- Angewandte Chemie International Edition, Vol. 54, Issue 52
Bimetallic catalysts for upgrading of biomass to fuels and chemicals
journal, January 2012
- Alonso, David Martin; Wettstein, Stephanie G.; Dumesic, James A.
- Chemical Society Reviews, Vol. 41, Issue 24, p. 8075-8098