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Title: Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks

Abstract

This work showcases the first instance of cooperative photoelectrochemical oxidation within a chromophore/catalyst-incorporated metal–organic framework.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, Virginia Tech, Blacksburg, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1690284
Grant/Contract Number:  
SC0012445
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Faraday Discussions
Additional Journal Information:
Journal Name: Faraday Discussions; Journal ID: ISSN 1359-6640
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lin, Shaoyang, Cairnie, Daniel R., Davis, Dylan, Chakraborty, Arnab, Cai, Meng, and Morris, Amanda J.. Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks. United Kingdom: N. p., 2021. Web. https://doi.org/10.1039/D0FD00021C.
Lin, Shaoyang, Cairnie, Daniel R., Davis, Dylan, Chakraborty, Arnab, Cai, Meng, & Morris, Amanda J.. Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks. United Kingdom. https://doi.org/10.1039/D0FD00021C
Lin, Shaoyang, Cairnie, Daniel R., Davis, Dylan, Chakraborty, Arnab, Cai, Meng, and Morris, Amanda J.. Fri . "Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks". United Kingdom. https://doi.org/10.1039/D0FD00021C.
@article{osti_1690284,
title = {Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks},
author = {Lin, Shaoyang and Cairnie, Daniel R. and Davis, Dylan and Chakraborty, Arnab and Cai, Meng and Morris, Amanda J.},
abstractNote = {This work showcases the first instance of cooperative photoelectrochemical oxidation within a chromophore/catalyst-incorporated metal–organic framework.},
doi = {10.1039/D0FD00021C},
journal = {Faraday Discussions},
number = ,
volume = ,
place = {United Kingdom},
year = {2021},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/D0FD00021C

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Works referenced in this record:

Real-Time Visualization of Active Species in a Single-Site Metal–Organic Framework Photocatalyst
journal, February 2018


Fundamental Insights into Photoelectrocatalytic Hydrogen Production with a Hole-Transport Bismuth Metal–Organic Framework
journal, December 2019

  • García-Sánchez, Alba; Gomez-Mendoza, Miguel; Barawi, Mariam
  • Journal of the American Chemical Society, Vol. 142, Issue 1
  • DOI: 10.1021/jacs.9b10261

Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis
journal, August 2011

  • Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E.
  • Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454
  • DOI: 10.1021/ja203564w

Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells
journal, September 2016

  • Brennaman, M. Kyle; Dillon, Robert J.; Alibabaei, Leila
  • Journal of the American Chemical Society, Vol. 138, Issue 40
  • DOI: 10.1021/jacs.6b06466

Metal–organic framework materials for light-harvesting and energy transfer
journal, January 2015

  • So, Monica C.; Wiederrecht, Gary P.; Mondloch, Joseph E.
  • Chemical Communications, Vol. 51, Issue 17
  • DOI: 10.1039/C4CC09596K

Unexpected Roles of Triethanolamine in the Photochemical Reduction of CO 2 to Formate by Ruthenium Complexes
journal, December 2019

  • Sampaio, Renato N.; Grills, David C.; Polyansky, Dmitry E.
  • Journal of the American Chemical Society, Vol. 142, Issue 5
  • DOI: 10.1021/jacs.9b11897

Conformal coating of ultrathin metal-organic framework on semiconductor electrode for boosted photoelectrochemical water oxidation
journal, December 2018


Visible Region Photooxidation on TiO 2 with a Chromophore−Catalyst Molecular Assembly
journal, October 1999

  • Treadway, Joseph A.; Moss, John A.; Meyer, Thomas J.
  • Inorganic Chemistry, Vol. 38, Issue 20
  • DOI: 10.1021/ic990466m

Photoinduced Electron Transfer in a Chromophore–Catalyst Assembly Anchored to TiO 2
journal, November 2012

  • Ashford, Dennis L.; Song, Wenjing; Concepcion, Javier J.
  • Journal of the American Chemical Society, Vol. 134, Issue 46
  • DOI: 10.1021/ja3084362

Photosensitizing Metal–Organic Layers for Efficient Sunlight-Driven Carbon Dioxide Reduction
journal, September 2018

  • Lan, Guangxu; Li, Zhe; Veroneau, Samuel S.
  • Journal of the American Chemical Society, Vol. 140, Issue 39
  • DOI: 10.1021/jacs.8b08357

Nonthermalized Electron Transport in Dye-Sensitized Nanocrystalline TiO 2 Films:  Transient Photocurrent and Random-Walk Modeling Studies
journal, November 2001

  • van de Lagemaat, J.; Frank, A. J.
  • The Journal of Physical Chemistry B, Vol. 105, Issue 45
  • DOI: 10.1021/jp0118468

The mechanism behind the beneficial effect of light soaking on injection efficiency and photocurrent in dye sensitized solar cells
journal, January 2011

  • Listorti, Andrea; Creager, Charlotte; Sommeling, Paul
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01443a

Photochemical Reduction of Low Concentrations of CO 2 in a Porous Coordination Polymer with a Ruthenium(II)-CO Complex
journal, January 2016

  • Kajiwara, Takashi; Fujii, Machiko; Tsujimoto, Masahiko
  • Angewandte Chemie International Edition, Vol. 55, Issue 8
  • DOI: 10.1002/anie.201508941

Reductive Electron Transfer Quenching of MLCT Excited States Bound To Nanostructured Metal Oxide Thin Films
journal, January 2003

  • Bergeron, Bryan V.; Meyer, Gerald J.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 1
  • DOI: 10.1021/jp026823n

Rethinking Band Bending at the P3HT–TiO 2 Interface
journal, March 2014

  • Haring, Andrew J.; Ahrenholtz, Spencer R.; Morris, Amanda J.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 6
  • DOI: 10.1021/am500101u

Elucidating Charge Separation Dynamics in a Hybrid Metal–Organic Framework Photocatalyst for Light-Driven H 2 Evolution
journal, February 2018

  • Yang, Sizhuo; Fan, Donghua; Hu, Wenhui
  • The Journal of Physical Chemistry C, Vol. 122, Issue 6
  • DOI: 10.1021/acs.jpcc.8b00471

Self-Healing of Molecular Catalyst and Photosensitizer on Metal–Organic Framework: Robust Molecular System for Photocatalytic H 2 Evolution from Water
journal, July 2016

  • Kim, Dongha; Whang, Dong Ryeol; Park, Soo Young
  • Journal of the American Chemical Society, Vol. 138, Issue 28
  • DOI: 10.1021/jacs.6b04552

Electrochemical Water Oxidation by a Catalyst-Modified Metal-Organic Framework Thin Film
journal, December 2016

  • Lin, Shaoyang; Pineda-Galvan, Yuliana; Maza, William A.
  • ChemSusChem, Vol. 10, Issue 3
  • DOI: 10.1002/cssc.201601181

Photocatalytic CO 2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal–Organic Framework
journal, July 2015


Concentration Dependent Dimensionality of Resonance Energy Transfer in a Postsynthetically Doped Morphologically Homologous Analogue of UiO-67 MOF with a Ruthenium(II) Polypyridyl Complex
journal, June 2015

  • Maza, William A.; Padilla, Roberto; Morris, Amanda J.
  • Journal of the American Chemical Society, Vol. 137, Issue 25
  • DOI: 10.1021/jacs.5b03071

Ruthenium( ii )-polypyridyl zirconium( iv ) metal–organic frameworks as a new class of sensitized solar cells
journal, January 2016

  • Maza, W. A.; Haring, A. J.; Ahrenholtz, S. R.
  • Chemical Science, Vol. 7, Issue 1
  • DOI: 10.1039/C5SC01565K

Solvothermal Growth and Photophysical Characterization of a Ruthenium(II) Tris(2,2′-Bipyridine)-Doped Zirconium UiO-67 Metal Organic Framework Thin Film
journal, June 2014

  • Maza, William A.; Ahrenholtz, Spencer R.; Epley, Charity C.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 26
  • DOI: 10.1021/jp5034195

Metal–organic frameworks for artificial photosynthesis via photoelectrochemical route
journal, October 2019


Insight into Metal-Organic Framework Reactivity: Chemical Water Oxidation Catalyzed by a [Ru(tpy)(dcbpy)(OH 2 )] 2+ -Modified UiO-67
journal, January 2018


Construction of a Stable Ru–Re Hybrid System Based on Multifunctional MOF-253 for Efficient Photocatalytic CO 2 Reduction
journal, June 2018


Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues
journal, October 1982


TiO 2 Surface Functionalization to Control the Density of States
journal, October 2008

  • Morris, Amanda J.; Meyer, Gerald J.
  • The Journal of Physical Chemistry C, Vol. 112, Issue 46
  • DOI: 10.1021/jp801338y

Light-harvesting and energy transfer in ruthenium(II)-polypyridyl doped zirconium(IV) metal-organic frameworks: A look toward solar cell applications
journal, July 2017


Photophysical Characterization of a Ruthenium(II) Tris(2,2′-bipyridine)-Doped Zirconium UiO-67 Metal–Organic Framework
journal, April 2014

  • Maza, William A.; Morris, Amanda J.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 17
  • DOI: 10.1021/jp501140r

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

The role of redox hopping in metal–organic framework electrocatalysis
journal, January 2018

  • Lin, Shaoyang; Usov, Pavel M.; Morris, Amanda J.
  • Chemical Communications, Vol. 54, Issue 51
  • DOI: 10.1039/C8CC01664J

A review on metal-organic frameworks for photoelectrocatalytic applications
journal, July 2020


Watching Photoactivation in a Ru(II) Chromophore–Catalyst Assembly on TiO 2 by Ultrafast Spectroscopy
journal, November 2013

  • Wang, Li; Ashford, Dennis L.; Thompson, David W.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 46
  • DOI: 10.1021/jp410571x

Excited State Electron Transfer from Ru(II) Polypyridyl Complexes Anchored to Nanocrystalline TiO 2 through Rigid-Rod Linkers
journal, October 2004

  • Wang, Dong; Mendelsohn, Richard; Galoppini, Elena
  • The Journal of Physical Chemistry B, Vol. 108, Issue 43
  • DOI: 10.1021/jp047454t