Investigating the compressive strength and strain localization of nanotwinned nickel alloys
Abstract
Sputter deposited nickel-molybdenum-tungsten (Ni-Mo-W) thin films possess a beneficial suite of properties that stem from the extremely fine growth twins that form during the deposition process. Previously these materi- als were only characterized in tension, however, in this study in situ micropillar compression and post-mortem microstructural analysis of nanotwinned Ni84Mo11W5 micropillars were employed to measure the compressive response and elucidate the attendant deformation mechanisms. The pillars exhibit Hookean behavior to com- pressive strengths of 3-3.5 GPa and the onset of non-linear plastic flow was manifest by discrete strain bursts and highly localized shear bands. Plastic deformation was concentrated at the top of the pillar, while the bulk of the micropillar was nominally unaffected. Post-mortem investigations indicate that at sufficiently high stresses shear banding is triggered, resulting in intense and highly localized plastic deformation that led to the formation of twin-free nanocrystalline grains within highly deformed shear bands. By contrast, the regions adjacent to the shear bands were unaffected. The absence of detwinning and dislocation glide mechanisms was unexpected and in direct contrast to what has been observed in nanotwinned Cu-Al. Post-mortem observations of the Ni-Mo-W micropillars suggest that the ultrafine twins create a unique form of dislocation starvation and source-limitedmore »
- Authors:
-
- Johns Hopkins Univ., Baltimore, MD (United States)
- Texas A & M Univ., College Station, TX (United States)
- Nanomechanics Inc./KLA-Tencor, Oak Ridge, TN (United States)
- Univ. of Illinois at Urbana-Champaign, IL (United States)
- Publication Date:
- Research Org.:
- Johns Hopkins Univ., Baltimore, MD (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1724100
- Alternate Identifier(s):
- OSTI ID: 1809733
- Grant/Contract Number:
- FG02-07ER46437; -FG02-07ER46437
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Materialia
- Additional Journal Information:
- Journal Volume: 204; Journal ID: ISSN 1359-6454
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Anisotropy; Shear bands; Nanotwins; Localization; Micropillar
Citation Formats
Valentino, Gianna M., Xiang, Sisi, Ma, Luoning, Xie, Kelvin Y., He, Mo-Rigen, Oliver, Warren C., Pharr, George M., Krogstad, Jessica A., Weihs, Timothy P., and Hemker, Kevin J. Investigating the compressive strength and strain localization of nanotwinned nickel alloys. United States: N. p., 2020.
Web. doi:10.1016/j.actamat.2020.116507.
Valentino, Gianna M., Xiang, Sisi, Ma, Luoning, Xie, Kelvin Y., He, Mo-Rigen, Oliver, Warren C., Pharr, George M., Krogstad, Jessica A., Weihs, Timothy P., & Hemker, Kevin J. Investigating the compressive strength and strain localization of nanotwinned nickel alloys. United States. https://doi.org/10.1016/j.actamat.2020.116507
Valentino, Gianna M., Xiang, Sisi, Ma, Luoning, Xie, Kelvin Y., He, Mo-Rigen, Oliver, Warren C., Pharr, George M., Krogstad, Jessica A., Weihs, Timothy P., and Hemker, Kevin J. Sun .
"Investigating the compressive strength and strain localization of nanotwinned nickel alloys". United States. https://doi.org/10.1016/j.actamat.2020.116507. https://www.osti.gov/servlets/purl/1724100.
@article{osti_1724100,
title = {Investigating the compressive strength and strain localization of nanotwinned nickel alloys},
author = {Valentino, Gianna M. and Xiang, Sisi and Ma, Luoning and Xie, Kelvin Y. and He, Mo-Rigen and Oliver, Warren C. and Pharr, George M. and Krogstad, Jessica A. and Weihs, Timothy P. and Hemker, Kevin J.},
abstractNote = {Sputter deposited nickel-molybdenum-tungsten (Ni-Mo-W) thin films possess a beneficial suite of properties that stem from the extremely fine growth twins that form during the deposition process. Previously these materi- als were only characterized in tension, however, in this study in situ micropillar compression and post-mortem microstructural analysis of nanotwinned Ni84Mo11W5 micropillars were employed to measure the compressive response and elucidate the attendant deformation mechanisms. The pillars exhibit Hookean behavior to com- pressive strengths of 3-3.5 GPa and the onset of non-linear plastic flow was manifest by discrete strain bursts and highly localized shear bands. Plastic deformation was concentrated at the top of the pillar, while the bulk of the micropillar was nominally unaffected. Post-mortem investigations indicate that at sufficiently high stresses shear banding is triggered, resulting in intense and highly localized plastic deformation that led to the formation of twin-free nanocrystalline grains within highly deformed shear bands. By contrast, the regions adjacent to the shear bands were unaffected. The absence of detwinning and dislocation glide mechanisms was unexpected and in direct contrast to what has been observed in nanotwinned Cu-Al. Post-mortem observations of the Ni-Mo-W micropillars suggest that the ultrafine twins create a unique form of dislocation starvation and source-limited plasticity. The ultrahigh compressive strength is governed by the triggering of shear bands rather than the activa- tion of dislocation glide. Finally, the specialized nature of plasticity in nanotwinned Ni-Mo-W is clear, even though the precise trigger for shear band formation in nanotwinned Ni-Mo-W remains to be identified.},
doi = {10.1016/j.actamat.2020.116507},
journal = {Acta Materialia},
number = ,
volume = 204,
place = {United States},
year = {Sun Nov 22 00:00:00 EST 2020},
month = {Sun Nov 22 00:00:00 EST 2020}
}
Works referenced in this record:
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
Nanostructured materials: basic concepts and microstructure
journal, January 2000
- Gleiter, H.
- Acta Materialia, Vol. 48, Issue 1
Mechanical properties of nanocrystalline materials
journal, May 2006
- Meyers, M. A.; Mishra, A.; Benson, D. J.
- Progress in Materials Science, Vol. 51, Issue 4
Nanostructured materials
journal, February 2001
- Moriarty, Philip
- Reports on Progress in Physics, Vol. 64, Issue 3
High tensile ductility in a nanostructured metal
journal, October 2002
- Wang, Yinmin; Chen, Mingwei; Zhou, Fenghua
- Nature, Vol. 419, Issue 6910
Evading the strength–ductility trade-off dilemma in steel through gradient hierarchical nanotwins
journal, April 2014
- Wei, Yujie; Li, Yongqiang; Zhu, Lianchun
- Nature Communications, Vol. 5, Issue 1
Stress-assisted discontinuous grain growth and its effect on the deformation behavior of nanocrystalline aluminum thin films
journal, May 2006
- Gianola, D. S.; Van Petegem, S.; Legros, M.
- Acta Materialia, Vol. 54, Issue 8
Direct observation of deformation-induced grain growth during the nanoindentation of ultrafine-grained Al at room temperature
journal, October 2004
- Jin, M.; Minor, A. M.; Stach, E. A.
- Acta Materialia, Vol. 52, Issue 18
Thermal stability of nanocrystalline Ni
journal, November 1995
- Klement, U.; Erb, U.; El-Sherik, A. M.
- Materials Science and Engineering: A, Vol. 203, Issue 1-2
In situ TEM observations of fast grain-boundary motion in stressed nanocrystalline aluminum films
journal, August 2008
- Legros, Marc; Gianola, Daniel S.; Hemker, Kevin J.
- Acta Materialia, Vol. 56, Issue 14
Grain growth and strain release in nanocrystalline copper
journal, June 2001
- Lu, L.; Tao, N. R.; Wang, L. B.
- Journal of Applied Physics, Vol. 89, Issue 11
Experimental Observations of Stress-Driven Grain Boundary Migration
journal, December 2009
- Rupert, T. J.; Gianola, D. S.; Gan, Y.
- Science, Vol. 326, Issue 5960
Interpreting the ductility of nanocrystalline metals 1
journal, May 2013
- Sharon, John A.; Padilla, Henry A.; Boyce, Brad L.
- Journal of Materials Research, Vol. 28, Issue 12
Rapid stress-driven grain coarsening in nanocrystalline Cu at ambient and cryogenic temperatures
journal, August 2005
- Zhang, Kai; Weertman, J. R.; Eastman, J. A.
- Applied Physics Letters, Vol. 87, Issue 6
Ultrahigh Strength and High Electrical Conductivity in Copper
journal, April 2004
- Lu, L.
- Science, Vol. 304, Issue 5669
Growth Twins and Deformation Twins in Metals
journal, July 2014
- Beyerlein, Irene J.; Zhang, Xinghang; Misra, Amit
- Annual Review of Materials Research, Vol. 44, Issue 1
In Situ Nanoindentation Studies on Detwinning and Work Hardening in Nanotwinned Monolithic Metals
journal, July 2015
- Liu, Y.; Li, N.; Bufford, D.
- JOM, Vol. 68, Issue 1
Strengthening Materials by Engineering Coherent Internal Boundaries at the Nanoscale
journal, April 2009
- Lu, K.; Lu, L.; Suresh, S.
- Science, Vol. 324, Issue 5925
Thermal stability of sputtered Cu films with nanoscale growth twins
journal, May 2008
- Anderoglu, O.; Misra, A.; Wang, H.
- Journal of Applied Physics, Vol. 103, Issue 9
Nanoscale-twinning-induced strengthening in austenitic stainless steel thin films
journal, February 2004
- Zhang, X.; Misra, A.; Wang, H.
- Applied Physics Letters, Vol. 84, Issue 7
Tensile properties of copper with nano-scale twins
journal, May 2005
- Shen, Y. F.; Lu, L.; Lu, Q. H.
- Scripta Materialia, Vol. 52, Issue 10
Strength, strain-rate sensitivity and ductility of copper with nanoscale twins
journal, December 2006
- Dao, M.; Lu, L.; Shen, Y. F.
- Acta Materialia, Vol. 54, Issue 20
Revealing the Maximum Strength in Nanotwinned Copper
journal, January 2009
- Lu, L.; Chen, X.; Huang, X.
- Science, Vol. 323, Issue 5914
Dislocation nucleation governed softening and maximum strength in nano-twinned metals
journal, April 2010
- Li, Xiaoyan; Wei, Yujie; Lu, Lei
- Nature, Vol. 464, Issue 7290
Deformation mechanisms in nanotwinned metal nanopillars
journal, July 2012
- Jang, Dongchan; Li, Xiaoyan; Gao, Huajian
- Nature Nanotechnology, Vol. 7, Issue 9
Plastic anisotropy and associated deformation mechanisms in nanotwinned metals
journal, January 2013
- You, Zesheng; Li, Xiaoyan; Gui, Liangjin
- Acta Materialia, Vol. 61, Issue 1
Enhanced hardening in Cu/330 stainless steel multilayers by nanoscale twinning
journal, February 2004
- Zhang, X.; Misra, A.; Wang, H.
- Acta Materialia, Vol. 52, Issue 4
Thermal stability of twins and strengthening mechanisms in differently oriented epitaxial nanotwinned Ag films
journal, May 2013
- Bufford, Daniel; Wang, Haiyan; Zhang, Xinghang
- Journal of Materials Research, Vol. 28, Issue 13
On the mechanical performance and deformation of nanotwinned Ag
journal, April 2014
- Furnish, T. A.; Hodge, A. M.
- APL Materials, Vol. 2, Issue 4
Optimization of strength and ductility in nanotwinned ultra-fine grained Ag: Twin density and grain orientations
journal, September 2015
- Ott, R. T.; Geng, J.; Besser, M. F.
- Acta Materialia, Vol. 96
Observation of twin faults in sputter-deposited high-purity nickel
journal, August 1975
- Wang, R.; Dahlgren, S. D.
- Journal of Materials Science, Vol. 10, Issue 8
The thermal stability of Ni–Mo and Ni–W thin films: Solute segregation and planar faults
journal, July 2013
- Kurz, S. J. B.; Ensslen, C.; Welzel, U.
- Scripta Materialia, Vol. 69, Issue 1
Anomalously high density and thermal stability of nanotwins in Ni(W) thin films: Quantitative analysis by x-ray diffraction
journal, August 2014
- Kurz, S. J. B.; Leineweber, A.; Mittemeijer, E. J.
- Journal of Materials Research, Vol. 29, Issue 15
The influence of tungsten on the thermal stability and mechanical behavior of electrodeposited nickel MEMS structures
journal, December 2010
- Suresha, S. J.; Haj-Taieb, M.; Bade, K.
- Scripta Materialia, Vol. 63, Issue 12
High-Strength Nanotwinned Al Alloys with 9R Phase
journal, January 2018
- Li, Qiang; Xue, Sichuang; Wang, Jian
- Advanced Materials, Vol. 30, Issue 11
Ultra-strong nanotwinned Al–Ni solid solution alloys with significant plasticity
journal, January 2018
- Zhang, Y. F.; Li, Q.; Xue, S. C.
- Nanoscale, Vol. 10, Issue 46
High strength, deformable nanotwinned Al–Co alloys
journal, November 2018
- Xue, S.; Li, Qiang; Xie, D. Y.
- Materials Research Letters, Vol. 7, Issue 1
Influence of a nanotwinned, nanocrystalline microstructure on aging of a Ni-25Mo-8Cr superalloy
journal, September 2018
- Emigh, Megan G.; McAuliffe, Rebecca D.; Chen, Changqiang
- Acta Materialia, Vol. 156
Development of a heterogeneous nanostructure through abnormal recrystallization of a nanotwinned Ni superalloy
journal, August 2020
- Bahena, Joel A.; Heckman, Nathan M.; Barr, Christopher M.
- Acta Materialia, Vol. 195
Nanotwinned metal MEMS films with unprecedented strength and stability
journal, June 2017
- Sim, Gi-Dong; Krogstad, Jessica A.; Reddy, K. Madhav
- Science Advances, Vol. 3, Issue 6
Tailoring the mechanical properties of sputter deposited nanotwinned nickel-molybdenum-tungsten films
journal, February 2018
- Sim, Gi-Dong; Krogstad, Jessica A.; Xie, Kelvin Y.
- Acta Materialia, Vol. 144
Nanotwin formation in Ni–Mo–W alloys deposited by dc magnetron sputtering
journal, September 2020
- Valentino, Gianna M.; Shetty, Pralav P.; Chauhan, Ankur
- Scripta Materialia, Vol. 186
Fabrication of Freestanding Metallic Ni-Mo-W Microcantilever Beams With High Dimensional Stability
journal, June 2020
- Valentino, Gianna M.; Shetty, Pralav P.; Krogstad, Jessica A.
- Journal of Microelectromechanical Systems, Vol. 29, Issue 3
Tailoring the coefficient of thermal expansion of ternary nickel alloys through compositional control and non-contact measurements
journal, August 2020
- Valentino, Gianna M.; Krogstad, Jessica A.; Weihs, Timothy P.
- Journal of Alloys and Compounds, Vol. 833
Study of strain softening behavior of Al–Al3Sc multilayers using microcompression testing
journal, September 2009
- Han, Seung Min; Phillips, Mark A.; Nix, William D.
- Acta Materialia, Vol. 57, Issue 15
Deformation structures and textures in cold-rolled 70:30 brass
journal, August 1978
- Duggan, B. J.; Hatherly, M.; Hutchinson, W. B.
- Metal Science, Vol. 12, Issue 8
Shear bands in deformed metals
journal, May 1984
- Hatherly, M.; Malin, A. S.
- Scripta Metallurgica, Vol. 18, Issue 5
Micro-pillar plasticity: 2.5D mesoscopic simulations
journal, September 2009
- Benzerga, A. Amine
- Journal of the Mechanics and Physics of Solids, Vol. 57, Issue 9
Unravelling the physics of size-dependent dislocation-mediated plasticity
journal, January 2015
- El-Awady, Jaafar A.
- Nature Communications, Vol. 6, Issue 1
Nanoscale gold pillars strengthened through dislocation starvation
journal, June 2006
- Greer, Julia R.; Nix, William D.
- Physical Review B, Vol. 73, Issue 24
Size dependence of mechanical properties of gold at the micron scale in the absence of strain gradients
journal, April 2005
- Greer, Julia R.; Oliver, Warren C.; Nix, William D.
- Acta Materialia, Vol. 53, Issue 6
Stochastic nature of plasticity of aluminum micro-pillars
journal, May 2008
- Ng, K. S.; Ngan, A. H. W.
- Acta Materialia, Vol. 56, Issue 8
Contribution to size effect of yield strength from the stochastics of dislocation source lengths in finite samples
journal, February 2007
- Parthasarathy, Triplicane A.; Rao, Satish I.; Dimiduk, Dennis M.
- Scripta Materialia, Vol. 56, Issue 4
Suppression of shear banding in high-strength Cu/Mo nanocomposites with hierarchical bicontinuous intertwined structures
journal, December 2017
- Cui, Yuchi; Derby, Benjamin; Li, Nan
- Materials Research Letters, Vol. 6, Issue 3
Transition from dislocation controlled plasticity to grain boundary mediated shear in nanolayered aluminum/palladium thin films
journal, March 2011
- Dayal, P.; Quadir, M. Z.; Kong, C.
- Thin Solid Films, Vol. 519, Issue 10
Mechanism for shear banding in nanolayered composites
journal, July 2010
- Mara, N. A.; Bhattacharyya, D.; Hirth, J. P.
- Applied Physics Letters, Vol. 97, Issue 2
Anisotropy, size, and aspect ratio effects on micropillar compression of Al SiC nanolaminate composites
journal, August 2016
- Mayer, C. R.; Yang, L. W.; Singh, S. S.
- Acta Materialia, Vol. 114
Ultra-high strength and plasticity mediated by partial dislocations and defect networks: Part I: Texture effect
journal, February 2020
- Su, Ruizhe; Neffati, Dajla; Li, Qiang
- Acta Materialia, Vol. 185
Failure mechanisms in metal–metal nanolaminates at elevated temperatures: Microcompression of Cu–W multilayers
journal, March 2015
- Wheeler, J. M.; Raghavan, R.; Chawla, V.
- Scripta Materialia, Vol. 98
Achieving optimum mechanical performance in metallic nanolayered Cu/X (X = Zr, Cr) micropillars
journal, March 2014
- Zhang, J. Y.; Li, J.; Liang, X. Q.
- Scientific Reports, Vol. 4, Issue 1
Shear band formation and ductility in nanotwinned Cu
journal, December 2011
- Hodge, A. M.; Furnish, T. A.; Navid, A. A.
- Scripta Materialia, Vol. 65, Issue 11
Shear-Induced Mixing Governs Codeformation of Crystalline-Amorphous Nanolaminates
journal, July 2014
- Guo, Wei; Jägle, Eric A.; Choi, Pyuck-Pa
- Physical Review Letters, Vol. 113, Issue 3
Plastic instability mechanisms in bimetallic nanolayered composites
journal, October 2014
- Zheng, S. J.; Wang, J.; Carpenter, J. S.
- Acta Materialia, Vol. 79
Emergence of localized plasticity and failure through shear banding during microcompression of a nanocrystalline alloy
journal, February 2014
- Khalajhedayati, Amirhossein; Rupert, Timothy J.
- Acta Materialia, Vol. 65
Nucleation and thickening of shear bands in nano-scale twin/matrix lamellae of a Cu–Al alloy processed by dynamic plastic deformation
journal, May 2010
- Hong, C. S.; Tao, N. R.; Huang, X.
- Acta Materialia, Vol. 58, Issue 8
Detwinning mechanisms for growth twins in face-centered cubic metals
journal, April 2010
- Wang, J.; Li, N.; Anderoglu, O.
- Acta Materialia, Vol. 58, Issue 6
Twin stability in highly nanotwinned Cu under compression, torsion and tension
journal, June 2012
- Hodge, A. M.; Furnish, T. A.; Shute, C. J.
- Scripta Materialia, Vol. 66, Issue 11
Influence of slip transmission on the migration of incoherent twin boundaries in epitaxial nanotwinned Cu
journal, January 2011
- Li, N.; Wang, J.; Huang, J. Y.
- Scripta Materialia, Vol. 64, Issue 2
Plasticity and ultra-low stress induced twin boundary migration in nanotwinned Cu by in situ nanoindentation studies
journal, June 2014
- Liu, Y.; Jian, J.; Chen, Y.
- Applied Physics Letters, Vol. 104, Issue 23
Motion of 1/3⟨111⟩ dislocations on Σ3 {112} twin boundaries in nanotwinned copper
journal, January 2014
- Lu, N.; Du, K.; Lu, L.
- Journal of Applied Physics, Vol. 115, Issue 2