Guidelines for performing lignin-first biorefining

Abu-Omar, Mahdi M.; Barta, Katalin; Beckham, Gregg T.; Luterbacher, Jeremy S.; Ralph, John; Rinaldi, Roberto; Román-Leshkov, Yuriy; Samec, Joseph S. M.; Sels, Bert F.; Wang, Feng

doi:10.1039/D0EE02870C

Title: Guidelines for performing lignin-first biorefining

Journal Article · 25 January 2021 · Energy & Environmental Science

DOI: https://doi.org/10.1039/D0EE02870C · OSTI ID:1712788

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Department of Chemical Engineering and Department of Chemistry & Biochemistry, University of California, Santa Barbara, USA
Stratingh Institute for Chemistry, University of Groningen, 9747 AG Groningen, The Netherlands
Renewable Resources and Enabling Sciences Center, National Renewable Energy Laboratory, Golden, USA, Center for Bioenergy Innovation, Oak Ridge
Laboratory of Sustainable and Catalytic Processing, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland
U.S. Department of Energy Great Lakes Bioenergy Research Center, University of Wisconsin-Madison, Madison, USA
Department of Chemical Engineering, Imperial College London, London SW7 2AZ, UK
Department of Chemical Engineering, MIT, Cambridge, USA
Department of Organic Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden
Center for Sustainable Catalysis and Engineering, KU Leuven, 3001 Leuven, Belgium
State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian

With these guidelines, we aim to unite the lignin-first biorefining research field around best practices for performing or reporting feedstock analysis, reactor design, catalyst performance, and product yields.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC36-08GO28308; SC0018409

OSTI ID:: 1712788

Journal Information:: Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 1 Vol. 14; ISSN EESNBY; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (179)

Biomass Composition, Properties, and Characterization de Jong, Wiebren; De Jong, Wiebren; Van Ommen, J. Ruud Biomass as a Sustainable Energy Source for the Future: Fundamentals of Conversion Processes https://doi.org/10.1002/9781118916643.ch2	book	September 2014
Catalytic Biorefining of Plant Biomass to Non-Pyrolytic Lignin Bio-Oil and Carbohydrates through Hydrogen Transfer Reactions Ferrini, Paola; Rinaldi, Roberto Angewandte Chemie International Edition, Vol. 53, Issue 33 https://doi.org/10.1002/anie.201403747	journal	June 2014
Paving the Way for Lignin Valorisation: Recent Advances in Bioengineering, Biorefining and Catalysis Rinaldi, Roberto; Jastrzebski, Robin; Clough, Matthew T. Angewandte Chemie International Edition, Vol. 55, Issue 29 https://doi.org/10.1002/anie.201510351	journal	June 2016
Nitrogen-Doped Ordered Mesoporous Carbon Supported Bimetallic PtCo Nanoparticles for Upgrading of Biophenolics Wang, Guang-Hui; Cao, Zhengwen; Gu, Dong Angewandte Chemie International Edition, Vol. 55, Issue 31 https://doi.org/10.1002/anie.201511558	journal	June 2016
Protection Group Effects During α,γ-Diol Lignin Stabilization Promote High-Selectivity Monomer Production Lan, Wu; Amiri, Masoud Talebi; Hunston, Christopher M. Angewandte Chemie International Edition, Vol. 57, Issue 5 https://doi.org/10.1002/anie.201710838	journal	January 2018
Highly Selective Oxidation and Depolymerization of α,γ‐Diol‐Protected Lignin Lan, Wu; de Bueren, Jean Behaghel; Luterbacher, Jeremy S. Angewandte Chemie International Edition, Vol. 58, Issue 9 https://doi.org/10.1002/anie.201811630	journal	February 2019
Protection Strategies Enable Selective Conversion of Biomass Luo, Xiaolin; Li, Yanding; Gupta, Navneet Kumar Angewandte Chemie International Edition, Vol. 59, Issue 29 https://doi.org/10.1002/anie.201914703	journal	April 2020
A thioacidolysis method tailored for higher-throughput quantitative analysis of lignin monomers Harman-Ware, Anne E.; Foster, Cliff; Happs, Renee M. Biotechnology Journal, Vol. 11, Issue 10 https://doi.org/10.1002/biot.201600266	journal	September 2016
Gas-liquid mass transfer in “dead-end” autoclave reactors Chaudhari, R. V.; Gholap, R. V.; Emig, G. The Canadian Journal of Chemical Engineering, Vol. 65, Issue 5 https://doi.org/10.1002/cjce.5450650506	journal	October 1987
Selective Degradation of Wood Lignin over Noble‐Metal Catalysts in a Two‐Step Process Yan, Ning; Zhao, Chen; Dyson, Paul J. ChemSusChem, Vol. 1, Issue 7 https://doi.org/10.1002/cssc.200800080	journal	July 2008
Selective Route to 2-Propenyl Aryls Directly from Wood by a Tandem Organosolv and Palladium-Catalysed Transfer Hydrogenolysis Galkin, Maxim V.; Samec, Joseph S. M. ChemSusChem, Vol. 7, Issue 8 https://doi.org/10.1002/cssc.201402017	journal	June 2014
Lignin Valorization through Catalytic Lignocellulose Fractionation: A Fundamental Platform for the Future Biorefinery Galkin, Maxim V.; Samec, Joseph S. M. ChemSusChem, Vol. 9, Issue 13 https://doi.org/10.1002/cssc.201600237	journal	June 2016
Metal Triflates for the Production of Aromatics from Lignin Deuss, Peter J.; Lahive, Ciaran W.; Lancefield, Christopher S. ChemSusChem, Vol. 9, Issue 20 https://doi.org/10.1002/cssc.201600831	journal	September 2016
Catalytic Upstream Biorefining through Hydrogen Transfer Reactions: Understanding the Process from the Pulp Perspective Ferrini, Paola; Rezende, Camila A.; Rinaldi, Roberto ChemSusChem, Vol. 9, Issue 22 https://doi.org/10.1002/cssc.201601121	journal	October 2016
Lignin-Derived Thioacidolysis Dimers: Reevaluation, New Products, Authentication, and Quantification Yue, Fengxia; Lu, Fachuang; Regner, Matt ChemSusChem, Vol. 10, Issue 5 https://doi.org/10.1002/cssc.201700101	journal	February 2017
Reductive Cleavage Method for Quantitation of Monolignols and Low-Abundance Monolignol Conjugates Regner, Matt; Bartuce, Allison; Padmakshan, Dharshana ChemSusChem, Vol. 11, Issue 10 https://doi.org/10.1002/cssc.201800617	journal	May 2018
Getting Closer to Absolute Molar Masses of Technical Lignins Zinovyev, Grigory; Sulaeva, Irina; Podzimek, Stepan ChemSusChem, Vol. 11, Issue 18 https://doi.org/10.1002/cssc.201801177	journal	August 2018
Assessing the Viability of Recovery of Hydroxycinnamic Acids from Lignocellulosic Biorefinery Alkaline Pretreatment Waste Streams Karlen, Steven D.; Fasahati, Peyman; Mazaheri, Mona ChemSusChem, Vol. 13, Issue 8 https://doi.org/10.1002/cssc.201903345	journal	March 2020
Lignin‐First Fractionation of Softwood Lignocellulose Using a Mild Dimethyl Carbonate and Ethylene Glycol Organosolv Process De Santi, Alessandra; Galkin, Maxim V.; Lahive, Ciaran W. ChemSusChem, Vol. 13, Issue 17 https://doi.org/10.1002/cssc.201903526	journal	March 2020
Mesoscale Reaction–Diffusion Phenomena Governing Lignin‐First Biomass Fractionation Thornburg, Nicholas E.; Pecha, M. Brennan; Brandner, David G. ChemSusChem, Vol. 13, Issue 17 https://doi.org/10.1002/cssc.202000558	journal	May 2020
Mechanistic Study of Diaryl Ether Bond Cleavage during Palladium‐Catalyzed Lignin Hydrogenolysis Li, Yanding; Karlen, Steven D.; Demir, Benginur ChemSusChem, Vol. 13, Issue 17 https://doi.org/10.1002/cssc.202000753	journal	April 2020
Derivatization in gas chromatography Ahuja, S. Journal of Pharmaceutical Sciences, Vol. 65, Issue 2 https://doi.org/10.1002/jps.2600650203	journal	February 1976
A comparison of the insoluble residues produced by the Klason lignin and acid detergent lignin procedures Hatfield, Ronald D.; Jung, Hans-Joachim G.; Ralph, John Journal of the Science of Food and Agriculture, Vol. 65, Issue 1, p. 51-58 https://doi.org/10.1002/jsfa.2740650109	journal	May 1994
Compensation for Spin–Spin Coupling Effects during Adiabatic Pulses Kupče, Ēriks; Freeman, Ray Journal of Magnetic Resonance, Vol. 127, Issue 1 https://doi.org/10.1006/jmre.1997.1193	journal	July 1997
Methods in Lignin Chemistry Timell, T. E.; Lin, Stephen Y.; Dence, Carlton W. Springer Series in Wood Science https://doi.org/10.1007/978-3-642-74065-7	book	January 1992
Feruloyl and p-coumaroyl esterase from anaerobic fungi in relation to plant cell wall degradation Borneman, William S.; Hartley, Roy D.; Morrison, W. Herbert Applied Microbiology and Biotechnology, Vol. 33, Issue 3 https://doi.org/10.1007/BF00164534	journal	June 1990
A structural model of softwood lignin Sakakibara, A. Wood Science and Technology, Vol. 14, Issue 2 https://doi.org/10.1007/BF00584038	journal	January 1980
Organosolv pretreatment of lignocellulosic biomass for enzymatic hydrolysis Zhao, Xuebing; Cheng, Keke; Liu, Dehua Applied Microbiology and Biotechnology, Vol. 82, Issue 5 https://doi.org/10.1007/s00253-009-1883-1	journal	February 2009
Effects on Lignin Structure of Coumarate 3-Hydroxylase Downregulation in Poplar Ralph, John; Akiyama, Takuya; Coleman, Heather D. BioEnergy Research, Vol. 5, Issue 4 https://doi.org/10.1007/s12155-012-9218-y	journal	May 2012
Biomass Production and Composition of Perennial Grasses Grown for Bioenergy in a Subtropical Climate Across Florida, USA Fedenko, Jeffrey R.; Erickson, John E.; Woodard, Kenneth R. BioEnergy Research, Vol. 6, Issue 3 https://doi.org/10.1007/s12155-013-9342-3	journal	June 2013
Naturally p-Hydroxybenzoylated Lignins in Palms Lu, Fachuang; Karlen, Steven D.; Regner, Matt BioEnergy Research, Vol. 8, Issue 3 https://doi.org/10.1007/s12155-015-9583-4	journal	February 2015
Compositional Analysis of Biomass Reference Materials: Results from an Interlaboratory Study Templeton, David W.; Wolfrum, Edward J.; Yen, James H. BioEnergy Research, Vol. 9, Issue 1 https://doi.org/10.1007/s12155-015-9675-1	journal	October 2015
A simple and rapid preparation of alditol acetates for monosaccharide analysis Blakeney, Anthony B.; Harris, Philip J.; Henry, Robert J. Carbohydrate Research, Vol. 113, Issue 2 https://doi.org/10.1016/0008-6215(83)88244-5	journal	March 1983
Heterogeneous distribution of diarylpropane structures in spruce lignins Lapierre, Catherine; Pollet, Brigitte; Monties, Bernard Phytochemistry, Vol. 30, Issue 2 https://doi.org/10.1016/0031-9422(91)83747-9	journal	January 1991
Chemical properties of lignin from Aralia cordata Hibino, Takashi; Shibata, Daisuke; Ito, Takashi Phytochemistry, Vol. 37, Issue 2, p. 445-448 https://doi.org/10.1016/0031-9422(94)85076-3	journal	January 1994
Organosolv pulping — methods and pulp properties Johansson, Allan; Aaltonen, Olli; Ylinen, Paula Biomass, Vol. 13, Issue 1 https://doi.org/10.1016/0144-4565(87)90071-0	journal	January 1987
Chemical analysis of lignocellulose materials Theander, Olof Animal Feed Science and Technology, Vol. 32, Issue 1-3 https://doi.org/10.1016/0377-8401(91)90007-F	journal	January 1991
Aqueous-phase reforming of methanol and ethylene glycol over alumina-supported platinum catalysts Shabaker, J. Journal of Catalysis, Vol. 215, Issue 2 https://doi.org/10.1016/S0021-9517(03)00032-0	journal	April 2003
p-coumaroylated syringyl units in maize lignin: Implications for β-ether cleavage by thioacidolysis Grabber, John H.; Quideau, Stephane; Ralph, John Phytochemistry, Vol. 43, Issue 6, p. 1189-1194 https://doi.org/10.1016/S0031-9422(96)00431-1	journal	December 1996
Differences in the chemical structure of the lignins from sugarcane bagasse and straw del Río, José C.; Lino, Alessandro G.; Colodette, Jorge L. Biomass and Bioenergy, Vol. 81 https://doi.org/10.1016/j.biombioe.2015.07.006	journal	October 2015
Features of promising technologies for pretreatment of lignocellulosic biomass Mosier, Nathan; Wyman, Charles; Dale, Bruce Bioresource Technology, Vol. 96, Issue 6, p. 673-686 https://doi.org/10.1016/j.biortech.2004.06.025	journal	April 2005
Coordinated development of leading biomass pretreatment technologies Wyman, Charles E.; Dale, Bruce E.; Elander, Richard T. Bioresource Technology, Vol. 96, Issue 18, p. 1959-1966 https://doi.org/10.1016/j.biortech.2005.01.010	journal	December 2005
Mild hydrogenolysis of in-situ and isolated Pinus radiata lignins Torr, Kirk M.; van de Pas, Daniel J.; Cazeils, Emmanuel Bioresource Technology, Vol. 102, Issue 16 https://doi.org/10.1016/j.biortech.2011.05.040	journal	August 2011
Reductive catalytic fractionation: state of the art of the lignin-first biorefinery Renders, Tom; Van den Bossche, Gil; Vangeel, Thijs Current Opinion in Biotechnology, Vol. 56 https://doi.org/10.1016/j.copbio.2018.12.005	journal	April 2019
Lignin structure and its engineering Ralph, John; Lapierre, Catherine; Boerjan, Wout Current Opinion in Biotechnology, Vol. 56 https://doi.org/10.1016/j.copbio.2019.02.019	journal	April 2019
Design of Nickel Supported on Water-Tolerant Nb2O5 Catalysts for the Hydrotreating of Lignin Streams Obtained from Lignin-First Biorefining Leal, Glauco F.; Lima, Sérgio; Graça, Inês iScience, Vol. 15 https://doi.org/10.1016/j.isci.2019.05.007	journal	May 2019
Integrated techno-economic assessment of a biorefinery process: The high-end valorization of the lignocellulosic fraction in wood streams Tschulkow, Maxim; Compernolle, Tine; Van den Bosch, Sander Journal of Cleaner Production, Vol. 266 https://doi.org/10.1016/j.jclepro.2020.122022	journal	September 2020
Compensated adiabatic inversion pulses: Broadband INEPT and HSQC Kupče, Eriks; Freeman, Ray Journal of Magnetic Resonance, Vol. 187, Issue 2 https://doi.org/10.1016/j.jmr.2007.05.009	journal	August 2007
Flowthrough Reductive Catalytic Fractionation of Biomass Anderson, Eric M.; Stone, Michael L.; Katahira, Rui Joule, Vol. 1, Issue 3 https://doi.org/10.1016/j.joule.2017.10.004	journal	November 2017
A Convergent Approach for a Deep Converting Lignin-First Biorefinery Rendering High-Energy-Density Drop-in Fuels Cao, Zhengwen; Dierks, Michael; Clough, Matthew Thomas Joule, Vol. 2, Issue 6 https://doi.org/10.1016/j.joule.2018.03.012	journal	June 2018
The role of pretreatment in the catalytic valorization of cellulose Liao, Yuhe; de Beeck, Beau Op; Thielemans, Karel Molecular Catalysis, Vol. 487 https://doi.org/10.1016/j.mcat.2020.110883	journal	May 2020
Recent innovations in analytical methods for the qualitative and quantitative assessment of lignin Lupoi, Jason S.; Singh, Seema; Parthasarathi, Ramakrishnan Renewable and Sustainable Energy Reviews, Vol. 49 https://doi.org/10.1016/j.rser.2015.04.091	journal	September 2015
Identification of 4–O–5-Units in Softwood Lignins via Definitive Lignin Models and NMR Yue, Fengxia; Lu, Fachuang; Ralph, Sally Biomacromolecules, Vol. 17, Issue 6 https://doi.org/10.1021/acs.biomac.6b00256	journal	May 2016
NMR Assignment for Diaryl Ether Structures (4–O–5 Structures) in Pine Wood Lignin Li, Yanding; Akiyama, Takuya; Yokoyama, Tomoya Biomacromolecules, Vol. 17, Issue 6 https://doi.org/10.1021/acs.biomac.6b00257	journal	April 2016
Characterization and Elimination of Undesirable Protein Residues in Plant Cell Wall Materials for Enhancing Lignin Analysis by Solution-State Nuclear Magnetic Resonance Spectroscopy Kim, Hoon; Padmakshan, Dharshana; Li, Yanding Biomacromolecules, Vol. 18, Issue 12 https://doi.org/10.1021/acs.biomac.7b01223	journal	November 2017
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels Li, Changzhi; Zhao, Xiaochen; Wang, Aiqin Chemical Reviews, Vol. 115, Issue 21, p. 11559-11624 https://doi.org/10.1021/acs.chemrev.5b00155	journal	October 2015
Bright Side of Lignin Depolymerization: Toward New Platform Chemicals Sun, Zhuohua; Fridrich, Bálint; de Santi, Alessandra Chemical Reviews, Vol. 118, Issue 2 https://doi.org/10.1021/acs.chemrev.7b00588	journal	January 2018
Perspective on Overcoming Scale-Up Hurdles for the Reductive Catalytic Fractionation of Lignocellulose Biomass Cooreman, Elias; Vangeel, Thijs; Van Aelst, Korneel Industrial & Engineering Chemistry Research, Vol. 59, Issue 39 https://doi.org/10.1021/acs.iecr.0c02294	journal	July 2020
Atomic-Level Structure Characterization of Biomass Pre- and Post-Lignin Treatment by Dynamic Nuclear Polarization-Enhanced Solid-State NMR Perras, Frédéric A.; Luo, Hao; Zhang, Ximing The Journal of Physical Chemistry A, Vol. 121, Issue 3 https://doi.org/10.1021/acs.jpca.6b11121	journal	January 2017
Influence of Acidic (H ₃ PO ₄ ) and Alkaline (NaOH) Additives on the Catalytic Reductive Fractionation of Lignocellulose Renders, Tom; Schutyser, Wouter; Van den Bosch, Sander ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.5b02906	journal	February 2016
Liquid-Phase H-Transfer from 2-Propanol to Phenol on Raney Ni: Surface Processes and Inhibition Kennema, Marco; de Castro, Ilton Barros Daltro; Meemken, Fabian ACS Catalysis, Vol. 7, Issue 4 https://doi.org/10.1021/acscatal.6b03201	journal	March 2017
Catechyl Lignin Extracted from Castor Seed Coats Using Deep Eutectic Solvents: Characterization and Depolymerization Wang, Shuizhong; Su, Shihao; Xiao, Ling-Ping ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 18 https://doi.org/10.1021/acssuschemeng.0c00462	journal	April 2020
Lignin Monomers from beyond the Canonical Monolignol Biosynthetic Pathway: Another Brick in the Wall del Río, José C.; Rencoret, Jorge; Gutiérrez, Ana ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 13 https://doi.org/10.1021/acssuschemeng.0c01109	journal	March 2020
Structural Modifications of Sugarcane Bagasse Lignins during Wet-Storage and Soda-Oxygen Pulping Yue, Fengxia; Lan, Wu; Hu, Songnan ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 10 https://doi.org/10.1021/acssuschemeng.6b00726	journal	June 2016
Reductive Catalytic Fractionation of Corn Stover Lignin Anderson, Eric M.; Katahira, Rui; Reed, Michelle ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 12 https://doi.org/10.1021/acssuschemeng.6b01858	journal	October 2016
Kinetic Studies of Lignin Solvolysis and Reduction by Reductive Catalytic Fractionation Decoupled in Flow-Through Reactors Anderson, Eric M.; Stone, Michael L.; Hülsey, Max J. ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 6 https://doi.org/10.1021/acssuschemeng.8b01256	journal	April 2018
Reductive Catalytic Fractionation of C-Lignin Stone, Michael L.; Anderson, Eric M.; Meek, Kelly M. ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 9 https://doi.org/10.1021/acssuschemeng.8b02741	journal	August 2018
Formation and Fate of Carboxylic Acids in the Lignin-First Biorefining of Lignocellulose via H-Transfer Catalyzed by Raney Ni Graça, Inês; Woodward, Robert T.; Kennema, Marco ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 10 https://doi.org/10.1021/acssuschemeng.8b03190	journal	August 2018
Automated Transformation of Lignin Topologies into Atomic Structures with LigninBuilder Vermaas, Josh V.; Dellon, Lauren D.; Broadbelt, Linda J. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 3 https://doi.org/10.1021/acssuschemeng.8b05665	journal	December 2018
Computational Evidence for Kinetically Controlled Radical Coupling during Lignification Gani, Terry Z. H.; Orella, Michael J.; Anderson, Eric M. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 15 https://doi.org/10.1021/acssuschemeng.9b02506	journal	July 2019
Lignin-KMC: A Toolkit for Simulating Lignin Biosynthesis Orella, Michael J.; Gani, Terry Z. H.; Vermaas, Josh V. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 22 https://doi.org/10.1021/acssuschemeng.9b03534	journal	September 2019
Complementing Vanillin and Cellulose Production by Oxidation of Lignocellulose with Stirring Control Zhu, Yuting; Liao, Yuhe; Lv, Wei ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 6 https://doi.org/10.1021/acssuschemeng.9b04837	journal	January 2020
Structure and Interactions of Plant Cell-Wall Polysaccharides by Two- and Three-Dimensional Magic-Angle-Spinning Solid-State NMR Dick-Pérez, Marilú; Zhang, Yuan; Hayes, Jennifer Biochemistry, Vol. 50, Issue 6 https://doi.org/10.1021/bi101795q	journal	February 2011
Milled Wood Lignin: A Linear Oligomer Crestini, Claudia; Melone, Federica; Sette, Marco Biomacromolecules, Vol. 12, Issue 11 https://doi.org/10.1021/bm200948r	journal	November 2011
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals Zakzeski, Joseph; Bruijnincx, Pieter C. A.; Jongerius, Anna L. Chemical Reviews, Vol. 110, Issue 6, p. 3552-3599 https://doi.org/10.1021/cr900354u	journal	June 2010
Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions Madon, Rostam J.; Boudart, Michel Industrial & Engineering Chemistry Fundamentals, Vol. 21, Issue 4, p. 438-447 https://doi.org/10.1021/i100008a022	journal	November 1982
Tests for Transport Limitations in Experimental Catalytic Reactors Mears, D. E. Industrial & Engineering Chemistry Process Design and Development, Vol. 10, Issue 4 https://doi.org/10.1021/i260040a020	journal	October 1971
Gas/Liquid Mass Transfer in Small Laboratory Batch Reactors: Comparison of Methods Meille, Valérie; Pestre, Nathalie; Fongarland, Pascal Industrial & Engineering Chemistry Research, Vol. 43, Issue 4 https://doi.org/10.1021/ie030569j	journal	February 2004
Alkaline Hydrogenation Pulping Sobolev, Igor.; Arlt, H. G.; Schuerch, Conrad. Industrial & Engineering Chemistry, Vol. 49, Issue 9 https://doi.org/10.1021/ie50573a041	journal	September 1957
Studies on Lignin and Related Compounds. LXXXIV. The High Pressure Hydrogenation of Maple Wood: Hydrol Lignin ¹ Brewer, Charles P.; Cooke, Lloyd M.; Hibbert, Harold Journal of the American Chemical Society, Vol. 70, Issue 1 https://doi.org/10.1021/ja01181a018	journal	January 1948
Studies on Lignin and Related Compounds. LXXXVII. High Pressure Hydrogenation of Maple Wood ¹ Pepper, James M.; Hibbert, Harold Journal of the American Chemical Society, Vol. 70, Issue 1 https://doi.org/10.1021/ja01181a021	journal	January 1948
Studies on Lignin and Related Compounds. LXVII. Isolation and Identification of 1-(4-Hydroxy-3,5-dimethoxyphenyl)-2-propanone and 1-(4-Hydroxy-3-methoxyphenyl)-2-propanone from Maple Wood Ethanolysis Products. Metabolic Changes in Lower and Higher Plants Kulka, Marshall; Hibbert, Harold Journal of the American Chemical Society, Vol. 65, Issue 6 https://doi.org/10.1021/ja01246a046	journal	June 1943
Studies on Lignin and Related Compounds. LXXI. The Course of Formation of Native Lignin in Spruce Buds ¹ Bower, John R.; Cooke, Lloyd M.; Hibbert, Harold Journal of the American Chemical Society, Vol. 65, Issue 6 https://doi.org/10.1021/ja01246a050	journal	June 1943
Reaction of Hardwood Lignin with Hydrogen Harris, Elwin E.; D'Ianni, James; Adkins, Homer Journal of the American Chemical Society, Vol. 60, Issue 6 https://doi.org/10.1021/ja01273a056	journal	June 1938
Studies on Lignin and Related Compounds. LXII. High Pressure Hydrogenation of Wood Using Copper Chromite Catalyst (Part 1) Godard, Hugh P.; McCarthy, Joseph L.; Hibbert, Harold Journal of the American Chemical Society, Vol. 63, Issue 11 https://doi.org/10.1021/ja01856a055	journal	November 1941
Studies on Lignin and Related Compounds. LXIII. Hydrogenation of Wood (Part 2) Bower, John R.; McCarthy, Joseph L.; Hibbert, Harold Journal of the American Chemical Society, Vol. 63, Issue 11 https://doi.org/10.1021/ja01856a056	journal	November 1941
Hydrogenation of Wood Godard, H. P.; McCarthy, Joseph L.; Hibbert, Harold Journal of the American Chemical Society, Vol. 62, Issue 4 https://doi.org/10.1021/ja01861a508	journal	April 1940
Studies on Lignin and Related Compounds. XLII. The Isolation of a Bisulfite Soluble “Extracted Lignin” Steeves, William H.; Hibbert, Harold. Journal of the American Chemical Society, Vol. 61, Issue 8 https://doi.org/10.1021/ja01877a064	journal	August 1939
Quantitative 2D HSQC (Q-HSQC) via Suppression of J -Dependence of Polarization Transfer in NMR Spectroscopy: Application to Wood Lignin Heikkinen, Sami; Toikka, Merja M.; Karhunen, Pirkko T. Journal of the American Chemical Society, Vol. 125, Issue 14 https://doi.org/10.1021/ja029035k	journal	April 2003
Simultaneous Quantification and Identification of Individual Chemicals in Metabolite Mixtures by Two-Dimensional Extrapolated Time-Zero ¹ H− ¹³ C HSQC (HSQC ₀ ) Hu, Kaifeng; Westler, William M.; Markley, John L. Journal of the American Chemical Society, Vol. 133, Issue 6 https://doi.org/10.1021/ja1095304	journal	February 2011
Aromatic Monomers by in Situ Conversion of Reactive Intermediates in the Acid-Catalyzed Depolymerization of Lignin Deuss, Peter J.; Scott, Martin; Tran, Fanny Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03693	journal	June 2015
Electrochemical Aminoxyl-Mediated Oxidation of Primary Alcohols in Lignin to Carboxylic Acids: Polymer Modification and Depolymerization Rafiee, Mohammad; Alherech, Manar; Karlen, Steven D. Journal of the American Chemical Society, Vol. 141, Issue 38 https://doi.org/10.1021/jacs.9b07243	journal	September 2019
Pyrolysis-GC-MS characterization of forage materials Ralph, John; Hatfield, Ronald D. Journal of Agricultural and Food Chemistry, Vol. 39, Issue 8 https://doi.org/10.1021/jf00008a014	journal	August 1991
Carbohydrate composition of alfalfa cell walls isolated from stem sections differing in maturity Hatfield, R. D. Journal of Agricultural and Food Chemistry, Vol. 40, Issue 3 https://doi.org/10.1021/jf00015a012	journal	March 1992
Model Studies of Ferulate−Coniferyl Alcohol Cross-Product Formation in Primary Maize Walls: Implications for Lignification in Grasses Grabber, John H.; Ralph, John; Hatfield, Ronald D. Journal of Agricultural and Food Chemistry, Vol. 50, Issue 21, p. 6008-6016 https://doi.org/10.1021/jf0205312	journal	October 2002
NMR Characterization of Lignins Isolated from Fruit and Vegetable Insoluble Dietary Fiber Bunzel, Mirko; Ralph, John Journal of Agricultural and Food Chemistry, Vol. 54, Issue 21 https://doi.org/10.1021/jf061525z	journal	October 2006
Compositional Analysis of Water-Soluble Materials in Corn Stover Chen, Shou-Feng; Mowery, Richard A.; Scarlata, Christopher J. Journal of Agricultural and Food Chemistry, Vol. 55, Issue 15 https://doi.org/10.1021/jf0700327	journal	July 2007
Compositional Analysis of Lignocellulosic Feedstocks. 1. Review and Description of Methods Sluiter, Justin B.; Ruiz, Raymond O.; Scarlata, Christopher J. Journal of Agricultural and Food Chemistry, Vol. 58, Issue 16, p. 9043-9053 https://doi.org/10.1021/jf1008023	journal	August 2010
Compositional Analysis of Lignocellulosic Feedstocks. 2. Method Uncertainties Templeton, David W.; Scarlata, Christopher J.; Sluiter, Justin B. Journal of Agricultural and Food Chemistry, Vol. 58, Issue 16 https://doi.org/10.1021/jf100807b	journal	August 2010
Chemical Characterization of Klason Lignin Preparations from Plant-Based Foods Bunzel, Mirko; Schüßler, Anne; Tchetseubu Saha, Gérard Journal of Agricultural and Food Chemistry, Vol. 59, Issue 23 https://doi.org/10.1021/jf2031378	journal	December 2011
Syntheses of Lignin-Derived Thioacidolysis Monomers and Their Uses as Quantitation Standards Yue, Fengxia; Lu, Fachuang; Sun, Run-Cang Journal of Agricultural and Food Chemistry, Vol. 60, Issue 4 https://doi.org/10.1021/jf204481x	journal	January 2012
Structural Characterization of the Lignin in the Cortex and Pith of Elephant Grass ( Pennisetum purpureum ) Stems del Río, José C.; Prinsen, Pepijn; Rencoret, Jorge Journal of Agricultural and Food Chemistry, Vol. 60, Issue 14 https://doi.org/10.1021/jf300099g	journal	March 2012
Structural Characterization of Wheat Straw Lignin as Revealed by Analytical Pyrolysis, 2D-NMR, and Reductive Cleavage Methods del Río, José C.; Rencoret, Jorge; Prinsen, Pepijn Journal of Agricultural and Food Chemistry, Vol. 60, Issue 23 https://doi.org/10.1021/jf301002n	journal	December 2011
A Stable-Isotope Dilution GC-MS Approach for the Analysis of DFRC (Derivatization Followed by Reductive Cleavage) Monomers from Low-Lignin Plant Materials Schäfer, Judith; Urbat, Felix; Rund, Katharina Journal of Agricultural and Food Chemistry, Vol. 63, Issue 10 https://doi.org/10.1021/jf506221p	journal	March 2015
Compositional Analysis of Water-Soluble Materials in Switchgrass Chen, Shou-Feng; Mowery, Richard A.; Sevcik, Richard S. Journal of Agricultural and Food Chemistry, Vol. 58, Issue 6 https://doi.org/10.1021/jf9033877	journal	March 2010
Derivatization Followed by Reductive Cleavage (DFRC Method), a New Method for Lignin Analysis: Protocol for Analysis of DFRC Monomers Lu, Fachuang; Ralph, John Journal of Agricultural and Food Chemistry, Vol. 45, Issue 7 https://doi.org/10.1021/jf970258h	journal	July 1997
DFRC Method for Lignin Analysis. 1. New Method for β-Aryl Ether Cleavage: Lignin Model Studies Lu, Fachuang; Ralph, John Journal of Agricultural and Food Chemistry, Vol. 45, Issue 12 https://doi.org/10.1021/jf970539p	journal	December 1997
Detection and Determination of p-Coumaroylated Units in Lignins Lu, Fachuang; Ralph, John Journal of Agricultural and Food Chemistry, Vol. 47, Issue 5, p. 1988-1992 https://doi.org/10.1021/jf981140j	journal	May 1999
Metal Particle Growth during Glucose Hydrogenation over Ru/SiO ₂ Evaluated by X-ray Absorption Spectroscopy and Electron Microscopy Maris, Erin P.; Ketchie, William C.; Oleshko, Vladimir The Journal of Physical Chemistry B, Vol. 110, Issue 15 https://doi.org/10.1021/jp057022y	journal	April 2006
A Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization in Acidic Environments Sturgeon, Matthew R.; Kim, Seonah; Lawrence, Kelsey ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 3, p. 472-485 https://doi.org/10.1021/sc400384w	journal	November 2013
Lignins: Natural polymers from oxidative coupling of 4-hydroxyphenyl- propanoids Ralph, John; Lundquist, Knut; Brunow, Gösta Phytochemistry Reviews, Vol. 3, Issue 1-2, p. 29-60 https://doi.org/10.1023/B:PHYT.0000047809.65444.a4	journal	January 2004
Peroxidase-dependent cross-linking reactions of p-hydroxycinnamates in plant cell walls Ralph, John; Bunzel, Mirko; Marita, Jane M. Phytochemistry Reviews, Vol. 3, Issue 1-2, p. 79-96 https://doi.org/10.1023/B:PHYT.0000047811.13837.fb	journal	January 2004
Folding of xylan onto cellulose fibrils in plant cell walls revealed by solid-state NMR Simmons, Thomas J.; Mortimer, Jenny C.; Bernardinelli, Oigres D. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13902	journal	December 2016
Whole plant cell wall characterization using solution-state 2D NMR Mansfield, Shawn D.; Kim, Hoon; Lu, Fachuang Nature Protocols, Vol. 7, Issue 9 https://doi.org/10.1038/nprot.2012.064	journal	August 2012
Differences in S/G ratio in natural poplar variants do not predict catalytic depolymerization monomer yields Anderson, Eric M.; Stone, Michael L.; Katahira, Rui Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09986-1	journal	May 2019
Stabilization strategies in biomass depolymerization using chemical functionalization Questell-Santiago, Ydna M.; Galkin, Maxim V.; Barta, Katalin Nature Reviews Chemistry, Vol. 4, Issue 6 https://doi.org/10.1038/s41570-020-0187-y	journal	May 2020
Fractionation of lignocellulosic biomass to produce uncondensed aldehyde-stabilized lignin Talebi Amiri, Masoud; Dick, Graham R.; Questell-Santiago, Ydna M. Nature Protocols, Vol. 14, Issue 3 https://doi.org/10.1038/s41596-018-0121-7	journal	February 2019
Solar energy-driven lignin-first approach to full utilization of lignocellulosic biomass under mild conditions Wu, Xuejiao; Fan, Xueting; Xie, Shunji Nature Catalysis, Vol. 1, Issue 10 https://doi.org/10.1038/s41929-018-0148-8	journal	October 2018
Solution-state 2D NMR of ball-milled plant cell wall gels in DMSO-d6/pyridine-d5 Kim, Hoon; Ralph, John Org. Biomol. Chem., Vol. 8, Issue 3 https://doi.org/10.1039/B916070A	journal	January 2010
A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass Parsell, Trenton; Yohe, Sara; Degenstein, John Green Chemistry, Vol. 17, Issue 3 https://doi.org/10.1039/C4GC01911C	journal	January 2015
Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood Van den Bosch, S.; Schutyser, W.; Koelewijn, S. -F. Chemical Communications, Vol. 51, Issue 67 https://doi.org/10.1039/C5CC04025F	journal	January 2015
Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps Van den Bosch, S.; Schutyser, W.; Vanholme, R. Energy & Environmental Science, Vol. 8, Issue 6 https://doi.org/10.1039/C5EE00204D	journal	January 2015
Influence of bio-based solvents on the catalytic reductive fractionation of birch wood Schutyser, W.; Van den Bosch, S.; Renders, T. Green Chemistry, Vol. 17, Issue 11 https://doi.org/10.1039/C5GC01442E	journal	January 2015
A mild biomass pretreatment using γ-valerolactone for concentrated sugar production Shuai, Li; Questell-Santiago, Ydna M.; Luterbacher, Jeremy S. Green Chemistry, Vol. 18, Issue 4 https://doi.org/10.1039/C5GC02489G	journal	January 2016
Quantification of acidic compounds in complex biomass-derived streams Karp, Eric M.; Nimlos, Claire T.; Deutch, Steve Green Chemistry, Vol. 18, Issue 17 https://doi.org/10.1039/C6GC00868B	journal	January 2016
Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading Schutyser, W.; Renders, T.; Van den Bosch, S. Chemical Society Reviews, Vol. 47, Issue 3 https://doi.org/10.1039/C7CS00566K	journal	January 2018
Lignin-first biomass fractionation: the advent of active stabilisation strategies Renders, T.; Van den Bosch, S.; Koelewijn, S. -F. Energy & Environmental Science, Vol. 10, Issue 7 https://doi.org/10.1039/C7EE01298E	journal	January 2017
Sustainable sources need reliable standards Galkin, Maxim V.; Di Francesco, Davide; Edlund, Ulrica Faraday Discussions, Vol. 202 https://doi.org/10.1039/C7FD00046D	journal	January 2017
Effect of methanol in controlling defunctionalization of the propyl side chain of phenolics from catalytic upstream biorefining Ferrini, Paola; Chesi, Claudio; Parkin, Nicholas Faraday Discussions, Vol. 202 https://doi.org/10.1039/C7FD00069C	journal	January 2017
Phenolic acetals from lignins of varying compositions via iron( iii ) triflate catalysed depolymerisation Deuss, Peter J.; Lancefield, Christopher S.; Narani, Anand Green Chemistry, Vol. 19, Issue 12 https://doi.org/10.1039/C7GC00195A	journal	January 2017
Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al ₂ O ₃ catalyst pellets during lignin-first fractionation Van den Bosch, S.; Renders, T.; Kennis, S. Green Chemistry, Vol. 19, Issue 14 https://doi.org/10.1039/C7GC01324H	journal	January 2017
Predicting lignin depolymerization yields from quantifiable properties using fractionated biorefinery lignins Phongpreecha, Thanaphong; Hool, Nicholas C.; Stoklosa, Ryan J. Green Chem., Vol. 19, Issue 21 https://doi.org/10.1039/C7GC02023F	journal	January 2017
Lignin depolymerization to monophenolic compounds in a flow-through system Kumaniaev, Ivan; Subbotina, Elena; Sävmarker, Jonas Green Chemistry, Vol. 19, Issue 24 https://doi.org/10.1039/C7GC02731A	journal	January 2017
Lignin extraction and catalytic upgrading from genetically modified poplar Luo, Hao; Abu-Omar, Mahdi M. Green Chemistry, Vol. 20, Issue 3 https://doi.org/10.1039/C7GC03417B	journal	January 2018
Life cycle assessment of adipic acid production from lignin Corona, Andrea; Biddy, Mary J.; Vardon, Derek R. Green Chemistry, Vol. 20, Issue 16 https://doi.org/10.1039/C8GC00868J	journal	January 2018
Catalytic lignocellulose biorefining in n -butanol/water: a one-pot approach toward phenolics, polyols, and cellulose Renders, T.; Cooreman, E.; Van den Bosch, S. Green Chemistry, Vol. 20, Issue 20 https://doi.org/10.1039/C8GC01031E	journal	January 2018
Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor Li, Yanding; Demir, Benginur; Vázquez Ramos, Leida M. Green Chemistry, Vol. 21, Issue 13 https://doi.org/10.1039/C9GC00986H	journal	January 2019
Establishing lignin structure-upgradeability relationships using quantitative ¹ H– ¹³ C heteronuclear single quantum coherence nuclear magnetic resonance (HSQC-NMR) spectroscopy Talebi Amiri, Masoud; Bertella, Stefania; Questell-Santiago, Ydna M. Chemical Science, Vol. 10, Issue 35 https://doi.org/10.1039/C9SC02088H	journal	January 2019
608. The chemistry of the wood cell wall. Part II. The isolation of beech and spruce acid-soluble and modified lignins Campbell, W. G.; McDonald, I. R. C. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/JR9520003180	journal	January 1952
Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation–hydrogenolysis process Song, Qi; Wang, Feng; Cai, Jiaying Energy & Environmental Science, Vol. 6, Issue 3, p. 994-1007 https://doi.org/10.1039/c2ee23741e	journal	January 2013
Non-degradative dissolution and acetylation of ball-milled plant cell walls: high-resolution solution-state NMR Lu, Fachuang; Ralph, John The Plant Journal, Vol. 35, Issue 4 https://doi.org/10.1046/j.1365-313X.2003.01817.x	journal	August 2003
A polymer of caffeyl alcohol in plant seeds Chen, F.; Tobimatsu, Y.; Havkin-Frenkel, D. Proceedings of the National Academy of Sciences, Vol. 109, Issue 5 https://doi.org/10.1073/pnas.1120992109	journal	January 2012
Revisiting the Mechanism of β- O -4 Bond Cleavage During Acidolysis of Lignin. Part 6: A Review Yokoyama, Tomoya Journal of Wood Chemistry and Technology, Vol. 35, Issue 1 https://doi.org/10.1080/02773813.2014.881375	journal	September 2014
Formation rate of benzyl cation intermediate from p -Hydroxyphenyl, guaiacyl, or syringyl nucleus in acidolysis of lignin Shioya, Toshinao; Akiyama, Takuya; Yokoyama, Tomoya Journal of Wood Chemistry and Technology, Vol. 37, Issue 2 https://doi.org/10.1080/02773813.2016.1235587	journal	October 2016
The Condensation Reactions of Lignin Model Compounds in Alkaline Pulping Liquors Fullerton, Terry J. Journal of Wood Chemistry and Technology, Vol. 7, Issue 4 https://doi.org/10.1080/02773818708085279	journal	January 1987
Condensation Reactions of Softwood and Hardwood Lignin Model Compounds Under Organic Acid Cooking Conditions Shimada, K.; Hosoya, S.; Ikeda, T. Journal of Wood Chemistry and Technology, Vol. 17, Issue 1-2 https://doi.org/10.1080/02773819708003118	journal	February 1997
Calculation of Flame Ionization Detector Relative Response Factors Using the Effective Carbon Number Concept Scanlon, J. T.; Willis, D. E. Journal of Chromatographic Science, Vol. 23, Issue 8 https://doi.org/10.1093/chromsci/23.8.333	journal	August 1985
Tricin, a Flavonoid Monomer in Monocot Lignification Lan, Wu; Lu, Fachuang; Regner, Matthew Plant Physiology, Vol. 167, Issue 4 https://doi.org/10.1104/pp.114.253757	journal	February 2015
Hydroxystilbenes Are Monomers in Palm Fruit Endocarp Lignins Carlos del Río, José; Rencoret, Jorge; Gutiérrez, Ana Plant Physiology, Vol. 174, Issue 4 https://doi.org/10.1104/pp.17.00362	journal	June 2017
Systematic Structural Characterization of Metabolites in Arabidopsis via Candidate Substrate-Product Pair Networks Morreel, Kris; Saeys, Yvan; Dima, Oana The Plant Cell, Vol. 26, Issue 3 https://doi.org/10.1105/tpc.113.122242	journal	March 2014
Molecular phenotyping of lignin-modified tobacco reveals associated changes in cell-wall metabolism, primary metabolism, stress metabolism and photorespiration: Molecular phenotyping of lignin-modified tobacco Dauwe, Rebecca; Morreel, Kris; Goeminne, Geert The Plant Journal, Vol. 52, Issue 2 https://doi.org/10.1111/j.1365-313X.2007.03233.x	journal	August 2007
Rapid analysis of poplar lignin monomer composition by a streamlined thioacidolysis procedure and near-infrared reflectance-based prediction modeling Robinson, Andrew R.; Mansfield, Shawn D. The Plant Journal, Vol. 58, Issue 4 https://doi.org/10.1111/j.1365-313X.2009.03808.x	journal	May 2009
Tricin-lignins: occurrence and quantitation of tricin in relation to phylogeny Lan, Wu; Rencoret, Jorge; Lu, Fachuang The Plant Journal, Vol. 88, Issue 6 https://doi.org/10.1111/tpj.13315	journal	November 2016
Monolignol ferulate conjugates are naturally incorporated into plant lignins Karlen, Steven D.; Zhang, Chengcheng; Peck, Matthew L. Science Advances, Vol. 2, Issue 10 https://doi.org/10.1126/sciadv.1600393	journal	October 2016
An “ideal lignin” facilitates full biomass utilization Li, Yanding; Shuai, Li; Kim, Hoon Science Advances, Vol. 4, Issue 9 https://doi.org/10.1126/sciadv.aau2968	journal	September 2018
Stabilization Wedges: Solving the Climate Problem for the Next 50 Years with Current Technologies Pacala, S. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1100103	journal	August 2004
The Path Forward for Biofuels and Biomaterials Ragauskas, Arthur J.; Williams, Charlotte K.; Davison, Brian H. Science, Vol. 311, Issue 5760, p. 484-489 https://doi.org/10.1126/science.1114736	journal	January 2006
Valorization of Biomass: Deriving More Value from Waste Tuck, C. O.; Perez, E.; Horvath, I. T. Science, Vol. 337, Issue 6095, p. 695-699 https://doi.org/10.1126/science.1218930	journal	August 2012
Nonenzymatic Sugar Production from Biomass Using Biomass-Derived -Valerolactone Luterbacher, J. S.; Rand, J. M.; Alonso, D. M. Science, Vol. 343, Issue 6168 https://doi.org/10.1126/science.1246748	journal	January 2014
Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization Shuai, Li; Amiri, Masoud Talebi; Questell-Santiago, Ydna M. Science, Vol. 354, Issue 6310 https://doi.org/10.1126/science.aaf7810	journal	October 2016
A sustainable wood biorefinery for low–carbon footprint chemicals production Liao, Yuhe; Koelewijn, Steven-Friso; Van den Bossche, Gil Science, Vol. 367, Issue 6484 https://doi.org/10.1126/science.aau1567	journal	February 2020
Lignin and related compounds. I. A comparative study of catalysts for lignin hydrogenolysis Pepper, J. M.; Lee, Y. W. Canadian Journal of Chemistry, Vol. 47, Issue 5 https://doi.org/10.1139/v69-118	journal	March 1969
Lignin and related compounds. VI. A study of variables affecting the hydrogenolysis of spruce wood lignin using a rhodium-on-charcoal catalyst Pepper, James M.; Supathna, Punsri Canadian Journal of Chemistry, Vol. 56, Issue 7 https://doi.org/10.1139/v78-150	journal	April 1978
Lignin Biosynthesis Boerjan, Wout; Ralph, John; Baucher, Marie Annual Review of Plant Biology, Vol. 54, Issue 1, p. 519-546 https://doi.org/10.1146/annurev.arplant.54.031902.134938	journal	June 2003
Overcoming cellulose recalcitrance in woody biomass for the lignin-first biorefinery Yang, Haibing; Zhang, Ximing; Luo, Hao Biotechnology for Biofuels, Vol. 12, Issue 1 https://doi.org/10.1186/s13068-019-1503-y	journal	June 2019
Lignin and Lignans Heitner, Cyril; Dimmel, Don; Schmidt, John https://doi.org/10.1201/EBK1574444865	book	August 2010
Comparison of hydrogenolysis with thioacidolysis for lignin structural analysis van de Pas, Daniel J.; Nanayakkara, Bernadette; Suckling, Ian D. Holzforschung, Vol. 68, Issue 2 https://doi.org/10.1515/hf-2013-0075	journal	February 2014
Über die Hydrogenolyse von Lignin. 6. Mitt. Anwendung eines Halbmikroverfahrens bei Untersuchungen am Hydrogenolysesystem Hoffmann, P.; Schweers, W. Holzforschung, Vol. 29, Issue 1 https://doi.org/10.1515/hfsg.1975.29.1.18	journal	January 1975
Hydrogenolysis of Protolignin - XVII. Isolation of three dimeric compounds with y—0—4, ß—1, and ß—0—4 linkages from hardwood lignin Hwang, Byung Ho; Sakakibara, Akira; Miki, Keiji Holzforschung, Vol. 35, Issue 5 https://doi.org/10.1515/hfsg.1981.35.5.229	journal	January 1981
Thioacidolysis of Poplar Lignins: Identification of Monomeric Syringyl Products and Characterization of Guaiacyl-Syringyl Lignin Fractions Lapierre, Catherine; Monties, Bernard; Rolando, Christian Holzforschung, Vol. 40, Issue 2 https://doi.org/10.1515/hfsg.1986.40.2.113	journal	January 1986
Chemical Structures of Sulfuric Acid Lignin - Pt.X.Reaction of Syringylglycerol-ß-syringyl Ether and Condensation of Syringyl Nucleus with Guaiacyl Lignin Model Compounds in Sulfuric Acid Yasuda, Seiichi; Ota, Katsuhito Holzforschung, Vol. 41, Issue 1 https://doi.org/10.1515/hfsg.1987.41.1.59	journal	January 1987
Formation of Condensation Products on Treatment of Non-Phenolic Lignin Units of the β-Aryl Ether Type with Alkali. Model Studies on a Novel Mode of Alkaline Lignin Condensation Gierer, Josef; Norén, Isa; Wännström, Sune Holzforschung, Vol. 41, Issue 2 https://doi.org/10.1515/hfsg.1987.41.2.79	journal	January 1987
Formic Acid/Peroxyformic Acid Pulping. III. Condensation Reactions of ß-Aryl Ether Model Compounds in Formic Acid Ede, Richard M.; Brunow, Gösta Holzforschung, Vol. 43, Issue 5 https://doi.org/10.1515/hfsg.1989.43.5.317	journal	January 1989
Cell Wall Carbohydrates of Flaccidgrass Plant Parts. I. Neutral Sugar Composition of Fermented Residues ¹ Ruiter, J. M.; Burns, J. C. Crop Science, Vol. 27, Issue 5 https://doi.org/10.2135/cropsci1987.0011183X002700050047x	journal	September 1987
Can Lignin Be Accurately Measured? Hatfield, Ronald; Fukushima, Romualdo S. Crop Science, Vol. 45, Issue 3 https://doi.org/10.2135/cropsci2004.0238	journal	January 2005
Preventing Lignin Condensation to Facilitate Aromatic Monomer Production Lan, Wu; Luterbacher, Jeremy S. CHIMIA International Journal for Chemistry, Vol. 73, Issue 7 https://doi.org/10.2533/chimia.2019.591	journal	August 2019
High Throughput Screening Technologies in Biomass Characterization Decker, Stephen R.; Harman-Ware, Anne E.; Happs, Renee M. Frontiers in Energy Research, Vol. 6 https://doi.org/10.3389/fenrg.2018.00120	journal	November 2018
Acid Degradation of Lignin. II. Separation and Identification of Low Molecular Weight Phenols. Lundquist, Knut; Sydberger, Tomas; Bjerrum, Jannik Acta Chemica Scandinavica, Vol. 24 https://doi.org/10.3891/acta.chem.scand.24-0889	journal	January 1970
Microscale alkaline nitrobenzene oxidation method for high-throughput determination of lignin aromatic components Yamamura, Masaomi; Hattori, Takefumi; Suzuki, Shiro Plant Biotechnology, Vol. 27, Issue 4 https://doi.org/10.5511/plantbiotechnology.27.305	journal	January 2010

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