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Title: Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy

Abstract

The purpose of this review is to provide an overview of uranium speciation using vibrational spectroscopy methods including Raman and IR. Uranium is a naturally occurring, radioactive element that is utilized in the nuclear energy and national security sectors. Fundamental uranium chemistry is also an active area of investigation due to ongoing questions regarding the participation of 5f orbitals in bonding, variation in oxidation states and coordination environments, and unique chemical and physical properties. Importantly, uranium speciation affects fate and transportation in the environment, influences bioavailability and toxicity to human health, controls separation processes for nuclear waste, and impacts isotopic partitioning and geochronological dating. This work provides a thorough discussion of the vibrational modes for U(IV), U(V), and U(VI) and applications of infrared absorption and Raman scattering spectroscopies in the identification and detection of both naturally occurring and synthetic uranium species in solid and solution states. The vibrational frequencies of the uranyl moiety, including both symmetric and asymmetric stretches are sensitive to the coordinating ligands and used to identify individual species in water, organic solvents, and ionic liquids or on the surface of materials. Additionally, vibrational spectroscopy allows for the in situ detection and real-time monitoring of chemical reactions involvingmore » uranium. Finally, techniques to enhance uranium species signals with vibrational modes are discussed to expand the application of vibrational spectroscopy to biological, environmental, inorganic, and materials scientists and engineers.« less

Authors:
 [1];  [1];  [1]
  1. Univ. of Iowa, Iowa City, IA (United States)
Publication Date:
Research Org.:
Univ. of Iowa, Iowa City, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
OSTI Identifier:
1668719
Grant/Contract Number:  
SC0013980
Resource Type:
Accepted Manuscript
Journal Name:
Coordination Chemistry Reviews
Additional Journal Information:
Journal Volume: 374; Journal ID: ISSN 0010-8545
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; uranium; Raman; vibrational spectroscopy; infrared

Citation Formats

Lu, Grace, Haes, Amanda J., and Forbes, Tori Z. Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy. United States: N. p., 2018. Web. doi:10.1016/j.ccr.2018.07.010.
Lu, Grace, Haes, Amanda J., & Forbes, Tori Z. Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy. United States. https://doi.org/10.1016/j.ccr.2018.07.010
Lu, Grace, Haes, Amanda J., and Forbes, Tori Z. Tue . "Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy". United States. https://doi.org/10.1016/j.ccr.2018.07.010. https://www.osti.gov/servlets/purl/1668719.
@article{osti_1668719,
title = {Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy},
author = {Lu, Grace and Haes, Amanda J. and Forbes, Tori Z.},
abstractNote = {The purpose of this review is to provide an overview of uranium speciation using vibrational spectroscopy methods including Raman and IR. Uranium is a naturally occurring, radioactive element that is utilized in the nuclear energy and national security sectors. Fundamental uranium chemistry is also an active area of investigation due to ongoing questions regarding the participation of 5f orbitals in bonding, variation in oxidation states and coordination environments, and unique chemical and physical properties. Importantly, uranium speciation affects fate and transportation in the environment, influences bioavailability and toxicity to human health, controls separation processes for nuclear waste, and impacts isotopic partitioning and geochronological dating. This work provides a thorough discussion of the vibrational modes for U(IV), U(V), and U(VI) and applications of infrared absorption and Raman scattering spectroscopies in the identification and detection of both naturally occurring and synthetic uranium species in solid and solution states. The vibrational frequencies of the uranyl moiety, including both symmetric and asymmetric stretches are sensitive to the coordinating ligands and used to identify individual species in water, organic solvents, and ionic liquids or on the surface of materials. Additionally, vibrational spectroscopy allows for the in situ detection and real-time monitoring of chemical reactions involving uranium. Finally, techniques to enhance uranium species signals with vibrational modes are discussed to expand the application of vibrational spectroscopy to biological, environmental, inorganic, and materials scientists and engineers.},
doi = {10.1016/j.ccr.2018.07.010},
journal = {Coordination Chemistry Reviews},
number = ,
volume = 374,
place = {United States},
year = {2018},
month = {7}
}

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  • Journal of Raman Spectroscopy, Vol. 38, Issue 11
  • DOI: 10.1002/jrs.1796

Spectroscopy and DFT studies of uranyl carbonate, rutherfordine, UO 2 CO 3 : a model for uranium transport, carbon dioxide sequestration, and seawater species
journal, November 2017

  • Kalashnyk, N.; Perry, D. L.; Massuyeau, F.
  • Journal of Physics D: Applied Physics, Vol. 50, Issue 50
  • DOI: 10.1088/1361-6463/aa968a

Raman spectroscopic study of the multi-anion uranyl mineral schroeckingerite
journal, January 2007

  • Frost, Ray L.; Čejka, Jiří; Ayoko, Godwin A.
  • Journal of Raman Spectroscopy, Vol. 38, Issue 12
  • DOI: 10.1002/jrs.1827

Raman spectroscopic study of the uranyl carbonate mineral zellerite
journal, January 2008

  • Frost, Ray L.; Dickfos, Marilla J.; Čejka, Jiří
  • Journal of Raman Spectroscopy, Vol. 39, Issue 5
  • DOI: 10.1002/jrs.1879

Raman spectroscopic study of the uranyl carbonate mineral voglite: Raman studies of the uranyl carbonate mineral voglite
journal, December 2007

  • Frost, Ray L.; Čejka, Jiří; Ayoko, Godwin A.
  • Journal of Raman Spectroscopy, Vol. 39, Issue 3
  • DOI: 10.1002/jrs.1829

Raman spectroscopy of uranyl rare earth carbonate kamotoite-(Y)
journal, November 2006

  • Frost, Ray L.; Weier, Matt L.; Čejka, Jiří
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 65, Issue 3-4
  • DOI: 10.1016/j.saa.2005.12.004

Crystal structure of UO2SO4·2.5H2O: Full anisotropic refinement and vibration characteristics
journal, November 2009


Raman spectral studies of uranyl sulphate and its urea complex structural isomers
journal, July 1993

  • Faulques, Eric; Russo, Richard E.; Perry, Dale L.
  • Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 49, Issue 7
  • DOI: 10.1016/0584-8539(93)80216-W

Molecular structure of the uranyl mineral uranopilite—a Raman spectroscopic study
journal, January 2005


Raman spectroscopy of uranopilite of different origins—implications for molecular structure
journal, January 2007

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt L.
  • Journal of Raman Spectroscopy, Vol. 38, Issue 4
  • DOI: 10.1002/jrs.1660

Raman spectroscopic study of the uranyl sulphate mineral jáchymovite (UO 2 ) 8 (SO 4 )(OH) 14 · 13H 2 O: RS study of the mineral jáchymovite
journal, February 2009

  • Čejka, Jiří; Frost, Ray L.; Sejkora, Jiří
  • Journal of Raman Spectroscopy, Vol. 40, Issue 11
  • DOI: 10.1002/jrs.2227

Raman spectroscopic study of the molecular structure of the uranyl mineral zippeite from Jáchymov (Joachimsthal), Czech Republic
journal, August 2007

  • Frost, Ray L.; Čejka, Jiří; Bostrom, Thor
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 67, Issue 5
  • DOI: 10.1016/j.saa.2006.10.011

Raman spectroscopic and SEM analysis of sodium-zippeite
journal, January 2007

  • Frost, Ray L.; Čejka, Jiří; Ayoko, Godwin A.
  • Journal of Raman Spectroscopy, Vol. 38, Issue 10
  • DOI: 10.1002/jrs.1768

A Raman spectroscopic study of the uranyl sulphate mineral johannite
journal, September 2005

  • Frost, Ray L.; Erickson, Kristy L.; Čejka, Jiří
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 61, Issue 11-12
  • DOI: 10.1016/j.saa.2004.10.013

Raman spectroscopic study of the uranyl mineral pseudojohannite Cu6.5[(UO2)4O4(SO4)2]2(OH)5·25H2O
journal, December 2009

  • Frost, Ray L.; Plášil, Jakub; Čejka, Jiří
  • Journal of Raman Spectroscopy, Vol. 40, Issue 12
  • DOI: 10.1002/jrs.2268

Crystal structure and formula revision of deliensite, Fe[(UO 2 ) 2 (SO 4 ) 2 (OH) 2 ](H 2 O) 7
journal, December 2012


Meisserite, Na 5 (UO 2 )(SO 4 ) 3 (SO 3 OH)(H 2 O), a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA
journal, October 2013


Bluelizardite, Na7(UO2)(SO4)4Cl(H2O)2, a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA
journal, April 2014


Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jachymov, Czech Republic
journal, January 2012

  • Plasil, J.; Hlousek, J.; Veselovsky, F.
  • American Mineralogist, Vol. 97, Issue 2-3
  • DOI: 10.2138/am.2012.3976

The Crystal Structure of Na 6 [(UO 2 )(SO 4 ) 4 ](H 2 O) 4 : X-Ray and Raman Spectroscopy Study
journal, August 2015

  • Plášil, Jakub; Meisser, Nicolas; Čejka, Jiří
  • The Canadian Mineralogist, Vol. 54, Issue 1
  • DOI: 10.3749/canmin.1400095

Shumwayite, [(UO 2 )(SO 4 )(H 2 O) 2 ] 2 ·H 2 O, a new uranyl sulfate mineral from Red Canyon, San Juan County, Utah, USA
journal, April 2017


Near- and mid-infrared spectroscopy of the uranyl selenite mineral haynesite (UO2)3(SeO3)2(OH)2·5H2O
journal, January 2009

  • Frost, Ray L.; Čejka, Jiří
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 71, Issue 5
  • DOI: 10.1016/j.saa.2008.07.026

A Raman spectroscopic study of the uranyl selenite mineral haynesite
journal, January 2006

  • Frost, Ray L.; Weier, Matt L.; Reddy, B. Jagannadha
  • Journal of Raman Spectroscopy, Vol. 37, Issue 8
  • DOI: 10.1002/jrs.1508

Vibrational spectroscopic study of the uranyl selenite mineral derriksite Cu4UO2(SeO3)2(OH)6⋅H2O
journal, January 2014

  • Frost, Ray L.; Čejka, Jiří; Scholz, Ricardo
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 117
  • DOI: 10.1016/j.saa.2013.08.026

Raman spectroscopic study of the uranyl selenite mineral demesmaekerite Pb 2 Cu 5 (UO 2 ) 2 (SeO 3 ) 6 (OH) 6 ·2H 2 O
journal, May 2009

  • Frost, Ray L.; Čejka, Jiří; Dickfos, Marilla J.
  • Journal of Raman Spectroscopy, Vol. 40, Issue 5
  • DOI: 10.1002/jrs.2074

Raman spectroscopic study of the mineral guilleminite Ba(UO 2 ) 3 (SeO 3 ) 2 (OH) 4 ·3H 2 O
journal, April 2009

  • Frost, Ray L.; Čejka, Jiří; Dickfos, Marilla J.
  • Journal of Raman Spectroscopy, Vol. 40, Issue 4
  • DOI: 10.1002/jrs.2068

Vibrational spectroscopy of synthetic analogues of ankoleite, chernikovite and intermediate solid solution
journal, March 2016

  • Clavier, N.; Crétaz, F.; Szenknect, S.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 156
  • DOI: 10.1016/j.saa.2015.11.035

Raman and infrared spectroscopic studies of phurcalite from Red Canyon, Utah, USA – Implications for the molecular structure
journal, June 2014


Solubility properties of synthetic and natural meta-torbernite
journal, November 2013


A Raman spectroscopic study of the uranyl phosphate mineral bergenite
journal, April 2007

  • Frost, Ray L.; Čejka, Jiří; Ayoko, Godwin A.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 66, Issue 4-5
  • DOI: 10.1016/j.saa.2006.04.036

A Raman spectroscopic study of the uranyl phosphate mineral threadgoldite
journal, November 2006

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 65, Issue 3-4
  • DOI: 10.1016/j.saa.2005.12.043

A Raman spectroscopic study of the uranyl phosphate mineral parsonsite
journal, January 2006

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt
  • Journal of Raman Spectroscopy, Vol. 37, Issue 9
  • DOI: 10.1002/jrs.1517

Raman spectroscopic study of the uranyl phosphate mineral dewindtite
journal, January 2006

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt
  • Journal of Raman Spectroscopy, Vol. 37, Issue 12
  • DOI: 10.1002/jrs.1551

Raman spectroscopic study of the uranyl phosphate mineral dumontite Pb 2 [(UO 2 ) 3 O 2 (PO 4 ) 2 ]·5H 2 O
journal, June 2009

  • Frost, Ray L.; Čejka, Jiří
  • Journal of Raman Spectroscopy, Vol. 40, Issue 6
  • DOI: 10.1002/jrs.2143

Phosphowalpurgite, the (Po4)-Dominant Analogue of Walpurgite, from Smrkovec, Slavkovsky les Mountains, Czech Republic
journal, August 2004


Synthesis and characterization of francoisite-(Nd): Nd[(UO2)3O(OH)(PO4)2]{middle dot}6H2O
journal, February 2011

  • Armstrong, C. R.; Nash, K. L.; Griffiths, P. R.
  • American Mineralogist, Vol. 96, Issue 2-3
  • DOI: 10.2138/am.2011.3609

Raman spectroscopic study of the uranyl minerals vanmeersscheite U(OH)4[(UO2)3(PO4)2(OH)2]·4H2O and arsenouranylite Ca(UO2)[(UO2)3(AsO4)2(OH)2]·(OH)2·6H2O
journal, January 2009

  • Frost, Ray L.; Čejka, Jiří; Dickfos, Marilla J.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 71, Issue 5
  • DOI: 10.1016/j.saa.2008.06.041

Raman spectroscopic study of the uranyl mineral metauranospinite Ca[(UO2)(AsO4)]2·8H2O
journal, December 2009

  • Čejka, Jiří; Sejkora, Jiří; Frost, Ray L.
  • Journal of Raman Spectroscopy, Vol. 40, Issue 12
  • DOI: 10.1002/jrs.2242

Influence of extreme conditions on the formation and structures of caesium uranium( vi ) arsenates
journal, January 2015

  • Yu, Na; Kegler, Philip; Klepov, Vladislav V.
  • Dalton Transactions, Vol. 44, Issue 47
  • DOI: 10.1039/C5DT03842A

Raman spectroscopy of walpurgite
journal, January 2006

  • Frost, Ray L.; Weier, Matt L.; Čejka, Jiří
  • Journal of Raman Spectroscopy, Vol. 37, Issue 5
  • DOI: 10.1002/jrs.1483

Structural, mechanical and vibrational study of uranyl silicate mineral soddyite by DFT calculations
journal, September 2017

  • Colmenero, Francisco; Bonales, Laura J.; Cobos, Joaquín
  • Journal of Solid State Chemistry, Vol. 253
  • DOI: 10.1016/j.jssc.2017.06.002

A Raman and infrared spectroscopic study of the uranyl silicates—Weeksite, soddyite and haiweeite
journal, May 2006

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt L.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 64, Issue 2
  • DOI: 10.1016/j.saa.2005.07.028

A Raman and infrared spectroscopic study of the uranyl silicates—Weeksite, soddyite and haiweeite: Part 2
journal, February 2006

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt L.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 63, Issue 2
  • DOI: 10.1016/j.saa.2005.05.015

Syntheses and spectroscopic characterization of uranium(VI) silicate minerals
journal, October 2007

  • Lehmann, S.; Geipel, G.; Foerstendorf, H.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 275, Issue 3
  • DOI: 10.1007/s10967-007-7060-z

Molecular structure of the uranyl silicates—a Raman spectroscopic study
journal, January 2006

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt L.
  • Journal of Raman Spectroscopy, Vol. 37, Issue 4
  • DOI: 10.1002/jrs.1430

Raman spectroscopy study of selected uranophanes
journal, May 2006


Synthesis and characterization of 1:1 layered uranyl silicate mineral phases
journal, July 2010


Intercalation of Iodic Acid into the Layered Uranyl Iodate, UO 2 (IO 3 ) 2 (H 2 O)
journal, January 2007

  • Ling, Jie; Albrecht-Schmitt, Thomas E.
  • Inorganic Chemistry, Vol. 46, Issue 2
  • DOI: 10.1021/ic062072i

Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na 2 [UO 2 (IO 3 ) 4 (H 2 O)]
journal, October 2006

  • Bray, Travis H.; Beitz, James V.; Bean, Amanda C.
  • Inorganic Chemistry, Vol. 45, Issue 20
  • DOI: 10.1021/ic060957o

A Raman spectroscopic study of the uranyl tellurite mineral schmitterite
journal, November 2006

  • Frost, Ray L.; Čejka, Jiří; Weier, Matt
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 65, Issue 3-4
  • DOI: 10.1016/j.saa.2005.12.013

Raman spectroscopic study of the uranyl tellurite mineral moctezumite PbUO 2 (TeO 3 ) 2
journal, January 2009

  • Frost, Ray L.; Čejka, Jiří; Dickfos, Marilla J.
  • Journal of Raman Spectroscopy, Vol. 40, Issue 1
  • DOI: 10.1002/jrs.2069

A new structural family of heteropolytungstate lacunary complexes with the uranyl, UO22+, cation
journal, January 2003

  • Gaunt, Andrew J.; May, Iain; Copping, Roy
  • Dalton Transactions, Issue 15
  • DOI: 10.1039/b302955g

Vibrational spectroscopy of selected natural uranyl vanadates
journal, October 2005


Mathesiusite, K5(UO2)4(SO4)4(VO5)(H2O)4, a new uranyl vanadate-sulfate from Jachymov, Czech Republic
journal, April 2014

  • Pla il, J.; Veselovsky, F.; Hlou ek, J.
  • American Mineralogist, Vol. 99, Issue 4
  • DOI: 10.2138/am.2014.4681

Synthesis, characterization and reactivity of some novel dinuclear mixed-ligand peroxouranium(VI) complexes
journal, October 1997


Expanding the Crystal Chemistry of Uranyl Peroxides: Four Hybrid Uranyl-Peroxide Structures Containing EDTA
journal, October 2014

  • Qiu, Jie; Ling, Jie; Sieradzki, Claire
  • Inorganic Chemistry, Vol. 53, Issue 22
  • DOI: 10.1021/ic5018906

Closing Uranyl Polyoxometalate Capsules with Bismuth and Lead Polyoxocations
journal, September 2016

  • Renier, Olivier; Falaise, Clément; Neal, Harrison
  • Angewandte Chemie International Edition, Vol. 55, Issue 43
  • DOI: 10.1002/anie.201607151

Synthesis of a Uranyl Persulfide Complex and Quantum Chemical Studies of Formation and Topologies of Hypothetical Uranyl Persulfide Cage Clusters
journal, April 2012

  • Grant, Daniel J.; Weng, Zhehui; Jouffret, Laurent J.
  • Inorganic Chemistry, Vol. 51, Issue 14
  • DOI: 10.1021/ic3008574

Coordination Trends in Alkali Metal Crown Ether Uranyl Halide Complexes:  The Series [A(Crown)] 2 [UO 2 X 4 ] Where A = Li, Na, K and X = Cl, Br
journal, July 2001

  • Danis, Janet A.; Lin, Mavis R.; Scott, Brian L.
  • Inorganic Chemistry, Vol. 40, Issue 14
  • DOI: 10.1021/ic0011056

Raman spectra of uranyl complexes with hexamethylphosphorotriamide
journal, January 1977

  • Shchelokov, R. N.; Tsivadze, A. Yu.; Orlova, I. M.
  • Inorganic and Nuclear Chemistry Letters, Vol. 13, Issue 8
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Raman spectra of uranyl fluoro and thiocyanato complexes
journal, January 1977

  • Shchelokov, R. N.; Tsivadze, A. Yu.; Orlova, I. M.
  • Inorganic and Nuclear Chemistry Letters, Vol. 13, Issue 8
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Chemical Speciation of the Uranyl Ion under Highly Alkaline Conditions. Synthesis, Structures, and Oxo Ligand Exchange Dynamics
journal, April 1999

  • Clark, David L.; Conradson, Steven D.; Donohoe, Robert J.
  • Inorganic Chemistry, Vol. 38, Issue 7
  • DOI: 10.1021/ic981137h

Structurally Characterized Ternary U−O−N Compound, UN 4 O 12 :  UO 2 (NO 3 ) 2 ·N 2 O 4 or NO + UO 2 (NO 3 ) 3 - ?
journal, November 2005

  • Crawford, Margaret-Jane; Mayer, Peter
  • Inorganic Chemistry, Vol. 44, Issue 23
  • DOI: 10.1021/ic050409v

A structural study on uranyl (VI) nitrate complexes with cyclic amides: N-n-butyl-2-pyrrolidone, N-cyclohexylmethyl-2-pyrrolidone, and 1,3-dimethyl-2-imidazolidone
journal, March 2005

  • Koshino, Nobuyoshi; Harada, Masayuki; Nogami, Masanobu
  • Inorganica Chimica Acta, Vol. 358, Issue 6
  • DOI: 10.1016/j.ica.2004.12.036

Thermochromic Uranyl Isothiocyanates: Influencing Charge Transfer Bands with Supramolecular Structure
journal, February 2018


Synthesis and characterization of heterometallic uranyl pyridinedicarboxylate compounds
journal, October 2017

  • Jayasinghe, Ashini S.; Payne, Maurice K.; Forbes, Tori Z.
  • Journal of Solid State Chemistry, Vol. 254
  • DOI: 10.1016/j.jssc.2017.07.002

Synthesis and crystal structure analysis of uranyl triple acetates
journal, December 2016

  • Klepov, Vladislav V.; Serezhkina, Larisa B.; Serezhkin, Victor N.
  • Journal of Solid State Chemistry, Vol. 244
  • DOI: 10.1016/j.jssc.2016.09.019

Probing the Influence of N-Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials
journal, December 2015

  • Carter, Korey P.; Kalaj, Mark; Cahill, Christopher L.
  • European Journal of Inorganic Chemistry, Vol. 2016, Issue 1
  • DOI: 10.1002/ejic.201501118

Uranium( vi ) complexes with isonicotinic acid: from monomer to 2D polymer with unique U–N bonding
journal, January 2015

  • Zhang, Yingjie; Karatchevtseva, Inna; Price, Jason R.
  • RSC Advances, Vol. 5, Issue 42
  • DOI: 10.1039/C5RA01272D

Spectral Analysis of the Uranyl Squarate and Croconate System: Evaluating Differences between the Solution and Solid-State Phases
journal, September 2017


Tetrameric entity resulting from two distinct dinuclear uranyl-centered motifs bridged through μ2-OH and pyridazine-3,6-dicarboxylate
journal, February 2011

  • Henry, Natacha; Lagrenée, Michel; Loiseau, Thierry
  • Inorganic Chemistry Communications, Vol. 14, Issue 2
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Utilizing bifurcated halogen-bonding interactions with the uranyl oxo group in the assembly of a UO 2 –3-bromo-5-iodobenzoic acid coordination polymer
journal, March 2017

  • Kalaj, Mark; Carter, Korey P.; Cahill, Christopher L.
  • Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 73, Issue 2
  • DOI: 10.1107/S2052520617001639

How to Bend the Uranyl Cation via Crystal Engineering
journal, February 2018


Engaging the Terminal: Promoting Halogen Bonding Interactions with Uranyl Oxo Atoms
journal, August 2017

  • Carter, Korey P.; Kalaj, Mark; Surbella, Robert G.
  • Chemistry - A European Journal, Vol. 23, Issue 61
  • DOI: 10.1002/chem.201702744

Fourier transform infrared and Raman spectra of uranyl bis(2-hydroxybenzaldehyde): UO2(sal)2
journal, November 2000


Vibrational Spectra and Normal Framework Coordinate Analysis of Uranyl Bis(2-Hydroxy-1-Naphthaldehyde)
journal, January 1996

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Infrared and raman spectra (solid state) of uranyl 2,4-pentanedionate: UO2(acac)2
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Raman, resonance Raman and infrared spectra of potassium uranyl croconate
journal, February 1994

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Perturbation of the O–U–O Angle in Uranyl by Coordination to a 12-Membered Macrocycle
journal, May 2016


Copper(I) and Copper(II) Uranyl Heterometallic Hybrid Materials
journal, July 2014

  • Weng, Zhehui; Zhang, Zhi-hui; Olds, Travis
  • Inorganic Chemistry, Vol. 53, Issue 15
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Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies
journal, July 2013

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Occurence of an Octanuclear Motif of Uranyl Isophthalate with Cation–Cation Interactions through Edge-Sharing Connection Mode
journal, July 2011

  • Mihalcea, Ionut; Henry, Natacha; Clavier, Nicolas
  • Inorganic Chemistry, Vol. 50, Issue 13
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New ligands for uranium complexation: A stable uranyl dimer bearing 2,6-diacetylpyridine dioxime
journal, April 2017

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The synthesis and spectroscopic characterization of an aromatic uranium amidoxime complex
journal, September 2014

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Nitrogen-rich Compounds of the Actinoids: Dioxouranium(VI) 5,5′-Azobis[tetrazolide] Pentahydrate and Its Unusually Small Uranyl Angle
journal, May 2012

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Structural, spectroscopic and redox properties of uranyl complexes with a maleonitrile containing ligand
journal, January 2011

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Spectroscopic studies on the uranyl-schiff base solid complex (N,N'-p-phenylenebis(salicylideneiminato)UO2)
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A Trigonal Bipyramidal Uranyl Amido Complex:  Synthesis and Structural Characterization of [Na(THF) 2 ][UO 2 (N(SiMe 3 ) 2 ) 3 ]
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Three New Silver Uranyl Diphosphonates: Structures and Properties
journal, February 2014

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Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures
journal, July 2017


[H 2 bipy] 2 [(UO 2 ) 6 Zn 2 (PO 3 OH) 4 (PO 4 ) 4 ]·H 2 O: An Open-Framework Uranyl Zinc Phosphate Templated by Diprotonated 4,4′-Bipyridyl
journal, October 2008

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First Actinide Complexes of the Nitrogen-Containing Ligands Dinitramide (N(NO 2 ) 2 ), 4,5-Dicyano-1,2,3-triazolate (C 4 N 5 ), and Dicyanamide (N(CN) 2 )
journal, March 2010

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Works referencing / citing this record:

In Situ Generation of Organic Peroxide to Create a Nanotubular Uranyl Peroxide Phosphate
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Interaction of An VI with Isothiocyanate Ion in Water-Organic Media (An = U, Np, Pu) : Interaction of An
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  • Fedoseev, Aleksander; Charushnikova, Iraida; Budantseva, Nina
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 645, Issue 22
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Two New Coordination Polymers with UO 2 2+ Units and Fluorinated Aromatic Carboxylate Linkers
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  • Christoffels, Ronja; Ruschewitz, Uwe
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 646, Issue 3
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Actinyl-cation interactions: experimental and theoretical assessment of [Np( vi )O 2 Cl 4 ] 2− and [U( vi )O 2 Cl 4 ] 2− systems
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  • Bjorklund, Jennifer L.; Pyrch, Mikaela M.; Basile, Madeline C.
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Formation of a uranyl hydroxide hydrate via hydration of [(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O
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Ionic liquids with polychloride anions as effective oxidants for the dissolution of UO 2
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Layer-structured uranyl-oxide hydroxy-hydrates with Pr( iii ) and Tb( iii ) ions: hydroxyl to oxo transition driven by interlayer cations
journal, January 2020

  • Lu, Kimbal Thane; Zhang, Yingjie; Wei, Tao
  • Dalton Transactions, Vol. 49, Issue 18
  • DOI: 10.1039/d0dt00526f

Impacts of hydrogen bonding interactions with Np( v / vi )O 2 Cl 4 complexes: vibrational spectroscopy, redox behavior, and computational analysis
journal, January 2020

  • Pyrch, Mikaela M.; Bjorklund, Jennifer L.; Williams, James M.
  • Dalton Transactions, Vol. 49, Issue 20
  • DOI: 10.1039/d0dt00848f

Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates
journal, November 2018


In Situ Generation of Organic Peroxide to Create a Nanotubular Uranyl Peroxide Phosphate
journal, November 2019

  • Kravchuk, Dmytro V.; Forbes, Tori Z.
  • Angewandte Chemie International Edition, Vol. 58, Issue 51
  • DOI: 10.1002/anie.201910287