Nickel(ii)-methyl complexes adopting unusual seesaw geometries

Hill, Ethan A.; Zhao, Norman; Filatov, Alexander S.; Anderson, John S.

doi:10.1039/c9cc09249h

Title: Nickel(ii)-methyl complexes adopting unusual seesaw geometries

Journal Article · 21 January 2020 · ChemComm

DOI: https://doi.org/10.1039/c9cc09249h · OSTI ID:1669137

Hill, Ethan A. ^[1];

^[1];

^[1]

Univ. of Chicago, IL (United States)

Here, we report four-coordinate nickel(II)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1669137

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 57 Vol. 56; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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CCDC 1968521: Experimental Crystal Structure Determination A., Hill, Ethan; Norman, Zhao,; S., Filatov, Alexander https://doi.org/10.5517/ccdc.csd.cc242dpb The current record is supplemented by this dataset	dataset	January 2020
CCDC 1968522: Experimental Crystal Structure Determination A., Hill, Ethan; Norman, Zhao,; S., Filatov, Alexander https://doi.org/10.5517/ccdc.csd.cc242dqc The current record is supplemented by this dataset	dataset	January 2020
CCDC 1968523: Experimental Crystal Structure Determination A., Hill, Ethan; Norman, Zhao,; S., Filatov, Alexander https://doi.org/10.5517/ccdc.csd.cc242drd The current record is supplemented by this dataset	dataset	January 2020
CCDC 1968524: Experimental Crystal Structure Determination A., Hill, Ethan; Norman, Zhao,; S., Filatov, Alexander https://doi.org/10.5517/ccdc.csd.cc242dsf The current record is supplemented by this dataset	dataset	January 2020

Title: Nickel(ii)-methyl complexes adopting unusual seesaw geometries

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