Measuring the fast oxidation kinetics of a manganese oxygen carrier using microfluidized bed thermogravimetric analysis

Li, Ye; Li, Zhenshan; Liu, Lei; Cai, Ningsheng

doi:10.1016/j.cej.2019.123970

Title: Measuring the fast oxidation kinetics of a manganese oxygen carrier using microfluidized bed thermogravimetric analysis

Full Record
Other Related Research

Authors:: Li, Ye; Li, Zhenshan; Liu, Lei; Cai, Ningsheng

Publication Date:: 2020-04-01

Sponsoring Org.:: USDOE Office of Electricity (OE), Advanced Grid Research & Development. Power Systems Engineering Research

OSTI Identifier:: 1703919

Grant/Contract Number:: 2017YFE0112500

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Chemical Engineering Journal

Additional Journal Information:: Journal Name: Chemical Engineering Journal Journal Volume: 385 Journal Issue: C; Journal ID: ISSN 1385-8947

Publisher:: Elsevier

Country of Publication:: Switzerland

Language:: English

Citation Formats


                    Li, Ye, Li, Zhenshan, Liu, Lei, and Cai, Ningsheng. Measuring the fast oxidation kinetics of a manganese oxygen carrier using microfluidized bed thermogravimetric analysis.  Switzerland: N. p., 2020. 
Web.  doi:10.1016/j.cej.2019.123970.

Copy to clipboard


                    Li, Ye, Li, Zhenshan, Liu, Lei, & Cai, Ningsheng. Measuring the fast oxidation kinetics of a manganese oxygen carrier using microfluidized bed thermogravimetric analysis.  Switzerland.  https://doi.org/10.1016/j.cej.2019.123970

Copy to clipboard


                    Li, Ye, Li, Zhenshan, Liu, Lei, and Cai, Ningsheng. Wed .  
"Measuring the fast oxidation kinetics of a manganese oxygen carrier using microfluidized bed thermogravimetric analysis".  Switzerland.  https://doi.org/10.1016/j.cej.2019.123970.

Copy to clipboard


                    
@article{osti_1703919,

  title        = {Measuring the fast oxidation kinetics of a manganese oxygen carrier using microfluidized bed thermogravimetric analysis},

  author       = {Li, Ye and Li, Zhenshan and Liu, Lei and Cai, Ningsheng},

  abstractNote = {},

  doi          = {10.1016/j.cej.2019.123970},

  journal      = {Chemical Engineering Journal},

  number       = C,

  volume       = 385,

  place        = {Switzerland},

  year         = {2020},

  month        = {4}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.cej.2019.123970

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Unique phase identification of trimetallic copper iron manganese oxygen carrier using simultaneous differential scanning calorimetry/thermogravimetric analysis during chemical looping combustion reactions with methane

Journal Article Benincosa, William ; Siriwardane, Ranjani ; Tian, Hanjing ; ... - Applied Energy

Chemical looping combustion (CLC) is a promising combustion technology that generates heat and sequestration-ready carbon dioxide that is undiluted by nitrogen from the combustion of carbonaceous fuels with an oxygen carrier, or metal oxide. This process is highly dependent on the reactivity and stability of the oxygen carrier. The development of oxygen carriers remains one of the major barriers for commercialization of CLC. Synthetic oxygen carriers, consisting of multiple metal components, have demonstrated enhanced performance and improved CLC operation compared to single metal oxides. However, identification of the complex mixed metal oxide phases that form after calcination or during CLCmore »« less
https://doi.org/10.1016/j.apenergy.2017.06.061

Full Text Available
Determination of kinetic data for soot oxidation: Modeling of competition between oxygen diffusion and reaction during thermogravimetric analysis

Journal Article Gilot, P ; Bonnefoy, F ; Marcuccilli, F ; ... - Combustion and Flame; (United States)

Kinetic data concerning carbon black oxidation in the temperature range between 600 and 900 C have been obtained using thermogravimetric analysis. Modeling of diffusion in a boundary layer above the pan and inside the porous medium coupled to oxygen reaction with carbon black is necessary to obtain kinetic constants as a function of temperature. These calculations require the knowledge of the oxidation rate at a given constant temperature as a function of the initial mass loading m[sub o]. This oxidation rate, expressed in milligrams of soot consumed per second and per milligram of initial soot loading, decreases when m[sub o]more »« less
https://doi.org/10.1016/0010-2180(93)90054-7
Application of a nonisothermal thermogravimetric method to the kinetic study of the reduction of metallic oxides: Part 2. A theoretical treatment of powder bed reduction and its application to the reduction of tungsten oxide by hydrogen

Journal Article Bustnes, J A ; Sichen, D ; Seetharaman, S - Metallurgical Transactions, B (Process Metallurgy); (United States)

Theoretical treatment of nonisothermal kinetic studies has been extended in the present work to gas-solid reactions in powder beds. An expression for the activation energies for the reaction has been derived on the basis that the reaction proceeds by the movement of the reaction front, the velocity of the movement being kept constant. The reliability of the method has been tested by applying the same to the reduction of tungsten oxide by hydrogen. The experiments were carried out using thermogravimetric technique under both isothermal and nonisothermal conditions. The reaction front is considered to consist of a thin layer of smallmore »« less
https://doi.org/10.1007/BF02666430
Kinetics and mechanism of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 5. The influence of imidazole ligation of (meso-tetrakis(2,6-dimethylphenyl)porphinato)manganese(III) chloride on the rates of oxygen transfer from N-oxide to metalloporphyrin salt and the efficiency of oxidations by the intermediate higher valent manganese-oxo species

Journal Article Wong, W H ; Ostovic, D ; Bruice, T C - J. Am. Chem. Soc.; (United States)

Equilibrium constants for mono- and bisligation of imidazole (ImH) with (meso-tetrakis(2,6-dimethylphenyl)porphinato)manganese(III) chloride ((Me/sub 8/TPP)Mn/sup III/Cl) have been determined so that the concentrations (dry CH/sub 2/Cl/sub 2/) of the three species (Me/sub 8/TPP)Mn/sup III/Cl, ((Me/sub 8/TPP)Mn/sup III/(ImH))Cl, and ((Me/sub 8/TPP)Mn/sup III/(ImH)/sub 2/)Cl may be calculated at different ImH concentrations. The equilibrium constants for ligation of the one and two imidazoles are K/sub 1/ = 245 M/sup -1/ and ..beta../sub 2/ = 1.80 x 10/sup 5/ M/sup -1/. The reaction of p-cyano-N,N-dimethylaniline N-oxide (NO) with the manganese(III)porphyrin (under the pseudo-first-order conditions of (NO)/sub i/ >> ((Me/sub 8/TPP)Mn/sup III/Cl)/sub i/ and in themore »« less
https://doi.org/10.1021/ja00245a039
Hydrogen measurement during steam oxidation using coupled thermogravimetric analysis and quadrupole mass spectrometry

Journal Article Parkison, Adam J. ; Nelson, Andrew Thomas - Measurement

An analytical technique is presented with the goal of measuring reaction kinetics during steam oxidation reactions for three cases in which obtaining kinetics information often requires a prohibitive amount of time and cost. The technique presented relies on coupling thermogravimetric analysis (TGA) with a quantitative hydrogen measurement technique using quadrupole mass spectrometry (QMS). The first case considered is in differentiating between the kinetics of steam oxidation reactions and those for simultaneously reacting gaseous impurities such as nitrogen or oxygen. The second case allows one to independently measure the kinetics of oxide and hydride formation for systems in which both ofmore »« less
Cited by 2
https://doi.org/10.1016/j.measurement.2015.11.043

Full Text Available

Similar Records