Organic room-temperature phosphorescence from halogen-bonded organic frameworks: hidden electronic effects in rigidified chromophores

Zhou, Jiawang; Stojanović, Ljiljana; Berezin, Andrey A.; Battisti, Tommaso; Gill, Abigail; Kariuki, Benson M.; Bonifazi, Davide; Crespo-Otero, Rachel; Wasielewski, Michael R.; Wu, Yi-Lin

doi:10.1039/D0SC04646A

Title: Organic room-temperature phosphorescence from halogen-bonded organic frameworks: hidden electronic effects in rigidified chromophores

Journal Article · 21 January 2021 · Chemical Science

DOI: https://doi.org/10.1039/D0SC04646A · OSTI ID:1714398

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Department of Chemistry, Institute for Sustainability and Energy at Northwestern, Northwestern University, Evanston, Illinois 60208-3113, USA
School of Biological and Chemical Sciences, Queen Mary University of London, London E1 4NS, UK
School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK
School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK, Institute of Organic Chemistry, Faculty of Chemistry, University of Vienna, Währinger Str. 38, Vienna, 1090, Austria

The number and position of halogen substituents in purely organic π–π* chromophores critically affect the efficiency of phosphorescence.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0020168

OSTI ID:: 1714398

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 2 Vol. 12; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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