Radiation-induced modifications in copper oxide growth

Bishop, Jessica L.; Cureton, Will F.; Crespillo, Miguel L.; Koehler, Michael; Auxier II, John D.; Lang, Maik

doi:10.1007/s10967-020-07486-x

Title: Radiation-induced modifications in copper oxide growth

Abstract

Cu samples were irradiated with 10 MeV Au³⁺ ions at 200 °C to damage levels of 5, 10, and 15 displacements per atom (dpa) as an analogue to study long term self-irradiation effects of alpha- decay in Pu. Samples were then subject to accelerated aging at 350 °C for 1 hour in air resulting in mixed oxide layer growth (Cu₂O and CuO). Raman spectroscopy revealed that the CuO phase fraction was gradually decreased as the damage level increased. These findings indicate that accumulated damage from self-irradiation causes quantifiable modifications in metal oxidation that could serve as a novel forensic signature.

Authors:

^[1]; Cureton, Will F. ^[2]; Crespillo, Miguel L. ^[2]; Koehler, Michael ^[3]; Auxier II, John D. ^[1]; Lang, Maik ^[2]

Univ. of Tennessee, Knoxville, TN (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States). Joint Inst. for Advance Materials Diffraction Facility

Publication Date:: 2020-11-19

Research Org.:: Univ. of Illinois, Chicago, IL (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE); US Dept. of Homeland Security (DHS), Domestic Nuclear Detection Office (DNDO). Academic Research Initiative (ARI); USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1724105

Grant/Contract Number:: NA0003975; AC02- 06CH11357; 2015-DN-077-ARI093

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Radioanalytical and Nuclear Chemistry

Additional Journal Information:: Journal Volume: 327; Journal Issue: 1; Journal ID: ISSN 0236-5731

Publisher:: Springer

Country of Publication:: United States

Language:: English

Subject:: 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; Radiation Damage; Oxidation; Copper; Raman Spectroscopy; Nuclear Forensics

Citation Formats


                    Bishop, Jessica L., Cureton, Will F., Crespillo, Miguel L., Koehler, Michael, Auxier II, John D., and Lang, Maik. Radiation-induced modifications in copper oxide growth.  United States: N. p., 2020. 
Web.  https://doi.org/10.1007/s10967-020-07486-x.

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                    Bishop, Jessica L., Cureton, Will F., Crespillo, Miguel L., Koehler, Michael, Auxier II, John D., & Lang, Maik. Radiation-induced modifications in copper oxide growth.  United States.  https://doi.org/10.1007/s10967-020-07486-x

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                    Bishop, Jessica L., Cureton, Will F., Crespillo, Miguel L., Koehler, Michael, Auxier II, John D., and Lang, Maik. Thu .  
"Radiation-induced modifications in copper oxide growth".  United States.  https://doi.org/10.1007/s10967-020-07486-x.  https://www.osti.gov/servlets/purl/1724105.

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@article{osti_1724105,

  title        = {Radiation-induced modifications in copper oxide growth},

  author       = {Bishop, Jessica L. and Cureton, Will F. and Crespillo, Miguel L. and Koehler, Michael and Auxier II, John D. and Lang, Maik},

  abstractNote = {Cu samples were irradiated with 10 MeV Au3+ ions at 200 °C to damage levels of 5, 10, and 15 displacements per atom (dpa) as an analogue to study long term self-irradiation effects of alpha- decay in Pu. Samples were then subject to accelerated aging at 350 °C for 1 hour in air resulting in mixed oxide layer growth (Cu2O and CuO). Raman spectroscopy revealed that the CuO phase fraction was gradually decreased as the damage level increased. These findings indicate that accumulated damage from self-irradiation causes quantifiable modifications in metal oxidation that could serve as a novel forensic signature.},

  doi          = {10.1007/s10967-020-07486-x},

  journal      = {Journal of Radioanalytical and Nuclear Chemistry},

  number       = 1,

  volume       = 327,

  place        = {United States},

  year         = {2020},

  month        = {11}

}

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Title: Radiation-induced modifications in copper oxide growth

Abstract

Citation Formats

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Self-irradiation effects in plutonium alloys stabilized in the δ-phase journal, November 2002

Brief review of oxidation kinetics of copper at 350 °C to 1050 °C journal, April 2006

Defect microstructure in copper alloys irradiated with 750 MeV protons journal, September 1994

Physical cryptographic verification of nuclear warheads
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Defect accumulation in pure fcc metals in the transient regime: a review
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Correlation of intrinsic point defects and the Raman modes of cuprous oxide
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New ion beam materials laboratory for materials modification and irradiation effects research
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Effects of self-irradiation in plutonium alloys
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Damage saturation effects on volume and resistivity changes induced by fission-fragment irradiation of copper
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Fission-track dating methods: What are the real alternatives?
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Swift heavy ion induced dewetting of metal oxide thin films on silicon
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A brief introduction to analytical methods in nuclear forensics
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Influence of surface oxygen vacancies on the catalytic activity of copper oxide
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GSAS-II : the genesis of a modern open-source all purpose crystallography software package
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Microstructure of copper following high dose 14-MeV Cu ion irradiation
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The irradiation response of ZrC ceramics under 10 MeV Au3+ ion irradiation at 800 ºC
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High‐precision measurements of lattice parameter changes in neutron‐irradiated copper
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