Self-assembly for electronics

Kagan, Cherie R.; Hyeon, Taeghwan; Kim, Dae-Hyeong; Ruiz, Ricardo; Tung, Maryann C.; Wong, H.-S. Philip

doi:10.1557/mrs.2020.248

Title: Self-assembly for electronics

Abstract

Self-assembly, a process in which molecules, polymers, and particles are driven by local interactions to organize into patterns and functional structures, is being exploited in advancing silicon electronics and in emerging, unconventional electronics. Additionally, silicon electronics has relied on lithographic patterning of polymer resists at progressively smaller lengths to scale down device dimensions. Yet, this has become increasingly difficult and costly. Assembly of block copolymers and colloidal nanoparticles allows resolution enhancement and the definition of essential shapes to pattern circuits and memory devices. As we look to a future in which electronics are integrated at large numbers and in new forms for the Internet of Things and wearable and implantable technologies, we also explore a broader material set. Semiconductor nanoparticles and biomolecules are prized for their size-, shape-, and composition-dependent properties and for their solution-based assembly and integration into devices that are enabling unconventional manufacturing and new device functions.

Authors:

Kagan, Cherie R. ^[1]; Hyeon, Taeghwan ^[2]; Kim, Dae-Hyeong ^[2]; Ruiz, Ricardo ^[3]; Tung, Maryann C. ^[4]; Wong, H.-S. Philip ^[4]

Univ. of Pennsylvania, Philadelphia, PA (United States)
Seoul National Univ. (South Korea). Center for Nanoparticle Research of the Inst. for Basic Science
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Stanford Univ., CA (United States)

Publication Date:: 2020-10-09

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1671767

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: MRS Bulletin

Additional Journal Information:: Journal Volume: 45; Journal Issue: 10; Journal ID: ISSN 0883-7694

Publisher:: Materials Research Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Kagan, Cherie R., Hyeon, Taeghwan, Kim, Dae-Hyeong, Ruiz, Ricardo, Tung, Maryann C., and Wong, H.-S. Philip. Self-assembly for electronics.  United States: N. p., 2020. 
Web.  doi:10.1557/mrs.2020.248.

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                    Kagan, Cherie R., Hyeon, Taeghwan, Kim, Dae-Hyeong, Ruiz, Ricardo, Tung, Maryann C., & Wong, H.-S. Philip. Self-assembly for electronics.  United States.  https://doi.org/10.1557/mrs.2020.248

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                    Kagan, Cherie R., Hyeon, Taeghwan, Kim, Dae-Hyeong, Ruiz, Ricardo, Tung, Maryann C., and Wong, H.-S. Philip. Fri .  
"Self-assembly for electronics".  United States.  https://doi.org/10.1557/mrs.2020.248.  https://www.osti.gov/servlets/purl/1671767.

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@article{osti_1671767,

  title        = {Self-assembly for electronics},

  author       = {Kagan, Cherie R. and Hyeon, Taeghwan and Kim, Dae-Hyeong and Ruiz, Ricardo and Tung, Maryann C. and Wong, H.-S. Philip},

  abstractNote = {Self-assembly, a process in which molecules, polymers, and particles are driven by local interactions to organize into patterns and functional structures, is being exploited in advancing silicon electronics and in emerging, unconventional electronics. Additionally, silicon electronics has relied on lithographic patterning of polymer resists at progressively smaller lengths to scale down device dimensions. Yet, this has become increasingly difficult and costly. Assembly of block copolymers and colloidal nanoparticles allows resolution enhancement and the definition of essential shapes to pattern circuits and memory devices. As we look to a future in which electronics are integrated at large numbers and in new forms for the Internet of Things and wearable and implantable technologies, we also explore a broader material set. Semiconductor nanoparticles and biomolecules are prized for their size-, shape-, and composition-dependent properties and for their solution-based assembly and integration into devices that are enabling unconventional manufacturing and new device functions.},

  doi          = {10.1557/mrs.2020.248},

  journal      = {MRS Bulletin},

  number       = 10,

  volume       = 45,

  place        = {United States},

  year         = {2020},

  month        = {10}

}

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Title: Self-assembly for electronics

Abstract

Citation Formats

Fabrication of Lithographically Defined Chemically Patterned Polymer Brushes and Mats journal, April 2011

Block Copolymer Lithography journal, November 2013

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Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals journal, December 2015

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Flexible colloidal nanocrystal electronics journal, January 2019

Surface affinity role in graphoepitaxy of lamellar block copolymers journal, July 2016

Path to Move Beyond the Resolution Limit with Directed Self-Assembly journal, May 2019

Roadmap on biological pathways for electronic nanofabrication and materials journal, January 2019

Extremely Vivid, Highly Transparent, and Ultrathin Quantum Dot Light-Emitting Diodes journal, October 2017

Double-Patterned Sidewall Directed Self-Assembly and Pattern Transfer of Sub-10 nm PTMSS- b -PMOST journal, June 2015

Pattern transfer with stabilized nanoparticle etch masks journal, February 2013

Polarity-Switching Top Coats Enable Orientation of Sub-10-nm Block Copolymer Domains journal, November 2012

Optimized Assembly and Covalent Coupling of Single-Molecule DNA Origami Nanoarrays journal, November 2014

Transfer of self-aligned spacer patterns for single-digit nanofabrication journal, February 2015

Large Area Directed Self-Assembly of Sub-10 nm Particles with Single Particle Positioning Resolution journal, August 2015

Charge transport in strongly coupled quantum dot solids journal, November 2015

Ultrathin Quantum Dot Display Integrated with Wearable Electronics journal, August 2017

Two-Dimensional Pattern Formation Using Graphoepitaxy of PS- b -PMMA Block Copolymers for Advanced FinFET Device and Circuit Fabrication journal, April 2014

Multifunctional wearable devices for diagnosis and therapy of movement disorders journal, March 2014

Designed Assembly and Integration of Colloidal Nanocrystals for Device Applications journal, December 2015

Stretchable Heater Using Ligand-Exchanged Silver Nanowire Nanocomposite for Wearable Articular Thermotherapy journal, May 2015

A wearable multiplexed silicon nonvolatile memory array using nanocrystal charge confinement journal, January 2016

Band-like transport, high electron mobility and high photoconductivity in all-inorganic nanocrystal arrays journal, April 2011

Surface Assembly Configurations and Packing Preferences of Fibrinogen Mediated by the Periodicity and Alignment Control of Block Copolymer Nanodomains journal, July 2016

Self-Assembly of Colloidal Nanocrystals: From Intricate Structures to Functional Materials journal, August 2016

Bandlike Transport in Strongly Coupled and Doped Quantum Dot Solids: A Route to High-Performance Thin-Film Electronics journal, April 2012

Recent Advances in Flexible and Stretchable Bio-Electronic Devices Integrated with Nanomaterials journal, January 2016

Directed Self-Assembly of Cylinder-Forming Block Copolymers: Prepatterning Effect on Pattern Quality and Density Multiplication Factor journal, November 2009

Epicardial Mesh Electronics: Stretchable Low‐Impedance Nanocomposite Comprised of Ag–Au Core–Shell Nanowires and Pt Black for Epicardial Recording and Stimulation (Adv. Mater. Technol. 3/2020) journal, January 2020

Implementation of surface energy modification in graphoepitaxy directed self-assembly for hole multiplication journal, November 2015

Fabrication of Lithographically Defined Chemically Patterned Polymer Brushes and Mats
journal, April 2011

Block Copolymer Lithography
journal, November 2013

Heat-assisted magnetic recording media materials
journal, February 2018

Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals
journal, December 2015

The quest for miniaturized soft bioelectronic devices
journal, March 2017

Colloidal Synthesis of Uniform-Sized Molybdenum Disulfide Nanosheets for Wafer-Scale Flexible Nonvolatile Memory
journal, August 2016

Three-Tone Chemical Patterns for Block Copolymer Directed Self-Assembly
journal, January 2016

Directed Self-Assembly and Pattern Transfer of Five Nanometer Block Copolymer Lamellae
journal, July 2017

Synthesis, assembly and applications of semiconductor nanomembranes
journal, September 2011

Human eye-inspired soft optoelectronic device using high-density MoS2-graphene curved image sensor array
journal, November 2017

Flexible, sticky, and biodegradable wireless device for drug delivery to brain tumors
journal, November 2019

III–V Nanocrystals Capped with Molecular Metal Chalcogenide Ligands: High Electron Mobility and Ambipolar Photoresponse
journal, January 2013

Large scale and integrated platform for digital mass culture of anchorage dependent cells
journal, October 2019

Fabrication of Nanoparticle Films Applying Directed Self-assembly
journal, January 2015

A General Design Strategy for Block Copolymer Directed Self-Assembly Patterning of Integrated Circuits Contact Holes using an Alphabet Approach
journal, January 2015

High-Aspect-Ratio Perpendicular Orientation of PS- b -PDMS Thin Films under Solvent Annealing
journal, October 2012

Directed self-assembly of high-chi block copolymer for nano fabrication of bit patterned media via solvent annealing
journal, September 2016

Density Multiplication and Improved Lithography by Directed Block Copolymer Assembly
journal, August 2008

Directed self-assembly of block copolymers for next generation nanolithography
journal, December 2013

Dense Self-Assembly on Sparse Chemical Patterns: Rectifying and Multiplying Lithographic Patterns Using Block Copolymers
journal, August 2008

The Limits of Lamellae-Forming PS- b -PMMA Block Copolymers for Lithography
journal, June 2015

Fabrication of templates with rectangular bits on circular tracks by combining block copolymer directed self-assembly and nanoimprint lithography
journal, July 2012

A Route to Nanoscopic Materials via Sequential Infiltration Synthesis on Block Copolymer Templates
journal, May 2011

Wearable red–green–blue quantum dot light-emitting diode array using high-resolution intaglio transfer printing
journal, May 2015

Self-Assembly and Directed Assembly of Polymer Grafted Nanocrystals via Solvent Annealing
journal, December 2017

Integration of nanoimprint lithography with block copolymer directed self-assembly for fabrication of a sub-20 nm template for bit-patterned media
journal, September 2014

Servo-Integrated Patterned Media by Hybrid Directed Self-Assembly
journal, November 2014

Fabrication of servo-integrated template for 1.5 Teradot/inch ² bit patterned media with block copolymer directed assembly
journal, July 2014

Chemically Tailored Dielectric-to-Metal Transition for the Design of Metamaterials from Nanoimprinted Colloidal Nanocrystals
journal, December 2012

Highly conductive, stretchable and biocompatible Ag–Au core–sheath nanowire composite for wearable and implantable bioelectronics
journal, August 2018

Symmetry Transitions of Polymer-Grafted Nanoparticles: Grafting Density Effect
journal, June 2019

A graphene-based electrochemical device with thermoresponsive microneedles for diabetes monitoring and therapy
journal, March 2016

Flexible, High-Speed CdSe Nanocrystal Integrated Circuits
journal, September 2015

Preparation of Ordered Monolayers of Polymer Grafted Nanoparticles: Impact of Architecture, Concentration, and Substrate Surface Energy
journal, February 2016

Block Copolymers—Designer Soft Materials
journal, February 1999

The surface science of nanocrystals
journal, January 2016

Synthesis of Semiconductor Nanocrystals, Focusing on Nontoxic and Earth-Abundant Materials
journal, July 2016

Flexible colloidal nanocrystal electronics
journal, January 2019

Surface affinity role in graphoepitaxy of lamellar block copolymers
journal, July 2016

Path to Move Beyond the Resolution Limit with Directed Self-Assembly
journal, May 2019

Roadmap on biological pathways for electronic nanofabrication and materials
journal, January 2019

Extremely Vivid, Highly Transparent, and Ultrathin Quantum Dot Light-Emitting Diodes
journal, October 2017

Double-Patterned Sidewall Directed Self-Assembly and Pattern Transfer of Sub-10 nm PTMSS- b -PMOST
journal, June 2015

Pattern transfer with stabilized nanoparticle etch masks
journal, February 2013

Polarity-Switching Top Coats Enable Orientation of Sub-10-nm Block Copolymer Domains
journal, November 2012

Optimized Assembly and Covalent Coupling of Single-Molecule DNA Origami Nanoarrays
journal, November 2014

Transfer of self-aligned spacer patterns for single-digit nanofabrication
journal, February 2015

Large Area Directed Self-Assembly of Sub-10 nm Particles with Single Particle Positioning Resolution
journal, August 2015

Charge transport in strongly coupled quantum dot solids
journal, November 2015

Ultrathin Quantum Dot Display Integrated with Wearable Electronics
journal, August 2017

Two-Dimensional Pattern Formation Using Graphoepitaxy of PS- b -PMMA Block Copolymers for Advanced FinFET Device and Circuit Fabrication
journal, April 2014

Multifunctional wearable devices for diagnosis and therapy of movement disorders
journal, March 2014

Designed Assembly and Integration of Colloidal Nanocrystals for Device Applications
journal, December 2015

Stretchable Heater Using Ligand-Exchanged Silver Nanowire Nanocomposite for Wearable Articular Thermotherapy
journal, May 2015

A wearable multiplexed silicon nonvolatile memory array using nanocrystal charge confinement
journal, January 2016

Band-like transport, high electron mobility and high photoconductivity in all-inorganic nanocrystal arrays
journal, April 2011

Surface Assembly Configurations and Packing Preferences of Fibrinogen Mediated by the Periodicity and Alignment Control of Block Copolymer Nanodomains
journal, July 2016

Self-Assembly of Colloidal Nanocrystals: From Intricate Structures to Functional Materials
journal, August 2016

Bandlike Transport in Strongly Coupled and Doped Quantum Dot Solids: A Route to High-Performance Thin-Film Electronics
journal, April 2012

Recent Advances in Flexible and Stretchable Bio-Electronic Devices Integrated with Nanomaterials
journal, January 2016

Directed Self-Assembly of Cylinder-Forming Block Copolymers: Prepatterning Effect on Pattern Quality and Density Multiplication Factor
journal, November 2009

Epicardial Mesh Electronics: Stretchable Low‐Impedance Nanocomposite Comprised of Ag–Au Core–Shell Nanowires and Pt Black for Epicardial Recording and Stimulation (Adv. Mater. Technol. 3/2020)
journal, January 2020

Implementation of surface energy modification in graphoepitaxy directed self-assembly for hole multiplication
journal, November 2015