Self-assembly of mono- and poly-dispersed nanoparticles on emulsion droplets: antagonistic vs. synergistic effects as a function of particle size

Khedr, Abeer; Striolo, Alberto

doi:10.1039/D0CP02588G

Title: Self-assembly of mono- and poly-dispersed nanoparticles on emulsion droplets: antagonistic vs. synergistic effects as a function of particle size

Abstract

In this work, using dissipative particle dynamics simulations, we provide fundamental insights into the self-assembly of nanoparticles (NPs) on oil droplet surfaces.

Authors:

Khedr, Abeer ^[1];

^[1]

Department of Chemical Engineering, University College London, UK

Publication Date:: 2020-10-15

Sponsoring Org.:: USDOE

OSTI Identifier:: 1670221

Grant/Contract Number:: AC0205CH11231

Resource Type:: Published Article

Journal Name:: Physical Chemistry Chemical Physics. PCCP (Print)

Additional Journal Information:: Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Volume: 22 Journal Issue: 39; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Khedr, Abeer, and Striolo, Alberto. Self-assembly of mono- and poly-dispersed nanoparticles on emulsion droplets: antagonistic vs. synergistic effects as a function of particle size.  United Kingdom: N. p., 2020. 
Web.  doi:10.1039/D0CP02588G.

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                    Khedr, Abeer, & Striolo, Alberto. Self-assembly of mono- and poly-dispersed nanoparticles on emulsion droplets: antagonistic vs. synergistic effects as a function of particle size.  United Kingdom.  https://doi.org/10.1039/D0CP02588G

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                    Khedr, Abeer, and Striolo, Alberto. Thu .  
"Self-assembly of mono- and poly-dispersed nanoparticles on emulsion droplets: antagonistic vs. synergistic effects as a function of particle size".  United Kingdom.  https://doi.org/10.1039/D0CP02588G.

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@article{osti_1670221,

  title        = {Self-assembly of mono- and poly-dispersed nanoparticles on emulsion droplets: antagonistic vs. synergistic effects as a function of particle size},

  author       = {Khedr, Abeer and Striolo, Alberto},

  abstractNote = {In this work, using dissipative particle dynamics simulations, we provide fundamental insights into the self-assembly of nanoparticles (NPs) on oil droplet surfaces.},

  doi          = {10.1039/D0CP02588G},

  journal      = {Physical Chemistry Chemical Physics. PCCP (Print)},

  number       = 39,

  volume       = 22,

  place        = {United Kingdom},

  year         = {2020},

  month        = {10}

}

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Title: Self-assembly of mono- and poly-dispersed nanoparticles on emulsion droplets: antagonistic vs. synergistic effects as a function of particle size

Abstract

Citation Formats

Numerical analysis of Pickering emulsion stability: insights from ABMD simulations journal, January 2016

Simulating Microscopic Hydrodynamic Phenomena with Dissipative Particle Dynamics journal, June 1992

Probing Diffusion of Single Nanoparticles at Water-Oil Interfaces journal, November 2011

Interfacial adsorption of pH-responsive polymers and nanoparticles journal, January 2017

Assembly of Nanoparticles at Liquid Interfaces: Crowding and Ordering journal, March 2014

Orientation and Self-Assembly of Cylindrical Particles by Anisotropic Capillary Interactions journal, October 2010

Particles as surfactants—similarities and differences journal, March 2002

Early Dynamics and Stabilization Mechanisms of Oil-in-Water Emulsions Containing Colloidal Particles Modified with Short Amphiphiles: A Numerical Study journal, December 2017

Controlling Pickering Emulsion Destabilisation: A Route to Fabricating New Materials by Phase Inversion journal, July 2016

Amphiphilic Silica Nanoparticles at the Decane−Water Interface: Insights from Atomistic Simulations journal, May 2011

Quantification of Ostwald Ripening in Emulsions via Coarse-Grained Simulations journal, August 2019

Wettability of silicananoparticle–surfactant nanocomposite interfacial layers journal, January 2012

Effect of electrolyte in silicone oil-in-water emulsions stabilised by fumed silica particles journal, January 2007

Switchable Pickering Emulsions Stabilized by Silica Nanoparticles Hydrophobized in Situ with a Conventional Cationic Surfactant journal, March 2015

Tailoring Interfacial Nanoparticle Organization through Entropy journal, March 2018

Recent developments in Pickering emulsions for biomedical applications journal, February 2019

Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics journal, January 2005

Entropy-Mediated Mechanomutable Microstructures and Mechanoresponsive Thermal Transport of Nanoparticle Self-Assembly in Block Copolymers journal, November 2019

Thermodynamically Stable Emulsions Using Janus Dumbbells as Colloid Surfactants journal, October 2013

Particles Adsorbed at the Oil−Water Interface: A Theoretical Comparison between Spheres of Uniform Wettability and “Janus” Particles journal, August 2001

Fast Parallel Algorithms for Short-Range Molecular Dynamics journal, March 1995

Dissipative particle dynamics: Bridging the gap between atomistic and mesoscopic simulation journal, September 1997

Pickering emulsions with stimulable particles: from highly- to weakly-covered interfaces journal, January 2007

Ellipsoidal Janus Nanoparticles Assembled at Spherical Oil/Water Interfaces journal, September 2014

Controlling the stability of Pickering emulsions by pH-responsive nanoparticles journal, January 2019

Buckling in armored droplets journal, January 2017

Nanoparticles Adsorbed at the Water/Oil Interface: Coverage and Composition Effects on Structure and Diffusion journal, December 2012

Self-Assembly and Rheology of Ellipsoidal Particles at Interfaces journal, March 2009

DPD Parameters Estimation for Simultaneously Simulating Water–Oil Interfaces and Aqueous Nonionic Surfactants journal, October 2018

Pickering Emulsions Stabilized by Monodisperse Latex Particles: Effects of Particle Size journal, July 2001

Structure of Microparticles in Solid-Stabilized Emulsions journal, April 2004

Mechanistic study of droplets coalescence in Pickering emulsions journal, January 2012

Order−Disorder Transition in Monolayers of Modified Monodisperse Silica Particles at the Octane−Water Interface journal, April 2003

Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces journal, January 2003

Understanding the self-assembly of charged nanoparticles at the water/oil interface journal, January 2006

Structure and Dynamics of Stimuli-Responsive Nanoparticle Monolayers at Fluid Interfaces journal, April 2018

Measuring single-nanoparticle wetting properties by freeze-fracture shadow-casting cryo-scanning electron microscopy journal, August 2011

Electrostatic interactions to modulate the reflective assembly of nanoparticles at the oil–water interface journal, January 2012

Self-assembly of nanoparticles at interfaces journal, January 2007

Physical Properties of Whey Protein Stabilized Emulsions as Related to pH and NaCl journal, March 1997

Influence of pH and CaCl2 on the stability of dilute whey protein stabilized emulsions journal, January 2000

Numerical analysis of Pickering emulsion stability: insights from ABMD simulations
journal, January 2016

Simulating Microscopic Hydrodynamic Phenomena with Dissipative Particle Dynamics
journal, June 1992

Probing Diffusion of Single Nanoparticles at Water-Oil Interfaces
journal, November 2011

Interfacial adsorption of pH-responsive polymers and nanoparticles
journal, January 2017

Assembly of Nanoparticles at Liquid Interfaces: Crowding and Ordering
journal, March 2014

Orientation and Self-Assembly of Cylindrical Particles by Anisotropic Capillary Interactions
journal, October 2010

Particles as surfactants—similarities and differences
journal, March 2002

Early Dynamics and Stabilization Mechanisms of Oil-in-Water Emulsions Containing Colloidal Particles Modified with Short Amphiphiles: A Numerical Study
journal, December 2017

Controlling Pickering Emulsion Destabilisation: A Route to Fabricating New Materials by Phase Inversion
journal, July 2016

Amphiphilic Silica Nanoparticles at the Decane−Water Interface: Insights from Atomistic Simulations
journal, May 2011

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journal, August 2019

Wettability of silicananoparticle–surfactant nanocomposite interfacial layers
journal, January 2012

Effect of electrolyte in silicone oil-in-water emulsions stabilised by fumed silica particles
journal, January 2007

Switchable Pickering Emulsions Stabilized by Silica Nanoparticles Hydrophobized in Situ with a Conventional Cationic Surfactant
journal, March 2015

Tailoring Interfacial Nanoparticle Organization through Entropy
journal, March 2018

Recent developments in Pickering emulsions for biomedical applications
journal, February 2019

Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics
journal, January 2005

Entropy-Mediated Mechanomutable Microstructures and Mechanoresponsive Thermal Transport of Nanoparticle Self-Assembly in Block Copolymers
journal, November 2019

Thermodynamically Stable Emulsions Using Janus Dumbbells as Colloid Surfactants
journal, October 2013

Particles Adsorbed at the Oil−Water Interface: A Theoretical Comparison between Spheres of Uniform Wettability and “Janus” Particles
journal, August 2001

Fast Parallel Algorithms for Short-Range Molecular Dynamics
journal, March 1995

Dissipative particle dynamics: Bridging the gap between atomistic and mesoscopic simulation
journal, September 1997

Pickering emulsions with stimulable particles: from highly- to weakly-covered interfaces
journal, January 2007

Ellipsoidal Janus Nanoparticles Assembled at Spherical Oil/Water Interfaces
journal, September 2014

Controlling the stability of Pickering emulsions by pH-responsive nanoparticles
journal, January 2019

Buckling in armored droplets
journal, January 2017

Nanoparticles Adsorbed at the Water/Oil Interface: Coverage and Composition Effects on Structure and Diffusion
journal, December 2012

Self-Assembly and Rheology of Ellipsoidal Particles at Interfaces
journal, March 2009

DPD Parameters Estimation for Simultaneously Simulating Water–Oil Interfaces and Aqueous Nonionic Surfactants
journal, October 2018

Pickering Emulsions Stabilized by Monodisperse Latex Particles: Effects of Particle Size
journal, July 2001

Structure of Microparticles in Solid-Stabilized Emulsions
journal, April 2004

Mechanistic study of droplets coalescence in Pickering emulsions
journal, January 2012

Order−Disorder Transition in Monolayers of Modified Monodisperse Silica Particles at the Octane−Water Interface
journal, April 2003

Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces
journal, January 2003

Understanding the self-assembly of charged nanoparticles at the water/oil interface
journal, January 2006

Structure and Dynamics of Stimuli-Responsive Nanoparticle Monolayers at Fluid Interfaces
journal, April 2018

Measuring single-nanoparticle wetting properties by freeze-fracture shadow-casting cryo-scanning electron microscopy
journal, August 2011

Electrostatic interactions to modulate the reflective assembly of nanoparticles at the oil–water interface
journal, January 2012

Self-assembly of nanoparticles at interfaces
journal, January 2007

Physical Properties of Whey Protein Stabilized Emulsions as Related to pH and NaCl
journal, March 1997

Influence of pH and CaCl2 on the stability of dilute whey protein stabilized emulsions
journal, January 2000