In operando x-ray photoelectron spectroscopy studies of H 2 oxidation and H 2 O electrolysis on gadolinia-doped ceria electrodes

Wang, Lei; Yu, Yi; Gaskell, Karen J.; Crumlin, Ethan J.; Liu, Zhi; Eichhorn, Bryan W.; Jackson, Gregory S.

doi:10.1088/2515-7655/abc354

Title: In operando x-ray photoelectron spectroscopy studies of H ₂ oxidation and H ₂ O electrolysis on gadolinia-doped ceria electrodes

Authors:

; Yu, Yi; Gaskell, Karen J.;

; Liu, Zhi; Eichhorn, Bryan W.;

Publication Date:: 2020-11-19

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Department of the Navy, Office of Naval Research (ONR)

OSTI Identifier:: 1720204

Alternate Identifier(s):: OSTI ID: 1720205; OSTI ID: 1763703

Grant/Contract Number:: AC02-05CH11231; N000140510711

Resource Type:: Published Article

Journal Name:: JPhys Energy

Additional Journal Information:: Journal Name: JPhys Energy Journal Volume: 3 Journal Issue: 1; Journal ID: ISSN 2515-7655

Publisher:: IOP Publishing

Country of Publication:: United Kingdom

Language:: English

Subject:: 42 ENGINEERING; in operando; ambient-pressure XPS; solid oxide electrochemical cell; GDC; charge transfer; Ni electrocatalysis

Citation Formats


                    Wang, Lei, Yu, Yi, Gaskell, Karen J., Crumlin, Ethan J., Liu, Zhi, Eichhorn, Bryan W., and Jackson, Gregory S.. In operando x-ray photoelectron spectroscopy studies of H 2 oxidation and H 2 O electrolysis on gadolinia-doped ceria electrodes.  United Kingdom: N. p., 2020. 
Web.  https://doi.org/10.1088/2515-7655/abc354.

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                    Wang, Lei, Yu, Yi, Gaskell, Karen J., Crumlin, Ethan J., Liu, Zhi, Eichhorn, Bryan W., & Jackson, Gregory S.. In operando x-ray photoelectron spectroscopy studies of H 2 oxidation and H 2 O electrolysis on gadolinia-doped ceria electrodes.  United Kingdom.  https://doi.org/10.1088/2515-7655/abc354

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                    Wang, Lei, Yu, Yi, Gaskell, Karen J., Crumlin, Ethan J., Liu, Zhi, Eichhorn, Bryan W., and Jackson, Gregory S.. Thu .  
"In operando x-ray photoelectron spectroscopy studies of H 2 oxidation and H 2 O electrolysis on gadolinia-doped ceria electrodes".  United Kingdom.  https://doi.org/10.1088/2515-7655/abc354.

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@article{osti_1720204,

  title        = {In operando x-ray photoelectron spectroscopy studies of H 2 oxidation and H 2 O electrolysis on gadolinia-doped ceria electrodes},

  author       = {Wang, Lei and Yu, Yi and Gaskell, Karen J. and Crumlin, Ethan J. and Liu, Zhi and Eichhorn, Bryan W. and Jackson, Gregory S.},

  abstractNote = {},

  doi          = {10.1088/2515-7655/abc354},

  journal      = {JPhys Energy},

  number       = 1,

  volume       = 3,

  place        = {United Kingdom},

  year         = {2020},

  month        = {11}

}

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Title: In operando x-ray photoelectron spectroscopy studies of H 2 oxidation and H 2 O electrolysis on gadolinia-doped ceria electrodes

Citation Formats

Surface electrochemistry of CO 2 reduction and CO oxidation on Sm-doped CeO 2−x : coupling between Ce 3+ and carbonate adsorbates journal, January 2015

AC Impedance Spectra Arising from Mixed Ionic Electronic Solid Electrolytes journal, January 2004

In situ investigation of electrochemical devices using ambient pressure photoelectron spectroscopy journal, October 2013

Highly Enhanced Concentration and Stability of Reactive Ce 3+ on Doped CeO 2 Surface Revealed In Operando journal, May 2012

In-situ photoelectron spectroscopy with online activity measurement for catalysis research journal, September 2012

Lowering the Temperature of Solid Oxide Fuel Cells journal, November 2011

Materials for fuel-cell technologies journal, November 2001

Syngas production at intermediate temperature through H2O and CO2 electrolysis with a Cu-based solid oxide electrolyzer cell journal, February 2014

Au-doped Ni/GDC as an Improved Cathode Electrocatalyst for H2O Electrolysis in SOECs journal, November 2018

Carbon dioxide reduction on gadolinia-doped ceria cathodes journal, July 2008

Surface and bulk oxygen non-stoichiometry and bulk chemical expansion in gadolinium-doped cerium oxide journal, July 2009

A review of anode materials development in solid oxide fuel cells journal, July 2004

Equilibrium and transient conductivity for gadolium-doped ceria under large perturbations: II. Modeling journal, December 2014

Multielement Activity Mapping and Potential Mapping in Solid Oxide Electrochemical Cells through the use of operando XPS journal, September 2012

Electrical and Ionic Conductivity of Gd-Doped Ceria journal, January 2000

A concerted migration mechanism of mixed oxide ion and electron conduction in reduced ceria studied by first-principles density functional theory journal, January 2012

In Situ Characterization of Ceria Oxidation States in High-Temperature Electrochemical Cells with Ambient Pressure XPS journal, November 2010

Operando observation of nickel/ceria electrode surfaces during intermediate temperature steam electrolysis journal, August 2017

Feasibility of low temperature solid oxide fuel cells operating on reformed hydrocarbon fuels journal, January 2012

Catalysis by Gold journal, January 1999

High electrochemical activity of the oxide phase in model ceria–Pt and ceria–Ni composite anodes journal, December 2011

Mechanistic Studies of Water Electrolysis and Hydrogen Electro-Oxidation on High Temperature Ceria-Based Solid Oxide Electrochemical Cells journal, July 2013

Origin of Overpotential-Dependent Surface Dipole at CeO 2– x /Gas Interface During Electrochemical Oxygen Insertion Reactions journal, August 2016

Threshold catalytic onset of carbon formation on CeO 2 during CO 2 electrolysis: mechanism and inhibition journal, January 2019

X-ray spectroscopy of energy materials under in situ/operando conditions journal, April 2015

Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy journal, September 2010

Nonstoichiometry of Ce0.9Gd0.1O1.95âˆ’x journal, March 1998

Modeling Elementary Heterogeneous Chemistry and Electrochemistry in Solid-Oxide Fuel Cells journal, January 2005

New insights on the co-electrolysis of CO2 and H2O through a solid oxide electrolyser operating at intermediate temperatures journal, February 2019

Electrical conductivity of thin film ceria grown by pulsed laser deposition journal, January 2007

Electronic Transport in Single Crystals of Gd-Doped Ceria journal, January 2007

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2 journal, May 2010

Appraisal of Ce1−yGdyO2−y/2 electrolytes for IT-SOFC operation at 500°C journal, April 2000

Developing 3-D Model of Intermediate-Temperature SOFC with GDC Electrolyte journal, October 2013

Field-enhanced ion transport in solids: Reexamination with molecular dynamics simulations journal, December 2016

Electrochemical Behaviors of Mixed Conducting Oxide Anodes for Solid Oxide Fuel Cell journal, January 2008

Insights into Hydrogen Oxidation on SOFC Anode Materials by Isotopic Exchange journal, January 2013

Eliminating degradation in solid oxide electrochemical cells by reversible operation journal, December 2014

Physical, chemical and electrochemical properties of pure and doped ceria journal, April 2000

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Title: In operando x-ray photoelectron spectroscopy studies of H ₂ oxidation and H ₂ O electrolysis on gadolinia-doped ceria electrodes

Surface electrochemistry of CO ₂ reduction and CO oxidation on Sm-doped CeO _2−x : coupling between Ce ³⁺ and carbonate adsorbates
journal, January 2015

AC Impedance Spectra Arising from Mixed Ionic Electronic Solid Electrolytes
journal, January 2004

In situ investigation of electrochemical devices using ambient pressure photoelectron spectroscopy
journal, October 2013

Highly Enhanced Concentration and Stability of Reactive Ce ³⁺ on Doped CeO ₂ Surface Revealed In Operando
journal, May 2012

In-situ photoelectron spectroscopy with online activity measurement for catalysis research
journal, September 2012

Lowering the Temperature of Solid Oxide Fuel Cells
journal, November 2011

Materials for fuel-cell technologies
journal, November 2001

Syngas production at intermediate temperature through H2O and CO2 electrolysis with a Cu-based solid oxide electrolyzer cell
journal, February 2014

Au-doped Ni/GDC as an Improved Cathode Electrocatalyst for H2O Electrolysis in SOECs
journal, November 2018

Carbon dioxide reduction on gadolinia-doped ceria cathodes
journal, July 2008

Surface and bulk oxygen non-stoichiometry and bulk chemical expansion in gadolinium-doped cerium oxide
journal, July 2009

A review of anode materials development in solid oxide fuel cells
journal, July 2004

Equilibrium and transient conductivity for gadolium-doped ceria under large perturbations: II. Modeling
journal, December 2014

Multielement Activity Mapping and Potential Mapping in Solid Oxide Electrochemical Cells through the use of operando XPS
journal, September 2012

Electrical and Ionic Conductivity of Gd-Doped Ceria
journal, January 2000

A concerted migration mechanism of mixed oxide ion and electron conduction in reduced ceria studied by first-principles density functional theory
journal, January 2012

In Situ Characterization of Ceria Oxidation States in High-Temperature Electrochemical Cells with Ambient Pressure XPS
journal, November 2010

Operando observation of nickel/ceria electrode surfaces during intermediate temperature steam electrolysis
journal, August 2017

Feasibility of low temperature solid oxide fuel cells operating on reformed hydrocarbon fuels
journal, January 2012

Catalysis by Gold
journal, January 1999

High electrochemical activity of the oxide phase in model ceria–Pt and ceria–Ni composite anodes
journal, December 2011

Mechanistic Studies of Water Electrolysis and Hydrogen Electro-Oxidation on High Temperature Ceria-Based Solid Oxide Electrochemical Cells
journal, July 2013

Origin of Overpotential-Dependent Surface Dipole at CeO _{2– x} /Gas Interface During Electrochemical Oxygen Insertion Reactions
journal, August 2016

Threshold catalytic onset of carbon formation on CeO ₂ during CO ₂ electrolysis: mechanism and inhibition
journal, January 2019

X-ray spectroscopy of energy materials under in situ/operando conditions
journal, April 2015

Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy
journal, September 2010

Nonstoichiometry of Ce0.9Gd0.1O1.95âˆ’x
journal, March 1998

Modeling Elementary Heterogeneous Chemistry and Electrochemistry in Solid-Oxide Fuel Cells
journal, January 2005

New insights on the co-electrolysis of CO2 and H2O through a solid oxide electrolyser operating at intermediate temperatures
journal, February 2019

Electrical conductivity of thin film ceria grown by pulsed laser deposition
journal, January 2007

Electronic Transport in Single Crystals of Gd-Doped Ceria
journal, January 2007

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2
journal, May 2010

Appraisal of Ce1−yGdyO2−y/2 electrolytes for IT-SOFC operation at 500°C
journal, April 2000

Developing 3-D Model of Intermediate-Temperature SOFC with GDC Electrolyte
journal, October 2013

Field-enhanced ion transport in solids: Reexamination with molecular dynamics simulations
journal, December 2016

Electrochemical Behaviors of Mixed Conducting Oxide Anodes for Solid Oxide Fuel Cell
journal, January 2008

Insights into Hydrogen Oxidation on SOFC Anode Materials by Isotopic Exchange
journal, January 2013

Eliminating degradation in solid oxide electrochemical cells by reversible operation
journal, December 2014

Physical, chemical and electrochemical properties of pure and doped ceria
journal, April 2000

Initial Steps in Forming the Electrode–Electrolyte Interface: H ₂ O Adsorption and Complex Formation on the Ag(111) Surface from Combining Quantum Mechanics Calculations and Ambient Pressure X-ray Photoelectron Spectroscopy
journal, April 2019