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Title: A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability

Abstract

Incorporation of a hole-transport material that also passivates surface defects results in perovskite solar cells with superior efficiency and stability.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1]; ORCiD logo [2]
  1. Department of Chemical and Biological Engineering, Princeton University, Princeton, USA
  2. Department of Chemical and Biological Engineering, Princeton University, Princeton, USA, Andlinger Center for Energy and the Environment
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1712784
Grant/Contract Number:  
EE0008560; SC0012704
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 13 Journal Issue: 11; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhao, By Xiaoming, Yao, Chao, Gu, Kaichen, Liu, Tianran, Xia, Yu, and Loo, Yueh-Lin. A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability. United Kingdom: N. p., 2020. Web. https://doi.org/10.1039/D0EE01655A.
Zhao, By Xiaoming, Yao, Chao, Gu, Kaichen, Liu, Tianran, Xia, Yu, & Loo, Yueh-Lin. A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability. United Kingdom. https://doi.org/10.1039/D0EE01655A
Zhao, By Xiaoming, Yao, Chao, Gu, Kaichen, Liu, Tianran, Xia, Yu, and Loo, Yueh-Lin. Thu . "A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability". United Kingdom. https://doi.org/10.1039/D0EE01655A.
@article{osti_1712784,
title = {A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability},
author = {Zhao, By Xiaoming and Yao, Chao and Gu, Kaichen and Liu, Tianran and Xia, Yu and Loo, Yueh-Lin},
abstractNote = {Incorporation of a hole-transport material that also passivates surface defects results in perovskite solar cells with superior efficiency and stability.},
doi = {10.1039/D0EE01655A},
journal = {Energy & Environmental Science},
number = 11,
volume = 13,
place = {United Kingdom},
year = {2020},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/D0EE01655A

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Works referenced in this record:

Understanding the Role of Cesium and Rubidium Additives in Perovskite Solar Cells: Trap States, Charge Transport, and Recombination
journal, January 2018

  • Hu, Yinghong; Hutter, Eline M.; Rieder, Philipp
  • Advanced Energy Materials, Vol. 8, Issue 16
  • DOI: 10.1002/aenm.201703057

Surface passivation of perovskite film for efficient solar cells
journal, April 2019


Dopant-Free Hole-Transporting Materials for Stable and Efficient Perovskite Solar Cells
journal, July 2017


Interfacial Engineering at the 2D/3D Heterojunction for High-Performance Perovskite Solar Cells
journal, September 2019


Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability
journal, January 2018


Rationalizing the Molecular Design of Hole‐Selective Contacts to Improve Charge Extraction in Perovskite Solar Cells
journal, June 2019

  • Wang, Qiong; Mosconi, Edoardo; Wolff, Christian
  • Advanced Energy Materials, Vol. 9, Issue 28
  • DOI: 10.1002/aenm.201900990

Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
journal, January 2020


Planar‐Structure Perovskite Solar Cells with Efficiency beyond 21%
journal, October 2017


Highly efficient perovskite solar cells with a compositionally engineered perovskite/hole transporting material interface
journal, January 2017

  • Cho, Kyung Taek; Paek, Sanghyun; Grancini, Giulia
  • Energy & Environmental Science, Vol. 10, Issue 2
  • DOI: 10.1039/C6EE03182J

The role of anion vacancy migration in lead halide photolysis
journal, September 1973


Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells
journal, June 2017


Efficient, stable solar cells by using inherent bandgap of α-phase formamidinium lead iodide
journal, November 2019


Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Interface engineering of highly efficient perovskite solar cells
journal, July 2014


Extrinsic ion migration in perovskite solar cells
journal, January 2017

  • Li, Zhen; Xiao, Chuanxiao; Yang, Ye
  • Energy & Environmental Science, Vol. 10, Issue 5
  • DOI: 10.1039/C7EE00358G

Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
journal, March 2018

  • Abdi-Jalebi, Mojtaba; Andaji-Garmaroudi, Zahra; Cacovich, Stefania
  • Nature, Vol. 555, Issue 7697
  • DOI: 10.1038/nature25989

Methylammonium-free, high-performance, and stable perovskite solar cells on a planar architecture
journal, October 2018

  • Turren-Cruz, Silver-Hamill; Hagfeldt, Anders; Saliba, Michael
  • Science, Vol. 362, Issue 6413
  • DOI: 10.1126/science.aat3583

Selective growth of layered perovskites for stable and efficient photovoltaics
journal, January 2018

  • Cho, Kyung Taek; Grancini, Giulia; Lee, Yonghui
  • Energy & Environmental Science, Vol. 11, Issue 4
  • DOI: 10.1039/C7EE03513F

Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes
journal, December 2015


In Situ Growth of 2D Perovskite Capping Layer for Stable and Efficient Perovskite Solar Cells
journal, February 2018

  • Chen, Peng; Bai, Yang; Wang, Songcan
  • Advanced Functional Materials, Vol. 28, Issue 17
  • DOI: 10.1002/adfm.201706923

Analyzing Interface Recombination in Lead‐Halide Perovskite Solar Cells with Organic and Inorganic Hole‐Transport Layers
journal, June 2020

  • Haddad, Jinane; Krogmeier, Benedikt; Klingebiel, Benjamin
  • Advanced Materials Interfaces, Vol. 7, Issue 16
  • DOI: 10.1002/admi.202000366

Controllable Self-Induced Passivation of Hybrid Lead Iodide Perovskites toward High Performance Solar Cells
journal, June 2014

  • Chen, Qi; Zhou, Huanping; Song, Tze-Bin
  • Nano Letters, Vol. 14, Issue 7
  • DOI: 10.1021/nl501838y

The influence of perovskite layer and hole transport material on the temperature stability about perovskite solar cells
journal, January 2018


Ion-Migration Inhibition by the Cation-π Interaction in Perovskite Materials for Efficient and Stable Perovskite Solar Cells
journal, June 2018


Room-temperature-processed fullerene single-crystalline nanoparticles for high-performance flexible perovskite photovoltaics
journal, January 2019

  • Zhao, Xiaoming; Tian, Lixian; Liu, Tianjun
  • Journal of Materials Chemistry A, Vol. 7, Issue 4
  • DOI: 10.1039/C8TA10510C

Dopant-Free Hole-Transporting Material with a C 3 h Symmetrical Truxene Core for Highly Efficient Perovskite Solar Cells
journal, February 2016

  • Huang, Chuyi; Fu, Weifei; Li, Chang-Zhi
  • Journal of the American Chemical Society, Vol. 138, Issue 8
  • DOI: 10.1021/jacs.6b00039

Efficient and stable solution-processed planar perovskite solar cells via contact passivation
journal, February 2017


A dopant-free hole-transporting material for efficient and stable perovskite solar cells
journal, January 2014

  • Liu, Jian; Wu, Yongzhen; Qin, Chuanjiang
  • Energy Environ. Sci., Vol. 7, Issue 9
  • DOI: 10.1039/C4EE01589D

Targeted Therapy for Interfacial Engineering Toward Stable and Efficient Perovskite Solar Cells
journal, August 2019

  • Wang, Shuhui; Chen, Haiyang; Zhang, Jiandong
  • Advanced Materials, Vol. 31, Issue 41
  • DOI: 10.1002/adma.201903691

Enhanced Thermal Stability in Perovskite Solar Cells by Assembling 2D/3D Stacking Structures
journal, January 2018


Planar perovskite solar cells with long-term stability using ionic liquid additives
journal, July 2019


Detrimental Effect of Unreacted PbI 2 on the Long‐Term Stability of Perovskite Solar Cells
journal, February 2020

  • Tumen‐Ulzii, Ganbaatar; Qin, Chuanjiang; Klotz, Dino
  • Advanced Materials, Vol. 32, Issue 16
  • DOI: 10.1002/adma.201905035

Rational Design of Dipolar Chromophore as an Efficient Dopant-Free Hole-Transporting Material for Perovskite Solar Cells
journal, August 2016

  • Li, Zhong’an; Zhu, Zonglong; Chueh, Chu-Chen
  • Journal of the American Chemical Society, Vol. 138, Issue 36
  • DOI: 10.1021/jacs.6b06291

Less is More: Dopant-Free Hole Transporting Materials for High-Efficiency Perovskite Solar Cells
journal, January 2018


Inverted planar perovskite solar cells with dopant free hole transporting material: Lewis base-assisted passivation and reduced charge recombination
journal, January 2017

  • Park, Sang Jin; Jeon, Seolhee; Lee, In Kyu
  • Journal of Materials Chemistry A, Vol. 5, Issue 25
  • DOI: 10.1039/C7TA02440A

Hybrid Perovskites Depth Profiling with Variable-Size Argon Clusters and Monatomic Ions Beams
journal, March 2019

  • Noël, Céline; Pescetelli, Sara; Agresti, Antonio
  • Materials, Vol. 12, Issue 5
  • DOI: 10.3390/ma12050726

Interfacial Sulfur Functionalization Anchoring SnO 2 and CH 3 NH 3 PbI 3 for Enhanced Stability and Trap Passivation in Perovskite Solar Cells
journal, November 2018

  • Wang, Zhen; Kamarudin, Muhammad Akmal; Huey, Ng Chi
  • ChemSusChem, Vol. 11, Issue 22
  • DOI: 10.1002/cssc.201801888

Infrared studies of lead(II) halide-1,10-phenanthroline photosensitive materials
journal, January 2009

  • Glatfelter, Alicia; Dybowski, Cecil; Bai, Shi
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 71, Issue 5
  • DOI: 10.1016/j.saa.2008.07.012

Enhanced optoelectronic quality of perovskite thin films with hypophosphorous acid for planar heterojunction solar cells
journal, November 2015

  • Zhang, Wei; Pathak, Sandeep; Sakai, Nobuya
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms10030

Stable and High‐Efficiency Methylammonium‐Free Perovskite Solar Cells
journal, January 2020


One-Year stable perovskite solar cells by 2D/3D interface engineering
journal, June 2017

  • Grancini, G.; Roldán-Carmona, C.; Zimmermann, I.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15684

Tuning Charge and Spin Excitations in Zigzag Edge Nanographene Ribbons
journal, July 2012

  • Dutta, Sudipta; Wakabayashi, Katsunori
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00519

Extending the Photovoltaic Response of Perovskite Solar Cells into the Near‐Infrared with a Narrow‐Bandgap Organic Semiconductor
journal, September 2019


Understanding the Doping Effect on NiO: Toward High-Performance Inverted Perovskite Solar Cells
journal, March 2018


Photodecomposition and thermal decomposition in methylammonium halide lead perovskites and inferred design principles to increase photovoltaic device stability
journal, January 2018

  • Juarez-Perez, Emilio J.; Ono, Luis K.; Maeda, Maki
  • Journal of Materials Chemistry A, Vol. 6, Issue 20
  • DOI: 10.1039/C8TA03501F

Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells
journal, January 2019

  • Al-Ashouri, Amran; Magomedov, Artiom; Roß, Marcel
  • Energy & Environmental Science, Vol. 12, Issue 11
  • DOI: 10.1039/C9EE02268F

Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013

  • Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong
  • Nature Photonics, Vol. 7, Issue 6, p. 486-491
  • DOI: 10.1038/nphoton.2013.80

Acid-Catalyzed Reactions Activate DMSO as a Reagent in Perovskite Precursor Inks
journal, June 2018


Efficient Defect Passivation for Perovskite Solar Cells by Controlling the Electron Density Distribution of Donor‐π‐Acceptor Molecules
journal, March 2019


Crystal Structure and IR Spectrum of Diaqua(o-phenanthroline) bis(saccharinato)lead(II)
journal, March 2000


Polymer-templated nucleation and crystal growth of perovskite films for solar cells with efficiency greater than 21%
journal, September 2016


Photoluminescence‐Based Characterization of Halide Perovskites for Photovoltaics
journal, May 2020

  • Kirchartz, Thomas; Márquez, José A.; Stolterfoht, Martin
  • Advanced Energy Materials, Vol. 10, Issue 26
  • DOI: 10.1002/aenm.201904134

Efficient, stable and scalable perovskite solar cells using poly(3-hexylthiophene)
journal, March 2019


Branched methoxydiphenylamine-substituted fluorene derivatives as hole transporting materials for high-performance perovskite solar cells
journal, January 2016

  • Malinauskas, Tadas; Saliba, Michael; Matsui, Taisuke
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C5EE03911H

Mixed 3D-2D Passivation Treatment for Mixed-Cation Lead Mixed-Halide Perovskite Solar Cells for Higher Efficiency and Better Stability
journal, April 2018

  • Cho, Yongyoon; Soufiani, Arman Mahboubi; Yun, Jae Sung
  • Advanced Energy Materials, Vol. 8, Issue 20
  • DOI: 10.1002/aenm.201703392

Cesium power: low Cs + levels impart stability to perovskite solar cells
journal, January 2017

  • Deepa, Melepurath; Salado, Manuel; Calio, Laura
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 5
  • DOI: 10.1039/C6CP08022G

A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells
journal, July 2018


A novel one-step synthesized and dopant-free hole transport material for efficient and stable perovskite solar cells
journal, January 2016

  • Zhao, Xiaoming; Zhang, Fei; Yi, Chenyi
  • Journal of Materials Chemistry A, Vol. 4, Issue 42
  • DOI: 10.1039/C6TA05254A

Dopant-free molecular hole transport material that mediates a 20% power conversion efficiency in a perovskite solar cell
journal, January 2019

  • Cao, Yang; Li, Yunlong; Morrissey, Thomas
  • Energy & Environmental Science, Vol. 12, Issue 12
  • DOI: 10.1039/C9EE02983D

Enhanced photovoltage for inverted planar heterojunction perovskite solar cells
journal, June 2018


Air-Exposure Induced Dopant Redistribution and Energy Level Shifts in Spin-Coated Spiro-MeOTAD Films
journal, January 2015

  • Hawash, Zafer; Ono, Luis K.; Raga, Sonia R.
  • Chemistry of Materials, Vol. 27, Issue 2
  • DOI: 10.1021/cm504022q

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016

  • Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C5EE03874J

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012


Doping strategies for small molecule organic hole-transport materials: impacts on perovskite solar cell performance and stability
journal, January 2019

  • Schloemer, Tracy H.; Christians, Jeffrey A.; Luther, Joseph M.
  • Chemical Science, Vol. 10, Issue 7
  • DOI: 10.1039/C8SC05284K

A generic interface to reduce the efficiency-stability-cost gap of perovskite solar cells
journal, November 2017


Quantitative analysis of the transient photoluminescence of CH 3 NH 3 PbI 3 /PC 61 BM heterojunctions by numerical simulations
journal, January 2018

  • Krogmeier, Benedikt; Staub, Florian; Grabowski, David
  • Sustainable Energy & Fuels, Vol. 2, Issue 5
  • DOI: 10.1039/C7SE00603A

Phenoxazine-Based Small Molecule Material for Efficient Perovskite Solar Cells and Bulk Heterojunction Organic Solar Cells
journal, January 2015


Thermally Stable Perovskite Solar Cells by Systematic Molecular Design of the Hole-Transport Layer
journal, January 2019


Defect Passivation by Amide-Based Hole-Transporting Interfacial Layer Enhanced Perovskite Grain Growth for Efficient p–i–n Perovskite Solar Cells
journal, September 2019

  • Wang, Shin-Yu; Chen, Chih-Ping; Chung, Chung-Lin
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 43
  • DOI: 10.1021/acsami.9b13952

Towards stable and commercially available perovskite solar cells
journal, October 2016


Substantial improvement of perovskite solar cells stability by pinhole-free hole transport layer with doping engineering
journal, May 2015

  • Jung, Min-Cherl; Raga, Sonia R.; Ono, Luis K.
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep09863

Degradation Mechanisms of Solution-Processed Planar Perovskite Solar Cells: Thermally Stimulated Current Measurement for Analysis of Carrier Traps
journal, November 2015

  • Qin, Chuanjiang; Matsushima, Toshinori; Fujihara, Takashi
  • Advanced Materials, Vol. 28, Issue 3
  • DOI: 10.1002/adma.201502610

FeCl 3 as a low-cost and efficient p-type dopant of Spiro-OMeTAD for high performance perovskite solar cells
journal, January 2018


Highly efficient and stable inverted perovskite solar cell employing PEDOT:GO composite layer as a hole transport layer
journal, January 2018


An interface stabilized perovskite solar cell with high stabilized efficiency and low voltage loss
journal, January 2019

  • Yoo, Jason J.; Wieghold, Sarah; Sponseller, Melany C.
  • Energy & Environmental Science, Vol. 12, Issue 7
  • DOI: 10.1039/C9EE00751B

Dithieno[3,2‐b:2′,3′‐d]pyrrol‐Cored Hole Transport Material Enabling Over 21% Efficiency Dopant‐Free Perovskite Solar Cells
journal, July 2019

  • Yin, Xinxing; Zhou, Jie; Song, Zhaoning
  • Advanced Functional Materials, Vol. 29, Issue 38
  • DOI: 10.1002/adfm.201904300

Amino-Functionalized Conjugated Polymer as an Efficient Electron Transport Layer for High-Performance Planar-Heterojunction Perovskite Solar Cells
journal, December 2015


Conjugated Small Molecule for Efficient Hole Transport in High-Performance p-i-n Type Perovskite Solar Cells
journal, July 2017

  • Yang, Liyan; Cai, Feilong; Yan, Yu
  • Advanced Functional Materials, Vol. 27, Issue 31
  • DOI: 10.1002/adfm.201702613