skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on September 15, 2021

Title: Polyethylene Terephthalate Deconstruction Catalyzed by a Carbon‐Supported Single‐Site Molybdenum‐Dioxo Complex

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry and the Institute for Catalysis in Energy Processes (ICEP) Northwestern University 2145 Sheridan Road Evanston IL 60208-3113 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1668096
Grant/Contract Number:  
FG02-03ER15457
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 132 Journal Issue: 45; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Kratish, Yosi, Li, Jiaqi, Liu, Shanfu, Gao, Yanshan, and Marks, Tobin J. Polyethylene Terephthalate Deconstruction Catalyzed by a Carbon‐Supported Single‐Site Molybdenum‐Dioxo Complex. Germany: N. p., 2020. Web. https://doi.org/10.1002/ange.202007423.
Kratish, Yosi, Li, Jiaqi, Liu, Shanfu, Gao, Yanshan, & Marks, Tobin J. Polyethylene Terephthalate Deconstruction Catalyzed by a Carbon‐Supported Single‐Site Molybdenum‐Dioxo Complex. Germany. https://doi.org/10.1002/ange.202007423
Kratish, Yosi, Li, Jiaqi, Liu, Shanfu, Gao, Yanshan, and Marks, Tobin J. Tue . "Polyethylene Terephthalate Deconstruction Catalyzed by a Carbon‐Supported Single‐Site Molybdenum‐Dioxo Complex". Germany. https://doi.org/10.1002/ange.202007423.
@article{osti_1668096,
title = {Polyethylene Terephthalate Deconstruction Catalyzed by a Carbon‐Supported Single‐Site Molybdenum‐Dioxo Complex},
author = {Kratish, Yosi and Li, Jiaqi and Liu, Shanfu and Gao, Yanshan and Marks, Tobin J.},
abstractNote = {},
doi = {10.1002/ange.202007423},
journal = {Angewandte Chemie},
number = 45,
volume = 132,
place = {Germany},
year = {2020},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 15, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Tris(pentafluorophenyl)boron-Catalyzed Hydrosilation of Aromatic Aldehydes, Ketones, and Esters
journal, January 1996

  • Parks, Daniel J.; Piers, Warren E.
  • Journal of the American Chemical Society, Vol. 118, Issue 39
  • DOI: 10.1021/ja961536g

Studies on thermal and thermo-oxidative degradation of poly(ethylene terephthalate) and poly(butylene terephthalate)
journal, January 2001


Combining Reclaimed PET with Bio-based Monomers Enables Plastics Upcycling
journal, April 2019


Efficient Homogeneous Catalytic Hydrogenation of Esters to Alcohols
journal, February 2006

  • Zhang, Jing; Leitus, Gregory; Ben-David, Yehoshoa
  • Angewandte Chemie International Edition, Vol. 45, Issue 7
  • DOI: 10.1002/anie.200503771

The Depolymerization of Poly(ethylene terephthalate) (PET) Using N-Heterocyclic Carbenes from Ionic Liquids
journal, May 2010

  • Kamber, Nahrain E.; Tsujii, Yasuhito; Keets, Kate
  • Journal of Chemical Education, Vol. 87, Issue 5
  • DOI: 10.1021/ed800152c

Fe-containing magnetic ionic liquid as an effective catalyst for the glycolysis of poly(ethylene terephthalate)
journal, March 2010


A novel catalyst for the glycolysis of poly(ethylene terephthalate)
journal, January 2003

  • Troev, K.; Grancharov, G.; Tsevi, R.
  • Journal of Applied Polymer Science, Vol. 90, Issue 8
  • DOI: 10.1002/app.12711

A review on thermal decomposition and combustion of thermoplastic polyesters
journal, December 2004

  • Levchik, Sergei V.; Weil, Edward D.
  • Polymers for Advanced Technologies, Vol. 15, Issue 12
  • DOI: 10.1002/pat.526

Kinetic Isotope Effects as a Guide to Transition State Geometries for the Intramolecular Cope and Ylide Elimination Reactions. An ab Initio MO Study
journal, July 1995

  • Bach, Robert D.; Gonzalez, Carlos; Andres, Jose L.
  • The Journal of Organic Chemistry, Vol. 60, Issue 14
  • DOI: 10.1021/jo00119a053

Thermal degradation of poly(ethylene terephthalate) at the processing temperature
journal, January 2004


Efficient carbon-supported heterogeneous molybdenum-dioxo catalyst for chemoselective reductive carbonyl coupling
journal, January 2017

  • Liu, Shengsi; Li, Jiaqi; Jurca, Titel
  • Catalysis Science & Technology, Vol. 7, Issue 11
  • DOI: 10.1039/C7CY00336F

Selective C–O bond cleavage of allylic esters using [MoH 4 (Ph 2 PCH 2 CH 2 PPh 2 ) 2 ] under light irradiation to give hydridocarboxylatomolybdenum( II ) complexes
journal, January 1990

  • Ito, Takashi; Matsubara, Tetsuaki; Yamashita, Yoichiro
  • J. Chem. Soc., Dalton Trans., Issue 8
  • DOI: 10.1039/DT9900002407

Superparamagnetic γ-Fe 2 O 3 nanoparticles as an easily recoverable catalyst for the chemical recycling of PET
journal, January 2014

  • Bartolome, Leian; Imran, Muhammad; Lee, Kyoung G.
  • Green Chem., Vol. 16, Issue 1
  • DOI: 10.1039/C3GC41834K

On the Functional Group Tolerance of Ester Hydrogenation and Polyester Depolymerisation Catalysed by Ruthenium Complexes of Tridentate Aminophosphine Ligands
journal, June 2015

  • Fuentes, José A.; Smith, Samuel M.; Scharbert, M. Theresa
  • Chemistry - A European Journal, Vol. 21, Issue 30
  • DOI: 10.1002/chem.201500907

Accumulation and fragmentation of plastic debris in global environments
journal, July 2009

  • Barnes, David K. A.; Galgani, Francois; Thompson, Richard C.
  • Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 364, Issue 1526
  • DOI: 10.1098/rstb.2008.0205

Multiphoton Infrared Initiated Thermal Reactions of Esters: Pseudopericyclic Eight-Centered cis -Elimination
journal, January 2009

  • Ji, Hua; Li, Li; Xu, Xiaolian
  • Journal of the American Chemical Society, Vol. 131, Issue 2
  • DOI: 10.1021/ja804812c

Chemically recyclable polymers: a circular economy approach to sustainability
journal, January 2017

  • Hong, Miao; Chen, Eugene Y. -X.
  • Green Chemistry, Vol. 19, Issue 16
  • DOI: 10.1039/C7GC01496A

An engineered PET depolymerase to break down and recycle plastic bottles
journal, April 2020


Chemical recycling of waste plastics for new materials production
journal, June 2017


Reactions of mer -Mo(H)(CO)(NO)(PMePh 2 ) 3 with Ethylene, Propylene, and Styrene That Bear on Alternating CO/Olefin Coupling Chemistry
journal, May 1997

  • Cheng, Tan-Yun; Southern, Joel S.; Hillhouse, Gregory L.
  • Organometallics, Vol. 16, Issue 11
  • DOI: 10.1021/om970160s

Melting Behavior of Poly(ethylene terephthalate) Crystallized and Annealed under Elevated Pressure
journal, February 1980


Molecular catalyst systems as key enablers for tailored polyesters and polycarbonate recycling concepts
journal, August 2018

  • Westhues, Stefan; Idel, Jasmine; Klankermayer, Jürgen
  • Science Advances, Vol. 4, Issue 8
  • DOI: 10.1126/sciadv.aat9669

Ethylene addition to group-6 transition metal oxo complexes – A theoretical study
journal, February 2008


A bacterium that degrades and assimilates poly(ethylene terephthalate)
journal, March 2016


News Feature: On the brink of a recycling revolution?
journal, January 2017


Enzyme-catalyzed transesterification of vinyl esters on cellulose solids
journal, January 2001

  • Xie, Jiangbing; Hsieh, You-Lo
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 39, Issue 11
  • DOI: 10.1002/pola.1170

β-Heteroatom versus β-Hydrogen Elimination:  A Theoretical Study
journal, February 2006

  • Zhao, Haitao; Ariafard, Alireza; Lin, Zhenyang
  • Organometallics, Vol. 25, Issue 4
  • DOI: 10.1021/om050703v

Glycolysis of postconsumer polyethylene terephthalate waste
journal, January 2010

  • Pingale, Navnath D.; Palekar, Vikrant S.; Shukla, S. R.
  • Journal of Applied Polymer Science, Vol. 115, Issue 1
  • DOI: 10.1002/app.31092

Ultrasmall Cobalt Nanoparticles as a Catalyst for PET Glycolysis: A Green Protocol for Pure Hydroxyethyl Terephthalate Precipitation without Water
journal, July 2018

  • Veregue, Fernanda Reis; Pereira da Silva, Cleiser Thiago; Moisés, Murilo Pereira
  • ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 9
  • DOI: 10.1021/acssuschemeng.8b02294

Efficient catalytic greenhouse gas-free hydrogen and aldehyde formation from aqueous alcohol solutions
journal, January 2017

  • Lohr, Tracy L.; Mouat, Aidan R.; Schweitzer, Neil M.
  • Energy & Environmental Science, Vol. 10, Issue 7
  • DOI: 10.1039/C6EE03739A

Room Temperature Organocatalyzed Reductive Depolymerization of Waste Polyethers, Polyesters, and Polycarbonates
journal, February 2015


Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels
journal, January 2020

  • Nunes, Beatriz F. S.; Oliveira, M. Conceição; Fernandes, Ana C.
  • Green Chemistry, Vol. 22, Issue 8
  • DOI: 10.1039/C9GC04206G

Depolymerization of Waste Plastics to Monomers and Chemicals Using a Hydrosilylation Strategy Facilitated by Brookhart’s Iridium(III) Catalyst
journal, June 2018

  • Monsigny, Louis; Berthet, Jean-Claude; Cantat, Thibault
  • ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 8
  • DOI: 10.1021/acssuschemeng.8b01842

Recent Developments in the Chemical Recycling of Postconsumer Poly(ethylene terephthalate) Waste
journal, September 2014

  • George, Neena; Kurian, Thomas
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 37
  • DOI: 10.1021/ie501995m

Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis
journal, September 2016


Solubilization and Upgrading of High Polyethylene Terephthalate Loadings in a Low-Costing Bifunctional Ionic Liquid
journal, January 2018


Benzoic acid recovery via waste poly(ethylene terephthalate) (PET) catalytic pyrolysis using sulphated zirconia catalyst
journal, September 2018

  • Diaz-Silvarrey, Laura S.; McMahon, Andrew; Phan, Anh N.
  • Journal of Analytical and Applied Pyrolysis, Vol. 134
  • DOI: 10.1016/j.jaap.2018.08.014

First-Row Transition Metal-Containing Ionic Liquids as Highly Active Catalysts for the Glycolysis of Poly(ethylene terephthalate) (PET)
journal, January 2015

  • Wang, Qian; Geng, Yanrong; Lu, Xingmei
  • ACS Sustainable Chemistry & Engineering, Vol. 3, Issue 2
  • DOI: 10.1021/sc5007522

The kinetic isotope effect in the pyrolysis of esters and the nature of the transition state
journal, January 1972

  • Taylor, R.
  • Journal of the Chemical Society, Perkin Transactions 2, Issue 2
  • DOI: 10.1039/p29720000165

Unexpected efficiency of cyclic amidine catalysts in depolymerizing poly(ethylene terephthalate)
journal, January 2013

  • Fukushima, Kazuki; Coady, Daniel J.; Jones, Gavin O.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 51, Issue 7
  • DOI: 10.1002/pola.26530

Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes
journal, February 2004

  • Aoyama, Hiroshi; Tokunaga, Makoto; Hiraiwa, Shin-ichiro
  • Organic Letters, Vol. 6, Issue 4
  • DOI: 10.1021/ol036228j

Catalytic pyrolysis of polystyrene and polyethylene terephthalate over Al-MSU-F
journal, July 2018


Conversion of Polyethylene Terephthalate Based Waste Carpet to Benzene-Rich Oils through Thermal, Catalytic, and Catalytic Steam Pyrolysis
journal, April 2016


Efficient Homogeneous Catalytic Hydrogenation of Esters to Alcohols
journal, February 2006

  • Zhang, Jing; Leitus, Gregory; Ben-David, Yehoshoa
  • Angewandte Chemie, Vol. 118, Issue 7
  • DOI: 10.1002/ange.200503771

Plastics recycling with a difference
journal, April 2018


Comparing conventional and microwave-assisted heating in PET degradation mediated by imidazolium-based halometallate complexes
journal, January 2019

  • Scé, Fabio; Cano, Israel; Martin, Carmen
  • New Journal of Chemistry, Vol. 43, Issue 8
  • DOI: 10.1039/C8NJ06090H

Manganese-, cobalt-, and zinc-based mixed-oxide spinels as novel catalysts for the chemical recycling of poly(ethylene terephthalate) via glycolysis
journal, April 2013


Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a β-Agostic Ethyl: Structure, Dynamics and Mechanism
journal, September 2018

  • Bezdek, Máté J.; Chirik, Paul J.
  • Journal of the American Chemical Society, Vol. 140, Issue 42
  • DOI: 10.1021/jacs.8b08460

Thermal degradation studies of terephthalate polyesters: 1. Poly(alkylene terephthalates)
journal, January 1991


Recycling of Polymers: A Review
journal, May 2014

  • Ignatyev, Igor A.; Thielemans, Wim; Vander Beke, Bob
  • ChemSusChem, Vol. 7, Issue 6
  • DOI: 10.1002/cssc.201300898

Controlled hydrogenative depolymerization of polyesters and polycarbonates catalyzed by ruthenium(ii) PNN pincer complexes
journal, January 2014

  • Krall, Eric M.; Klein, Tyler W.; Andersen, Ryan J.
  • Chemical Communications, Vol. 50, Issue 38
  • DOI: 10.1039/c4cc00541d

Chemical Recycling of Poly(ethylene terephthalate)
journal, April 1997

  • Paszun, Daniel; Spychaj, Tadeusz
  • Industrial & Engineering Chemistry Research, Vol. 36, Issue 4
  • DOI: 10.1021/ie960563c

Plastic waste inputs from land into the ocean
journal, February 2015


Der Abbau von Polyäthylenterephthalat
journal, March 1968


Mechanisms of Organocatalytic Amidation and Trans-Esterification of Aromatic Esters As a Model for the Depolymerization of Poly(ethylene) Terephthalate
journal, December 2012

  • Horn, Hans W.; Jones, Gavin O.; Wei, DiDi S.
  • The Journal of Physical Chemistry A, Vol. 116, Issue 51
  • DOI: 10.1021/jp304212y

Fe 3 O 4 -boosted MWCNT as an efficient sustainable catalyst for PET glycolysis
journal, January 2016

  • Al-Sabagh, A. M.; Yehia, F. Z.; Harding, David R. K.
  • Green Chemistry, Vol. 18, Issue 14
  • DOI: 10.1039/C6GC00534A

The Degradation of Poly(ethylene terephthalate)
journal, March 1968

  • Buxbaum, L. H.
  • Angewandte Chemie International Edition in English, Vol. 7, Issue 3
  • DOI: 10.1002/anie.196801821