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Title: Titanosilicate zeolite precursors for highly efficient oxidation reactions

Abstract

Titanosilicate zeolites are catalysts of interest in the field of fine chemicals. However, the generation and accessibility of active sites in titanosilicate materials for catalyzing reactions with large molecules is still a challenge. Herein, we prepared titanosilicate zeolite precursors with open zeolitic structures, tunable pore sizes, and controllable Si/Ti ratios through a hydrothermal crystallization strategy by using quaternary ammonium templates. A series of quaternary ammonium ions are discovered as effective organic templates. The prepared amorphous titanosilicate zeolites with some zeolite framework structural order have extra-large micropores and abundant octahedrally coordinated isolated Ti species, which lead to a superior catalytic performance in the oxidative desulfurization of dibenzothiophene (DBT) and epoxidation of cyclohexene. It is anticipated that the amorphous prezeolitic titanosilicates will benefit the catalytic conversion of bulky molecules in a wide range of reaction processes.

Authors:
ORCiD logo [1];  [2];  [1];  [1];  [1]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [2]; ORCiD logo [1]
  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
  2. Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, 46022 Valencia, Spain
  3. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  4. Department of Chemistry, Dalhousie University, Halifax, Canada
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1686194
Alternate Identifier(s):
OSTI ID: 1816481
Grant/Contract Number:  
DEAC02-06CH11357; AC02-06CH11357
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 11 Journal Issue: 45; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Bai, Risheng, Navarro, M. Teresa, Song, Yue, Zhang, Tianjun, Zou, Yongcun, Feng, Zhaochi, Zhang, Peng, Corma, Avelino, and Yu, Jihong. Titanosilicate zeolite precursors for highly efficient oxidation reactions. United Kingdom: N. p., 2020. Web. https://doi.org/10.1039/D0SC04603E.
Bai, Risheng, Navarro, M. Teresa, Song, Yue, Zhang, Tianjun, Zou, Yongcun, Feng, Zhaochi, Zhang, Peng, Corma, Avelino, & Yu, Jihong. Titanosilicate zeolite precursors for highly efficient oxidation reactions. United Kingdom. https://doi.org/10.1039/D0SC04603E
Bai, Risheng, Navarro, M. Teresa, Song, Yue, Zhang, Tianjun, Zou, Yongcun, Feng, Zhaochi, Zhang, Peng, Corma, Avelino, and Yu, Jihong. Wed . "Titanosilicate zeolite precursors for highly efficient oxidation reactions". United Kingdom. https://doi.org/10.1039/D0SC04603E.
@article{osti_1686194,
title = {Titanosilicate zeolite precursors for highly efficient oxidation reactions},
author = {Bai, Risheng and Navarro, M. Teresa and Song, Yue and Zhang, Tianjun and Zou, Yongcun and Feng, Zhaochi and Zhang, Peng and Corma, Avelino and Yu, Jihong},
abstractNote = {Titanosilicate zeolites are catalysts of interest in the field of fine chemicals. However, the generation and accessibility of active sites in titanosilicate materials for catalyzing reactions with large molecules is still a challenge. Herein, we prepared titanosilicate zeolite precursors with open zeolitic structures, tunable pore sizes, and controllable Si/Ti ratios through a hydrothermal crystallization strategy by using quaternary ammonium templates. A series of quaternary ammonium ions are discovered as effective organic templates. The prepared amorphous titanosilicate zeolites with some zeolite framework structural order have extra-large micropores and abundant octahedrally coordinated isolated Ti species, which lead to a superior catalytic performance in the oxidative desulfurization of dibenzothiophene (DBT) and epoxidation of cyclohexene. It is anticipated that the amorphous prezeolitic titanosilicates will benefit the catalytic conversion of bulky molecules in a wide range of reaction processes.},
doi = {10.1039/D0SC04603E},
journal = {Chemical Science},
number = 45,
volume = 11,
place = {United Kingdom},
year = {2020},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/D0SC04603E

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