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Title: Highly Tunable Thiol‐Ene Photoresins for Volumetric Additive Manufacturing

ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [2];  [3];  [2]; ORCiD logo [1]
  1. Lawrence Livermore National Laboratory Livermore CA 94550 USA
  2. Electrical, Computer, and Energy Engineering Department University of Colorado Boulder CO 80309 USA
  3. Materials Science and Engineering Program University of Colorado Boulder CO 80303 USA
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Published Article
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials; Journal ID: ISSN 0935-9648
Wiley Blackwell (John Wiley & Sons)
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Citation Formats

Cook, Caitlyn C., Fong, Erika J., Schwartz, Johanna J., Porcincula, Dominique H., Kaczmarek, Allison C., Oakdale, James S., Moran, Bryan D., Champley, Kyle M., Rackson, Charles M., Muralidharan, Archish, McLeod, Robert R., and Shusteff, Maxim. Highly Tunable Thiol‐Ene Photoresins for Volumetric Additive Manufacturing. Germany: N. p., 2020. Web. doi:10.1002/adma.202003376.
Cook, Caitlyn C., Fong, Erika J., Schwartz, Johanna J., Porcincula, Dominique H., Kaczmarek, Allison C., Oakdale, James S., Moran, Bryan D., Champley, Kyle M., Rackson, Charles M., Muralidharan, Archish, McLeod, Robert R., & Shusteff, Maxim. Highly Tunable Thiol‐Ene Photoresins for Volumetric Additive Manufacturing. Germany. doi:10.1002/adma.202003376.
Cook, Caitlyn C., Fong, Erika J., Schwartz, Johanna J., Porcincula, Dominique H., Kaczmarek, Allison C., Oakdale, James S., Moran, Bryan D., Champley, Kyle M., Rackson, Charles M., Muralidharan, Archish, McLeod, Robert R., and Shusteff, Maxim. Thu . "Highly Tunable Thiol‐Ene Photoresins for Volumetric Additive Manufacturing". Germany. doi:10.1002/adma.202003376.
title = {Highly Tunable Thiol‐Ene Photoresins for Volumetric Additive Manufacturing},
author = {Cook, Caitlyn C. and Fong, Erika J. and Schwartz, Johanna J. and Porcincula, Dominique H. and Kaczmarek, Allison C. and Oakdale, James S. and Moran, Bryan D. and Champley, Kyle M. and Rackson, Charles M. and Muralidharan, Archish and McLeod, Robert R. and Shusteff, Maxim},
abstractNote = {},
doi = {10.1002/adma.202003376},
journal = {Advanced Materials},
number = ,
volume = ,
place = {Germany},
year = {2020},
month = {10}

Journal Article:
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DOI: 10.1002/adma.202003376

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Works referenced in this record:

Photopolymerized Triazole-Based Glassy Polymer Networks with Superior Tensile Toughness
journal, April 2018

  • Song, Han Byul; Baranek, Austin; Worrell, Brady T.
  • Advanced Functional Materials, Vol. 28, Issue 22
  • DOI: 10.1002/adfm.201801095

Allylic monomers as reactive plasticizers of polyphenylene oxide. Part II: Cure kinetics
journal, September 2011

Understanding and Improving Mechanical Properties in 3D printed Parts Using a Dual-Cure Acrylate-Based Resin for Stereolithography
journal, September 2018

  • Uzcategui, Asais Camila; Muralidharan, Archish; Ferguson, Virginia L.
  • Advanced Engineering Materials, Vol. 20, Issue 12
  • DOI: 10.1002/adem.201800876

Thiol–ene Click Hydrogels for Therapeutic Delivery
journal, January 2016

  • Kharkar, Prathamesh M.; Rehmann, Matthew S.; Skeens, Kelsi M.
  • ACS Biomaterials Science & Engineering, Vol. 2, Issue 2
  • DOI: 10.1021/acsbiomaterials.5b00420

High-resolution tomographic volumetric additive manufacturing
journal, February 2020

Thiol-ene polymerisation: A promising technique to obtain novel biomaterials
journal, January 2017

Toughening of photo-curable polymer networks: a review
journal, January 2016

  • Ligon-Auer, Samuel Clark; Schwentenwein, Martin; Gorsche, Christian
  • Polymer Chemistry, Vol. 7, Issue 2
  • DOI: 10.1039/C5PY01631B

Rate-based approach for controlling the mechanical properties of ‘thiol–ene’ hydrogels formed with visible light
journal, January 2019

  • Wiley, Katherine L.; Ovadia, Elisa M.; Calo, Christopher J.
  • Polymer Chemistry, Vol. 10, Issue 32
  • DOI: 10.1039/C9PY00447E

Thiol-Ene Click Chemistry
journal, February 2010

  • Hoyle, Charles E.; Bowman, Christopher N.
  • Angewandte Chemie International Edition, Vol. 49, Issue 9, p. 1540-1573
  • DOI: 10.1002/anie.200903924

One-step volumetric additive manufacturing of complex polymer structures
journal, December 2017

  • Shusteff, Maxim; Browar, Allison E. M.; Kelly, Brett E.
  • Science Advances, Vol. 3, Issue 12
  • DOI: 10.1126/sciadv.aao5496

Stereolithographic 3D Printing for Deterministic Control over Integration in Dual‐Material Composites
journal, August 2019

  • Muralidharan, Archish; Uzcategui, Asais C.; McLeod, Robert R.
  • Advanced Materials Technologies, Vol. 4, Issue 11
  • DOI: 10.1002/admt.201900592

Exposure Reciprocity Law in Photopolymerization of Multi-Functional Acrylates and Methacrylates
journal, February 2007

  • Feng, Li; Suh, Byoung I.
  • Macromolecular Chemistry and Physics, Vol. 208, Issue 3
  • DOI: 10.1002/macp.200600480

Polymers for 3D Printing and Customized Additive Manufacturing
journal, July 2017

Tough, stable spiroacetal thiol-ene resin for 3D printing: Research Article
journal, February 2018

  • Sycks, Dalton G.; Wu, Tiffany; Park, Hyun Sang
  • Journal of Applied Polymer Science, Vol. 135, Issue 22
  • DOI: 10.1002/app.46259

Scavenging with TEMPO To Identify Peptide- and Protein-Based Radicals by Mass Spectrometry:  Advantages of Spin Scavenging over Spin Trapping
journal, July 2003

  • Wright, P. John; English, Ann M.
  • Journal of the American Chemical Society, Vol. 125, Issue 28
  • DOI: 10.1021/ja0291888

A photopolymerizable thermoplastic with tunable mechanical performance
journal, January 2020

  • Alim, Marvin D.; Childress, Kimberly K.; Baugh, Neil J.
  • Materials Horizons, Vol. 7, Issue 3
  • DOI: 10.1039/C9MH01336A

Multivascular networks and functional intravascular topologies within biocompatible hydrogels
journal, May 2019

  • Grigoryan, Bagrat; Paulsen, Samantha J.; Corbett, Daniel C.
  • Science, Vol. 364, Issue 6439
  • DOI: 10.1126/science.aav9750

Volumetric Bioprinting of Complex Living‐Tissue Constructs within Seconds
journal, August 2019

  • Bernal, Paulina Nuñez; Delrot, Paul; Loterie, Damien
  • Advanced Materials, Vol. 31, Issue 42
  • DOI: 10.1002/adma.201904209

Additive manufacture of lightly crosslinked semicrystalline thiol–enes for enhanced mechanical performance
journal, January 2020

  • Childress, Kimberly K.; Alim, Marvin D.; Hernandez, Juan J.
  • Polymer Chemistry, Vol. 11, Issue 1
  • DOI: 10.1039/C9PY01452G

Thiol-enes: Chemistry of the past with promise for the future
journal, January 2004

  • Hoyle, Charles E.; Lee, Tai Yeon; Roper, Todd
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 42, Issue 21
  • DOI: 10.1002/pola.20366

Degradable emulsion-templated scaffolds for tissue engineering from thiol–ene photopolymerisation
journal, January 2012

  • Caldwell, Sally; Johnson, David W.; Didsbury, Matthew P.
  • Soft Matter, Vol. 8, Issue 40
  • DOI: 10.1039/c2sm26250a

Real Time-NIR/MIR-Photorheology: A Versatile Tool for the in Situ Characterization of Photopolymerization Reactions
journal, April 2017

Propenyl ethers. I. The synthesis of propenyl ether monomers
journal, May 1993

The reciprocity law concerning light dose relationships applied to BisGMA/TEGDMA photopolymers: Theoretical analysis and experimental characterization
journal, June 2014

Volumetric additive manufacturing via tomographic reconstruction
journal, January 2019

  • Kelly, Brett E.; Bhattacharya, Indrasen; Heidari, Hossein
  • Science, Vol. 363, Issue 6431
  • DOI: 10.1126/science.aau7114

Urethane acrylate‐based photosensitive resin for three‐dimensional printing of stereolithographic elastomer
journal, April 2020

  • Deng, Yuhao; Li, Jie; He, Zuhan
  • Journal of Applied Polymer Science, Vol. 137, Issue 42
  • DOI: 10.1002/app.49294

Modular Elastomer Photoresins for Digital Light Processing Additive Manufacturing
journal, November 2017

  • Thrasher, Carl J.; Schwartz, Johanna J.; Boydston, Andrew J.
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 45
  • DOI: 10.1021/acsami.7b13909

Highly Stretchable and UV Curable Elastomers for Digital Light Processing Based 3D Printing
journal, February 2017

  • Patel, Dinesh K.; Sakhaei, Amir Hosein; Layani, Michael
  • Advanced Materials, Vol. 29, Issue 15
  • DOI: 10.1002/adma.201606000

Anisotropy of Photopolymer Parts Made by Digital Light Processing
journal, January 2017

  • Monzón, Mario; Ortega, Zaida; Hernández, Alba
  • Materials, Vol. 10, Issue 1
  • DOI: 10.3390/ma10010064

A Review of 3D Printing Technologies for Soft Polymer Materials
journal, April 2020

  • Zhou, Lu‐Yu; Fu, Jianzhong; He, Yong
  • Advanced Functional Materials, Vol. 30, Issue 28
  • DOI: 10.1002/adfm.202000187

Visible-Light Initiated Thiol-Michael Addition Photopolymerization Reactions
journal, March 2014

  • Chatani, Shunsuke; Gong, Tao; Earle, Brittany A.
  • ACS Macro Letters, Vol. 3, Issue 4
  • DOI: 10.1021/mz500132j

Storage Moduli and Porosity of Soft PDMS PolyMIPEs Can Be Controlled Independently Using Thiol–Ene Click Chemistry
journal, May 2020

Simultaneous Algebraic Reconstruction Technique (SART): A Superior Implementation of the Art Algorithm
journal, January 1984

Thiol-Ene versus Binary Thiol-Acrylate Chemistry: Material Properties and Network Characteristics of Photopolymers : Material Properties and Network Characteristics of Photopolymers
journal, November 2016

  • Sahin, Melahat; Ayalur-Karunakaran, Santhosh; Manhart, Jakob
  • Advanced Engineering Materials, Vol. 19, Issue 4
  • DOI: 10.1002/adem.201600620

Surface functionalization and dynamics of polymeric cell culture substrates
journal, August 2016