Adsorption of Colloidal Metal Nanoparticles via Solvent Engineering

Zhang, Laibao; Cullen, David A.; Zhai, Peng; Ding, Kunlun

doi:10.1021/acscatal.9b05148

Title: Adsorption of Colloidal Metal Nanoparticles via Solvent Engineering

Journal Article · 13 January 2020 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.9b05148 · OSTI ID:1720253

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^[2]; Zhai, Peng ^[1];

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Louisiana State Univ., Baton Rouge, LA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, United States

Colloidal metal nanoparticles (NPs) have long been regarded as ideal precursors for the synthesis of well-defined supported metal catalysts. However, the integration of colloidal metal NPs and catalyst supports remains challenging. We report a general protocol, antisolvent-induced adsorption, to deposit colloidal metal NPs onto a broad range of catalyst supports with great uniformity. The choice of antisolvent is dependent on the type of ligand and solvent employed in metal NP synthesis. Finally, this protocol may provide a bridge between the fields of colloidal science and heterogeneous catalysis.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1720253

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 3 Vol. 10; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
adsorption
antisolvent
colloidal nanoparticles
supported catalysts

Title: Adsorption of Colloidal Metal Nanoparticles via Solvent Engineering

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