Deep eutectic solvents in separations: Methods of preparation, polarity, and applications in extractions and capillary electrochromatography
Abstract
Deep eutectic solvents (DESs) have emerged as alternatives to conventional organic solvents and ionic liquids (ILs). Their tunable and designer physio-chemical properties, low cost, and ease of preparation make them attractive solvent systems for use in extractions and additives to chromatographic separations. However, due to the diverse range of hydrogen bond acceptors and donors that comprise DESs, choosing the appropriate solvent for separations can be challenging. This work discusses all methods of DES preparation and details their advantages and disadvantages. Since polarity is an important aspect in their use in separations, the classification of DESs based on the betaine dye and nile red scales as well as Kamlet-Taft parameters is also discussed. Finally, a summary of applications of DESs in various extraction processes (phenolics, fuels, metals, proteins, carbohydrates), solid-phase extraction, solid-phase microextraction, as well as capillary electrochromatography is provided.
- Authors:
-
- Ames Lab., and Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; USDOE
- OSTI Identifier:
- 1712674
- Alternate Identifier(s):
- OSTI ID: 1775878
- Report Number(s):
- IS-J-10,360
Journal ID: ISSN 0021-9673
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Chromatography
- Additional Journal Information:
- Journal Volume: 1633; Journal ID: ISSN 0021-9673
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; deep eutectic solvents; separation science; preparation methods; polarity; extractions; capillary electrochromatography
Citation Formats
Farooq, Muhammad Qamar, Abbasi, Nabeel Mujtaba, and Anderson, Jared L. Deep eutectic solvents in separations: Methods of preparation, polarity, and applications in extractions and capillary electrochromatography. United States: N. p., 2020.
Web. doi:10.1016/j.chroma.2020.461613.
Farooq, Muhammad Qamar, Abbasi, Nabeel Mujtaba, & Anderson, Jared L. Deep eutectic solvents in separations: Methods of preparation, polarity, and applications in extractions and capillary electrochromatography. United States. https://doi.org/10.1016/j.chroma.2020.461613
Farooq, Muhammad Qamar, Abbasi, Nabeel Mujtaba, and Anderson, Jared L. Sun .
"Deep eutectic solvents in separations: Methods of preparation, polarity, and applications in extractions and capillary electrochromatography". United States. https://doi.org/10.1016/j.chroma.2020.461613. https://www.osti.gov/servlets/purl/1712674.
@article{osti_1712674,
title = {Deep eutectic solvents in separations: Methods of preparation, polarity, and applications in extractions and capillary electrochromatography},
author = {Farooq, Muhammad Qamar and Abbasi, Nabeel Mujtaba and Anderson, Jared L.},
abstractNote = {Deep eutectic solvents (DESs) have emerged as alternatives to conventional organic solvents and ionic liquids (ILs). Their tunable and designer physio-chemical properties, low cost, and ease of preparation make them attractive solvent systems for use in extractions and additives to chromatographic separations. However, due to the diverse range of hydrogen bond acceptors and donors that comprise DESs, choosing the appropriate solvent for separations can be challenging. This work discusses all methods of DES preparation and details their advantages and disadvantages. Since polarity is an important aspect in their use in separations, the classification of DESs based on the betaine dye and nile red scales as well as Kamlet-Taft parameters is also discussed. Finally, a summary of applications of DESs in various extraction processes (phenolics, fuels, metals, proteins, carbohydrates), solid-phase extraction, solid-phase microextraction, as well as capillary electrochromatography is provided.},
doi = {10.1016/j.chroma.2020.461613},
journal = {Journal of Chromatography},
number = ,
volume = 1633,
place = {United States},
year = {Sun Oct 11 00:00:00 EDT 2020},
month = {Sun Oct 11 00:00:00 EDT 2020}
}
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A polymer monolith incorporating stellate mesoporous silica nanospheres for use in capillary electrochromatography and solid phase microextraction of polycyclic aromatic hydrocarbons and organic small molecules
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Green synthesis of monolithic enzyme microreactor based on thiol-ene click reaction for enzymatic hydrolysis of protein
journal, January 2020
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