Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating
Abstract
Abstract Surface passivation of perovskite solar cells (PSCs) using a low‐cost industrial organic pigment quinacridone (QA) is presented. The procedure involves solution processing a soluble derivative of QA, N , N ‐bis(tert‐butyloxycarbonyl)‐quinacridone (TBOC‐QA), followed by thermal annealing to convert TBOC‐QA into insoluble QA. With halide perovskite thin films coated by QA, PSCs based on methylammonium lead iodide (MAPbI 3 ) showed significantly improved performance with remarkable stability. A PCE of 21.1 % was achieved, which is much higher than 18.9 % recorded for the unmodified devices. The QA coating with exceptional insolubility and hydrophobicity also led to greatly enhanced contact angle from 35.6° for the pristine MAPbI 3 thin films to 77.2° for QA coated MAPbI 3 thin films. The stability of QA passivated MAPbI 3 perovskite thin films and PSCs were significantly enhanced, retaining about 90 % of the initial efficiencies after more than 1000 hours storage under ambient conditions.
- Authors:
-
[5]
- Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32306 USA
- Materials Science and Engineering Program Florida State University Tallahassee FL 32306 USA
- Department of Physics Florida State University Tallahassee FL 32306 USA
- Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology Daejeon 34141 Republic of Korea
- Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32306 USA, Materials Science and Engineering Program Florida State University Tallahassee FL 32306 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1724438
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 133 Journal Issue: 5; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
He, Qingquan, Worku, Michael, Liu, He, Lochner, Eric, Robb, Alex J., Lteif, Sandrine, Vellore Winfred, J. S. Raaj, Hanson, Kenneth, Schlenoff, Joseph B., Kim, Bumjoon J., and Ma, Biwu. Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating. Germany: N. p., 2020.
Web. doi:10.1002/ange.202012095.
He, Qingquan, Worku, Michael, Liu, He, Lochner, Eric, Robb, Alex J., Lteif, Sandrine, Vellore Winfred, J. S. Raaj, Hanson, Kenneth, Schlenoff, Joseph B., Kim, Bumjoon J., & Ma, Biwu. Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating. Germany. https://doi.org/10.1002/ange.202012095
He, Qingquan, Worku, Michael, Liu, He, Lochner, Eric, Robb, Alex J., Lteif, Sandrine, Vellore Winfred, J. S. Raaj, Hanson, Kenneth, Schlenoff, Joseph B., Kim, Bumjoon J., and Ma, Biwu. Fri .
"Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating". Germany. https://doi.org/10.1002/ange.202012095.
@article{osti_1724438,
title = {Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating},
author = {He, Qingquan and Worku, Michael and Liu, He and Lochner, Eric and Robb, Alex J. and Lteif, Sandrine and Vellore Winfred, J. S. Raaj and Hanson, Kenneth and Schlenoff, Joseph B. and Kim, Bumjoon J. and Ma, Biwu},
abstractNote = {Abstract Surface passivation of perovskite solar cells (PSCs) using a low‐cost industrial organic pigment quinacridone (QA) is presented. The procedure involves solution processing a soluble derivative of QA, N , N ‐bis(tert‐butyloxycarbonyl)‐quinacridone (TBOC‐QA), followed by thermal annealing to convert TBOC‐QA into insoluble QA. With halide perovskite thin films coated by QA, PSCs based on methylammonium lead iodide (MAPbI 3 ) showed significantly improved performance with remarkable stability. A PCE of 21.1 % was achieved, which is much higher than 18.9 % recorded for the unmodified devices. The QA coating with exceptional insolubility and hydrophobicity also led to greatly enhanced contact angle from 35.6° for the pristine MAPbI 3 thin films to 77.2° for QA coated MAPbI 3 thin films. The stability of QA passivated MAPbI 3 perovskite thin films and PSCs were significantly enhanced, retaining about 90 % of the initial efficiencies after more than 1000 hours storage under ambient conditions.},
doi = {10.1002/ange.202012095},
journal = {Angewandte Chemie},
number = 5,
volume = 133,
place = {Germany},
year = {2020},
month = {11}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.202012095
https://doi.org/10.1002/ange.202012095
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Imperfections and their passivation in halide perovskite solar cells
journal, January 2019
- Chen, Bo; Rudd, Peter N.; Yang, Shuang
- Chemical Society Reviews, Vol. 48, Issue 14
Oxidative Passivation of Metal Halide Perovskites
journal, November 2019
- Godding, Julian S. W.; Ramadan, Alexandra J.; Lin, Yen-Hung
- Joule, Vol. 3, Issue 11
Pi-Extended Diindole-Fused Azapentacenone: Synthesis, Characterization, and Photophysical and Lithium-Storage Properties
journal, January 2016
- Zhao, Jianfeng; Li, Renping; Ai, Wei
- Chemistry - An Asian Journal, Vol. 11, Issue 9
Surface passivation of perovskite film for efficient solar cells
journal, April 2019
- Jiang, Qi; Zhao, Yang; Zhang, Xingwang
- Nature Photonics, Vol. 13, Issue 7
NbF 5 : A Novel α‐Phase Stabilizer for FA‐Based Perovskite Solar Cells with High Efficiency
journal, February 2019
- Yuan, Shihao; Qian, Fang; Yang, Shaomin
- Advanced Functional Materials, Vol. 29, Issue 47
Charge extraction via graded doping of hole transport layers gives highly luminescent and stable metal halide perovskite devices
journal, February 2019
- Abdi-Jalebi, Mojtaba; Ibrahim Dar, M.; Senanayak, Satyaprasad P.
- Science Advances, Vol. 5, Issue 2
Direct Electrochemical Capture and Release of Carbon Dioxide Using an Industrial Organic Pigment: Quinacridone
journal, May 2014
- Apaydin, Dogukan Hazar; Głowacki, Eric Daniel; Portenkirchner, Engelbert
- Angewandte Chemie International Edition, Vol. 53, Issue 26
Dopant-free novel hole-transporting materials based on quinacridone dye for high-performance and humidity-stable mesoporous perovskite solar cells
journal, January 2019
- Pham, Hong Duc; Jain, Sagar M.; Li, Meng
- Journal of Materials Chemistry A, Vol. 7, Issue 10
Heavy Water Additive in Formamidinium: A Novel Approach to Enhance Perovskite Solar Cell Efficiency
journal, April 2020
- Solanki, Ankur; Tavakoli, Mohammad Mahdi; Xu, Qiang
- Advanced Materials, Vol. 32, Issue 23
Constructive molecular configurations for surface-defect passivation of perovskite photovoltaics
journal, December 2019
- Wang, Rui; Xue, Jingjing; Wang, Kai-Li
- Science, Vol. 366, Issue 6472
Promoting Thermodynamic and Kinetic Stabilities of FA-based Perovskite by an in Situ Bilayer Structure
journal, April 2020
- Xu, Alex Fan; Liu, Na; Xie, Fanlong
- Nano Letters, Vol. 20, Issue 5
Modulation of Defects and Interfaces through Alkylammonium Interlayer for Efficient Inverted Perovskite Solar Cells
journal, June 2020
- Wu, Shengfan; Zhang, Jie; Li, Zhen
- Joule, Vol. 4, Issue 6
Toward Eco-friendly and Stable Perovskite Materials for Photovoltaics
journal, July 2018
- Ju, Ming-Gang; Chen, Min; Zhou, Yuanyuan
- Joule, Vol. 2, Issue 7
Intermolecular π–π Conjugation Self‐Assembly to Stabilize Surface Passivation of Highly Efficient Perovskite Solar Cells
journal, April 2020
- Li, Hongshi; Shi, Jiangjian; Deng, Jun
- Advanced Materials, Vol. 32, Issue 23
Epindolidione-Based Conjugated Polymers: Synthesis, Electronic Structures, and Charge Transport Properties
journal, September 2015
- Yang, Chi-Yuan; Shi, Ke; Lei, Ting
- ACS Applied Materials & Interfaces, Vol. 8, Issue 6
Fabrication of Efficient and Stable Perovskite Solar Cells in High‐Humidity Environment through Trace‐Doping of Large‐Sized Cations
journal, April 2019
- Liu, Xueping; He, Jiang; Wang, Pengfei
- ChemSusChem
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
Surface passivation of perovskite thin films by phosphonium halides for efficient and stable solar cells
journal, January 2020
- He, Qingquan; Worku, Michael; Xu, Liangjin
- Journal of Materials Chemistry A, Vol. 8, Issue 4
A dual function-enabled novel zwitterion to stabilize a Pb–I framework and passivate defects for highly efficient inverted planar perovskite solar cells
journal, January 2020
- Wang, Deng; Huang, Lei; Chen, Qiyin
- Chemical Communications, Vol. 56, Issue 51
Bifunctional Stabilization of All-Inorganic α-CsPbI 3 Perovskite for 17% Efficiency Photovoltaics
journal, September 2018
- Wang, Yong; Zhang, Taiyang; Kan, Miao
- Journal of the American Chemical Society, Vol. 140, Issue 39
Selective growth of layered perovskites for stable and efficient photovoltaics
journal, January 2018
- Cho, Kyung Taek; Grancini, Giulia; Lee, Yonghui
- Energy & Environmental Science, Vol. 11, Issue 4
Quinacridone-Based Molecular Donors for Solution Processed Bulk-Heterojunction Organic Solar Cells
journal, August 2010
- Chen, John Jun-An; Chen, Teresa L.; Kim, BongSoo
- ACS Applied Materials & Interfaces, Vol. 2, Issue 9, p. 2679-2686
Defect and Contact Passivation for Perovskite Solar Cells
journal, April 2019
- Aydin, Erkan; Bastiani, Michele; Wolf, Stefaan
- Advanced Materials, Vol. 31, Issue 25
CuGaO 2 : A Promising Inorganic Hole-Transporting Material for Highly Efficient and Stable Perovskite Solar Cells
journal, December 2016
- Zhang, Hua; Wang, Huan; Chen, Wei
- Advanced Materials, Vol. 29, Issue 8
Fully solution processed p-i-n organic solar cells with an industrial pigment – Quinacridone
journal, July 2011
- Chen, Teresa L.; Chen, John Jun-An; Catane, Luis
- Organic Electronics, Vol. 12, Issue 7
Improving the stability and performance of perovskite solar cells via off-the-shelf post-device ligand treatment
journal, January 2018
- Zhang, Hong; Ren, Xingang; Chen, Xiwen
- Energy & Environmental Science, Vol. 11, Issue 8
Efficient and stable solution-processed planar perovskite solar cells via contact passivation
journal, February 2017
- Tan, Hairen; Jain, Ankit; Voznyy, Oleksandr
- Science, Vol. 355, Issue 6326
Facile Formation of 2D–3D Heterojunctions on Perovskite Thin Film Surfaces for Efficient Solar Cells
journal, December 2019
- He, Qingquan; Worku, Michael; Xu, Liangjin
- ACS Applied Materials & Interfaces, Vol. 12, Issue 1
Targeted Therapy for Interfacial Engineering Toward Stable and Efficient Perovskite Solar Cells
journal, August 2019
- Wang, Shuhui; Chen, Haiyang; Zhang, Jiandong
- Advanced Materials, Vol. 31, Issue 41
Tailored Phase Conversion under Conjugated Polymer Enables Thermally Stable Perovskite Solar Cells with Efficiency Exceeding 21%
journal, November 2018
- Meng, Lei; Sun, Chenkai; Wang, Rui
- Journal of the American Chemical Society, Vol. 140, Issue 49
Efficient and Stable Chemical Passivation on Perovskite Surface via Bidentate Anchoring
journal, February 2019
- Zhang, Hao; Wu, Yongzhen; Shen, Chao
- Advanced Energy Materials, Vol. 9, Issue 13
Adsorption, desorption, and film formation of quinacridone and its thermal cracking product indigo on clean and carbon-covered silicon dioxide surfaces
journal, September 2016
- Scherwitzl, Boris; Lassnig, Roman; Truger, Magdalena
- The Journal of Chemical Physics, Vol. 145, Issue 9
Synergistic Crystal and Interface Engineering for Efficient and Stable Perovskite Photovoltaics
journal, November 2018
- Tavakoli, Mohammad Mahdi; Saliba, Michael; Yadav, Pankaj
- Advanced Energy Materials, Vol. 9, Issue 1
Stabilizing halide perovskite surfaces for solar cell operation with wide-bandgap lead oxysalts
journal, August 2019
- Yang, Shuang; Chen, Shangshang; Mosconi, Edoardo
- Science, Vol. 365, Issue 6452
Effective Carrier-Concentration Tuning of SnO 2 Quantum Dot Electron-Selective Layers for High-Performance Planar Perovskite Solar Cells
journal, February 2018
- Yang, Guang; Chen, Cong; Yao, Fang
- Advanced Materials, Vol. 30, Issue 14
Hydrophobic Polystyrene Passivation Layer for Simultaneously Improved Efficiency and Stability in Perovskite Solar Cells
journal, May 2018
- Li, Minghua; Yan, Xiaoqin; Kang, Zhuo
- ACS Applied Materials & Interfaces, Vol. 10, Issue 22
Novel White Electroluminescent Single Polymer Derived from Fluorene and Quinacridone
journal, February 2008
- Liu, Jun; Gao, Baoxiang; Cheng, Yanxiang
- Macromolecules, Vol. 41, Issue 4
Enhanced optoelectronic quality of perovskite thin films with hypophosphorous acid for planar heterojunction solar cells
journal, November 2015
- Zhang, Wei; Pathak, Sandeep; Sakai, Nobuya
- Nature Communications, Vol. 6, Issue 1
Synthesis and Solution Processing of a Hydrogen-Bonded Ladder Polymer
journal, January 2017
- Zou, Yang; Ji, Xiaozhou; Cai, Jizhe
- Chem, Vol. 2, Issue 1
Perovskite-polymer composite cross-linker approach for highly-stable and efficient perovskite solar cells
journal, January 2019
- Han, Tae-Hee; Lee, Jin-Wook; Choi, Chungseok
- Nature Communications, Vol. 10, Issue 1
Rational Design of Dopant‐Free Coplanar D‐π‐D Hole‐Transporting Materials for High‐Performance Perovskite Solar Cells with Fill Factor Exceeding 80%
journal, August 2019
- Chen, Yatong; Xu, Xiuwen; Cai, Ning
- Advanced Energy Materials, Vol. 9, Issue 39
Observing Defect Passivation of the Grain Boundary with 2‐Aminoterephthalic Acid for Efficient and Stable Perovskite Solar Cells
journal, February 2020
- Liu, Zhongze; Cao, Fengren; Wang, Meng
- Angewandte Chemie International Edition, Vol. 59, Issue 10
Hysteresis Index: A Figure without Merit for Quantifying Hysteresis in Perovskite Solar Cells
journal, September 2018
- Habisreutinger, Severin N.; Noel, Nakita K.; Snaith, Henry J.
- ACS Energy Letters, Vol. 3, Issue 10
Interfacial Study To Suppress Charge Carrier Recombination for High Efficiency Perovskite Solar Cells
journal, November 2015
- Adhikari, Nirmal; Dubey, Ashish; Khatiwada, Devendra
- ACS Applied Materials & Interfaces, Vol. 7, Issue 48
Defects engineering for high-performance perovskite solar cells
journal, August 2018
- Wang, Feng; Bai, Sai; Tress, Wolfgang
- npj Flexible Electronics, Vol. 2, Issue 1
Direkte elektrochemische Speicherung und Freisetzung von Kohlendioxid unter der Verwendung eines Industriepigments: Chinacridon
journal, May 2014
- Apaydin, Dogukan Hazar; Głowacki, Eric Daniel; Portenkirchner, Engelbert
- Angewandte Chemie, Vol. 126, Issue 26
Surface optimization to eliminate hysteresis for record efficiency planar perovskite solar cells
journal, January 2016
- Yang, Dong; Zhou, Xin; Yang, Ruixia
- Energy & Environmental Science, Vol. 9, Issue 10
Conjugated Polymer–Assisted Grain Boundary Passivation for Efficient Inverted Planar Perovskite Solar Cells
journal, May 2019
- Chen, Wei; Wang, Yingfeng; Pang, Guotao
- Advanced Functional Materials
The Role of Heteroatoms Leading to Hydrogen Bonds in View of Extended Chemical Stability of Organic Semiconductors
journal, October 2015
- Enengl, Christina; Enengl, Sandra; Havlicek, Marek
- Advanced Functional Materials, Vol. 25, Issue 42
Hydrogen-Bonded Semiconducting Pigments for Air-Stable Field-Effect Transistors
journal, December 2012
- Głowacki, Eric Daniel; Irimia-Vladu, Mihai; Kaltenbrunner, Martin
- Advanced Materials, Vol. 25, Issue 11
Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations
journal, June 2017
- Zheng, Xiaopeng; Chen, Bo; Dai, Jun
- Nature Energy, Vol. 2, Issue 7
Observing Defect Passivation of the Grain Boundary with 2‐Aminoterephthalic Acid for Efficient and Stable Perovskite Solar Cells
journal, February 2020
- Liu, Zhongze; Cao, Fengren; Wang, Meng
- Angewandte Chemie, Vol. 132, Issue 10