Deformation mechanisms in amorphous Ni–Mo–P films coated on CoCrFeNi high-entropy alloys
Abstract
The Ni–Mo–P amorphous films were successfully deposited on the CoCrFeNi high-entropy alloys by electroless plating. This work will focus on reviewing and discussing the ambient-temperature mechanical properties, plastic deformation, and cracking mode of the coating-substrate system. The yielding strength (σy) and ultimate tensile strength (UTS) of the specimen plating for 1 h were 260 and 760 MPa, respectively, with 44.4% (σy) and 14.2% (UTS) improvement contrast to the uncoated HEAs (σy and UTS are 180 MPa and 560 MPa, respectively). It is attributed to the back stress and repulsive image stress to suppress the nucleation and mobility of dislocations. Due to the substrate confinement, the deformation model was gradually changed from cracking (with homogeneous flow) to shear banding (with homogeneous flow). Eventually, fully-homogeneous flows occur with reducing the film thickness, and the deformation mechanism map is developed to expound the transition of the deformation mode. The brittle fracture with a high velocity originating from amorphous films leads to cleavage cracking on the surface of the HEA substrate. The thicker film has higher crack velocity and causes deeper cracks penetration into the substrate, reducing the substrate ductility.
- Authors:
-
- Taiyuan Univ. of Technology (China)
- Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Univ. of Tennessee, Knoxville, TN (United States); Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1799739
- Alternate Identifier(s):
- OSTI ID: 1702874
- Grant/Contract Number:
- FE0008855; FE0011194; FE0024054; FE-0008855; FE-0024054; FE-0011194
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Intermetallics
- Additional Journal Information:
- Journal Volume: 114; Journal ID: ISSN 0966-9795
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; high-entropy alloy; mechanical behavior; deformation mechanisms; Ni–Mo–P amorphous films; shear bands; fracture
Citation Formats
Song, X. T., Guo, R. P., Wang, Z., Wang, X. J., Yang, H. J., Qiao, J. W., Han, L. N., Liaw, P. K., and Wu, Y. C. Deformation mechanisms in amorphous Ni–Mo–P films coated on CoCrFeNi high-entropy alloys. United States: N. p., 2019.
Web. doi:10.1016/j.intermet.2019.106591.
Song, X. T., Guo, R. P., Wang, Z., Wang, X. J., Yang, H. J., Qiao, J. W., Han, L. N., Liaw, P. K., & Wu, Y. C. Deformation mechanisms in amorphous Ni–Mo–P films coated on CoCrFeNi high-entropy alloys. United States. https://doi.org/10.1016/j.intermet.2019.106591
Song, X. T., Guo, R. P., Wang, Z., Wang, X. J., Yang, H. J., Qiao, J. W., Han, L. N., Liaw, P. K., and Wu, Y. C. Wed .
"Deformation mechanisms in amorphous Ni–Mo–P films coated on CoCrFeNi high-entropy alloys". United States. https://doi.org/10.1016/j.intermet.2019.106591. https://www.osti.gov/servlets/purl/1799739.
@article{osti_1799739,
title = {Deformation mechanisms in amorphous Ni–Mo–P films coated on CoCrFeNi high-entropy alloys},
author = {Song, X. T. and Guo, R. P. and Wang, Z. and Wang, X. J. and Yang, H. J. and Qiao, J. W. and Han, L. N. and Liaw, P. K. and Wu, Y. C.},
abstractNote = {The Ni–Mo–P amorphous films were successfully deposited on the CoCrFeNi high-entropy alloys by electroless plating. This work will focus on reviewing and discussing the ambient-temperature mechanical properties, plastic deformation, and cracking mode of the coating-substrate system. The yielding strength (σy) and ultimate tensile strength (UTS) of the specimen plating for 1 h were 260 and 760 MPa, respectively, with 44.4% (σy) and 14.2% (UTS) improvement contrast to the uncoated HEAs (σy and UTS are 180 MPa and 560 MPa, respectively). It is attributed to the back stress and repulsive image stress to suppress the nucleation and mobility of dislocations. Due to the substrate confinement, the deformation model was gradually changed from cracking (with homogeneous flow) to shear banding (with homogeneous flow). Eventually, fully-homogeneous flows occur with reducing the film thickness, and the deformation mechanism map is developed to expound the transition of the deformation mode. The brittle fracture with a high velocity originating from amorphous films leads to cleavage cracking on the surface of the HEA substrate. The thicker film has higher crack velocity and causes deeper cracks penetration into the substrate, reducing the substrate ductility.},
doi = {10.1016/j.intermet.2019.106591},
journal = {Intermetallics},
number = ,
volume = 114,
place = {United States},
year = {Wed Sep 18 00:00:00 EDT 2019},
month = {Wed Sep 18 00:00:00 EDT 2019}
}
Works referenced in this record:
Crack propagation in an elastic solid subjected to general loading—II. Non-uniform rate of extension
journal, June 1972
- Freund, L. B.
- Journal of the Mechanics and Physics of Solids, Vol. 20, Issue 3
Plastic flow and failure resistance of metallic glass: Insight from in situ compression of nanopillars
journal, April 2008
- Shan, Z. W.; Li, J.; Cheng, Y. Q.
- Physical Review B, Vol. 77, Issue 15
Cleavage cracking of ductile-metal substrates induced by brittle coating fracture
journal, June 2018
- Guo, Tao; Chen, Yanmeng; Cao, Ruohan
- Acta Materialia, Vol. 152
Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high entropy alloys
journal, May 2011
- Senkov, O. N.; Wilks, G. B.; Scott, J. M.
- Intermetallics, Vol. 19, Issue 5
The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy
journal, September 2013
- Otto, F.; Dlouhý, A.; Somsen, Ch.
- Acta Materialia, Vol. 61, Issue 15
The relationship between thin film fragmentation and buckle formation: Synchrotron-based in situ studies and two-dimensional stress analysis
journal, March 2009
- Frank, Stephan; Handge, Ulrich A.; Olliges, Sven
- Acta Materialia, Vol. 57, Issue 5
Bending behavior of electrodeposited glassy Pd–P and Pd–Ni–P thin films
journal, April 2013
- Cao, Q. P.; Ma, Y.; Xu, Y.
- Scripta Materialia, Vol. 68, Issue 7
Effects of Ni-P amorphous films on mechanical and corrosion properties of Al 0.3 CoCrFeNi high-entropy alloys
journal, March 2018
- Xia, Z. H.; Zhang, M.; Zhang, Y.
- Intermetallics, Vol. 94
Plasticity enhancement in bulk metallic glasses by electroless plating with Ni-P amorphous films
journal, December 2015
- Ren, L. W.; Wang, Z.; Meng, M. M.
- Journal of Non-Crystalline Solids, Vol. 430
Electroless Ni-P/nano-WO3 coating and its mechanical and corrosion protection properties
journal, November 2018
- Gholizadeh-Gheshlaghi, M.; Seifzadeh, D.; Shoghi, P.
- Journal of Alloys and Compounds, Vol. 769
Interaction of an edge dislocation with a thin-film-covered crack
journal, September 2000
- Zhang, Tong-Yi; Qian, Cai-Fu; Wang, Tianhong
- International Journal of Solids and Structures, Vol. 37, Issue 39
A tensile-film-cracking model for evaluating interfacial shear strength of elastic film on ductile substrate
journal, April 2000
- Chen, B. F.; Hwang, J.; Chen, I. F.
- Surface and Coatings Technology, Vol. 126, Issue 2-3
Compression testing of metallic glass at small length scales: Effects on deformation mode and stability
journal, October 2010
- Bharathula, Ashwini; Lee, Seok-Woo; Wright, Wendelin J.
- Acta Materialia, Vol. 58, Issue 17
Effect of WC–10%Co–4%Cr coating on the Ti–6Al–4V alloy fatigue strength
journal, May 2009
- Costa, M. Y. P.; Venditti, M. L. R.; Voorwald, H. J. C.
- Materials Science and Engineering: A, Vol. 507, Issue 1-2
Fatigue behavior of PVD coated Ti–6Al–4V alloy
journal, June 2011
- Costa, M. Y. P.; Venditti, M. L. R.; Cioffi, M. O. H.
- International Journal of Fatigue, Vol. 33, Issue 6
High temperature brittle film adhesion measured from annealing-induced circular blisters
journal, October 2017
- Guo, Tao; He, Jianying; Pang, Xiaolu
- Acta Materialia, Vol. 138
Microstructure and high-temperature wear mechanism of laser cladded CoCrBFeNiSi high-entropy alloy amorphous coating
journal, January 2018
- Shu, F. Y.; Wu, L.; Zhao, H. Y.
- Materials Letters, Vol. 211
In-situ tensile testing of crystalline diamond coatings using Raman spectroscopy
journal, December 2009
- Ahmed, Furqan; Durst, Karsten; Rosiwal, Stefan
- Surface and Coatings Technology, Vol. 204, Issue 6-7
Intrinsic and extrinsic size effects in the deformation of amorphous CuZr/nanocrystalline Cu nanolaminates
journal, November 2014
- Guo, Wei; Jägle, Eric; Yao, Jiahao
- Acta Materialia, Vol. 80
Stress evolution and cracking of crystalline diamond thin films on ductile titanium substrate: Analysis by micro-Raman spectroscopy and analytical modelling
journal, August 2011
- Ahmed, F.; Bayerlein, K.; Rosiwal, S. M.
- Acta Materialia, Vol. 59, Issue 14
Ductility of thin metal films on polymer substrates modulated by interfacial adhesion
journal, March 2007
- Li, Teng; Suo, Z.
- International Journal of Solids and Structures, Vol. 44, Issue 6
Effects of Ni P coating on mechanical properties of Al0.3CoCrFeNi high-entropy alloys
journal, April 2019
- Song, X. T.; Shi, X. H.; Xia, Z. H.
- Materials Science and Engineering: A, Vol. 752
Tensile ductility and necking of metallic glass
journal, August 2007
- Guo, H.; Yan, P. F.; Wang, Y. B.
- Nature Materials, Vol. 6, Issue 10
High ductility of a metal film adherent on a polymer substrate
journal, October 2005
- Xiang, Yong; Li, Teng; Suo, Zhigang
- Applied Physics Letters, Vol. 87, Issue 16
Evolution of microstructure, mechanical and corrosion properties of AlCoCrFeNi high-entropy alloy prepared by direct laser fabrication
journal, February 2017
- Wang, Rui; Zhang, Kai; Davies, Christopher
- Journal of Alloys and Compounds, Vol. 694
Metal films on polymer substrates stretched beyond 50%
journal, November 2007
- Lu, Nanshu; Wang, Xi; Suo, Zhigang
- Applied Physics Letters, Vol. 91, Issue 22, Article No. 221909
Stress-state-dependent deformation behavior in Ni–Nb metallic glassy film
journal, June 2012
- Ma, Y.; Cao, Q. P.; Qu, S. X.
- Acta Materialia, Vol. 60, Issue 10
Cracking and decohesion of a thin Al2O3 film on a ductile Al–5%Mg substrate
journal, January 2005
- Xie, Changjin; Tong, Wei
- Acta Materialia, Vol. 53, Issue 2
Failure of metals I: Brittle and ductile fracture
journal, April 2016
- Pineau, A.; Benzerga, A. A.; Pardoen, T.
- Acta Materialia, Vol. 107
Co-existence of homogeneous flow and localized plastic deformation in tension of amorphous Ni–P films on ductile substrate
journal, March 2016
- Lu, X. L.; Li, Y.; Lu, L.
- Acta Materialia, Vol. 106
Transition from a strong-yet-brittle to a stronger-and-ductile state by size reduction of metallic glasses
journal, February 2010
- Jang, Dongchan; Greer, Julia R.
- Nature Materials, Vol. 9, Issue 3
Duplex coatings with enhanced adhesion to Ti alloy substrate prepared by powder immersion nitriding and TiN/Ti multilayer deposition
journal, October 2015
- Avelar-Batista Wilson, J. C.; Wu, Shoujun; Gotman, I.
- Materials Letters, Vol. 157
Substrate cracking in Ti-6Al-4V driven by pulsed laser irradiation and oxidation
journal, August 2017
- Espejo, Héctor M.; Bahr, David F.
- Surface and Coatings Technology, Vol. 322
Mixed Mode Cracking in Layered Materials
book, January 1991
- Hutchinson, J. W.; Suo, Z.
- Advances in Applied Mechanics, Vol. 29, p. 63-191
Apparently homogeneous but intrinsically intermittent flow of taper-free metallic glass nanopillars
journal, December 2012
- Chen, C. Q.; Pei, Y. T.; De Hosson, J. Th. M.
- Scripta Materialia, Vol. 67, Issue 12
Stress concentration formula useful for all notch shape in a round bar (comparison between torsion, tension and bending)
journal, February 2006
- Noda, N.; Takase, Y.
- International Journal of Fatigue, Vol. 28, Issue 2
Theory of strengthening in fcc high entropy alloys
journal, October 2016
- Varvenne, Céline; Luque, Aitor; Curtin, William A.
- Acta Materialia, Vol. 118
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004
- Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
- Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
Enhancement of mechanical and electrochemical properties of Al0.25CrCoFe1.25Ni1.25 high-entropy alloys by coating Ni–P amorphous films
journal, March 2016
- Qiao, J. W.; Wang, Z.; Ren, L. W.
- Materials Science and Engineering: A, Vol. 657
Solid-Solution Phase Formation Rules for Multi-component Alloys
journal, June 2008
- Zhang, Y.; Zhou, Y. J.; Lin, J. P.
- Advanced Engineering Materials, Vol. 10, Issue 6, p. 534-538
Brittle versus ductile behaviour of nanotwinned copper: A molecular dynamics study
journal, May 2015
- Pei, Linqing; Lu, Cheng; Zhao, Xing
- Acta Materialia, Vol. 89
Brittle film-induced cracking of ductile substrates
journal, October 2015
- Guo, Tao; Qiao, Lijie; Pang, Xiaolu
- Acta Materialia, Vol. 99
Gradient Confinement Induced Uniform Tensile Ductility in Metallic Glass
journal, November 2013
- Lu, X. L.; Lu, Q. H.; Li, Y.
- Scientific Reports, Vol. 3, Issue 1
Electroless plating Ni-P cocatalyst decorated g-C3N4 with enhanced photocatalytic water splitting for H2 generation
journal, February 2019
- Qi, Kezhen; Xie, Yubo; Wang, Ruidan
- Applied Surface Science, Vol. 466
Effect of temperature and strain rate on deformation behavior in metallic glassy films
journal, June 2014
- Cao, Q. P.; Ma, Y.; Wang, C.
- Thin Solid Films, Vol. 561
Length-scale-dependent cracking and buckling behaviors of nanostructured Cu/Cr multilayer films on compliant substrates
journal, November 2015
- Wu, K.; Zhang, J. Y.; Li, J.
- Acta Materialia, Vol. 100
Brittle behavior of ductile metals during stress-corrosion cracking
journal, January 1985
- Sieradzki, K.; Newman, R. C.
- Philosophical Magazine A, Vol. 51, Issue 1
Effects of size on the mechanical response of metallic glasses investigated through in situ TEM bending and compression experiments
journal, January 2010
- Chen, C. Q.; Pei, Y. T.; De Hosson, J. T. M.
- Acta Materialia, Vol. 58, Issue 1
Effect of structural relaxation on plastic flow in a Ni–Nb metallic glassy film
journal, May 2012
- Ma, Y.; Cao, Q. P.; Qu, S. X.
- Acta Materialia, Vol. 60, Issue 8